• Journal of the Korean earth science society
• /
• v.39 no.6
• /
• pp.519-532
• /
• 2018

We investigated the effect of galactic plane toward molecular motion and kinematics in the northern filament (NF) of Orion Molecular Clouds Complex (OMC) using $^{12}CO$ (J=1-0) line. Observed data were from three areas including NF1, NF2, and NF3 in far-out order from galactic plane, for a total 270 hours by Seoul National University Radio Astronomy Observatory (SRAO) 6m telescope, with 2arcmin spatial resolution. galactic plane and OMC NF were connected to each other along the magnetic field at a density of 3% for $^{12}CO$ (J=2-1) and 9% for the case of dust. $^{12}CO$ (J=1-0), $^{12}CO$ (J=2-1), and interstellar dusts were distributed uniformly in NF3, but only in certain regions with relatively high density in NF1 and NF2. NF showed a single structure, partial shrinking motion in NF1, and rotational motion at the bottom of NF2, and spiral rotation associated with magnetic field only in NF3. The position-velocity analysis showed that the materials including $^{12}CO$ (J=1-0) could flow toward galactic plane along NF2 and NF3. However, there was no clear cause for the material to flow toward galactic plane in this result. Further detailed observation for rotational motion at the top of NF1 and NF2 might help to confirm it.

• The Bulletin of The Korean Astronomical Society
• /
• v.37 no.1
• /
• pp.102-102
• /
• 2012

타이탄의 근적외선 영역 스펙트럼에서 나타나는 특유의 넓은 흡수밴드를 고체 탄화수소화합물과 질소화합물의 조합으로 설명하고자 한다. 이 흡수 밴드는 대기권의 하층부에 존재하는 연무(haze)에 의한 것으로, 3.3 - 3.4 micron 부근과 2.30 - 2.35 micron 부근에서 유사한 형태가 발견됐다. 두 파장대 모두 C-H 스트레칭 모드가 존재하는 영역이라는 공통점이 있으며, 그 형태가 넓은 흡수밴드로 나타나므로 대기 중에 고체상태의 탄화수소화합물이 존재하는 것으로 유추할 수 있으며, 관련 분자들의 실험값과 복사전달모델을 이용하여 이를 설명하고자 한다. 또한, 이 흡수밴드는 고도에 따라 그 형태와 세기가 달라지므로, 연무 입자들의 고도에 따른 수직분포 및 크기 등을 파악할 수 있다. 이 연구에서는 기존에 타이탄에서 발견된 $CH_4$, $C_2H_6$, $CH_3CN$의 고체 분광선과, 해당 영역에서 흡수선을 보이는 $C_5H_{12}$, $C_6H_{12}$, $C_6H_{14}$ 등의 고체 분광선을 이용한 모델을 Cassini 탐사선의 VIMS 관측자료로부터 유도한 파장 및 고도에 따른 광학적 깊이 변화량과 비교하여 보여주고자 한다.

• Journal of the Korean Chemical Society
• /
• v.20 no.1
• /
• pp.3-14
• /
• 1976

The crystal structure of alicylaldehyde-4-piperidinothiosemicarbazone, $C_{13}H_{l7}N_3OS$, has been determined by single crystal X-ray analysis. The crystals are orthorhombic, space group $P2_12_12_1$, with unit cell dimensions a = 6.52(2), b = 13.42(4), c = 14.92(4)${\AA}$. There are four formular units in a unit cell. The structure was solved by the heavy atom method and refined by isotropic block diagonal least-squares methods to a final R value of 0.10 for 1019 observed reflections. The oxygen atom of the hydroxyl group is involved in two hydrogen bonds, one as donor in the intramolecular O-H${\cdots}$N hydrogen bond and the other as acceptor in the intermolecular N-H${\cdots}$O hydrogen bond, the distances of the hydrogen bonds 2.56 and 3.00${\AA}$ respectively.The molecules are joined into infinite columns by the N-H${\cdots}o$O hydrogen bonds which form spirals along the two fold screw axis parallel to the a axis. The molecular columns are held together by van der Waals forces.

• Korean Journal of Crystallography
• /
• v.13 no.1
• /
• pp.21-24
• /
• 2002

The crystal structure of cholesteryl crotonate was investigated by X-ray diffraction. Crystallo-graphic data for the title compound: P2₁, a = 13.446(4) , b = 11.802(3) , c = 18.782(5) , β = 103.99(2)°, Z = 4. Reflections were collected with an Enraf-Nonius CAD-4 diffractometer equipped with a graphite monochromator. The structure was solved by direct methods and refined by least-squares analyses. The final R value was 0.092 for 1604 reflections. The cholesterol fragment of the title compound were in good agreement with those for related cholesterol derivatives. The molecules were stacked in clearly separated layers. At the center of the layers, there were cholesterol-cholesteryl interactions between the symmetry-related A molecules and the cholesteryl-C(17) side chain of B molecules. There were also interactions between the C(17) side chain of A molecules and the crotonate chains off and B molecules in the interface region between layers. The crystal structure of the title compound turned out to be isostructural with those of cholesteryl ethylcarbonate, cholesteryl propylcarbonate, and cholesterol crotylcarbonate. The crystals show the liquid crystalline state having the cholesteric phase.

