• Journal of the Korean Chemical Society
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• v.17 no.6
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• pp.434-438
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• 1973

Distribution coefficients (C) of some transition metal ions such as Ni(II), Cu(II), Cd(II), Zn(II), and Hg(II) have been determined in methanol-, ethanol-, isopropanol-, acetone-, and dimethylsulfoxide-water mixtures by using Rexyn 101 (Na-form) resin and 0.2 M sodium chloride solution. The log C values of the metallic ions decrease almost straightly with the increase in reciprocal values of the dielectric constants of the mixed solvents. In the solvents having the same dielectric constants, the distribution coefficients of the metallic ions decrease with the increase in the basicity of the aprotic organic molecule and with the decrease in the molecular size of the protic organic molecule. The separation of the metallic ions has been accomplished with the eluting agent suggested by the C values.

• Journal of the Korea institute for structural maintenance and inspection
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• v.13 no.4 s.56
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• pp.180-187
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• 2009

The objective of this research is to verify the code-specified girder distribution factors (GDF) for continuous steel girder bridges by field testing. Previous analytical study revealed that current GDF's specified in AASHTO Standard and AASHTO LRFD, developed for the simple span bridges are conservative even for the continuous bridges. In this study, field tests were performed for three continuous steel girder bridges to validate the GDF's specified in the AASHTO codes. The results show that the code values are conservative when compared with field tests, and in some cases, too conservative. Also, strains measured from the field test are, in most cases, smaller than those expected from the analytical results. However, when the GDF's from measured strains are compared with GDF's from analysis, it is found that the analysis results are not conservative, and in some instance, the analytical results underestimate the actual GDF's, which can lead to a groundless notion of safety. In one case, test results showed that the code GDF's specified in AASHTO LRFD is too permissive. As a result, it is found that GDF's specified in AASHTO LRFD should be used with careful reservation.

• Analytical Science and Technology
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• v.21 no.4
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• pp.326-331
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• 2008

Distribution coefficients (Kd) of uranyl ion onto divinylbenzene amidoxime resins were measured in sodium carbonate solution and the Kd values were increased up to about 70 as the resin bead size was decreased. At a condition of 0.0044 M $Na_2CO_3$, the adsorption capacity for uranium was $3.4{\mu}mole$ U/g-resin. The Kd values in the 0.5 M $Na_2CO_3-NaHCO_3$ solution, ranging from pH 9 to pH 11, revealed that they were increased as the pH increased and revealed lower values than those in the pure sodium carbonate solution. The amidoxime resins were characterized by FTIR-ATR showing the absorption bands of the amidoxime functional groups. A species of the uranyltricarbonate complex, $UO_2(CO_3)_3^{-4}$, was confirmed by UV-Vis spectroscopy, revealing four absorption peaks between 400 and 500 nm. Uranium was separated from some fission products by a column operation. However, most of the uranium and fission products were eluted before an adsorption and only a small amount of uranium was adsorbed onto the resin due to the low capacity of the resin.

• 한국방재학회:학술대회논문집
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• 2009.02b
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• pp.118.2-118.2
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• 2009

• Journal of the Korean GEO-environmental Society
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• v.3 no.1
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• pp.13-26
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• 2002

In this study, column diffusion tests for Cd and Zn were conducted at $15^{\circ}C$ and $55^{\circ}C$ to investigate a temperature effect on effective diffusion coefficient. An increase in temperature from $15^{\circ}C$ to $55^{\circ}C$ caused up to ten times larger diffusion coefficient for each heavy metal. Besides, it caused the increased retardation of heavy metals, and hence the effective diffusion coefficient should be overestimated as we use an overestimated retardation factor to calibrate the coefficient. The results of sequential extraction analyses showed that Zn was occluded in carbonate phase and this trend was getting prominent with the increase in temperature. As for Cd, it was partitioned mainly in the exchangeable phase(over 60%) at any temperature.

• Proceedings of the Korea Water Resources Association Conference
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• 2012.05a
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• pp.74-78
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• 2012

본 연구는 하천에서 식생에 의한 흐름구조 변화가 오염물질 이동에 미치는 영향을 알아보기 위해 흐름방향 확산계수를 산정하였다. 정수식생 조건에서 횡방향 수심적분된 와점성계수는 비식생 조건에서의 와점성계수와 다르게 적용되어야 하며 이를 위해 유량 횡분배법을 Jordanova and James (2003) 실험에 적용하였다. 제시된 실험조건을 잘 재현하는 와점성계수의 값을 역산하였으며, 이에 관한 산술평균 값을 향후 수리모형의 적용을 위해 정수식생 조건에서의 무차원 와점성계수로 제안하였다. 결정된 무차원 와점성계수를 이용하여 부분식생 개수로 흐름에서 흐름방향 확산계수를 산정하여 오염물질의 이동에 대한 특성을 분석하였다.

