• Journal of Conservation Science
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• v.30 no.1
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• pp.1-11
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• 2014

Stabilization of iron artifacts is focused on desalination than corrosion inhibitors. However artifacts are not condition of desalination treatment must be applied to corrosion inhibitors. But iron artifacts is not representative of inhibitors which drug is most effective qualities have not been identified. Therefore in this study validates the effectiveness of existing inhibitors and its purpose is to suggest corrosion inhibitors for iron artifacts. In this study, Comparative experiment of corrosion inhibitors is selected BTA, DAN and MEA, TEA. This study was studied using Corrosion resistance test, Contact angle, XPS. As a result, all the samples treated with corrosion inhibitors was formed hydrophobic coating and was rising corrosion resistance. Also, the concentration of corrosion inhibitors was 3% better than 0.3%. BTA in the XPS experiment, the corrosive material to block the CH bond of the peak concentration was highly. This is considered corrosion potential is very high to see out the effect in the polarization experiment. Ethanolamine was superior to the MEA rather than in the TEA. MEA is likely to be appropriate in an outdoor iron artifacts seem to be suitable as corrosion inhibitors.

• Proceedings of the Membrane Society of Korea Conference
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• 1996.04a
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• pp.40-41
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• 1996

기존에 membrane의 소재로 사용되어 왔던 Polyethersulfone은 막 제조 특성이 우수하고 여러 가지 환경에 대한 저항성이 뛰어나서 많이 이용되어 왔지만 소수성을 띠므로 농도분극과 fouling등 많은 문제점을 안고 있다. 이런 문제점을 극복하기 위하여 친수성의 도입, 물리적, 화학적 세척등 여러 가지 방법을 사용하고 있고 본 연구에서는 hydrophobic Polyethersulfone에 hydrophilic Sulfonate group(-SO$_3$H)을 도입하여 이와같은 문제를 극복하고자 했다. 본 연구에서 사용한 sulfonating agent로는 Chlorosulfonic acid (in CCl$_4$)를 사용하였다.

• Proceedings of the Korean Magnestics Society Conference
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• 2002.12a
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• pp.172-173
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• 2002

스핀전자소자 연구 분야의 가장 큰 관심은 전하와 스핀의 자유도를 동시에 고려하여 메모리 및 논리용 트랜지스터를 구현하려는데 있다. 스핀 분극 된 전자를 자성금속으로부터 상자성 및 절연체를 이용하여 또 다른 자성체 및 반도체, 초전도체에 주입하는 일 (Spin injection)에 관한 연구가 일부 진행되어 왔다. 두 개의 자성 금속 사이에 Au등의 상자성 금속을 끼워 넣는 구조로 한쪽의 자성금속을 스핀 소스로 사용하여 상자성 금속에 스핀을 주입하고 다른 쪽의 자성금속으로 주입된 스핀을 검출하는 스핀 스위치 저장소자로서의 양극 스핀 트랜지스터 (bipolar spin transistor)를 많은 연구소에서 제조 연구하였다. (중략)

• Membrane Journal
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• v.11 no.2
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• pp.74-82
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• 2001

By using a phenomenological approach, model equations incorporating the resistance-in¬series concept were established to evaluate quantitatively concentration polarization in the boundary layer in feed adjacent to the membrane surface in the vapor permeation and separation of volatile organic compounds (VOCS)/$N_2$ mixture through po]y(dimethylsiloxane) (PDMS) membrane. The vapor permeations of various VOCS/$N_2$ mixtures through PDMS membrane were carried out at various feed flow rates. Chlorinated hydrocarbons, such as, methylene chloride, chlorofonn, 1,2-clichloroethane and 1,1,2-trichloroethane were used as organic vapor. By fitting the model equations to the experimental penneation data. the model parameters were detennined. respectively. Both the mass transfer coefficient of VOC across tbe boundary layer and concentration polarization modulus as a measure of the extent of concentration polarization were eitimated Quantitatively by the mooe1 equations with the determined model parameters. From the analysis on the detennined model parameters, the boundary layer resistance due to the concentration polarization of VOCs component was found to be more significant when the condensability of voe was greater. This study seeks to emphasize the importance of the boundary resistance on the vapor penneation of the vapor/gas mixtures with high permeability and high selectivity towards the minor component VOC.

• Journal of the Korean Society for Nondestructive Testing
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• v.19 no.6
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• pp.411-419
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• 1999

It has been well recognized that a long term service at elevated temperature of $350^{\circ}C{\sim}550^{\circ}C$ induces embrittlement damage due to carbide precipitation and/or P, Sb and Sn segregation at grain boundaries and thereby deteriorates the grain boundary strength of heat resisting components in the energy-related plants. Therefore, it is very important to assess quantitatively the extent of embrittlement damage of heat resisting components to secure the reliable and efficient service condition and to prevent brittle failure in service. However, because fracture tests are limited in size and number of specimen obtained from the structural components, nondestructive test method is required. In this study, the optimum electrochemical parameters are investigated and discussed to evaluate nondestructive embrittlement damage for aged 2.25Cr-1Mo steels by means of electrochemical polarization test method (ECPTM) in proper corrosive environment. In addition, the electrochemical test results are compared with embrittlement degree evaluated by semi-nondestructive SP test.

