• Korean Journal of Heritage: History & Science
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• v.56 no.2
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• pp.148-169
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• 2023

Hayeob pigment is known as one of the traditional dark green pigments, but the color, raw material, and manufacturing method have not been clearly identified. However, comparing the analysis results of the particle shape and constituent minerals of Hayeob pigments revealed through pigment analysis studies of colored cultural properties such as Dancheong, Gwaebul, and paintings, Hayeob pigments appear to be the same as Dongrok pigments produced by salt corrosion. Therefore, in order to restore Hayeob pigment, the manufacturing method of Dongrok pigment was studied based on the records of old literature. The Dongrok pigment manufacturing method confirmed in the old literature records is a natural corrosion method in which copper powder and a caustic are mixed and then left in a humid condition to corrode. Based on this, artificial corrosion using a corrosion tester was adopted to corrode the copper powder more efficiently, and an appropriate mixing ratio was selected by analyzing the state of corrosion products according to the mixing ratio of the caustic agent. In addition, the manufacturing method of Dongrok pigment was established by adding a salt removal process to remove residual caustic agents and a purification process to increase chroma during pigment coloring. The prepared Dongrok pigments have a bluish green or green color, show an elliptical particle shape and a form in which small particles are aggregated, and a porous surface is observed. The main constituent elements are copper(Cu) and chlorine(Cl), and the main constituent mineral is identified as atacamite [Cu₂Cl(OH)₃]. As a result of an accelerated weathering test to evaluate the stability of the prepared Dongrok pigments, it was found that the greenness partially decreased and the yellowness significantly increased as deterioration progressed. Before deterioration, the Dongrok pigments had lower yellowness compared to the Hayeob pigments of the old Dancheong, but after deterioration, yellowness increased significantly, and it was found to have a similar chromaticity range as Dancheong's Hayeob pigments. As a result, the prepared Dongrok pigments were confirmed to be similar to Dancheong's Hayeob pigments in terms of color as well as particle shape and constituent minerals.

• Journal of the Korea Concrete Institute
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• v.29 no.1
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• pp.109-116
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• 2017

The present study concerns quantitative assessment of chloride extraction, repassivation and structural behavior of concrete. Concrete specimen ($160{\times}160{\times}1000mm$) was fabricated with 3 steel bar located in the middle with 20 mm of the cover depth, containing 5.0% of chloride to accelerate corrosion process, then to be subjected to electrochemical treatment. The current density accounted for $750mA/m^2$ at 2, 4 and 8 weeks. As a result, it was found that an increase in the duration of the treatment resulted in an increase in the chloride extraction, accounting for 64.7-83.7% for the specimen at 8 weeks treatment. It implies that a portion of bound chlorides would turn free to be removed, considering the binding capacity of cement about 50-60% to total ones. Even after the treatment, the corrosion was still active; the corrosion rate was $6.5mA/m^2$ and 330 mV vs. SCE in the potential. For structural behavior, the maximum load was increased by corrosion on the steel bars, which was subsequently lowered by the treatment, but still higher than for control.

• Water for future
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• v.50 no.4
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• pp.30-35
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• 2017

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 1998.05a
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• pp.108-108
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• 1998

일반적으로 탄소강은 수용액 중에 노출될 경우 전면부식에 의한 손상을 받는다. 그러나 부식방지를 위하여 부식억제제를 적용할 경우, 탄소강의 부식거동은 현저한 변화를 겪게된다. 이러한 부식거동의 변화는 첨가되는 부식억제제의 종류에 따라 분 류할 수가 있는데, 양극부식억제제, 음극부식억제제 그리고 이들의 혼합부식억제제로 분류할 수가 있다. 현장에 적용된 부식억제제 시스템 중에는 자동차용 부동액과 가스히터용 열전달 매체액이 있다. 이러한 부식억제제가 적용된 시스댐은 정확한 부식억제능의 평가에 의한 그 교체 시기의 결정이 매우 중요하다. 교체 시기가 빠를 경우, 유지비용이 과다하게 소요되는 문제가 있으며, 교체시기가 늦을 경우 설비의 부식을 초래하는 문제 가 있다. 따라서 부식억제제의 정확한 성능 평가법은 매우 중요하며, 이에 대한 다양 한 연구가 진행 중이다. 부식억제제가 함유된 용액의 부식억제성능을 평가하는 방법에는 대표적으로 무게 감량법을 이용하고 있다. 이 방법은 다종의 금속이 적용된 자동차용 부동액을 실제 사용조건과 유사한 실험 조건에서 단기간, 가혹조건에서의 무게 감량에 의해 부식억 제능을 평가하는 방법이다. 그러나 이러한 방법은 특히 국부부식이 진행될 경우 부 식억제능을 정량화 하는데 어려움이 있다. 한편 전기화학적 측정방법으로는 분극곡선법을 이용한 $E_P$(공식개시전위), $E_R$(재부동태 화전위)의 측정법이 있다. 또한 부식억제피막의 안정성을 측정하기 위한 방법으로 인 위적인 양극전류 인가에 의한 피막의 파괴후에 피막이 복원가능 여부 및 그 속도 측 정에 의해 부식억제제의 건전성을 확인할 수가 었다. 본 연구에서는 가스히터의 주구성 재료인 A210 Gr Al의 탄소강을 사용하여, 사용기간이 5년 이상되어 부식억제 기능을 거의 상실한 것으로 여겨지는 열전달 매체액 과 신규 부식억제제가 적용된 시스템 등 객관적으로 확인된 부식억제제 시스랩에 대 하여 다양한 평가 방법을 동원 비교분석하고자 하였다. 실험은 KSM 2142에 의한 무게감량법, 분극곡선 측정에 의한 $E_P$(공식개시전위), $E_R$(재부동태화전위) 측정, 시간에 따른 자연전위 변화 측정 빛 이때의 부식속도(선형분극법), 인위적인 피막 파괴 전,후 의 전위 변화 및 부식속도 측정법에 의한 국부부식 발달 저지능 등을 평가하여 각 실험결과를 비교분석하여 보았다.

