• Korean Chemical Engineering Research
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• v.51 no.3
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• pp.358-363
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• 2013

Lithium-ammonia (Li-$NH_3$) solutions are possible to be successfully made under the vacuum condition but there still remains a problem of undergoing stable and reliable decomposition in vacuum for high-efficiency thermoelectric power generation. This paper describes a new method for improving the thermoelectric conversion efficiency of Li-$NH_3$ solutions in vacuum. The proposed method uses a 'U'-shaped Pyrex vacuum tube for the preparation and decomposition of pure fluid Li-$NH_3$ solutions. The tube is shaped so that a gas passageway ('U') connecting both legs of the 'U' helps to balance pressure inside both ends of the tube (due to $NH_3$ gasification) during decomposition on the hot side. Thermoelectric experimental results show that solution reaction in the 'U'-shaped tube proceeds more stably and efficiently than in the 'U'-shaped tube, and consequently, thermoelectric conversion efficiency is improved. It is also proved that the proposed method can provide a reversible reaction, which can rotate between synthesis and decomposition in the tube, for deriving the long-time, high-efficiency thermoelectric power.

• KDI Journal of Economic Policy
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• v.20 no.3_4
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• pp.175-222
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• 1998

본 논문에서는 우리나라 국방예산 운영의 국민경제적 파급효과에 대한 실증분석에 기초하여 국방예산 규모논쟁에 대한 검토, 지출구조의 개선방안, 그리고 지출구조 개성을 위한 국방부문의 효율화 방향을 제시하였다. 실증분석을 위해 Feder-Ram 2부문-외부효과모형에 기초하여 1970년대 이후 총국방비 운영유지비 방위력개선비 등 3가지의 국방부문 지표를 이용한 실증분석 결과, 방위력개선비가 국민총생산에 대해 유의한 정(正)의 효과를 갖는 것으로 나타났다. 총국방비의 경우 유의성이 없었으며, 운영유지비의 경우 유의한 부(負)의 효과를 갖는 것으로 나타났다. 국방예산 규모논쟁과 관련하여, 최근 GDP 대비 국방비 비중과 안보위협을 고려한 국가군별 비교 등을 통해볼 때, 지금까지의 우리나라 국방비규모의 상대적 비중이 하락하는 추세를 더 이상 기대하기는 어렵다고 보는 것이 현실적인 인식이라고 판단된다. 이제 국방예산 관련 논의의 초점은 상대적 규모를 포함하여 국방예산규모 자체보다는 국방예산의 지출구조와 내역에 맞추어져야 하고, 국방예산 운영의 낭비사례를 방지하고 효율성 투명성을 높여서 적절한 지출구조와 배분내역 방식을 이루는 것이 되어야 한다고 판단된다. 국방예산 지출구조의 개선을 위해서 투자비 성격의 방위력개선비 비중을 높이는 예산구조상의 개선이 매우 중요한 과제이다. 이를 위해 각종 경사경비에 대한 영점기준의 검토작업과 더불어 인력과 장비의 대체, 인력구조의 조정 등을 통해 기술집약형 전력구조를 지향하는 보다 근본적인 구조조정노력이 이루어져야 할 것이다. 미래전 양상에 대비한 군 첨단화의 핵심인 해상방위력 및 항공력 증강 등이 필수적이며, 지상군 위주에서 상대적으로 해 공군 중심의 군 구조로 개선되어야 할 것이다. 구조개선의 완급조절과 군별배분의 수평적 구조개선을 통해서 예산규모의 커다란 증대 압력 없이 추진 할 수 있는 구조개선은 시급히 실현되어야 할 것이며, 구조조정 재원의 상당부분은 군 내부의 낭비사례를 막고 생산성을 획기적으로 제고해서 확보할 수 있어야 할 것이다. 국방예산 운영의 효율성 투명성 제고를 위해서는 군 내부 자원관리기능이 강화되어야 하고, 군조직 운영에 있어서도 민간부문에 상응하는 경영효율성 개념의 과감한 도입이 요구된다. 지금까지의 '국방전력 극대화'를 위한 군인중심의 획일적 폐쇄적 군조직 운영에서 벗어나 조직 인사 예산 운영 전반에 걸친 경영혁신이 이루어져야 한다. 국방부문에 경영효율성 개념을 도입하여 경영혁신을 이루어나가는 주요 정책방향은 일부 기능 조직의 민영화 및 민간위탁의 확대, 민간전문인력의 활용도 제고, 자율적 책임경이 필요한 부문을 대상으로 한 "책임경영사업소(Agency)제도"의 도입 등이다. 또한 유사기능을 갖는 조직과 각군별로 별도로 설립되어 중복되는 기능을 수행하는 기관을 통폐합해야 할 것이다.

