• Title/Summary/Keyword: 부식현상

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Mechanical and Thermal Analysis of Oxide Fuel Rods

  • Ilsoon Hwang;Lee, Byungho;Lee, Changkun
    • Nuclear Engineering and Technology
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    • v.9 no.4
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    • pp.223-236
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    • 1977
  • An integral computer code has been developed for a mechanical and thermal design and performance analysis of an oxide fuel rod in a pressurized water reactor. The code designated as FROD 1.0 takes into account the phenomena of radial power depression within the pellet, cracking, densification and swelling of the pellet, fission gas release, clad creep, pellet-clad contact, heat transfer to coolant and buildup of corrosion layers on the clad surface. The FROD 1.0 code yields two-dimensional temperature distributions, dimensional changes, stresses, and internal pressure of a fuel rod as a function of irradiation time within a reasonable computation time. The code may also be used for the analyses of oxide fuel rods in other thermal reactors. As an application of FROD 1.0 the behavior of fuel rod loaded in the first core of Go-ri Nuclear Power Plant Unit 1 is predicted for the two power histories corresponding to steady state operation and Codition II of the ANS Classification. The results are compared with the design criteria described in the Final Safety Analysis Report and a discrepancy between these two values is discussed herein.

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Effect of Mg Content and Target Temperature on Corrosion and Adhesion Properties of Zn-Mg Coated steels (Mg 조성 및 타겟 온도 변화에 따른 Zn-Mg 도금강의 내식성 및 밀착성에 관한 연구)

  • Song, Myeon-Gyu;Ra, Jeong-Hyeon;Lee, Sang-Yul
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.88-88
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    • 2017
  • Zn코팅은 우수한 내식성과 경제성을 바탕으로 자동차나 건축자재 등 산업의 전반적인 분야에서 광범위하게 사용되고 있다. 하지만 최근 한정된 Zn의 매장량으로 인한 원자제의 가격상승과 습식 도금과정의 환경오염 물질 배출 문제가 기존 Zn 코팅의 약점으로 지적되고 있다. 따라서 새로운 원소의 첨가로 인한 Zn의 사용량 감소나 친환경적인 공정방법을 적용하는 연구가 대두되고 있다. 최근의 연구 결과에 따르면 Zn-Mg 합금이 다른 Zn계 합금에 비해 내식성이 우수하며, 이와 같은 우수한 내식성은 $Mg_2Zn_{11}$, $MgZn_2$와 같은 Mg-Zn 이원계의 합금상에 의한 것으로 알려져 있다. 따라서 본 연구에서는 친환경적인 비대칭 마그네트론 스퍼터 공정을 활용하여 다양한 공정조건 하에서 Zn-Mg 박막을 합성하여 최적의 공정 조건을 도출하고자 하였다. Zn-Mg 박막 합성 시 Mg타겟의 조성은 3~10 wt.%로 변화하였으며 Zn-Mg 합금 타겟의 온도를 제어하여 박막의 Mg 조성과 타겟 온도가 Zn-Mg 도금강의 내식성 및 밀착성에 미치는 영향을 평가하였다. 합성된 Zn-Mg 박막은 FE-SEM, EDS, XRD를 사용하여 미세조직, 두께, Mg 조성, 합금상 등을 분석하였으며, 염수분무시험 및 0T 굽힘 시험을 활용하여 Zn-Mg 박막의 내식성 및 내식성을 비교 분석하였다. FE-SE및 EDS분석 결과 Zn-Mg 박막의 Mg 조성은 합금 타겟의 조성이 증가함에 따라 증가하였으며, Mg 함량이 증가할수록 미세구조가 치밀하게 변화하였다. 또한 Zn-Mg 박막 합성 중 타겟의 온도가 상승할수록 박막의 치밀도는 감소하였다. XRD분석 결과 박막을 이루는 주요 합금상은 Zn상과 $Mg_2Zn_{11}$상이며 본 연구에서는 증착 조건에 따른 합금상의 큰 변화는 보이지 않았다. 염수분무실험 및 밀착성 평가 결과 박막의 미세조직이 치밀할수록 Zn-Mg 도금강의 내식성은 향상되었으나, 밀착성은 오히려 감소하는 경향을 나타내었다. 이러한 결과는 Zn-Mg 박막이 치밀한 미세구조일수록 부식환경에서의 강판에 대한 보호 효과는 증가하는 반면, 변형 시 박막의 파괴로 인한 박리 현상이 가속되기 때문으로 판단된다.

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Research for Investigation on the Browning of Paper due to the Corrosion of the Staples Used (스테이플러 철심에 의한 종이손상의 원인 연구)

  • Choi, Jungeun;Ha, Hyojin
    • Journal of Conservation Science
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    • v.29 no.2
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    • pp.103-110
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    • 2013
  • Since its development in the United Kingdom, the stapler has been used extensively to bind books. Staples comprising almost entirely of iron, first made in the early 1900s, are used to staple the cores of books. These staples change the colour of paper to brown and this browned paper ultimately crumbles. Basic research is being performed on solutions to prevent the deterioration in the quality of paper in the area around the staples. In this study, the cause of this browning of paper in the area was investigated. SEM-EDS, optical microscopy and FT-IR were used to analyze a browned area of three paper samples. It was found that the browned area had shortened fibres. In addition, iron was detected in this area. The corrosion of this iron led to this area of the paper being partially covered by iron(III) oxide, the product of the corrosion, as determined by FT-IR spectroscopy.