• Conservation Science in Museum
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• v.11
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• pp.9-16
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• 2010

The National Chuncheon Museum has carried out a conservation process in order to prevent corrosion of the seated iron Śākyamuni Buddha statue from Goreyo Dysnasty for its exhibition. Before the conservation process, the surface of the artifact showed exfoliation and the artifact was damaged from rear to legs so exhibition was impossible. Therefore a process to get rid of pollution and to reinforce and protect the artifact was carried out. Before the reinforcing process, a basic test was carried out using micro crystalline wax type with reference to foreign and domestic experiment results. As a result, as wax(in xylene) 5wt% of Dongnam petrochemical Ltd. showed no efflorescence and little change in surface color and was convenient to use, it was chosen as a reinforcing agent and used to suppress corrosion. For the restoration of damaged parts, an internal support was made and used with an epoxy resin, allowing removable restoration, thus increasing effectiveness for exhibition.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.4
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• pp.141-148
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• 2002

Repair were made for front pillar, center pillar and side-step panel for lightweight vehicles with head-on and 40% off-set collision of 15 km/h in a RCAR standard. The salt dilution was sprayed and the compression tests were performed for vehicles with and without anti-corrosional treatment after repair. After 764 hours of salt-dilt sprayed test without using anti-corrosion, the mean penetration depth fur corrosion was shown to be 58% of the thickness. The resulyed decrease in bending stiffness by 10∼20% can cause reduction of the residual life and crash-absorption capability for damaged vehicles. The corrosoin safety tests showed that the anti-corrosional treatment should be made to improve the safety characteristics for a or damaged car.

• Journal of Korea Soil Environment Society
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• v.4 no.1
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• pp.13-23
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• 1999

In this research, 3-hydroxypyridine(2-HP) metabolic ability of starving Arthrobacter crystallopoietes cell and the effect of humic acid on the metabolism of this starving cell were evaluated. 2-HP metabolic ability of exponential phase cell (acclimated cell) was much higher than that of lag phase cell (unacclimated cell) during starvation period. After 3 days of starvation, 2-HP half-life of the acclimated cell was 14 hours and that of the unacclimated cell was 46.5 hours. Humic acid enhanced the stability of 2-HP monooxygenase of starving co]1 and, after 2 days of starvation, the residual activity rate of this enzyme of the microbial cell starved in humic acid solution was 12% while the rate for control condition was 1.5%. After 14 days of starvation, 2-HP half-life for control condition was 43 hours and that for humic acid condition was 1.25 hour.

• Journal of Conservation Science
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• v.34 no.6
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• pp.503-515
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• 2018

Stupa of State Preceptor Jigwang at Beopcheonsa temple site, Wonju, was conserved and restored in 1957. It was necessary to assess the degree of damage to the used mortar and to provide objective data on the necessity of its removal. Therefore, the HCP(half-cell potential) measurement used in concrete fields was applied. Multi-regression analysis of HCP data, following the rapid corrosion test of the roofstone mortar used by the rebar, resulted in a high correlation of HCP values(0.86), depending on the amount of corrosion and cover depth used for the steel bar. As a result, high correlation values(0.86) for the coefficients of determination were derived. The showed that the measurement of the wet conditions -431 to -663 mV on the roofstone indicated a corrosion damage rate of 90% or more after removal and restoration.

