• Journal of the Korea Concrete Institute
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• v.18 no.3 s.93
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• pp.371-378
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• 2006

Recently sewage facilities mainly consisted of concrete structures are being deteriorated seriously by biodeterioration originated from sulfur-oxidizing bacteria. In this study, to prevent biochemical corrosion of the sewer concrete, antibiotics which prevent growth of sulfur-oxidizing bacteria were developed and antimicrobial performance of it was investigated. After that, to consider applicability of antibiotics to concrete, physical properties of concrete covered with antibiotics were investigated. As a results of the study, it was proved that the antimicrobial performance of antibiotics was available. Also compressive strength and bond strength of concrete didn't closely connected with antibiotics, and resistance to abrasion, water absorption, air permeability, carbonation, salt damage and chemical attack of concrete was improved remarkably by covering with it.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.79-79
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• 2018

마그네슘은 나트륨, 알루미늄과 함께 지구상에서 가장 풍부한 금속 중 하나로서 밀도가 약 $1.74g/cm^3$으로서 구조용 금속재료 중 가장 가볍고 우수한 비강도를 지니고 있으며, 우수한 열전도도, 전기전도도, 전자파 차폐능을 지닌다. 최근 마그네슘 및 그 합금은 항공기, 자동차, 전자제품, 기계류 및 생활용품 등에 쓰이고 있으며, 사용량 및 적용범위가 매년 급격히 증가되고 있는 추세이다. 그러나 마그네슘합금은 매우 낮은 표준 환원전위와 치밀하지 못한 표면 산화막으로 인하여 부식에 대한 저항성이 매우 취약하다는 한계를 가지고 있다. 따라서 마그네슘합금의 표면처리 가운데 부식에 대한 저항성을 보완할 수 있는 방법은 활발한 마그네슘합금의 응용에 필수적이다. 이러한 마그네슘합금의 내식성을 향상시키고자 전기화학적 플라즈마 전해 산화처리 (Plasma Electrolytic Oxidation)를 하게 되는데, 아노다이징, 화성피막처리 등 과 같은 기존의 산업적 표면처리 방안으로는 불가능한 수준의 표면경도를 확보할 수 있을 뿐만 아니라 두꺼운 산화피막 형성을 통해 이들 합금이 가진 기본적 취약점인 내식성 문제를 보완할 수 있는 장점이 있지만, 다공성 산화피막 형성만으로 기대할 수 있는 내식성 향상 효과가 매우 크지는 못하다. 따라서 다공성의 양극산화피막의 단점, 즉 다공성 물질로 부식성 물질의 이동을 허용할 수 있는 공간을 가지는 구조를 개선시킬 수 있는 추가적인 처리를 필요로 한다. 본 연구에서는 발수성 표면처리를 이용하여 다공성 구조물의 표면이 물에 대한 저항성을 가지도록 함으로써 초발수성 표면을 구현하고자 하였다. 이러한 방법은 기존의 후처리 방법인 봉공처리로는 얻을 수 없었던 다공성 구조물로의 부식성 물질의 침투를 억제할 수 있었으며, 상당한 수준의 내식성 향상 효과를 보여주었다. 또한 물에 대한 반발성은 표면에 물의 이동성을 높이는 효과를 보여주며 이로 인하여 자기세척 효과도 보여주었다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.144-144
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• 2016

플라즈마 전해 산화법(Plasma electrolytic oxidation)에 의해 형성된 코팅층은 특유의 기공구조로 인해 부식 환경에 노출 시 부식액의 침투가 급속히 이루어지는 단점이 있다. 이를 극복하기 위한 방법으로 유기코팅, sol-gel법, 폴리머 코팅 등에 의해 기공을 봉공(sealing)하는 방법이 제안되고 있다. 본 연구에서는 Al 합금의 플라즈마 전해 산화 처리 후 질산 세륨 수용액(Cerium nitrate solution)에 의한 봉공 효과를 확인하고자 하였다. PEO 코팅을 위한 전해액은 2g/L의 KOH와 $2g/L\;Na_2SiO_3$를 증류수에 용해시켜 준비하였다. PEO 코팅층은 Al 시편을 전해액 내에 위치시켜 양극으로 하고 STS를 음극으로 하여 $0.1A/cm^2$의 펄스 정전류밀도(주파수: 100Hz, 듀티비: 20%)를 15분 동안 인가하여 형성시켰다. 봉공을 위한 실링액은 증류수에 $0.3g/L\;H_2O_2$와 $1g/L\;H_3BO_3$를 첨가하고, $Ce(NO_3)_3$를 농도 변수로 첨가하여 준비하였으며, PEO 코팅 처리된 시편을 실링액에 침지하여 실링액의 농도와 침지시간을 달리하여 봉공을 실시하였다. 제작된 PEO 코팅층에 대해 SEM, EDS, XRD를 이용한 표면분석을 실시하였으며, 내식성을 확인하고자 동전위분극시험을 실시하였다. 연구 결과, 세륨 실링 처리된 PEO 코팅 층에서 미량의 세륨 성분이 검출되었으나, 세륨계 화합물 생성에 의한 마이크로 크기의 기공의 폐쇄는 관찰되지 않았다. 또한, 전기화학적 특성 평가 결과 실링 처리된 PEO 코팅층의 경우 Al 모재에 비해 2차수 정도 감소된 부식전류밀도를 나타내었다. 이 같은 내식성의 향상은 세륨 성분에 의한 부식 억제 효과 때문으로 판단된다.