• Journal of Korean Society of Steel Construction
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• v.18 no.5
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• pp.535-542
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• 2006

In this study, the effects of cross beams on the lateral distribution of live loads in composite rolled H-beam girder bridges, were investigated through three-dimensional finite element analysis. The parameters considered in this study were the inertial moment ratio between the main girder and the cross beam, the presence of the cross beam, and the number of cross beams. The live load lateral distribution factors were investigated through finite element analysis and the customary grid method. The results show that there was no difference between the bridge models with and without a cross beam. The cross beam of the beam and frame types also showed almost the same live load lateral distribution factors. However, the finite element analysis showed that the concrete slab deck plays a major role in the lateral distribution of a live load, and consequently, the effect of the cross beam is not so insignificant that it can be neglected.

• Journal of the Korea institute for structural maintenance and inspection
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• v.15 no.2
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• pp.88-97
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• 2011

For Korean design provisions are not equipped for skewed steel box girder bridges, when American provisions are adopted, load distribution factors different from real behavior are determinated. Furthermore the possibility of over or under estimated bridge design involves. The aim of this study is to provide more rational load distribution factor formulas based on real behavior for shear at obtuse corner of skewed steel box girder bridges. In order to accomplish the aim finite element analysis for a variety of skewed steel box girder bridge structural models is carried out, and each parameters degree of influence on wheel load distribution factors of skewed steel box girder bridges are analyzed. Then multiple regression analysis is fulfilled in order to propose formulas for determinating shear force load distribution factor of skewed steel box girder bridges.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.21 no.4
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• pp.325-334
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• 2008

The standard prestressed concrete I-girder bridge (PSC I-girder bridge) is one of the most prevalent types for small and medium bridges in Korea. When determining the member forces in a section to assess the safety of girder in this type of bridge, the general practice is to use the simplified practical equations or the live load distribution factors proposed in design standards rather than the precise analysis through the finite element method or so. Meanwhile, the live load distribution factors currently used in Korean design practice are just a reflection of overseas research results or design standards without alterations. Therefore, it is necessary to develop an equation of the live load distribution factors fit for the design conditions of Korea, considering the standardized section of standard PSC I-girder bridges and the design strength of concrete. In this study, to develop an equation of the live load distribution factors, a parametric analysis and sensitivity analysis were carried out on the parameters such as width of bridge, span length, girder spacing, width of traffic lane, etc. As a result, the major variables to determine the size of distribution factors were girder spacing, overhang length and span length in case of external girders. For internal adjacent girders, the determinant factors were girder spacing, overhang length, span length and width of bridge. For internal girders, the factors were girder spacing, width of bridge and span length. Then, an equation of live load distribution factors was developed through the multiple linear regression analysis on the results of parametric analysis. When the actual practice engineers design a bridge with the equation of live load distribution factors developed here, they will determine the design of member forces ensuring the appropriate safety rate more easily. Moreover, in the preliminary design, this model is expected to save much time for the repetitive design to improve the structural efficiency of PSC I-girder bridges.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.1
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• pp.83-89
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• 2000

Bentonite has been considered as a liner material to restrict the release of hazardous heavy metals from the landfill. The adsorption of copper onto a domestic bentonite was studied to provide the adsorption isotherm and the effect of solution chemistry and temperature. The copper adsorption was fitted well to a Freundlich isotherm, in which Freundlich constants and correlation coefficient were calculated to be $K_F=1.18$, n=1.65, and $r^2=0.97$, respectively. The distribution coefficients ($K_d$) for the adsorption of copper decreased with increasing initial copper concentration. The $K_d$ increased with increasing the pH of solution, and drastically increased at pH > 5.3 because of precipitation of most copper species. As the ion strength of $Na^+$ in solution increased the $K_d$ decreased, while it increased with increasing the concentration of $SO_4{^{2-}}$ in solution. An increase in the temperature of experimental solution decreased the $K_d$ values.