• Title/Summary/Keyword: 분산염색

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A Study on the Decomposition Properties of Disperse Dye Ozone Oxidation Treatment and the Optimum Treatment Condition(I) (Ozone 산화처리에 의한 분산염료의 분해성 및 최적처리조건에 관한 연구)

  • Kim, Sam Soo;Huh, Man Woo;Han, Myung Ho;Yoon, Jong Ho;Cho, Hwan;Kim, Dong Kwon
    • Textile Coloration and Finishing
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    • v.8 no.1
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    • pp.43-55
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    • 1996
  • When some disperse dye was decolored with oxidation power of ozone, the results in investigation of decoloration behavior with dye solution and its order of reaction and variation of TOC were as follow: 1. Order of decoloration for Some disperse dye is C.I. Disperse Blue 79>Blue 73> Red 343>Red 60>Blue 354>Yellow 42. 2. Velocity of decoloration for the all dyestuffs was the fastest when pH 3. 3. TOC was rapidly reduced between 10 min. and 20 min. 4. For the reduction of TOC ozone was needs many times as compared with decoloration of dyestuffs.

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Synthesis and Application of Acrylated Disperse Dyes (Acryl기를 도입한 분산염료의 합성과 염색성)

  • 박종호;한지연;정재윤
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.411-412
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    • 2003
  • 1990년 초 일본의 Shingosen이 출현 이후, 합성 섬유가 갖는 일련의 장점을 유지하면서 천연섬유의 특성을 모방한 폴리에스테르 극세섬유의 등장으로 고급화 및 차별화 된 폴리에스테르 섬유의 상품 추구가 가능하게 되었다. 근래에 와서 통상적인 방법으로 얻어지는 극세사(Micro fiber)는 약 1d이며, 현재에는 보통사와는 전혀 다른 고도의 유연성$\boxUl$ 촉감, 외관을 가지는 0.3d이하의 공업적 방사도 가능하게 되었다. (중략)

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Low Temperature Carrier Dyeing of PVC Filaments with Disperse Dyes (분산염료를 이용한 PVC 필라멘트의 캐리어 저온 염색법)

  • 조한문;김익수;김재필
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.255-258
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    • 2001
  • 가발을 만드는데 사용되는 재료는 크게 인모와 합성섬유로 나눌 수 있다. 이중 합성섬유는 인모에 비해 가격이 저렴하고 관리가 쉬우며 동일한 제품을 대량 생산할 수 있다는 장점이 있다. 이러한 장점을 이용한 가발용 합성섬유로는 모다크릴, 나일론, 폴리에스테르 등이 있는데, 근래에는 이들보다 생산이 쉽고 단가가 낮은 PVC 필라멘트의 사용이 증가하는 추세이다. (중략)

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Studies on Fabrics woven with Silk/Polyester Compound Yarn (고치와 폴리에스텔 복합사 직물의 시직)

  • 김영대;김남정
    • Journal of Sericultural and Entomological Science
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    • v.36 no.2
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    • pp.147-151
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    • 1994
  • This study was carried out investigate the characteristics of Habutae and Chiffon woven with silk and polyester(S/P) compound yarn. The S/P compound yarn could be produced by the automatic reeling machine with attachment of air jetting device, polyester yarn guider and tension control apparatus. The surface structure, tensile property and dyeing fastness of S/P compound fabric were examined for the fabric properties. Electron microscopy revealed that most part of S/P compound yarn was well interlaced and some silk part of compound yarn were hidden by polyester on an examination of surface of chiffon fabric. By the one bath and two step dyeing of disperse and acidic dyes, the colour fastness of S/P compound fabrics were 4 grade above. The tenacity and initial modulus of the finished S/P compound fabric were lower than those of grey and degummed fabrics, but reversed in elongation.

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Preparation and Polarization Properties of Poly(vinyl alcohol) Polarizing Film Using the Mixed System of Supercritical $CO_2$/Organic Solvents/Dichroic Dye (초임계 탄산가스/유기용매/이색성 염료의 혼합계를 이용한 폴리(비닐 알코올) 편광필름의 제조 및 편광특성)

  • Park, Ki-Sang;Choi, E-Joon;Chang, Jin-Ho;Park, Il-Hyun
    • Polymer(Korea)
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    • v.35 no.5
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    • pp.458-466
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    • 2011
  • In the mixed system of supercritical carbon dioxide/organic solvents, poly(vinyl alcohol)(PVA) film of high degree of hydrolysis could be dyed with a dichroic dye of C. I. direct black 22(DB22) and as a result, high durability was obtained. Especially, as a dye dispersant in a supercritical fluid phase, a mixed solvent system of ethylene glycol: dimethyl sulfoxide=4 : 6 weight ratio was investigated. Then the optimum pressure for dyeing could be reduced down to 200 bar. Using this supercritical fluid system, the maximum dyeing appeared as the transmittance of less than 1% and the waste amount was reduced to the level of 1/10. After 500% drawing of this PVA film, both the polarizing efficiency of 94% and the single piece transmittance of 30% were obtained. The limitation of DB22 and further improvements were also discussed.

Synthesis of Azo based Disperse Dyes for Dyeing Polyester Fiber in Supercritical Carbon Dioxide (초임계 유체 염색용 아조계 분산염료 합성 및 PET 섬유에 대한 염색 특성 연구)

  • Shin, Seung-Rim;An, Kyoung-Lyong;Lee, Sunhye;Lee, Seung Eun;Ko, Eunhee;Kim, Changil;Jun, Kun
    • Textile Coloration and Finishing
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    • v.31 no.3
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    • pp.135-146
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    • 2019
  • A series of azo based disperse dyes were synthesized and applied to polyester(PET) fiber in supercritical carbon dioxide($ScCO_2$). Various aniline derivatives were used as diazo component and coupled with glycine ethylester or carbonic acid ethylester derivatives to give azo based disperse dyes. Depending on the various diazo substituents, absorption maxima varied from 415 to 529nm in acetone. Dyeing in $ScCO_2$ was carried out at $120^{\circ}C$ and 250bar pressure for 2hrs with 0.5% o.w.f. of dye concentration. Dyed PET fiber had excellent brightness and good light, washing and perspiration(acid/alkali) fastness properties.

