• Proceedings of the Korean Society For Composite Materials Conference
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• 1999.04a
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• pp.217-220
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• 1999

• Journal of the Korean Society for Nondestructive Testing
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• v.21 no.3
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• pp.299-306
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• 2001

In this paper, artificial and real defects(delamination and debond) in composite structures were detected by using ESPI system. Three types of specimens, that is, composite laminates, honeycomb structures, and adhesive joints, were used to study the applicability of ESPI to composite structures. To detect defects in specimens, we selected thermal loading method that can easily induce the surface deformation of specimen. Experimental results show that defects in composite structures could be easily detected by ESPI. Moreover, it shows that ESPI could be usefully applied to the detection of defects in various composite structures.

• 한국신재생에너지학회:학술대회논문집
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• 2009.11a
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• pp.180-183
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• 2009

Composite bipolar plates offer several advantages of low cost, light weight, and ease of manufacturing compared to traditional graphite plate. However, it is difficult to achieve both high electrical conductivity and high flexural strength. In this study, the hybrid carbons filled epoxy composite bipolar plates were fabricated to test electrical conductivity and flexural properties. Graphite powders were used as the main conducting filler and continuous carbon fiber fabrics were inserted to improve the mechanical properties of the composite. This hybrid composite showed improved in-plane electrical conductivity and flexural property. The moldability of the hybrid composite was also improved comparing to the continuous prepreg composite. This study suggested that the continuous carbon fiber inserted graphite/epoxy composites can be a potential candidate material to overcome the disadvantages of conventional graphite composite or continuous prepreg composite bipolar plates.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.10
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• pp.4673-4678
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• 2011

In this paper, studies on a mixing characteristic and viscosity measurement of polymer/graphite composites for a bipolar plate of the polymer electrolyte membrane fuel cell were presented. Since the materials for the bipolar plate should be electrically conductive, contents of solid graphite in the composite are very high. As a consequence, a viscosity of the polymer/graphite composite used for the bipolar plate is very high and the measurement of the viscosity is difficult. Viscosity measurements of the polymer/graphite composites were not possible because pressure drops were continuously fluctuated during the viscosity measurements when a conventional capillary die was used. After the die design was optimized, the steady state pressure drop could be achieved, but the viscosity thus measured was not reproducible. After many trials with different experimental techniques, it was found that melt blending of the grinded powder mixtures of both PET and graphite provides reproducible viscosity measurements and electric conductivities of the polymer/graphite composites.

• Composites Research
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• v.14 no.1
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• pp.8-14
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• 2001

A simplified method for determining the three mode(I, II, III) components of the strain energy release rate of free-edge delaminations in composite laminates is proposed. The interlaminar stresses are evaluated using the interface moment and the interface shear forces which are obtained from the equilibrium equations at the interface between the adjacent layers. Deformation of an edge-delaminated laminate is analysed by using a generalized quasi-three dimensional classical laminated plate theory. The analysis provides closed-form expression for the three components of the strain energy release rate. The analyses are performed for composite laminates subjected to uniaxial tension, with free-edge delaminations located symmetrically and asymmetrically with respect to the laminate midplane. The analysis results agreed with a finite element solution using the virtual crack closure technique.

• Journal of the KSME
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• v.32 no.1
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• pp.4-17
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• 1992

이 글에서는 복합적층판의 역학적 특성인 층간분리, 모재균열, 초기파손 후의 거동에 대한 문헌을 간단히 서술하고 그 특성을 살펴 보았다. 이상에서 살펴본 바와 같이 이방성인 층으로 구성된 복합적층 구조의 역학적 특성은 균질인 단일구조와 달리 각층의 재료상수가 달라층과 층 사이의 층간응력이 존재하여 층간분리현상이 발생하지 않도록 섬유방향뿐만 아니라 적층순서를 중요한 설계변수로 고려하여야 한다. 또한 모재균열로 인한 기계적 거동의 변화를 이해하고 초기파손 후의 손상을 고려한 해석을 수행하여 복합적층 구조의 응력해석 및 파손, 강도예측을 한다.