Effect of polyol on urethane to increase the cavitation resistance (우레탄수지에서 캐비테이션 저항을 높이기 위한 Polyol의 영향)

  • Lee, Iksoo;Kim, Nackjoo;Pak, Daewon
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.628-634
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    • 2014
  • In this study, a new paint which is able to resist the cavitation erosion is tried to be developed by using urethane added with polyol such as poly propylene glycol(PPG), poly carbonate diol(PCD), polycaprolactone polyol (PCL-1), and poly caprolactone-tetramethylene gylcolether polyol(PCL-2). The new paint synthesized by adding polyol was characterized with physical properties and resistivity to cavitation erosion. Among polyol, the prepolymer added with PCD showed high hardness and wear resistance. However, due to too high in viscosity, the prepolymer added with PCL-1 was selected as a paint. The paint added with PCL-1 showed high resistivity to cavitation erosion and its surface was monitored by using Scanning Electron Microscope.

Hydrogeological Characteristics of Seawater Intrusion in the Coastal Area (임해지역 주변에서의 해수침투특성)

  • 김천수;김경수;배대석;송승호
    • Journal of the Korean Society of Groundwater Environment
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    • v.4 no.2
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    • pp.61-72
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    • 1997
  • With increasing activities for groundwater withdrawal and for the construction of underground cavern in the coastal areas, the seaward flow of groundwater has been disturbed or even reversed, resulting in seawater intrusion in aquifers. This phenomenon would be attributed to the freshwater contamination and the corrosion of steel materials. The hydrogeological and geochemical investigations have performed to characterize the seawater intrusion into the underground caverns located in the coastal area. Assumimg the inland aquifer as unconfined one, we have found out that the theoretical interface of freshwater-seawater is far different from the pathways identified. In the study site, the main pathways of seawater intrusion into the underground cavern are characterized as the sub-horizontal fractures (zones). The seawater intrusion in granitic terrane would depend mainly on the characteristics of conductive fracture system developed along the coastal area.

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A Study on the VHCF Fatigue Behaviors of Hydrogen Attacked Inconel 718 Alloy (수소취화된 인코넬 718의 VHCF(Very High Cycle Fatigue) 피로특성에 관한 연구)

  • Suh, Chang-Min;Nahm, Seung-Hoon;Kim, Jun-Hyong;Pyun, Young-Sik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.7
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    • pp.637-646
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    • 2016
  • This study is to investigate the influence of hydrogen attack and UNSM on fatigue behaviors of the Inconel 718 alloy. The decrease of the fatigue life between the untreated and the hydrogen attacked material is 10-20%. The fatigue lives of hydrogen attacked specimen decreased without a fatigue limit, similar to those of nonferrous materials. Due to hydrogen embrittlement, about 80% of the surface cracks were smaller than the average grain size of $13{\mu}m$. Many small surface cracks caused by the embrittling effect of hydrogen attack were initiated at the grain boundaries and surface scratches. Cracks were irregularly distributed, grew, and then coalesced through tearing, leading to a reduction of fatigue life. Results revealed that the fatigue lives of UNSM-treated specimens were longer than those of the untreated specimens.

A Study on Electrochemical Polarization Test for Embrittlement Damage Evaluation of Aged Cr-Mo Steel (Cr-Mo강 시효재의 취화손상 평가를 위한 전기화학적 분극시험에 관한 연구)

  • Yu, Hyo-Sun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.19 no.6
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    • pp.411-419
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    • 1999
  • It has been well recognized that a long term service at elevated temperature of $350^{\circ}C{\sim}550^{\circ}C$ induces embrittlement damage due to carbide precipitation and/or P, Sb and Sn segregation at grain boundaries and thereby deteriorates the grain boundary strength of heat resisting components in the energy-related plants. Therefore, it is very important to assess quantitatively the extent of embrittlement damage of heat resisting components to secure the reliable and efficient service condition and to prevent brittle failure in service. However, because fracture tests are limited in size and number of specimen obtained from the structural components, nondestructive test method is required. In this study, the optimum electrochemical parameters are investigated and discussed to evaluate nondestructive embrittlement damage for aged 2.25Cr-1Mo steels by means of electrochemical polarization test method (ECPTM) in proper corrosive environment. In addition, the electrochemical test results are compared with embrittlement degree evaluated by semi-nondestructive SP test.