Synthesis of Azo Based Disperse Dyes for Dyeing Polyester Fiber in Supercritical Carbon Dioxide (초임계 유체 염색용 아조계 분산염료 합성 및 PET 섬유에 대한 염색 특성 연구)

  • Shin, Seung-Rim;An, Kyoung-Lyong;Lee, Sunhye;Ko, Eunhee;Lee, In-Yeol;Kim, Changil;Jun, Kun
    • Textile Coloration and Finishing
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    • v.33 no.1
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    • pp.10-23
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    • 2021
  • In order to synthesize the dye suitable for supercritical carbon dioxide(ScCO2) dyeing, a series of azo based disperse dyes were prepared using various aniline derivatives as diazo components and indol derivatives as coupling components. Dyeing process in ScCO2 of the synthesized dyes was performed on PET fiber at 120℃ for 2 hrs under 250bar pressure with 0.5% o.w.f. of dye concentration. The absorption maxima varied from 400 to 580nm depending on the substituted groups in aniline derivatives and the indol derivatives. The dyes showed high molar extinction coefficients(ε) of 27,000~61,000M-1cm-1. Dyed PET fiber exhibited excellent brightness and good light, washing and perspiration(acid/alkali) fastness properties.

Dyeing of Cotton/Polyester Blends with Disperse Dyes and Crosslinking Agent - The Changes of Physical Properties and Colorfastness - (가교제와 분산염료를 이용한 면/폴리에스테르 혼방직물의 염색 - 그에 따른 물성 변화 및 염색견뢰도 -)

  • 김은아;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.10
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    • pp.1401-1411
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    • 2002
  • To Save energy and cost one bath/one step dyeing and finishing on cotton/polyester blends is carried out with disperse dyes in the presence of crosslinking agent. Cotton 100 %, cotton/polyester 70/30, 50/50, 35/65, polyester 100 % fabrics were used. wrinkle recovery angle, tensile strength retention and tearing strength retention were determined in according to the dyebath composition, and also determined while the concentration of DMDHEU, molecular weight and concentration of PEG were varied. Colorfastness to abrasion, washing and light were tested. For cotton and cotton/polyester blends dyed in the presence of DMDHEU/PEG, wrinkle recovery was improved. Tensile strength retention and tearing strength retention were decreased, in compared with dyed fabrics without DMDHEU. Colorfastness to abrasion was good but colorfastness to washing and to light were poor for the fabrics dyed in the presence of DMDHEU/PEG.

Dyeing of Cotton/Polyester Blends with Disperse Dyes in the Presence of DMDHEU/PEG (DMDHEU/PEG와 분산염료를 이용한 면/폴리에스테르 혼방직물의 염색)

  • 김은아;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.7
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    • pp.1025-1034
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    • 2000
  • Cotton differs from polyester in physical and chemical properties. When cotton/polyester blends are dyed, water-soluble dyes are generally used for cotton and disperse dye for polyester. Thus, two bath or one bath-two step dyeing process are usually accepted. These processes consume more energy and cost compared to a single step process. To save energy and cost, a single step dyeing and finishing is carried out with disperse dyes in the presence of a crossslinking agent. K/S values of the dyed fabrics were determined to examine the dyeing property of cotton, cotton/polyester, polyester fabrics dyed with disperse dyes in the presence of DMDHEU/PEG. The concentration of DMDHEU, molecular weight and concentration of PEG, curing time and curing temperature were varied.

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Dyeing Properties of Acetate/Functional Polyester Composite Yarn in Different Yarn Twisting Processes (연사방법에 따른 아세테이트/기능성 폴리에스터 복합사의 염색성에 관한 연구)

  • Kim, So-Jin;Jeon, Dong-Won;Park, Young-Hwan
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.2 s.150
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    • pp.255-265
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    • 2006
  • The purpose of this study was to examine the dyeing properties of four kinds of composite yams that were twisted in different processes. The composite yarns consist of acetate and functional polyester in ratio of 70 : 30. The composite yams were dyed at 100$^{circ}C$ and 125$^{circ}C$ using three types of dyes, disperse dyes for acetate fiber, PET fiber and PET-acetate blended fiber, in the three primary colors. The exhaustion($\%$) and K/S value were observed for each case. Also the effects of four different twisting processes to dyeing properties and physical properties were examined. Regardless of twisting methods, the composite yarns that were dyed at 125$^{circ}C$ had higher exhaustion($\%$) than those were dyed at 100$^{circ}C$ with all three types of dyes; However, tendency of the K/S value after reduction cleaning process was measured at 100$^{circ}C$ and the value measured 125$^{circ}C$ had a great difference with disperse dyes for acetate and dyes for PET. The difference of the K/S values of composite yarns, when dyed at 100$^{circ}C$ and 125$^{circ}C$ with disperse dyes for PET-acetate blended fiber, was almost negligible. According to twisting methods K/S values were in the following order: AP1 > AP3 > AP4> AP2. This means that AP1, treated at 220$^{circ}C$, had the highest K/S value and K/S value becomes higher as the yam is higher twisted and becomes lower as lower twisted. On the other hand, the dry shrinkage and wet shrinkage showed low shrinkage rate when the twist was high and steam setting temperature was high.