• Title/Summary/Keyword: 부식 속도

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Weibull Statistical Analysis on the Mechanical Properties of SiC by Immersion in Acidic and Alkaline Solutions (산 및 알칼리 용액에 부식된 SiC의 기계적 특성에 대한 와이블 통계 해석)

  • Ahn, Seok-Hwan;Jeong, Sang-Cheol;Nam, Ki-Woo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.9
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    • pp.767-773
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    • 2016
  • A Weibull statistical analysis of the mechanical properties of SiC ceramics was carried out by immersion in acidic and alkaline solutions. The heat treatment was carried out at 1373 K. The corrosion of SiC was carried out in acidic and alkaline solutions under KSL1607. The bending strength of corroded crack-healed specimens decreased 47% and 70% compared to those of uncorroded specimens in acidic and alkaline solutions, respectively. The corrosion of SiC ceramics is faster in alkaline solution than in acid solution. The scale and shape parameters were evaluated for the as-received and corroded materials, respectively. The shape parameter of the as-received material corroded in acidic and alkaline solutions was significantly more apparent in the acidic solution. Further, the heat-treated material was large in acidic solution but small in alkaline solution. The shape parameters of the as-received and heat-treated materials were smaller in both acidic and alkaline solutions.

월성원자력발전소 압력관 Zr-2.5Nb 합금의 수소흡수 및 부식특성 변화

  • 주기남;권상철;김영석
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.05b
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    • pp.61-66
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    • 1997
  • 월성1호기 압력관의 수소흡수 관련 자료들을 분석하였으며, 캐나다 발전소들의 결과와도 비교하였다. 압력관의 수소흡수 특성은 압력관내 위치, 사용온도, 가동이력 등에 영향을 받아 Inlet 쪽보다는 Outlet 쪽이, 사용온도가 높을수록, 또한 가동에 따른 조사량이 증가할수록 수소흡수량이 증가하였다. 한편 압력관내로의 수소흡수 거동을 규명하기 위해 Zr-2.5wt%Nb 합금의 열처리 조직 차이에 따른 수소흡수특성을 분석하였다. 수소흡수는$\alpha$-Zr 상에 비해 $\beta$-Zr, $\beta$-Nb 상에 크게 영향을 받는 것으로 보인다. 또한 합금내의 수소량 증가가 압력관 부식특성 자체에 미치는 영향을 분석하기 위하여 열처리 시편에 일정량의 수소를 charging 시킨 후 부식시험을 수행하였다. Zr-2.5wt%Nb 합금의 부식거동은 미세조직에 가장 큰 영향을 받아$\alpha$-Zr과 $\beta$-Zr 상의 시편이$\alpha$-Zr과$\beta$-Nb 상의 시편에 비해 큰 부식속도를 보였다. 또한 시편내 150ppm 이하의 수소함량은 시편의 부식거동에 별다른 영향을 없거나, 부식속도를 약간 감소시키는 것으로 추정된다.

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An Experimental Study on Relationship Between Half-Cell Potential and Corrosion Current Density of Chloride-Induced Corroded Steel in Concrete (염해에 따라 콘크리트 속에서 부식된 철근의 반전지전위와 부식전류밀도의 상관관계에 관한 실험적 연구)

  • Jo, Sang-Hyeon;Kim, Dong-Won;Kee, Seong-Hoon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.6
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    • pp.1-13
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    • 2022
  • This study aims to investigate the feasibility of the half-cell potential (HCP) measurements on the concrete surface for evaluation of corrosion rate (or corrosion levels) of reinforcing steel in concrete. A series of experimental study is performed to measure HCP (or corrosion potential, Ecorr) and corrosion current density (icorr) of reinforcing steel in concrete cube specimens, with a side length of 200 mm. Various corrosion levels in a range of 0% to 20% of the test specimens are accelerated by impressing current to the reinforcing steel in concrete immersed in 3.0 % NaCl solution. HCP is measured in accordance with ASTM C876-15, and corrosion current density is determined by using the Stern-Geary equation and measured polarization resistance measured by electrochemical impedance spectroscopy (EIS). As a result, a numerical formula that relates HCP and icorr in the test specimen is established by a regression analysis of the measured data in this study. It is observed that HCP is linearly correlated with log(icorr) with a R2 greater than 0.87, which is less affected by the experimental variables such as concrete mixture proportion, diameter of reinforcing steel and the amount of applied current in this study. These results exhibit that HCP measurements could be effective for evaluation of corrosion rate (or corrosion levels) of reinforcing steel in concrete in the case of exposed to a certain consistent environment.

Electrochemical Corrosion Characteristics of the Intermetallic Compound NiTi from Pure Metals (금속간 화합물 NiTi와 순금속 니켈 및 티타늄의 전기화학적 부식 특성)

  • Lee, Kyu Hwan;Shin, Myung Chul
    • Analytical Science and Technology
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    • v.5 no.1
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    • pp.97-101
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    • 1992
  • Potentiodynamic corrosion tests were conducted to know the corrosion characteristics of the NiTi intermetallic compound composed of pure Ni and Ti in artificial saline. Tafel extrapolation and linear polarization technique show similar results. Corrosion current Icorr and corrosion rate was increased in the order of NiTi

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Effect of Compliant Structure in the Accelerated Heart Valve Fatigue Tester on the Surface Pitting of the Disk (기계식 인공판막의 표면 부식에 영향을 미치는 가속내구시험기의 컴플라이언스 구조에 관한 연구)

  • Kim, Dong-Uk;Lee, Hwan-Seong;Kim, Nam-Gyun
    • Journal of Biomedical Engineering Research
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    • v.19 no.3
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    • pp.285-290
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    • 1998
  • There are various reports on the fracture of mechanical heart valves implanted in human or animal, and they are pointed out that problems are induced by an erosion of disk surface, due to a cavitation effect. We have been investigating this mechanism using accelerated fatigue tester, and it was found that erosion was enhanced by a compliance effect in the test circuit. In this study, effects of compliance value and location on erosion were discussed, while disk closing velocity was measured by a high speed video camera. It was clarified that faster closing velocity was resulting in a enhancement of erosion on the disk surface.

