• Title/Summary/Keyword: 분극성

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Effect of Zr/Ti Concentration in the PLZT(10/y/z) Thin Films From the Aspect of NVFRAM Application (비휘발성 메모리소자로의 응용의 관점에서 PLZT(10/y/z) 박막에서의 Zr/Ti 농도변화 효과)

  • Kim, Seong-Jin;Gang, Seong-Jun;Yun, Yeong-Seop
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.38 no.5
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    • pp.313-322
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    • 2001
  • The effects of Zr/Ti concentration ratio in PLZT (10/y/z) thin films prepared by sol-gel method are investigated for the NVFRAM application. Rosette and pyrochlore phase are observed in PLZT (10/40/60) thin film and the (100) orientation, the grain size, and the surface roughness of PLZT thin films increase due to the increase of Ti amount in Zr/Ti concentration ratio. As Ti amount of Zr/Ti concentration ratio increases, the dielectric constants at 10KHz decrease from 600 to 400, while the loss tangents increase from 0.028 to 0.053 and the leakage current densities at 170 kY/cm decrease from 1.64$\times$10$^{-6}$ to 1.26$\times$10$^{-7}$ A/$\textrm{cm}^2$. In the results of hysteresis loops measured at $\pm$ 170 ㎸/cm, the remanent polarization and the coercive field increase from 6.62 to 12.86 $\mu$C/$\textrm{cm}^2$ and from 32.15 to 56.45 ㎸/cm, respectively, according to the change from 40/60 to 0/100 in Zr/Ti concentration ratio. Fatigue and retention properties also improve much as the Zr/Ti concentration ratio change from 40/60 to 0/100. After applying 10$^{9}$ square pulses with $\pm$5V, the remanent polarization of the PLZT (10/40/60) thin film decreases 50% from the initial state while that of the PLZT (10/0/100) thin film decreases 30%. In the results of retention measurements of 10$^{5}$ s, the remanent polarization of the PLZT (10/0/100) thin film decreases only 11% from the initial state, while that of the PLZT (10/40/60) thin film decreases 40%.

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Forward probing utilizing electrical resistivity and induced polarization for predicting mixed-ground ahead of TBM tunnel face (전기비저항과 유도분극을 활용한 TBM 터널 굴착면 전방 복합지반 예측 기법)

  • Ryu, Jinwoo;Park, Jinho;Lee, Seong-Won;Lee, In-Mo;Kim, Byung-Kyu
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.20 no.1
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    • pp.55-72
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    • 2018
  • A method that can predict the mixed-ground condition ahead of a TBM tunnel face during tunnel construction utilizing electrical resistivity and induced polarization (IP) was proposed in this study. Effect of TBM advancement approaching the mixed-ground condition (composed of soil layer overlying rock layer) when currently running through soil zone on the electrical resistivity and IP measuring was assessed with laboratory-scale experiments. The resistivity and IP values were measured using four electrodes, by installing two electrodes on the tunnel face (at the cutterhead), and the other two electrodes on the segment lining. The test results showed that both of the measured resistivity and IP values were kept increasing as the TBM is approaching the soil-rock mixed-ground. Also, to get the more reliable results for predicting the mixed-ground condition, it was recommended that the measurement is made at the tunnel face utilizing 4-electrodes installed at the cutterhead as well as it is made utilizing the 2-electrodes installed at the segment lining along with the 2-electrodes installed on the tunnel face (at the cutterhead) so that two measured results are compared each other.

Origin of Decreasing the Dielectric Constant and the Effect of Ionic Polarization (유전상수가 낮아지는 원인과 이온 분극의 효과)

  • Oh, Teresa
    • Journal of the Korean Vacuum Society
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    • v.18 no.6
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    • pp.453-458
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    • 2009
  • SiOC film was deposited by the chemical vapor deposition using BTMSM and oxygen mixed precursor. The characteristic of SiOC film varied with increasing of the gas flow rate ratios. The dielectric constant was obtained by C-V measurement using the structure of metal/SiOC film/Si. The space effect due to the steric hindrance between alkyl group at terminal bond of Si-$CH_3$ made the pores, and increased the thickness. However, the SiOC film due to the lowering of the polarization decreased the thickness and then decreased the dielectric constant. After annealing process, the dielectric constant decreased because of the evaporation of the OH or $H_2O$ sites. The thickness was related to the lowering of the dielectric constant by the reduction of the polarization and the thickness decreased with the decrease of the dielectric constant. The refractive index was in inverse proportion to thickness. The trends of the thickness and refractive index did not change after annealing.