• Composites Research
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• v.32 no.6
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• pp.327-334
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• 2019

The delamination is a special mode of failure occurring in composite laminates. Several numerical studies with finite element analysis have been carried out on the delamination behavior of unidirectional composite laminates. On the other hand, the fracture for the multi-directional composite laminates may occur not only along the resin-fiber interface between plies known as interply or interlaminar fracture but also within a ply known as interyarn or intralaminar fracture accompanied by matrix cracking and fiber bridging. In addition, interlaminar and intralaminar cracks appear at irregular proportions and intralaminar cracks proceeded at arbitrary angle. The probabilistic analysis method for the prediction of crack growth behavior within a layer is more advantageous than the deterministic analysis method. In this paper, we analyze the crack path when the mode I load is applied to the cross-ply carbon/epoxy composite laminates and collect and analyze the probability data to be used as the basis of the probabilistic analysis in the future. Two criteria for the theoretical analysis of the crack growth direction were proposed by analyzing the stress field at the crack tip of orthotropic materials. Using the proposed method, the crack growth directions of the cross-ply carbon/epoxy laminates were analyzed qualitatively and quantitatively and compared with experimental results.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.5
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• pp.3627-3632
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• 2015

We investigated mechanical, rheological and electrical properties of graphite/PP/LCP composites for a bipolar plate of the polymer electrolyte membrane fuel cell. The composites containing very low molecular weighted PP showed much higher electrical conductivity compared with other thermoplastics. This was attributed to the enhanced dispersion of graphite particles due to the low viscosity of the PP. The conductivity of the composites was increased in a great extent by incorporation of small amount of carbon nano tube (CNT). However, the acid treated CNT which contains oxygen atoms did not increase the conductivity of the composite. From this result, it is concluded that the CNT has higher affinity with non polar polymer. The composite with low molecular weighted PP provided good processability so that the composites can be processed by an injection molding while the mechanical strength is deficient compared to other polymers. In order to reinforce the low mechanical property, LCP/PP was used as a binder and the graphite/PP/LCP composite showed the higher conductivity and moderate mechanical strength maintaining suitable processability.

• Composites Research
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• v.12 no.4
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• pp.8-16
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• 1999

In this study, when the applied directions of tensile loading is changed fatigue damage of quasi-isotropic composite laminates was discussed. Low cycle fatigue tests of $[0/-60/+60]_s$ laminates and $[+30/-30/90]_s$ laminates were carried out. Material systems used were AS4/Epoxy and AS4/PEEK. The fatigue damage of $[+30/-30/90]_s$ laminates differed from that of $[0/-60/+60]_s$ laminates. The position of delamination generated at AS4/Epoxy and AS4/PEEK $[+30/-30/90]_s$ laminates appeared differently according to the kind of matrix. Critical values of strain energy release rate were obtained by using the strain measured at the initiation of delamination. The experimental results agreed well with the results obtained by the proposed method for determining strain energy release rate.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.166-166
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• 2011

연료전지 핵심 부품 가운데 하나인 분리판(Bipolar plate)는 막전극체(MEA), 기체확산층(GDL)과 함께 발생한 전류의 수집 및 전달, 반응 가스의 수송, 반응/생성물의 수송 및 제거, 반응열 제거 등을 위한 냉각수 전달 등의 다양한 역할을 담당한다. 이러한 역할을 위하여 분리판은 우수한 전기전도성, 열전도성, 화학적 안정성이 요구되어 진다. 기존의 연료전지용 분리판은 흑연계 소재 및 수지와 흑연을 혼합한 복합 흑연 재료를 통해 제조하여 요구 되어지는 물성을 만족시켜 왔으나 흑연계 분리판의 경우 강도 및 가스 밀폐성 측면에서 낮은 특성을 보이며 특히 고가의 제조 공정 비용과 낮은 양산성으로 인하여 자동차 연료전지 상용화에 수많은 해결 과제를 안고 있었다. 흑연계 분리판의 이러한 문제점을 대체하기 위한 연구로 최근 금속계 분리판의 적용 및 개발이 활발하게 진행되고 있다. 특히 금속계 분리판은 양산 제조 공정이 적용 가능하여 대량생산이 가능하며 자동차 연료전지 스택의 경량화 및 박판화가 가능하다는 장점을 가지고 있다. 그러나, 박판의 스테인리스강을 소재로 적용한 금속분리판의 양산을 위하여 반드시 선행되어야 할 연구가 바로 금형 코팅 연구이다. 일반 자동차 생산 금형을 평균 약 50만타로 예측한다면 연료전지 금속계 분리판 성형 금형의 현재 수명은 약 10만타로 추정 가능하다. 이러한 원인은 고하중의 프레스 사용과 정밀 금형으로 인한 극한 공정 조건으로 야기된 결과이며 문제 해결을 위하여 성형 금형에 PVD 코팅 적용 연구를 진행하였다. 성형 금형의 PVD 코팅 적용을 통하여 금형 교체 주기 감소를 통한 생산 원가 절감 및 이형성 개선을 통한 성형성 확보를 목표로 본 연구를 진행하였다.