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Etching of MTJ (Magnetic Tunnel Junction) in an ICP Etching System for STT-MRAM applications

  • Park, Jong-Yun;Gang, Se-Gu;Jeon, Min-Hwan;Yeom, Geun-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.169-169
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    • 2011
  • STT-MRAM (수직자화 자기메모리)는 자화반전 현상을 원리로 구동하는 비휘발성 메모리로 기존의 메모리 장치에 비해 빠른 접근 속도와 높은 저장 밀도를 가지며 영구적인 기록이 가능하다. 이러한 장점들에 더해 적은 소모 전력을 지니므로 기존의 SRAM등의 한계를 극복할 대안으로 각광받고 있으며 차세대 메모리 군의 선두주자로 가장 적합한 후보중 하나이다. STT-MRAM의 건식 식각 방식에 있어 가장 큰 이슈는 소자 구동에 핵심적인 역할을 하는 MTJ(Magnetic Tunnel Junction)의 식각이다. MTJ는 free layer, tunnel barrier, pinned layer 3개의 층으로 구성되어 있으며 양 끝 layer에는 강자성체인 CoFeB가 사용되고 tunnel barrier에는 절연층인 MgO가 사용되고 있다. 이러한 물질들은 기존의 반도체 소자에서는 사용되지 않았던 물질들로 기존 공정에서 사용되던 Cl2 based plasma etching에서는 측벽에 비화발성 반응물과 잔류 Cl2에 의해 부식이 발생하는 문제점이 드러나고 있다. 이러한 문제점을 해결하기 위한 새로운 대안으로 CO/NH3/Ar나 CH4/Ar 같은 새로운 가스 조합을 사용하는 연구가 진행되고 있다. 이러한 연구에 의해 기존의 Cl2 plasma를 이용한 식각에서 나타나는 문제점은 해결이 되었으나 또 다른 문제점들이 보고되고 있다. 본 연구에서는 stack MRAM sample을 사용하여 기존의 사용되는 Cl2/Ar plasma와 대안 gas인 CO/NH3, CH4/Ar plasma에서의 식각을 진행하였으며 실험 조건(gas 비율 변화, Bias power 변화, 식각 시간)에 따른 식각 속도의 변화나 식각 후의 profile에 대하여 관찰하였다. 이에 따라 식각후에 어떠한 차이점이 있는 지를 알아보았으며 CO/NH3나 CH4/Ar plasma에서 식각시 나타나는 문제점에 대하여도 조명해 보았다.

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Experimental and Numerical Analysis in the Surroundings of Impingement Baffle Plate of the Extracting Nozzle for Disclosing Shell Wall Thinning of a Feedwater Heater (급수가열기 추기노즐 충격판 주변의 동체감육 현상의 완화를 위한 실험 및 수치해석적 연구)

  • Jung, Sun-Hee;Kim, Kyung-Hoon;Hwang, Kyeung-Mo;Song, Seock-Yoon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.19 no.12
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    • pp.821-830
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    • 2007
  • Feedwater heaters of many nuclear power plants have recently experienced severe wall thinning damage, which will increase as operating time progresses. Several nuclear power plants in Korea have experienced wall thinning damage in the area around the impingement baffle-installed downstream of the high pressure turbine extraction steam line- inside number 5A and 5B feedwater heaters. At that point, the extracted steam from the high pressure turbine is two phase fluid at high temperature, high pressure, and high speed. Since it flows in reverse direction after impinging the impingement baffle, the shell wall of the number 5 high pressure feedwater heater may be affected by flow-accelerated corrosion. This paper describes the comparisons between the numerical results using the FLUENT code and the down scale experimental data on effect of geometry of the impingement baffle plate on the shell wall thinning. Additionally, a new type impingement baffle plate was installed above the impingement baffle plate in the feedwater heater and then the numerical and experimental study were performed in the same progress.

An Ecochemical Study on Soil Sickness (인삼 연작 장해의 발생 원인 구명을 위한 생태화학적 연구)

  • 이춘영;임선욱
    • Journal of Ginseng Research
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    • v.1 no.1
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    • pp.51-58
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    • 1976
  • The phenomenon of sail sickness in the continuous cropping of ginseng is n serious problem for the cultivation practices and is an unelucidated subject scientifically. Present study is concerned mainly with ecochemical search on the cause of soil sickness in the continuous cropping of ginseng and the obtained results are summarized as follows: The humic substances isolated from both cultivated and uneulvidated soils with ginseng were compared with respect to its IR spectra but any difference which may be causative of sail sickness between them was not detected. In contrast, same saponin-like substances extracted from the ginseng cultivate soil in root tone were detected but not from the uncultivated soil. Presumably. the saponin like substances in the soils are originate) from the ginseng radices and are accumulaetd in root zone year by year, while the interrelation between the root exudate of ginseng and soil sickness is still obscure. According to a survey on the distributive Pattern of microflora in rhizosphere of ginseng radices the number of fungi is relatively diminished with the cul tivation years, while the number of actinomycetes is increased. It is supposed that the soil sickness in the continuous cropping of ginseng has any correlation between the activities of microflora in rhizosphere and the reef exudates.

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