Three Dimensional Induced Polarization Modeling (3차원 IP 탐사의 모형 응답 계산)

  • Nam Myung-Jin;Suh Jung-Hee
    • Geophysics and Geophysical Exploration
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    • v.4 no.1
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    • pp.1-7
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    • 2001
  • The application of geophysical survey methods need to be integrated to meet the increasing demands of imaging of the subsurface in the practical application of civil engineering, underground water survey and environmental problems. This paper examines the IP survey which can be surveyed simultaneously with DC resistivity survey. In this study, 3-D IP modeling algorithm was developed. The 3-D IP modeling algorithm was based on 3-D resistivity modeling by finite-element method. The result of 3-D modeling was compared with 2-dimensional modeling result. The result showed that the 3-D modeling algorithm developed in this study was accurate. Finally, the 3-D modeling algorithm developed in this paper will be useful for the study of IP data.

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Fabrication and Properties of $(Pb_{1-x}C_{ax})((Co_{\frac{1}{2}}W_{\frac{1}{2}})_yTi_{1-y})O_3+(MnO_2, NiO)$ piezoelectric ceramic (압전세라믹 $(Pb_{1-x}C_{ax})((Co_{\frac{1}{2}}W_{\frac{1}{2}})_yTi_{1-y})O_3+(MnO_2, NiO)$)

  • Mun, Dong-Jin;Do, Si-Hong;Jang, Ji-Won
    • The Journal of the Acoustical Society of Korea
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    • v.6 no.4
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    • pp.55-63
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    • 1987
  • Modified $PbTiO_3$ piezoelectric ceramics added with 0.2, 0.25, 0.3 mol of $CaCO_3$ and 0.04 mol of $(Co_{\frac{1}{2}}W_{\frac{1}{2}})$ and 0.05 mol of $MnO_2$ and NiO have been fabricated. These ceramics can be poled sufficiently within 10 minutes at $100^{\circ}C$ under about d.c. field of 40 kv/cm. Detailed measurement was performed on dielectric constants, cutie temperatures, elastic and piezoelectric properties and coupling factors for the fabricated ceramics. The most value of the piezoelectric coupling factors was coupling factor of thickness mode kt and its value for 0.25 mol of Ca was about $45\%$. Dielectric constants of $\varepsilon_{33}^T$ and $\varepsilon_{11}^T$ for 0.25 mol of Ca were 242 and 260, and coupling factor ratio (kt/Kp) and Qm were 6 and 357 respectively.

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New Equivalent Circuit Model for Interpreting Spectral Induced Polarization Anomalous Data (광대역유도분극 이상 자료의 해석을 위한 새로운 등가회로 모델)

  • Shin, Seungwook;Park, Samgyu;Shin, Dongbok
    • Geophysics and Geophysical Exploration
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    • v.17 no.4
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    • pp.242-246
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    • 2014
  • Spectral induced polarization (SIP) is a useful technique, which uses electrochemical properties, for exploration of metallic sulfide minerals. Equivalent circuit analysis is commonly conducted to calculate IP parameters from SIP data. An equivalent circuit model, which indicates the SIP response of rock, has a non-uniqueness problem. For this reason, it is very important to select the proper model for accurate analysis. Thus, this study focused on suggesting a new model, which suitable for the analysis of an anomalous SIP response, such as ore. A suitability of the new model was verified by comparing it with the existing Dias model and Cole-Cole models. Analysis errors were represented as a normalized root mean square error (NRMSE). The analysis result using the Dias model was the NRMSE of 10.50% and was the NRMSE using the Cole-Cole model of 17.03%. Howerver, because the NRMSE of the new model is 0.87%, it is considered that the new model is more useful for analyzing the anomalous SIP data than other models.

Electrochemical characteristics in water cavitation peening for Al bronze in distilled water (동합금 Water cavitation peening에 의한 전기화학적 특성 연구)