• Journal of Soil and Groundwater Environment
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• v.9 no.3
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• pp.1-11
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• 2004

To evaluate the applicability of dielectric constant measurement method on the geoenvironmental investigation of subsurface contaminated by landfill leachate, the analysis on dielectric characteristics of sand containing contaminated pore water by landfill leachate was performed. The separate real and imaginary parts of dielectric constant were investigated in the frequency range of 75kHz to 12MHz. The real part of dielectric constant increased at the lower frequency wherea the real part of dielectric constant decreased at the higher frequency as the concentration of leachate increased. These results can be explained by the frequency dependence of space charge polarization and orientation polarization. The imaginary part of dielectric constant on the contaminated sand with leachate increased with their concentration for whole frequency range. These results are caused by the increase of energy loss due to the enhancement of conduction in soil with leachate concentration. The results in this study indicate that the dielectric constant measurement method has potential in evaluating the contaminated soil and pore water by landfill leachate.

• Korean Chemical Engineering Research
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• v.61 no.1
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• pp.155-161
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• 2023

Ion concentration polarization (ICP) is one of the essential important mechanisms for biomolecule preconcentration devices as well as a fundamental transport phenomenon found in electrodialysis, electrochemical cell, etc. The ICP triggered by externally applied voltage enables the biomolecular analyte to be preconcentrated at an arbitrary position by a locally amplified electric field inside the microchannel. Conventional preconcentration methodologies using the ICP have two limitations: uncertain equilibrium position and hydrodynamic instability of preconcentration plug. In this work, a new preconcentration method in the dead-end microchannel around cation exchange membrane was numerically studied to resolve the limitations. As a result, the numerical model showed that the analyte was concentrated at a shock front developed in a geometrically confined dead-end channel. Furthermore, the electrokinetic behaviors for preconcentration dynamics were analyzed by changing microchannel's applied voltage and volumetric charge concentration of microchannel as key parameters to describe the dynamics. This work would provide an effective means for a point-of-care platform that requires ultra-fast preconcentration method.

• Journal of the Korean Magnetics Society
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• v.26 no.6
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• pp.179-184
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• 2016

For an industrial spin-transfer torque (STT) MRAM, low switching current and high thermal stability are required, simultaneously. For this point of view, it is essential to find magnetic materials which satisfy high spin polarization and strong perpendicular magnetocrystalline anisotropy (MCA). In this paper, we investigate electronic structures and MCA energies of perovskite $CoFeX_3$ (X = O, F, S, Cl). For X = F and Cl, spin polarization at the Fermi level are 97 % and 96 %, respectively, which are close to a half metal. Furthermore, Co-terminated 5-monolayer (ML) $CoFeX_3$ (X = O, F, S, Cl) films show perpendicular MCA. In particular, the MCA energy of the Co-terminated $CoFeCl_3$ is about 1.0 meV/cell which is three times larger than that of a 5-ML CoFe film. Therefore, we expect to realize a magnetic material with high spin polarization and strong perpendicular MCA energy by utilizing group 6 and 7 elements in the periodic table, and to contribute to commercializing of the STT-MRAM.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1993.05a
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• pp.87-89
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• 1993

용융탄산염 연료전지 양극 재료인 tape casting된 다공성 Ni-Cr 합금과 Ni-Al 합금의 전기화학적 특성과 소결 및 creep특성이 양극조건의 분위기 $650^{\circ}C$에서 조사되었다. 이들 전극재료의 전류밀도는 100 mV의 과전압에서 약 100~150㎃/$\textrm{cm}^2$의 크기이었다. Ni-Al 합금에서는 Ni 표면에 형성된 $Al_2$O$_3$의 영향으로 소결저항성이 큰 것으로 나타났으며, Creep 특성도 Al 첨가량의 증가에 의해 향상되었다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2009.05a
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• pp.119-120
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• 2009

시뮬레이션을 활용하여 ABS 수지상의 전해도금에서 음극 보조물에 의한 도금 두께 변화를 관찰하였다. 분극 실험 및 효율 측정실험을 통하여 시뮬레이션 입력 데이터를 산출하였으며, 음극 보조물은 제품형상에 따라 최적으로 설계되어야 도금 두께 균일화가 가장 높은 것을 시뮬레이션을 통하여 알 수 있었다. 시뮬레이션을 활용하여 설계되어진 음극 보조물을 실제 제품에 적용한 결과 음극 보조물을 적용하기 전에 비하여 도금 두께균일성이 증가하였고, 그로 인하여 표면 크랙현상이 개선되었다.