• Title/Summary/Keyword: 분자선

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The Expression changes of AMPK, ERK-1/2, and p38 protein associated with Exercise in the Mouse hippocampus exposed to Radiofrequency Radiation (전자파(電磁波)에 노출된 생쥐의 해마에서 운동이 AMPK, ERK-1/2, p38 단백 발현 변화에 미치는 생체 영향)

  • Lee, Min-Sun;Park, Oak Jin;Kim, Hyun Taeg;Kim, Myeung Ju
    • Journal of Digital Convergence
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    • v.18 no.3
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    • pp.267-273
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    • 2020
  • To determine the biological effects of exercise on hippocampus in mice brain exposed to radiofrequency radiaton (RF), the expression of AMPKα, p-AMPKα, ERK1/2, p-ERK1/2, p38, and p-p38 protein in the mouse exposed to RF were investigated in the hippocampal tissues, Western blot method was used to compare the protein expression levels for each molecule. Significant increases in protein expression of individual and phosphorylated molecules were observed in the spontaneous exercise group, and the expression of these molecules was notably decreased in the RF exposure and spontaneous exercise group. This study shows that neuroplasticity can be increased by exercise in hippocampus that is responsible for memory, but memory and cognitive function may be affected by exposure to RF. We may expect clinically interesting results on dementia or Alzheimer disease if we proceed further investigation on the effect of RF.

The Crystal Structure of an Iondine Sorption Complex of Dehydrated Calcium and Silver Exchanged Zeolite A ($Ag^+$이온과 $Ca^{2+}$이온으로 치환한 제올라이트 A를 탈수한 후 요오드를 흡착한 결정구조)

  • Bae, Myung-Nam;Kim, Yang;Kim, Un-Sik
    • Korean Journal of Crystallography
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    • v.6 no.2
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    • pp.118-124
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    • 1995
  • The crystal structure of an iodine sorption complex of vacumm-dehydrated Ag+ and Ca2+ exchanged zeolite A(a=12.174(3)Å) has been determined at 21℃ by single-crystal X-ray diffraction techniques in the cubic space group Pm3m. The crystal was prepared by flow method for three days using exchange solution in solution in which mole ratio of AgNO3 and Ca(NO3)2 was 1:150 with total concentration of 0.05 M. The complex was prepared by dehydration at 360℃ and 2×10-6 Torr for 2 days, followed by exposure to about 14.3 Torr of iodine vaporat 80℃ for 24 hours. Full-matrix least-squares refinement converged to the final error indices of R1=0.082, R2=0.068 using 122 reflections for which I > 3σ(I). Two Ag+ ions, 1.1 Ag+ ions, and 4.45 Ca2+ ions per unit cell are located on three different three-fold axes associated with 6-ring oxygens. Two Ag+ ions per unit cell are in the large cavity, 1.399(4)Å from the (111) plane of three oxygens. Another 1.1 Ag+ ions are found at opposite sites. Six iodine molecules are sorbed per unit cell. Each I2 molecule approaches a framework oxide ion axially (O-I=3.43(2)Å, I-I=2.92Å, I-I-O;166.1(3)°), by a charge transfer complex interaction. Two Ag+ ions make a close approach to the iodine molecules (Ag-I ; 2.73(2)Å).

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Structure of a Spiro Orthocarbonate, 3,3'-Spirobi[1H, 5H-naphtho [1,8-ef] [1,3] dioxocin] (Spiro Orthocarbonate, 3,3'-Spirobi[1H, 5H-naphtho[1,8-ef] [1,3] dioxocin]의 분자구조)