  • Kim, Seong-Jong;Park, Jae-Cheol;Kim, Min-Seong;Han, Min-Su
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2011.05a
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    • pp.79-79
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    • 2011
  • water cavitation peening(WCP)은 water jet 과정으로 인한 cavitation이 발생할 때, 금속표면 cavitation 현상에 의해 재료표면의 잔류응력과 경도 등의 물성을 변화시키게 되며, 그로 인해 생긴 잔류 응력으로 재료의 내구성 및 수명을 향상시키는 기술이다. 최근에는 water jet을 이용한 장치들이 건설 분야, 일반기계분야, 컷팅 공정, 분쇄 등 다양한 분야에서도 사용되고있다. 그러나 water jet을 이용한 peening은 소개 된지 20여년이 경과했음에도 불구하고 연구 및 개발 내용은 shot peening에 비해 아직 초기 단계이다. water cavitation peening은 기존의 피닝 방법의 단점을 보완 할 뿐만 아니라 환경적인 측면에서도 그 가치가 크다. 아직은 다른 peening 기법 보다 잔류압축응력 부가 측면에서 그 효과가 떨어지지만, water cavitation peening은 열에 영향을 받는 영역이 생성되지 않으며, 기계의 표면 가공을 하는 동안 어떤 미세한 먼지도 생성하지 않아 친환경적이다. 또한 복잡한 외형을 가지는 부품 및 내면에 적용성이 뛰어나고, 표면 정밀도 저하가 낮다는 장점이 있다. 본 연구에서는 조류발전용 블레이드의 재료로 사용하려는 동합금에 대하여 증류수 내에서 water cavitation peening 시간, 거리, 파형 등의 변수를 적용하여 최적 조건을 찾고, 다양한 전기화학적 실험을 실시하였으며, water cavitation peening 부의 부식특성을 평가 하였다. ASTM-G32 규정에 의거하여 압전효과를 용한 진동발생 장치(RB 111-CE)를 이용하여 동합금 표면에 water cavitation peening을 실시하고, 실험 후 표면의 손상거동을 관찰하기 위하여 3D현미경 및 전자주사현미경(SEM)을 사용하였다. 물성치 변화를 확인하기 위하여 SHIMADZU사의 HVM-2 Model의 비커스 경도기를 이용하여 표면 경도값을 측정하였다. 전기화학실험은 각 3회 이상 실시하였으며, Tafel 분석결과로 부식전류밀도와 부식전위의 평균, 부식전위를 알 수 있었고, 음분극 실험결과, 용존산소 환원반응에 의한 농도분극에서 수소가스발생에 의한 활성화 분극으로 진행되는 변곡점을 확일 할 수 있었다.

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Synthesis of trans, trans-4-(2-Fluoro-3-isothiocyanato-4-propylphenyl)-4-alkylbicyclohexyl for Liquid Crystal Display (액정 디스플레이를 위한 트랜스, 트랜스-4-(2-플르로로-3-아이소싸이오싸이아네이토-4-프로필페닐)-4'-알킬바이싸이클로헥실의 합성)

  • Lee, Seon-Hui;Kim, Seong-Hun
    • Journal of the Korean Chemical Society
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    • v.48 no.5
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    • pp.499-503
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    • 2004
  • We designed and synthesized compounds which have negative dielectric anisotropy (N type) for VA-LCD mode. Due to the large dipole moments toward the minor axis of molecule and anisotropy of polarizability, they can be used as N type LC. F atom and NCS group and propyl group were introduced as substituents on bicyclohexylbenzene core unit and alkyl chains (propyl~heptyl) were introduced on terminal part. All of the synthesized compounds showed negative dielectric anisotropy as expected.

A Study on Approximate Analysis of Superconductor Antenna (초전도체 안테나의 근사해석에 관한 연구)

  • Hwang, Jae-Ho
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2012.05a
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    • pp.77-79
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    • 2012
  • The paper deals with the approximate analysis of printed antenna like superconductor antenna. Analysis of antenna with polarization current in dielectric layer using Moment method. This approximation is very useful for printed antenna on dielectric plane with low dielectric constant. In this paper, we compared numerical results of this method with measurement results.

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On Evaluation of CFRP Composite Laimates Using Ultrasonic Transducers with Polarization Direetion (초음파 탐촉자의 분극성에 따른 CFRP 복합적층판 평가에 관한 연구)

  • Ra, Seung-Woo;Im, Kwang-Hee;Yang, In-Young
    • Journal of the Korean Society of Safety
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    • v.17 no.1
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    • pp.39-44
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    • 2002
  • This paper shows error in the polarization direction on ultrasonic transducers how sensitive the shear ultrasonic waves are to a little misoriented plies according to the angle variation of shear ultrasonic waves $0{\circ},\;45{\circ}$ and $90{\circ}$. Also, it is shown that shear waves, particularly the transmission mode with the transmitter and receiver perpendicular to cach other, have high sensitivity for detecting anomalies in fiber orientation and ply layup sequence that may occur in the manufacturing of composite laminates. Experimental results are agreed with a modeling solutions which was based on decomposition of shear wave polarization vector as it propagates through the composite laminates. This wave appeared considerably to be sensitive to CFRP composites to thickness direction along in-plane fibers.