• Applied Chemistry for Engineering
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• v.33 no.4
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• pp.431-435
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• 2022

The reduction of nitrogen-containing compounds (NC) containing the model crude methylnaphthalene oil (CMNO) of 5 compounds system was experimentally studied by solvent extraction. The model CMNO consisting of 3 kinds of NC including quinolone (QU), iso-quinoline (IQU), indole(IN) and 2 kinds of bicyclic aromatic compounds such as 1-methylnaphthalene (1MNA), 2-methylnaphthalene (2MNA) as raw materials, as well as the aqueous solution of formamide as a solvent, were used. The increase in the volume fraction of water to the solvent at the initial state (y_w,0) sharply decreased, but the distribution coefficient and the yield of NC conversely increased the selectivity of NC based on 2MNA, and an increase in the volume fraction of solvent to feed (S/F) simultaneously increased the distribution coefficient, yield and selectivity of NC. The yields of QU, IQU and IN under constant conditions (y_w,0 = 0.1, S/F = 1, equilibrium temperature 303 K) were 30%, 31% and 10%, respectively, and selectivity was 15, 15 and 20, respectively. From the excellent yield and selectivity of NC, the formamide extraction method of this study was expected as a method for reducing the NC contained in the model CMNO.

• Applied Chemistry for Engineering
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• v.34 no.6
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• pp.665-669
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• 2023

The crude methylnaphthalene oil (CMNO) contains nitrogen compounds (NCs) such as quinoline (QU), isoquinoline (IQU), and indole (IN). These NCs in the CMNO are treated as impurities contained in the CMNO due to contamination of the atmospheric environment and unpleasant odors. In order to improve the quality of CMNO, this study examined the effect of extraction experimental factors on the reduction of NCs contained in CMNO using CMNO as a raw material and an aqueous formamide solution as a solvent, respectively. The increase in the volume ratio of solvent to feed in initial (S/F)₀ in initial increased the distribution coefficient of NCs and the selectivity of NCs in reference to 2-methylnaphthalene (2MNA). Additionally, an increase in operating temperature (T) increased the distribution coefficient of NCs but conversely decreased selectivity. The compositions of QU, IQU, and IN in the raffinate oil recovered through equilibrium extraction under a constant condition (volume fraction of water to solvent in initial (y_w,0) = 0.1, (S/F)₀ = 9, T = 303 K, liquid-liquid contacting time = 72 h) were reduced by about 58.5 wt%, 61.9 wt%, and 73.4 wt%, respectively, compared to those of CMNO. The formamide extraction method in this study was expected to be an effective reduction method for NCs contained in CMNO.

• Proceedings of the Korea Water Resources Association Conference
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• 2005.05b
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• pp.1148-1153
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• 2005

하수관거는 국민의 정맥이라고 할 수 있을 정도로 도시의 환경관리와 치수, 쾌적한 환경조성에 있어서 매우 중요한 시설이며 그 규모가 광범위하고 복잡한 네트워크로 구성되어 있다. 이러한 하수관망을 통해 이송되는 물은 지저분하고 냄새가 심하기 때문에 지하에 관의 형태로 대부분 시공되어 왔으며, 상수관망처럼 압력관이 아니라 대부분 중력에 의한 이송방식을 채택하고 있어 문제 발생 시 원인파악과 대처를 힘들게 하는 요인을 가지고 있다. 특히 하수관거의 관리 소홀은 곧바로 토양오염과 인근 환경오염으로 직결되며 장기적으로는 상수를 오염시키는 요인으로 작용하므로 체계적인 방법과 장기적인 안목을 가지고 명확한 분석을 시행할 수 있는 시스템을 가지고 최적으로 유지관리 되어야 한다. 최근 들어 이러한 하수도 시설을 효율적으로 관리 및 개선하기 위해 대도시를 중심으로 근거 조사와 정비 사업이 활발히 시행되고 있다. 그러나, 사업효과를 검증하거나 관로의 유지관리를 위하여 국내 실정에 맞지 않는 외국하수관망 흐름 해석 프로그램을 그대로 사용하고 있고 정확한 해석이 이루어지지 않고 있어 효율적인 유지관리가 어렵다. 이와 같은 문제점을 해결하기 위하여 하수관망해석이나 하수관망 정비시 필요한 불명수산정이 가능하고 국내실정에 맞는 프로그램 개발이 시급한 실정이며, 아울러 프로그램을 효율적 운영하고 관리하는 제어관리 기술을 개발, 진행하고 있다. 본 논문에서는 개발된 프로그램의 부정류 해석 기능을 활용하여 대상구역의 해석을 실시하여 기존분석방법의 I/I결과와 비교하였으며 최적관리를 위한 방안을 제시하였다.준편차가 증가하고 있음을 알 수 있다. 본 연구에서는 상용 CFD모형인 FLOW-3D를 계획 중인 하수처리장의 침전지 유입부 설계에 적용하였으며 저류벽의 위치와 폭, 유공정류벽의 유공율에 따른 유입하수의 분배효과를 분석하였다. 실험을 수행하여 보다 정밀한 공식으로 개선할 수 있었다.$10,924m^3/s$ 및 $10,075m^3/s$로서 실험 I의 $2,757m^3/s$에 비해 통수능이 많이 개선되었음을 알 수 있다.함을 알 수 있다. 상수관로 설계 기준에서는 관로내 수압을 $1.5\~4.0kg/cm^2$으로 나타내고 있는데 $6kg/cm^2$보다 과수압을 나타내는 경우가 $100\%$로 밸브를 개방하였을 때보다 $60\%,\;80\%$ 개방하였을 때가 더 빈번히 발생하고 있으므로 대상지역의 밸브 개폐는 $100\%$ 개방하는 것이 선계기준에 적합한 것으로 나타났다. 밸브 개폐에 따른 수압 변화를 모의한 결과 밸브 개폐도를 적절히 유지하여 필요수량의 확보 및 누수방지대책에 활용할 수 있을 것으로 판단된다.8R(mm)(r^2=0.84)$로 지수적으로 증가하는 경향을 나타내었다. 유거수량은 토성별로 양토를 1.0으로 기준할 때 사양토가 0.86으로 가장 작았고, 식양토 1.09, 식토 1.15로 평가되어 침투수에 비해 토성별 차이가 크게 나타났다. 이는 토성이 세립질일 수록 유거수의 저항이 작기 때문으로 생각된다. 경사에 따라서는