  • Young Mi Song;Jung Mi Shin;Young Ja Park
    • Journal of the Korean Chemical Society
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    • v.36 no.4
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    • pp.536-539
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    • 1992
  • Eight-membered ring spiro orthocarbonate (C$_{25}H_{20}O_4$, M$_r$ = 384) is monoclinic, space group C2/c, with a = 15.319(4), b = 9.057(3), c = 13.168(3)${\AA}$, ${\beta}$ = 98.53(3)$^{\circ}$, Z = 4, F(000) = 808, T = 290 K, ${\mu}$(Mo-K${\alpha}$) = 0.55 cm$_1$, D$_c$ = 1.36 g/cm$^3$ and D$_m$ = 1.40 g/cm$^3$. The intensity data were collected with Mo-K${\alpha}$ radiation (${\lambda}$ = 0.7107 ${\AA}$) on an automatic four-circle diffractometer with a graphite monochromater. The structure was solved by direct methods and refined by full matrix least-squares methods. The final R value was 0.052 for 1412 observed reflections. The molecule has C$_2$point symmetry. The eight-membered ring has a chair conformation with pseudo-C$_s$ symmetry. The naphthyl ring is planar with the C-C bond lengths being in the range of 1.352∼1.444${\AA}$ and bond angles of 117.2∼123.5$^{\circ}$. The bond lengths of C(1)-C(9), C(8)-C(9) and C(9)-C(10) are somewhat longer than those of the other C-C bonds.

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The structure and synthesis of intercalation compounds between layered basic copper acetate and alkyl sulfonates (알킬술폰이 삽입된 층상구조의 염기성 초산구리의 합성과 구조)

  • 조영식;허영덕
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.3
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    • pp.431-434
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    • 1998
  • Layered basic copper acetate, $Cu(OH)(CH_3COO){cdot}H_2O$ was synthesized. Intercalation compounds of alkyl sulfonates into layered basic copper acetate have been synthesized via anionic exchange. From the X-ray diffraction data and the alkyl sulfonate size, the orientation of the intercalated alkyl sulfonate into layered basic copper acetate was determined.

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New water-soluble hydrate formers (새로운 수용성 하이드레이트 형성체 연구)

  • Lee, Jong-Won;Lu, Hailong;Moudrakovski, Igor L.;Ratcliffe, Christopher I.;Ripmeester, John A.
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.580-583
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    • 2008
  • 다양한 고리형 에스테르 및 고리형 케톤 화합물을 시도하여 새로운 구조-II 및 구조-H 수용성 하이드레이트 형성체를 발견하였다. 이렇게 새로이 발견된 하이드레이트 형성체에 대해서는 상평형 측정 및 분광학적 분석을 수행하여 안정영역과 분자 거동을 파악하였다. 새로이 발견된 하이드레이트 형성체는 물과의 용해성이 우수하여 하이드레이트 형성이 빠른 속도로 이루어져 실제 응용 분야에서 중요하게 사용될 수 있을 것으로 전망된다.

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Short note: on the use of radioelement ratios to enhance gamma-ray spectrometric data (단보: 감마선 스펙트로미터 자료의 짙을 향상시키기 위한 방사성원소 비의 사용에 대하여)

  • Minty, Brian
    • Geophysics and Geophysical Exploration
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    • v.14 no.1
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    • pp.116-120
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    • 2011
  • Radioelement ratios are useful for mapping subtle variations in radiometric signatures in map data. But the conventional method for calculating radioelement ratios has the significant limitation that if just one of the radioelements comprising the ratio has a small spread of concentration estimates relative to its mean, then it will not contribute significantly to the ratio map. However, if both the numerator and denominator are first normalised to approximately the same mean and spread prior to ratioing, then they will contribute equally to the enhancement of the differences between them across the map area.