• Economic and Environmental Geology
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• v.34 no.2
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• pp.157-166
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• 2001

Numerous base-metal bearing hydrothermal quartz vein deposits occur in the Hunan province of southern China. The Tangguanpu lead-zinc-tin-silver mine is the major producer among these deposits. Lead-zinc-tin-silver mineralization occurs in a single stage of massive quartz veins which filled fractures in fault zones within Paleozoic metasedimentary rocks. Sphalerite, chalcopyrite, galena, pyrite, arsenopyrite and pyrrhotite are the principal sulphide minerals in the Tangguanpu lead-zinc ores with minor amounts of tin- and antimony-bearing sulphides (stannite, teallite, boulangerite and tetrahedrite). Based on the iron and zinc partitioning between coexisting stannite and sphalerite, the formation temperature for this mineral assemblage range from 300$^{\circ}$ to 330$^{\circ}$C, which relatively agree with the upper part of homogenization temperature of fluid inclusion in quartz (20T-358$^{\circ}$C). Fluid inclusion data show that main lead-zine-tin-silver mineralization occurred from $H_{2}O$-NaCl fluids with relatively low salinities (11.2-7.3 wl.% eg. NaCI) at temperatures between 207$^{\circ}$ and 358$^{\circ}$C. The relationship between homogenization temperature and salinity suggests a history of cooling and dilution followed by initial boiling. Evidence of initial fluid boiling may indicate the fluid trapping pressures of 180 bars. The ${\delta}^{34}S{{\Sigma}S}$ values of -5.0 to 1.1 %, indicate an igneous source of sulfur in the Tangguanpu lead-zinc-tin-silver hydrothermal fluids.

• Journal of the Korean Society of Safety
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• v.11 no.4
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• pp.143-150
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• 1996

This is an explicit-Implicit, finite element analysis for linear as well as nonlinear hygrothermal stress problems. Additional features, such as moisture diffusion equation, crack element and virtual crack extension(VCE ) method for evaluating J-integral are implemented in this program. The Linear Elastic Fracture Mechanics(LEFM) Theory is employed to estimate the crack driving force under the transient condition for and existing crack. Pores in materials are assumed to be saturated with moisture in the liquid form at the room temperature, which may vaporize as the temperature increases. The vaporization effects on the crack driving force are also studied. The Ideal gas equation is employed to estimate the thermodynamic pressure due to vaporization at each time step after solving basic nodal values. A set of field equations governing the time dependent response of porous media are derived from balance laws based on the mixture theory Darcy's law Is assumed for the fluid flow through the porous media. Perzyna's viscoplastic model incorporating the Von-Mises yield criterion are implemented. The Green-Naghdi stress rate is used for the invariant of stress tensor under superposed rigid body motion. Isotropic elements are used for the spatial discretization and an iterative scheme based on the full newton-Raphson method is used for solving the nonlinear governing equations.

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.2
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• pp.68-75
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• 2018

In this study, to solve the problems of the conventional crack repair and injection method, high elasticity latex was used as the material of the storage tube to withstand the high pressure in the center part differently from the general port. When the repair solution was injected into the crack part, The TPS method was developed so that the air existing in the TPS can be discharged. In addition, a new infusion port in which a valve blocking the backflow of the remediation solution was installed at the injection port was developed and the physical characteristics of the port were analyzed. As a result of the evaluation, it was found that the filling rate of the remedial solution was improved compared to the existing ordinary injector method, and the cracks were completely filled in the test conditions. Compressive strength and tensile strength after repair showed about 20% decrease after repair in case of using ordinary injector method, while TPS method showed about 2~7% increase after repair. The results of this study showed that the injection port method using the elastic storage tube increased the injection performance and the quality after repair compared to the conventional injector method. The result of this study is expected to be utilized as the basic data for application and commercialization of the result to the practical structure.

• Tunnel and Underground Space
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• v.27 no.3
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• pp.132-145
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• 2017

Shock loss was not applied for the tunnel ventilation of road tunnel in the past. However, pressure losses due to the shock loss can be significant in network double-deck road tunnel in which combining and separating road structures exist. For the optimum ventilation design of network double-deck road tunnel, this study conducted 3D CFD numerical analysis for the shock loss at the combining and separating flows. The CFD model was made with the real-scale model that was the standard section of double-deck road tunnel. The shock loss coefficient of various combining and separating angles and road width was obtained and compared to the existing design values. As a result of the comparison, the shock loss coefficient of the $30^{\circ}$ separating flow model was higher and that of the two-lane combining flow model was lower. Since the combining and separating angles and road width can be important for the design of shock loss estimation, it is considered that this study can provide the accurate design factors for the calculation of ventilation system capacity. In addition, this study conducted 3D CFD analysis in order to calculate the shock loss coefficient of both combining and separating flows at flared intersection, and the result was compared with the design values of ASHRAE. The model that was not widened at the intersection showed three times higher at the most, and the other model that was widened at the intersection resulted two times higher shock loss coefficients.