• Environmental and Resource Economics Review
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• v.20 no.4
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• pp.827-858
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• 2011

In Korea, various environmentally harmful subsidies are granted in agriculture, fishery, energy, electricity, transportation, steel and shipbuilding industry. Examples include tax-exempt fuel for agriculture & fishery, VAT- exemption for briquette & anthracite, temporary subsidy for fuel, production stabilizing subsidy for coal mining, subsidy for briquette. Korea's yearly total subsidy in energy area is about 5,291 billion won, among them is 4,870 billion won. To reduce air pollutants and to mitigate climate change, Korea has to review the phase-out of environmentally harmful subsidies and the phase-in of environment-friendly subsidy. The reduction or removal of environmentally harmful subsidies will enhance economic efficiency and bring about environmental benefits. Economic efficiency means less use of inputs, which reduces environmental cost and improves social benefits. This paper applies the Shoven and Whalley's model to the Korean economy and analyzes the general equilibrium incidence effects of reforming environmentally harmful subsidies in the energy and electricity in Korea. We consider several counterfactual scenarios in which current environmentally harmful subsidies are reduced or abolished, compare them with the reference case in the economy, and evaluated the change in efficiency costs and distributional incidence of tax reforms related to subsidies.

• Analytical Science and Technology
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• v.26 no.3
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• pp.174-181
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• 2013

Pyrifluquinazon is classified with a quinazoline insecticide that regulates food intake by controling the feeding behavior acting on the endocrine or nervous system of pests such as aphids and white fly. To keep safety on pyrifluquinazon residues in agricultural commodities a simple, accurate and rapid analytical method was developed and validated using high performance liquid chromatograph (HPLC-UVD). The pyrifluquinazon residues acidified with 1% formic acid in samples were extracted with acetonitrile and partitioned with hexane subsequently to dichloromethane then purified with silica solid phase extraction (SPE) cartridge. The purified samples were detected using HPLC-UVD. The method was validated using apple and pear spiked with pyrifluquinazon at 0.02, 0.05 and 0.1 mg/kg and hulled rice, pepper, soybean at 0.05 and 0.1 mg/kg. Average recoveries were 70.5~107.9% with relative standard deviation less than 10%. The result of recoveries and overall coefficient of variation of a laboratory results in Gwangju regional FDA and Daejeon regional FDA was followed with Codex guideline (CODEX CAC/GL 40). This method is appropriated at pyrifluquinazon residues determination and will be used as official method of analysis.

• The Korean Journal of Pesticide Science
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• v.15 no.1
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• pp.8-14
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• 2011

Methoxyfenozide and novaluron was sprayed on Aster scaber during cultivation period. Samples were collected 7 times in 0-10 days after spraying. Both methoxyfenozide and novaluron were extracted with methanol, partitioned with dichloromethane and analyzed by HPLC. At the fortified level of 0.4 and $2\;mg{\cdot}kg^{-1}$, average recovery of methoxyfenozide were $102.5{\pm}3.03$ and $84.4{\pm}2.82%$, and novaluron were $88.7{\pm}2.32$ and $90.6{\pm}4.50%$, respectively. Biological half-life of methoxyfenozide was 3.99 days and novaluron which was 3.16 days at recommended spray level on cultivation period of the plant. The major reducing factor of novaluron was the increased weight of the plant. In case of application of methoxyfenozide and novaluron following pesticide guide line for safe use, the final residue level was calculated to lower than maximum residue level (MRL).

