• Journal of the Korean Ceramic Society
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• v.11 no.4
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• pp.5-18
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• 1974

본 연구에 있어서는 연료유의 연소에 의한 내화물의 부식을 연구하기 위하여 시멘트소성용 회전가마, 보일러 및 판유리제조용 탱크가마에 쓰이는 여러 내화물을 짤라서 그 가운데에 구멍을 파고 중유재의 주성분인 V2O5, Na2CO3, Fe2O3, Fe 및 황산철을 미리 그 구멍속에 넣어 응용 확산시킨 다음 이들을 그들의 상용온도인 145$0^{\circ}C$로 황 함유량이 다른 연류유로 소성하여 얻은 결과는 다음과 같다. 일반적으로 5산화 바나듐-알루미나, 고알루미나질 및 염기성 내화물; 산화나트륨-고알루미나질, 실리마나이트질 및 염기성 내화물은 2%미만의 황 함유 연류유소성에 의하여 부식이 적고 3.5%이상의 황하유 연료유소성시는 황에 의하여 대개가 침식을 당하였다. 무수 아황산 분위기속에서 규산알루미늄 및 구석계의 내화점토질내화물은 산화철이 환원되어 색이 연해지고 고알루미나질 벽돌은 색이 짙어지는 경향이 있고 산화철은 황산철로 변하여 풍화의 원인이 되어 침식을 당하게 되었고, 소성시간이 길면 길수록 부식은 증가하고 황산소다보다 탄산소다에 의하여 훨씬 더 많이 부식을 당하였다.

• Proceedings of the KSR Conference
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• 2000.11a
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• pp.535-542
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• 2000

Pure copper, Cu-1.1wt%Cd and ACSR(Aluminum Conductor Steel Reinforced) have been used as Catenary Materials in Electric Railway System. Since these materials may have chance to be exposed to the corrosive environments like polluted air, acid rain and sea water, it is important not only to investigate the corrosion characteristics but also to measure corrosion rates in various corrosive environments. In order to examine corrosion characteristics according to the dissolved oxygen content, pH, chloride ion concentration ion, and the addition of Cd to Cu, a series of tests such as potentiodynamic polarization. a.c impedance spectroscopy and galvanic corrosion tests were carried out in these materials. Results showed that the addition of Cd to Cu and chloride ion in the solution have an adverse effect on the resistance to corrosion. Additionally, Galvanic currents between Al and steel wires of ACSR were confirmed by using ZRA(zero resistance ammeter) method.

• Applied Chemistry for Engineering
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• v.9 no.5
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• pp.667-673
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• 1998

Rebar corrosion in a simulated pore solution (SPS) with chloride ion was analyzed by Tafel and AC impedance method and corrosion effects of surface roughness and iron oxide layer were also investigated. Corrosion estimation of rebar by electrochemical impedance spectroscopy is very useful, and the measured value can be adapted to proposed electrochemical equivalent circuit model. Corrosion potential increased to the cathodic direction as the concentration of chloride ions increased and corrosion current had the same tendency as above. Surface films were analyzed with scanning electron microscope and Auger electron spectroscopy. Thermally oxidized layer by torch flame for 15 sec was very poor at anti-corrosive property. The corrosion rate of rebar increased as the surface roughness increased. Also, higher temperatures above RT of SPS in initial stage caused a rebar to be corroded faster.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.6
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• pp.2465-2471
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• 2012

For the steel structures those are used in harsh sea environments, corrosion fatigue is a challenging issue in connection with design life. In this research, in order to investigate the influence of cathodic overprotection on the corrosion fatigue crack propagation behavior, corrosion fatigue crack propagation test under the condition of -950mV vs SCE was conducted by using of high tensile TMCP steel plate and the relationships between da/dN-${\Delta}K$ were obtained. At this test, when ${\Delta}K$ is low, the crack propagation rates were accelerated compared to those of seawater condition, however, when ${\Delta}K$ is high, the crack propagation rates were lower than those of seawater condition. As the cause for the acceleration and deceleration of corrosion fatigue crack propagation rates under the condition of cathodic overprotection, the role of hydrogen and calcareous deposits are discussed.

• Journal of the Korean Institute of Gas
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• v.5 no.3 s.15
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• pp.63-72
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• 2001

An alternating current (AC) corrosion using coupon and electric resistance (ER) probe has been studied. Coupon coupled with ER probe were applied in terms of AC voltage from high value to low value through the survey of AC voltages on buried gas transmission pipeline over the country. Parameters such as AC current density of coupon, AC voltage, cathodic protection potential, soil resistivity and frequency were monitored continually. Corrosion induced by AC was observed even under cathodically protected condition that met cathodic protection criterion (below -850mv vs. CSE). Corrosion rate was affected mainly not by AC voltage but by both of frequency and AC current density. An experimental corrosion rate relationship could be obtained statistically, In which AC corrosion rate increased linearly with effective AC current density and its slope was 0.619 in case of coupon and 0.885 in case of ER probe.