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Zircaloy의 요드 응력부식균열 속도 측정

  • 류우석;홍준화;국일현
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05c
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    • pp.188-192
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    • 1996
  • 재결정 Zircaloy-2의 요드에 의한 응력부식균열의 전파속도를 직류전압강하측정법 (DCPD, Direct Current Potential Drop)을 이용하여 측정하고 임계응력집중계수( $K_{ISCC}$)를 구하였다. 임계요드농도 이상인 0.01 MPa의 요드농도에서, $K_{ISCC}$는 300 $^{\circ}C$의 경우 약 15 MPa√m, 350 $^{\circ}C$의 경우 약 12 MPa√m의 응력계수였으며, plateau 구역에서의 균열속도는 $10^{-4}$~ $10^{-3}$ mm/sec 영역이었다.

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Ni-Cr-Fe-합금에서 Cr 함량 변화의 영향

  • 장진성;김우곤;정만교;한창희;국일현
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05c
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    • pp.151-157
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    • 1996
  • Cr 함량이 alloy 600과 alloy 690의 Cr함량 사이에 위치하는 Ni-Cr-Fe 합금을 진공유도 용해법을 이용하여 제조하였다. 합금 인고트에 대하여 열간 가공성 시험을 수행하여 열간 압연 조건을 구하였다. 열간 및 냉간 압연을 거친 시편을 900~120$0^{\circ}C$ 사이의 여러 온도에서 소둔 열처리하였고, 열처리한 시편에 대하여 기계적 특성과 부식특성을 측정, 분석하였다. Cr 함량은 기계적 강도에는 다소 영향을 미치는 것이 발견되었으나 연신율에는 거의 영향을 미치지 않는 것으로 나타났다. 부식속도는 Cr 함량 변화보다 소둔 열처리 온도에 따라 증가하였으며, 110$0^{\circ}C$ 에서 열처리한 경우에는 부식속도가 얼마간 감소하는 것으로 나타났다.

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Hydrodynamic and Atmospheric Effects on Corrosion of Zinc in Borate Buffer Solution (Borate 완충용액에서 아연의 부식에 대한 대류와 대기의 영향)

  • Chung, Se-Jin;Kim, Youn-Kyoo
    • Journal of the Korean Chemical Society
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    • v.55 no.4
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    • pp.575-580
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    • 2011
  • It was investigated into the effects on zinc corrosion of the rotation speed of Zn-RDE and the oxygen concentration in borate buffer solution. Zinc corrosion was heavily influenced on the rotation speed of electrode and the oxygen concentration. We have suggested the disproportion reaction following the reversible one electron transfer as the corrosion mechanism of zinc.

Evaluation of Relative Corrosion Rate depending on Local Location and Installation of Structural Member in Steel Water Gate (강재 수문의 부재 위치 및 설치 방향에 따른 상대 부식속도 평가)

  • Ha, Min-Gyun;Jeong, Young Soo;Park, Seung hun;Ahn, Jin-Hee
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.7
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    • pp.16-24
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    • 2019
  • The corrosion amounts of steel structures can be different depending on their installation condition and height. Thus, their corrosion maintenance should be considered depending on installation conditions of local structural members. In this study, an atmospheric exposure test was conducted to evaluate the corrosion amount and the corrosion rate depending on the installation condition and height of a steel water gate using monitoring steel plates and corrosion environment measuring sensors. The mean corrosion depth was evaluated using the weight loss method and the galvanic corrosion current was measured by corrosion environment measuring sensors. Local corrosion rate of local structural member in steel water gate was estimated using measured mean corrosion depths and galvanic corrosion currents. From this measurement results, the corrosion damage in horizontal member of the cross beam was highly evaluated than those of other structural member as skin plate, etc. The relative difference in the corrosion rate of a local structural member could be highly affected by local corrosion environments of steel water gate members. Therefore, an appropriate maintenance method should be considered for local corrosion damages of local structural members determined by local corrosion environments of a steel water gate.

Corrosion Behavior and Effect of Alloying Elements of Fe-base and Ni-base Superalloys on Hot Molten Salt (고온 용융염에서 Fe기 및 Ni기 초합금의 부식거동 및 합금원소의 영향)

  • Jo, Su-Haeng;Jang, Jun-Seon;Jeong, Myeong-Su;O, Seung-Cheol;Sin, Yeong-Jun
    • Korean Journal of Materials Research
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    • v.9 no.10
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    • pp.985-991
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    • 1999
  • Corrosion behaviors of Incoloy 800H, KSA(Kaeri Superalloy)-6, Inconel 600 and Hastelloy C-276 in molten salts were investigated in the temperature range of 650 ~ $850^{\circ}C$. Due to $\textrm{Li}_{2}\textrm{O}$-induced basic fluxing mechanism, the corrosion rates of the alloys in mixed molten salt of LiC1-$\textrm{Li}_{2}\textrm{O}$ were significantly higher than those in molten salt of LiCl. In the mixed molten salt, Fe-base alloys showed higher corrosion resistance than the Ni-base alloys. and Hastelloy C-276 with high Mo and W contents exhibited the highest corrosion rate among the examined alloys. The single layer of $\textrm{LiCrO}_{2}$ was formed in molten salt of LiCl and two phase structure of a scale consisted of oxides and Ni was formed in the mixed molten salt.

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