• Corrosion Science and Technology
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• v.15 no.6
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• pp.303-310
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• 2016

The tap water used in Seoul was found to be corrosive. Its corrosivity was effectively reduced by that the additions of alkali agent such as NaOH, $Ca(OH)_2$ and corrosion inhibitor such as $H_3PO_4$. For the corrosion test, carbon steel pipe 50 m long was exposed to the drinking water produced by a pilot plant at $36.5^{\circ}C$, similar to the existing process where it takes about 20 minutes to reduce the initial chlorine content of 0.5 mg/L to 0.05 mg/L. $CO_2$ and $Ca(OH)_2$ was added not only to control the Langelier index (LI) above -1.0 and but also, to increase the duration time of residual chlorine by about 6 times. The persistence effect of residual chlorine was in the order of $H_3PO_4$ > $Ca(OH)_2$ > NaOH. Measurements of weight loss showed that corrosion inhibition was effective in order of $Ca(OH)_2$ > $H_3PO_4$ > NaOH > no addition, where the concentrations of $Ca(OH)_2$ and phosphate were 5 ~ 10 mg/L (as $Ca^{2+}$) and 1 mg/L (as $PO{_4}^{3-}$), respectively.

• Journal of the Korean Institute of Gas
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• v.6 no.1 s.17
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• pp.92-97
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• 2002

This paper was studied on corrosion characteristics of gas absorption refrigeration & hot water system using $LiBr-H_2O$ working fluids. In the $62\%$ lithium bromide solution at $60^{\circ}C$, polarization test of Cu, $10\%$ cupronickel($90-10\%$ Cu-Ni) and $30\%$ cupronickel($70-30\%$ Cu-Ni) tube was carried out. And polarization behavior, polarization resistance characteristics, open circuit potential, anodic polarization of heat exchanger tube for gas absorption refrigeration & hot water system were considered. The main results are as following: 1) Polarization resistance of heat exchange tubes appears high in order of $30\%$ cupronickel tube > $10\%$ cupronickel tube > Cu tube. B) Open circuit potential of cupronickel tube is more noble than that of Cu tube, and corrosion current density of cupronickel is controlled than Cu tube. 3) Potential of passive region of $30\%$ cupronickel tube is more wide than that of $10\%$ cupronickel tube, and the passivation critical current of $30\%$ cupronickel tube is lower than that of $10\%$ cupronickel tube.

• Conservation Science in Museum
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• v.11
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• pp.9-16
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• 2010

The National Chuncheon Museum has carried out a conservation process in order to prevent corrosion of the seated iron Śākyamuni Buddha statue from Goreyo Dysnasty for its exhibition. Before the conservation process, the surface of the artifact showed exfoliation and the artifact was damaged from rear to legs so exhibition was impossible. Therefore a process to get rid of pollution and to reinforce and protect the artifact was carried out. Before the reinforcing process, a basic test was carried out using micro crystalline wax type with reference to foreign and domestic experiment results. As a result, as wax(in xylene) 5wt% of Dongnam petrochemical Ltd. showed no efflorescence and little change in surface color and was convenient to use, it was chosen as a reinforcing agent and used to suppress corrosion. For the restoration of damaged parts, an internal support was made and used with an epoxy resin, allowing removable restoration, thus increasing effectiveness for exhibition.

• Journal of the Korea institute for structural maintenance and inspection
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• v.10 no.2
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• pp.67-75
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• 2006

Recently sewage facilities mainly consisted of concrete structures are being deteriorated seriously by biodeterioration originated from sulfur-oxidizing bacteria. In this study, to prevent biochemical corrosion of the sewer concrete, antibiotics which prevent growth of sulfur-oxidizing bacteria were developed and antimicrobial performance of it was investigated. After that, to consider applicability of antibiotics to concrete, physical properties of concrete spread with antibiotics were investigated. As a results of the study, it was proved that the antimicrobial performance of antibiotics was available. Also compressive strength and bond strength of concrete didn't closely connected with antibiotics, and resistance to abrasion, water absorption and air permeability of concrete was improved remarkably by spraying with it.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.10a
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• pp.229-232
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• 1998

Recently it has become general to use the inhibitor with a view to protecting corrosion of rebars in concrete. As the inhibitors used in construction works are almost made in America or Japan, we immediately need to begin home production of inhibitors. In this paper, to estimate the domestic anodic inhibitor of nitrite in comparison with foreign made inhibitor we made some fundamental experiments of setting time, slump and compressive strength. Besides, we analysed the effect of corrosion protection of inhibitor on the ground of corrosion current, resistance to chloride penetration and diffusion of chloride ingress in concrete.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.10a
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• pp.299-302
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• 1997

Generally the corrosion expansion of the steel due to outdoor corrosive environmental factor brings about serious problem on the durability of concrete structures. It is the purpose of this study to see whether adapted sacrificial anode method is effective or not. from the experimental results. the potential of steel in concrete in case of adapting the sacrificial anode method satisfies protection standard value (less than -850mV vs CSE).

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2011.06a
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• pp.21-22
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• 2011