Determination of Polycyclic Aromatic Hydrocarbons in Chinmey Soot Extract by High-Resolution Gas Chromatography (고분리능 기체크로마토그라피에 의한 굴뚝재추출물안의 다환방향족 탄화수소의 정량에 관한 연구)

  • 서영화;이광우;허귀석
    • Journal of Korean Society for Atmospheric Environment
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    • v.4 no.2
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    • pp.11-19
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    • 1988
  • 대기오염물질 속에 함유되어 있는 다환방향족 탄화수소 (PAHs)는 분자식 구조가 비슷한 수십개의 이성질체가 여러 종류의 유기화합물과 혼합되어 존재한다. 본 연구에서는 환경오염 시료중의 PAHs를 분석하는데 있어서 분석방법과 결과를 비교하기 위하여 지침이 될 수 있는 환경표준 기준물을 개발할 목적으로 굴뚝 안쪽벽에서 긁어 채취한 검댕을 시료로 선책하여 액체/액체 용매 추출방법에 의해 PAHs 분류부분을 얻었다. Phenanthrene 이외의 30여종의 PAHs 화합물을 가스크로마토그라피의 머무른시간과 가스크로마토그라피/질량분석기에 의하여 분리, 판명하였고 5종의 주 PAHs 화합물을 정확하게 정량 분석하였다. 정량분석 결과의 신뢰도, 정확도, 정밀도는 미국 NBS의 표준기준물 1647을 분석하여 검정치와 비교함으로써 평가하였다.

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Effects of Various Reagents on Textural Properties of Soy Protein Gel (대두단백겔의 물성에 미치는 분자결합력 저해 시약의 영향)

  • 배동호;정호선
    • Food Science and Preservation
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    • v.5 no.1
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    • pp.65-71
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    • 1998
  • The changes in gel characteristics of soy protein as a result of various reagents that alter specific interactions which affect the formation and textural properties of gels, were studied. The reagents were added to 15% soy protein solutions prior to heat treatment. The gels were not formed with urea, indicating that hydrogen bonds significantly contributed to the formation and hardness of soy protein gel. Hydrophobic interactions and disulfide bonds compensated for hydrogen bonds and the contributions of electrostatic interactions to gel hardness are relatively insignificant. The farce primarily responsible for gel cohesiveness appeared to be disulfide bonds, because a significant decrease in cohesiveness was found only with the presence of N-ethylmaleimide. Adhesiveness decreased only with the addition of urea, and thus the contribution of hydrogen bonding to adhesiveness of gel could be concluded to be resent. However, adhesiveness was suggested to be interpreted not only wile molecular forces involved in gel formation but also with hydration properties of protein.

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Review of the Recent Research on Nanoelectronic Devices (나노전자소자기술)

  • Jang, M.G.;Kim, Y.Y.;Choi, C.J.;Jun, M.S.;Park, B.C.;Lee, S.G.
    • Electronics and Telecommunications Trends
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    • v.20 no.5 s.95
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    • pp.28-45
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    • 2005
  • 무어의 법칙을 근간으로 하는 전계효과 트랜지스터는 매 18개월마다 0.7배씩의 성공적인 소형화를 거듭하여 최근에는 50nm 크기로 구성된 약 1억 개의 트랜지스터가 집적된 칩을 생산하고 있다. 그러나 트랜지스터의 크기가 50nm 이하로 줄어들면서는 단순한 소형화 과정은 근본적인 물리적인 한계에 접근하게 되었다. 특히 게이트 절연막의최소 두께는 트랜지스터의 소형화에 가장 직접적인 중요한 요소이나, 실리콘 산화막의 두께가 2nm 이하가 되면서 게이트 절연막을 집적 터널링하는 전자에 의한 누설전류의 급격한 증가로 인하여 그 사용이 어려워지고 있는 추세이다. 따라서 본 논문에서는 트랜지스터의 소형화에 악영향을 미치는 물리적인 한계요소에 대하여 살펴보고, 이러한 소형화의 한계를 뛰어넘기 위한 노력의 일환으로 연구되고 있는 이중게이트 구조의 트랜지스터, 쇼트키 트랜지스터, 나노선을 이용한 트랜지스터 및 분자소자 등의 새로운 소자구도에 대하여 살펴보고자 한다.