• Journal of Korean Society of Disaster and Security
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• v.16 no.4
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• pp.75-84
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• 2023

Many developing countries face challenges in estimating long-term discharge due to the lack of hydrological data for water supply planning, making it difficult to establish a rational water supply plan for decision-making on water distribution. The study area, the Bandung region in Indonesia, is experiencing rapid urbanization and population concentration, leading to a severe shortage of freshwater. The absence of water reservoir prediction methods has resulted in a water supply rate of approximately 20%. In this study, we aimed to propose an approach for predicting water reservoirs in developing countries by analyzing water safety and potential water supply using the MODSIM (Modified SIMYLD) network model. To assess the suitability of the MODSIM model, we applied the unit hydrograph method to calculate long-term discharge based on 19 years of discharge data (2002-2020) from the Pataruman observation station. The analysis confirmed alignment with the existing monthly optimal operation curve. The analysis of power plant capacity revealed a difference of approximately 0.30% to 0.50%, and the water intake safety at the Pataruman point showed 1.64% for Q95% flow and 0.47% for Q355 flow higher. Operational efficiency, compared to the existing reservoir optimal operation curve, was measured at around 1%, confirming the potential of using the MODSIM network model for water supply evaluation and the need for water supply facilities.

• The Korean Journal of Pesticide Science
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• v.18 no.3
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• pp.123-129
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• 2014

The present work was aimed to determine the pre-harvest residue limits (PHRLs) and the safety management of commonly used pesticides namely buprofezin and penthiopyrad on oriental melon (Cucumis melon var. makuwa). In this study, the buprofezin (diluted two thousand fold) and penthiopyrad (diluted four thousand fold) were sprayed single time on oriental melon in the cultivation areas Sangju (site 1) and Sungju (site 2). Oriental melon were randomly collected from the both areas at the end of 0 (2 hours after pesticides spaying), 1, 2, 3, 5, 7, 9 and 10 days. For analysis, each samples were partitioned twice (80 and 70 mL) with dichloromethane and purified by florisil SPE cartridge. Finally, the residual amounts of both pesticides in all samples were analyzed using gas chromatography/nitrogen phosphorus detector (GC/NPD). In this study, the method limit of quantification (MLOQ) for both buprofezin and penthiopyrad in oriental melon was found to be $0.01mg\;kg^{-1}$ and their recovery levels were 91.1~98.6% and 90.0~104.6%, respectively. Further, the calculated biological half-life for buprofezin and penthiopyrad in oriental melon were 3.9 and 3.5, and 3.0 and 2.7 days in site 1 and 2, respectively. The results of this study found that the PHRLs for buprofezin and penthiopyrad were 4.24 and $2.31mg\;kg^{-1}$, respectively at 10 days before harvest. Consequently, the present study suggest that the residual amounts of both pesticides will be lower than the maximum residue limits (MRLs) when oriental melon is harvested.

• The Korean Journal of Pesticide Science
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• v.18 no.2
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• pp.79-87
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• 2014

Pyriofenone is an aryl phenyl ketone fungicide that is newly registered in Korea in 2013 to control powdery mildew on food. The objective of this study was to develop reliable and sensitive analytical method for determination of pyriofenone residue in agricultural products for ensuring the food safety. The pyriofenone residues in all samples(Korean melon, pepper, potato, mandarin, soybean, and hulled rice) were extracted with acetonitrile, partitioned with dichloromethane, and then purified with a silica cartridge. The purified samples were analyzed by HPLC-UVD and confirmed with LC-MS. The linear range of pyriofenone was 0.05~5 mg/kg with the correlation coefficient ($r^2$) > 0.999. Average recoveries of pyriofenone ranged from 72.8% to 99.5% at the spiked level of 0.05 and 0.5 mg/kg, while the relative standard deviation was 2.3%~6.4%. In addition, the limit of detection and limit of quantification were 0.01 and 0.05 mg/kg, respectively. The results revealed that the developed and validated analytical method was suitable for pyriofenone determination in agricultural products.

• Korean Journal of Food Science and Technology
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• v.45 no.3
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• pp.285-292
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• 2013

This study was carried out to validate the safety of ametoctradin residues in agricultural commodities by developing an official analysis method. An analytical method was developed and validated using HPLC-PDA detectors. The samples were extracted with methanol, subsequently partitioned with dichloromethane and purified with florisil column chromatograph using acetone/hexane (30/70, v/v) as solvent. The method was validated by using grape, hulled rice, mandarin, and potato spiked with ametoctradin at 0.05 and 5.0 mg/kg, and pepper at 0.05 and 2.0 mg/kg. Average recoveries were 76-114.8% with relative standard deviation less than 10%, and the limit of detection and limit of quantification were 0.0125 and 0.05 mg/kg, respectively. The result of recoveries and overall coefficient of variation of the laboratory results from Gwangju regional Food and Drug Administration (FDA) and Daejeon regional FDA was accorded with Codex Alimentarius Commission Guideline (CAC/GL 40). Based on these results, this method was found to be appropriate for ametoctradin residue determination and can be used as the official method of analysis.