• Korean Journal of Materials Research
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• v.9 no.12
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• pp.1245-1251
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• 1999

Phase-change optical disk very rapid recording, high densification of data, resulting in high feedback rate and good C/N(carrier to noise) ratio of a feedback signal. However, repetitive thermal energy may cause the deformation of a disk or the lowering of an eliminability and a cyclability of the recording. The lowering of the cyclability can be reduced by insertion of thin layer of ZnS-$SiO_2$ dielectric thin film in appropriate disk structure between the upper and lower part of the recording film. Using the Taguchi method, optimum conditions satisfying both the optimized quality characteristic values and the scattering values for film formation were found to be the target R.F. power of 200W, the substrate R.F. power of 20W, the Ar pressure of 6mTorr, and the electrode distance of 6cm. From the refractive index data, the existence of the strong interaction between the electrode distance and Ar pressure was confirmed, and so was the large effect of the electrode distance on transmittance. According to the analysis of TEM and XRD, the closer the electrode distance was, the finer was the grain size due to the high deposition rate. However, the closer electrode distance brought the negative effect on the morphology of the film and caused the reduction of transmittance. AFM and SEM analyses showed that the closer the electrode distance was, the worse was the morphology due to the high rate of the deposition. Under optimum condition, the deposited thin film showed a good morphology and dense microstructure with less defects.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.32 no.5
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• pp.287-296
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• 2019

In this study, the effect of ground boundary conditions on the evaluation of blast resistance performance of precast arch structures was evaluated by a numerical analysis method. Two types of boundary conditions, namely, fixed boundary conditions and a perfectly matched layer (PML) were applied to numerical models. Blast loads that were much higher than the design load of the target structure were applied to compare the effects of the boundary conditions. The distribution and path of the ground explosion pressure, structural displacement, fracture of concrete, stress of concrete, and reinforcing bars were compared according to the ground boundary condition settings. As a result, the reflecting pressure shock wave at the ground boundaries could be effectively eliminated using PML elements; furthermore, the displacement of the foundation was reduced. However, no distinct difference could be observed in the overall structural behavior including the fracture and stress of the concrete and rebar. Therefore, when blast simulations are performed in the design of protective structures, it is rational to apply the fixed boundary condition on the ground boundaries as conservative design results can be achieved with relatively short computation times.

• Journal of the Korean Institute of Gas
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• v.25 no.3
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• pp.27-38
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• 2021

We devised the system to automatically shutdown the boiler and to fundamentally block the harmful gases, including carbon monoxide, into the indoor when the exhaust system swerves: (1) The discharge pressure of the exhaust gas decreases when the exhaust pipe is disconnected. The monitoring system of the exhaust pipe is implemented by measuring the output voltage of APS(Air Pressure Sensor) installed to control the amount of combustion air. (2) The operating software was modified so that when the system recognizes the fault condition of a flue pipe, the boiler control unit displays the fault status on the indoor regulator while shutting down the boiler. In accordance with the ventilation facility standards in the "Rules for Building Equipment Standards" by the Ministry of Land, Infrastructure and Transport, experiments were conducted to ventilate indoor air. When carbon monoxide leaked in worst-case scenario, it was possible to prevent poisoning accidents. However, since 2013, the number of indoor air exchange times has been mitigated from 0.7 to 0.5 times per hour. We observed the concentration exceeding TWA 30 ppm occasionally and thus recommend to reinforce this criterion. In conclusion, if the flue pipe fault detection and the indoor air ventilation system are introduced, carbon monoxide poisoning accidents are expected to decrease significantly. Also when the manufacturing and inspection steps, the correct installation and repair are supplemented with the user's attention in missing flue, it will be served to prevent human casualties from carbon monoxide poisoning.

• Korean Chemical Engineering Research
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• v.57 no.4
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• pp.475-483
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• 2019

Special chemical warfare agents are lethal gases that attack the human respiratory system. One of such gases are blood agents that react with the irons present in the electron transfer system of the human body. This reaction stops internal respiration and eventually causes death. The molecular sizes of these agents are smaller than the pores of an activated carbon, making chemical adsorption the only alternative method for removing them. In this study, we carried out a Computational Fluid Dynamics simulation by passing a blood agent: cyanogen chloride gas through an SG-1 gas mask canister developed by SG Safety Corporation. The adsorption bed consisted of a Silver-Zinc-Molybdenum-Triethylenediamine activated carbon impregnated with copper, silver, zinc and molybdenum ions. The kinetic analysis of the chemical adsorption was performed in accordance with the test procedure for the gas mask canister and was validated by the kinetic data obtained from experimental results. We predicted the dynamic behaviors of the main variables such as the pressure drop inside the canister and the amount of gas adsorbed by chemisorption. By using a granular packed bed instead of the Ergun equation that is used to model porous materials in Computational Fluid Dynamics, applicable results of the activated carbon were obtained. Dynamic simulations and flow analyses of the chemical adsorption with varying gas flow rates were also executed.