• Korean journal of applied entomology
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• v.50 no.4
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• pp.267-278
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• 2011

This study was conducted to estimate the effects of fire intensity and recovery methods on coleopteran communities in three burned forests, Goseong, Gangneung, and Samcheok in Gangwon province, Korea. Four sampling sites were selected in each study area according to disturbance degree (DD) caused by fire intensity and recovery methods. DD in the study sites were categorized as 0 (no fire), 1 (weak fire), 2 (strong fire), and 3 (strong fire followed by human disturbance). Beetles collected by pitfall traps were classified into 3 functional guilds: detritivore, herbivore, and carnivore. Diversity and abundance were slightly higher in the burned sites (DD = 1-3) than in the unburned sites (DD = 0), although there was no statistical significance. Coleopteran communities differed according to fire intensity and recovery method. This suggests that recovery of burned forests using both natural recovery and reforestation may increase the diversity of coleopteran communities.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.6-6
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• 2018

본 연구에서는 고문헌에 기록된 도금 재료와 도금법 등을 확인하고 이를 기초자료로 활용하여 매실산을 사용한 금(Au)-수은(Hg) 아말감기법으로 고대 도금(鍍金)기술을 되살리고, 이를 토대로 경주 월지에서 출토된 금동삼존판불을 복원하였다. 먼저, 전통 도금법을 되살리기 위해서, "오주서종박물고변", "확지신편", 조선시대 각종 의궤 등에 공통적으로 기록되어 있는 매실에 주목하고, 매실을 3~4개월 발효 숙성 후 착즙한 뒤 그것을 농축하여 만든 매실산을 도금 실험에 적용하였다. 금아말감 도금을 위하여 월지 출토 금동삼존판불의 바탕소지금속인 청동삼존판불을 구리와 주석 89:11(Cu:6kg, Su:750g)로 합금하여 주물사 주조법으로 복원하였으며, 동일한 합금비로 제작된 $2.3cm{\times}3.5cm$(가로${\times}$세로)의 시편에 사전 실험을 실시하였다. 현대적 산처리 방식에 사용되는 질산과 전통방식으로 사용되는 매실산으로 시편에 산처리 한 후 각각 비교해 보고, 금분과 금박, 상온과 가온에 따른 아말감상태를 비교하는 실험을 진행하였는데, 실험에 사용된 매실산 70%는 pH가 1.94로, 오늘날 산처리에 사용하고 있는 질산 20%와는 차이가 있지만, 청동 시편 실험을 통해 매실산에 20분 정도 담근 뒤 금아말감을 도포 후 24시간 지나 가열($380{\sim}400^{\circ}C$) 했을 때 금도금이 잘 되어, 현대적 방법인 질산처리로 도금을 한 시편과 큰 차이가 없는 것으로 관찰되었다. 사전 실험을 통한 결과를 적용한 월지 출토 금동삼존판불 복원은 청동삼존판불 표면처리, 금-수은 합금 및 도금하기, 도금 후 표면처리의 순서로 진행되었는데, 금과 소지금속의 밀착력을 높이기 위해 표면을 숯을 이용해 탈지한 후 물로 씻어내고 매실산을 도포하여 20분 동안 두어 부식 및 세척을 시행하였다. 금도금을 위한 금-수은아말감은 가온할 때 수은이 증발하는 양을 고려하여 금1 : 수은10 비율로 합금하여 완성하였으며, 금아말감 도포 후 약 24시간 지난 다음, $380{\sim}400^{\circ}C$에 가열하여 수은을 기화시켜 도금작업을 완성하였다. 금아말감도금은 평균적으로 6~7차례 시행하여야 완벽히 도금되지만, 본 연구에서는 단 4차례의 도금만으로 금아말감도금을 완성시켰는데, 이것은 금아말감을 바탕소지인 청동에 도포한 후 24시간 동안 금아말감과 청동과의 반응 시간을 두게한 것이 큰 역할을 한 것으로 보이며, 이는 청동시편을 이용한 실험과 과학적 분석을 통하여 입증하였다. SEM으로 표면을 관찰한 결과 아말감 도포시간이 즉시인 경우 도금이 거의 되지 않은 것을 확인할 수 있었고 36시간이 넘어갈 경우 금 도금층이 불균일하게 관찰되었으므로 도금시간은 12시간~24시간 이내가 적절함을 확인할 수 있었다. EDS로 성분을 분석한 결과 산처리 시간이 20분인 시료의 경우 5 wt% 내외로 수은의 비율이 다른 시료에 비해 낮은 것을 확인할 수 있었다. 실험 및 분석결과 산처리 시간이 20분이고 아말감 도포시간이 24시간일 때 도금이 잘 이루어지므로 이 결과를 토대로 금동삼존판불을 복원하였다. 이번 연구를 통해 도금법에 표면을 세척하고 부식시키기 위해 사용한 물질이 매실산임을 찾아내어 확인할 수 있었는데, 이러한 점 에서 이 연구의 가장 큰 의미는 전통 소재와 기술을 복원한 것으로, 앞으로 매실산을 이용한 금 도금기술은 관련 학계에도 큰 기여를 할 것으로 기대된다.