• Applied Chemistry for Engineering
• /
• v.32 no.5
• /
• pp.504-508
• /
• 2021

In this study, the effect of molecular features of guest molecules on the structure, property, and formation of poly(vinyl alcohol) (PVA)/beta-cyclodextrin (bCD) inclusion compound hybrid films was investigated using three types of guest molecules such as hydroquinone (HQ), arbutin (AB), and tranexamic acid (TA). First, the successful formation of inclusion compounds between bCD and the guest molecules, and polymer/inclusion compound hybrid were proved using Raman spectroscopy. The effect of bCD-based inclusion compounds on the structure and property of PVA matrix composites containing inclusion compounds was also studied using X-ray diffraction (XRD) and thermal analyses such as differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). It was notable that the effect of TA to the crystalline structure of the PVA was significantly different from that of using other guest molecules including HQ and AB. It was also supported by a simple molecular simulation result. This article will be a good example for demonstrating the effect of molecular characteristics on the inclusion compound formation in polymer films, which can provide important information for relevant future research.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
• /
• v.17 no.3
• /
• pp.146-154
• /
• 2024

In this paper, we present a convenient liquid crystal (LC) molecular alignment method using brush hairs as an alternative to the rubbing process in the LC display industry. Titanium strontium yttrium zirconium oxide (TiSrYZrO) solution was prepared using a sol-gel process, and the TiSrYZrO alignment film production and LC molecular alignment were integrated through a one-step brush coating process. As the curing temperature increased, the LC molecule alignment of the LC cell improved, and the formation of a physical surface anisotropic structure due to the shear stress caused by the movement of the brush hairs on the coating surface led to uniform alignment of the LC molecules. Uniform and homogeneous LC molecular alignment was confirmed through polarizing optical microscopy and pretilt angle measurement. Through thermal oxidation using X-ray photoelectron spectroscopy, the TiSrYZrO thin film well formed of metal oxide was confirmed and verified to have excellent optical transparency. From these results, it is expected that a convenient LC molecular alignment method using brush hairs as an alternative to the rubbing process will be a viable next-generation technology.

• Maxillofacial Plastic and Reconstructive Surgery
• /
• v.23 no.4
• /
• pp.306-323
• /
• 2001

종양발생에서 유전자 발현을 확인하고 profile 변화를 monitor하는 것은 병리학적 변화의 원인뿐 아니라 질병탐지와 진료의 새로운 목표를 확인하기 위한 새로운 기회를 제공해준다. cDNA microarray는 수천개의 유전자 발현을 동시에 연구할 수 있는 최신의 방법으로 피부, 유방, 간을 비롯한 다른 인체장기에서는 일부 이루어졌으나 array를 이용해 타액선 종양 연구에서는 전혀 이루어지지 않았다. 인간의 타액선 세포의 악성형질전환을 조절하는 분자적 상태를 연구하기 위해 본 연구는 약 2,000개의 유전자가 print된 cDNA microarray를 이용하여 인간 타액선 도관상피세포주(HSG)와 악하선에서 기원한 미분화 선암종(SGT)간에 비교연구를 하였다. Cy3와 Cy5 dye로 각각의 세포주에서 얻은 RNA와 reciprocal hybridize시키고 GenePix 4000 scanner로 스캔하고 GenePix Pro로 분석한 후 log2로 평균발현비율을 전환시켜 최소 2배이상의 발현을 보이는 유전자를 분석대상으로 하였다. 90%이상의 유전자가 비슷한 발현을 보였으며 2배이상의 발현을 보이는 경우 HSG가 SGT에 비해 72개 유전자가, SGT가 HSG에 비해 111개의 유전자 발현이 up-regulation되어 총 10%미만의 발현차이를 보였고 반복된 hybridization 으로부터 얻은 선택된 spot의 Pearson 상관계수는 -0.85이였다. HSG에서는 6번 p 염색체에서 과발현되는 유전자가 가장 많았고, SGT에서는 11번 q 염색체에서 가장 많았는데 HSG에서는 SGT에 비해 9, 13, 17, 18, 20, 21, 22염색체에서 과발현 되는 유전자 수가 많았고, SGT에서는 HSG에 비해 2, 7, 10, 15 염색체에서 유전자 발현 증가가 관찰되었다. HSG와 SGT간의 유전 발현을 기능별로 분석한 결과 몇 가지 주요 경로가 세포악성에 관련됨을 발견하였고, 타액선 도관상피세포에서 선암종을 구별하는데 기여하는 관련된 몇종의 과다 발현된 유전자를 찾았는데 전사인자, 성장인자 및 수용기, 세포골격 및 세포외기질 단백, 세포내 신호전달조절자 및 인자, 세포표면 항원등의 그룹으로 분류할 수 있었다. 따라서 이러한 microarray를 이용한 분자학적 표지자 연구가 악성 타액선 종양 발생과정에서 큰 도움을 줄 수 있을 뿐 아니라 유전자 조절에 의한 진단, 예후, 치료에서의 정확성을 개선시킬 수 있으리라 여겨진다.

• Korean Journal of Crystallography
• /
• v.13 no.3_4
• /
• pp.148-151
• /
• 2002

The molecular and crystal structure of metalaxyl C/sub15/H/sub21/NO₄, was determined by single crystal x-ray diffraction study. Crystallographic data for, title compound P2₁/c, a=7.849(4) Å, b=13.081(5) Å, c=15.100(3) Å, β=101.8(2)°, V= 1517.6(3) ų, Z=4. The molecular. Structure model was solved by direct method and refined by full-matrix least- squares. The final reliable factor, R, is 0.067 for 1694 independent reflections (F/sub o//sup 2/>4σ(F/sub o//sup 2/)). The molecular structure of title compound shows an intramolecular hydrogen bond: Cl2-Hl2A…O1.

• Journal of the Korean Society for Precision Engineering
• /
• v.19 no.8
• /
• pp.7-15
• /
• 2002

• Proceedings of the Korean Nutrition Society Conference
• /
• 2004.05a
• /
• pp.168-168
• /
• 2004