• Membrane Journal
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• v.7 no.3
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• pp.136-141
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• 1997

Humic acid has been extracted and purified from biologically nondegradable humic substances. Using the ion exchange capability of carboxylic acids which are the main component of the humic acids, a membrane was prepared with poly(viny1 alcohol). Its transport behavior of biologically active ions, $K^+$and $Na^+$, were investigated. The ion transport velocity increased with hydrogen ion concentration, especially, in the range of $10^-1$~$10^0$. The selectivity increased with increasing the concentrations of $K^{＋}$ and Na$^{＋}$, In particular, the transport velocity of $K^+$ increased twice compared to that of $Na^+$ at the 100 hydrogen ion concentration. In this regards, humic acid may be used as a new material for ion exchange membranes.

• 전기의세계
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• v.44 no.4
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• pp.25-30
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• 1995

복수기 및 열교환기는 진공증발 등 특수한 것을 제외하면 면적을 크게하여 유속을 부여하고 전도효율을 높이기 위해 금속관을 주체로 하는 다관식이 많다. 냉각수는 다량으로 필요하기 때문에 하수나 지하수보다 질이 떨어지는 공업용수나 해수가 많이 사용되나, 우리나라는 용수 부족등으로 인하여 해안지방에 화력 및 원자력 발전소, 정유공장 및 일반산업체 등이 집중되어 있어 대부분의 경우 해수를 냉각수로 사용하고 있는 실정으로 해수에 의한 심한 부식성으로 tube, tube sheet 및 water box가 빠른 속도로 부식되어 열교환기 이용률을 저하시키며 잦은 고장으로 인한 발전 및 조업중단등의 사고를 야기할 수 있으므로 부식손상등의 종류 및 대책드을 강구하기 위하여 적정 방식법을 논의 하기로 한다.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2016.05a
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• pp.141-142
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• 2016

• Journal of the Korean Society for Nondestructive Testing
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• v.23 no.4
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• pp.349-355
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• 2003

Material degradation due to corrosion fatigue was evaluated nondestructively using backward radiated Rayleigh surface wave. h corrosion fatigue test was carried out for the specimens made of thermo-mechanically controlled process steel in 3.5wt.% NaCl solution at $25^{\circ}C$. The backward radiation profile, which is the amplitude variation of backward radiated ultrasound according to the incident angle, of the specimens were measured in water at room temperature after the corrosion fatigue test. The velocity of Rayleigh surface wave, determined from the incident angle at which the profile of the backward radiated ultrasound became maximum, decreased for the specimen that had the large number of cycles to failure in the corrosion fatigue test. This fact implies that the corrosion degradation occurred at specimen surface in this specific test is dominantly dependant on the me exposed to corrosion environment. The result observed in the present work demonstrates the high potential of backward radiated Rayleigh surface wave as a tool for nondestructive evaluation of corrosion degradation of aged materials.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.7
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• pp.473-479
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• 2012

Water reuse has been highlighted as a representative alternative to solve the lacking water resource. This study carried out a study on the pipe corrosion and water quality change which can occur through the supply of reclaimed water, using a simulated reclaimed water distribution pipeline. Galvanized steel pipe (GSP), cast iron pipe (CIP), stainless steel pipe (STSP) and PVC pipe (PVCP) were used for the pipe materials. Reclaimed water(RW) and tap water(TW) were respectively supplied into simulated reclaimed water distribution pipelines. As a result of performing a loop test to supply reclaimed water to simulated reclaimed water distribution pipelines, the weight reduction of pipe coupons showed the sequence of CIP > GSP > STSP ${\approx}$ PVCP. In addition, reclaimed water showed a high corrosion rate comparing to that of tap water. In case of CIP, the initial corrosion rate showed 3.511 mdd(milligrams per square decimeter per day) for reclaimed water and 2.064 mdd for tap water and the corrosion rate for 90 days showed 0.833 mdd for reclaimed water and 0.294 mdd for tap water. Also in case of GSP, the initial corrosion rate showed 2.703 mdd for reclaimed water and 2.499 mdd for tap water and the corrosion rate for 90 days showed 0.349 mdd for reclaimed water and 0.248 mdd for tap water, which was a tendency similar to that appeared in CIP with a tendency to reduce the corrosion rate. As a result of water quality changes of reclaimed water at pipe materials to carry out the loop test, there was higher conversion ratio of ammonia into nitrate in CIP and GSP with higher corrosion rate than that in STSP and PVCP where no corrosion has occurred. The highest denitrification rate of nitrate could be observed from CIP with the most particles generated from corrosion. In CIP, it could be confirmed that there was MIC (Microbiologically Induced Corrosion) as a result of EDS (Energy Dispersive X-ray spectrometer System) analysis results.