• Title/Summary/Keyword: 보존처리제

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Performance Improvement of Hydrogenated Bisphenol-A Epoxy Resin/Inorganic Additives Composites for Stone Conservation by Controlling Their Composition (석조문화재 보존을 위한 HBA계 에폭시 수지/무기 첨가물 복합체의 혼합조건에 따른 성능 개선 연구)

  • Choi, Yong Seok;Lee, Jung Hyun;Jeong, Yong Soo;Kang, Yong Soo;Won, Jongok;Kim, Jeong-Jin;Kim, Sa Dug
    • Journal of Conservation Science
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    • v.28 no.3
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    • pp.265-276
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    • 2012
  • Physicochemical properties of HBA epoxy resins were controlled by varying hardener mixture and reactive diluent to improve applicability for stone conservation. The epoxy risen comprises hydrogenated Bisphenol-A based epoxide (HBA), fast curing agent (FH), slow curing agent poly(propyleneglycol)bis(2- aminopropylether) (SH) and difunctional polyglycidyl epoxide (DPE). Talc was used as an inorganic additive. The changes in viscosity and temperature during curing reactions depending on the composition of the epoxy resins were investigated. Additionally, bending, tensile and adhesive strengths were measured to identify the effective mechanical strength in stone conservation. Finally various compositions of epoxy resin/inorganic additives were developed for stone conservation by controlling cure kinetics and mechanical properties.

A Study on Manufacturing Techniques and Conservation Treatment for Yongjam, Ceremonial Hairpin with a Dragon-shaped Engraving in 17th Century - Focusing on Yongjam of the Clothes Worn by Oejae Yi Dan-ha and His wife, National Folklore Cultural Heritage No.4 - (17세기 대례용 용잠의 제작기법 조사와 보존처리 - 국가민속문화재 제4호 외재 이단하 내외옷 용잠을 중심으로 -)

  • Ryu, Dongwan;An, Boyeon;Lee, Ryangmi;Lee, Jaesung;Park, Yeonghwan;You, Harim
    • Journal of Conservation Science
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    • v.37 no.3
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    • pp.270-281
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    • 2021
  • The Yongjam of Oejae, Yi Dan-ha's wife, is an ornamental hairpin with a dragon-shaped engraving; designated as National Folklore Cultural Heritage No. 4. It is also a component of the ceremonial costume, and an artifact of great value as it clearly identifies the position of the wearer and the period of this artifact. The Yongjam has been well preserved in general; however, various pollutants and corrosive products have affected the engraved patterns, requiring conservation treatment. Furthermore, a non-destructive analysis was conducted to identify the components of the materials and the manufacturing techniques used in the ornament. The Yongjam is hollow inside to reduce its weight when placed in the hair and has a color contrast of gold, red, and black. The decorative part and the body were made separately. That is, the body was made from an alloy of copper, silver, and zinc, and its joint was elaborately connected without any overlaps. In the decorative part, different alloy ratios were identified in the dragon's face, beard, horn, body, and fin. Further, for the dragon's face with its delicate patterns, an alloy of silver and copper was used, likely to make the face appear as realistic as possible.

A Study on the Application of SILRES BS OH 100 Consolidants for Shale (셰일에 대한 SILRES BS OH 100 강화제 적용연구)

  • Lee, Sang-Jin;Kim, Jin-Hyung;Do, Jin-Young
    • Journal of Conservation Science
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    • v.21
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    • pp.33-40
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    • 2007
  • The consolidation application of SILRES BS OH 100 was investigated, which has been used for consolidation of the weathered shale. The liquid SILRES BS OH 100 was polymerized by the sol-gel reaction with air moisture, and the XRD patterns showed that the gel was an amorphous solid. The drastic weight reduction of the sample was found by differential thermal analysis, which was followed to the formation of $Si(OH)_4$ particles. After consolidation, the polymerized gel was filled into the voids within the shale. The capillary water absorption of the consolidated shale was reduced to 48.7%, and the abrasive strength was improved.

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Scientific Conservation Treatment of the Celadon Jar with the Inscription of 'the Fourth Sunhwa Year'(National Treasure No.326) (국보 제326호 청자 '순화4년'명 항아리의 과학적 보존처리)

  • Lee, Sun Myung;Kwon, Oh Young;Park, Jongseo;Han, Woo Rim
    • Journal of Conservation Science
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    • v.35 no.5
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    • pp.453-469
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    • 2019
  • The celadon jar with inscription of 'the Fourth Sunhwa Year' is an important chronology that shows the conditions of production of the early celadon due to the inscription on the bottom including its purpose, application, and the producer. This celadon jar has been restored several times in the past. However, concerns over the structural stability, such as the separation and level differences in the joined cracks, have risen because of the aging of the repair materials, which were subjected to various environmental changes over a long time. By examining the conditions of preservation, the major damage was identified as the '入' shaped crack on the front, the 'V' shaped restored part and the crack on its left side, and the 'J' shaped crack on the back side. In the past, the cracks were found to be joined using a refined lacquer containing camphor, drying oil, rosin, etc. mixed with soil powder. The joint line was repainted with the refined lacquer and covered with gold powder. The missing parts were restored with gypsum and colored with acrylic color. After that, the repair materials were aged and emergency treatment was performed at the National Museum of Korea in 1981. At that time, Cemedine C or Cemedine C mixed with microballoons was used for reinforcing the cracks. Conservation treatment focused on removing the past repair materials and reinforcing the physically fragile parts by joining and restoring them based on the examination of the preservation condition. in addition, the area around the restored part was colored for future exhibition.

Application Experiments of Consolidation Treatment for Pelitic Sedimentary Rocks: Bird Track Fossils in Haman Formation (점토질 퇴적암의 강화처리 적용실험 연구: 함안층 새발자국 화석지)

  • Lee, Gyu Hye;Lee, Chan Hee;Yang, Hye Ri
    • Economic and Environmental Geology
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    • v.53 no.1
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    • pp.87-98
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    • 2020
  • The bird track fossil site in Haman Formation is divided into seven sedimental layers by the sedimentary structures, lithofacies and sequences. The bird tracks top on the highest layer, which includes ripple marks and suncracks. The layer has lithofacies with reddish grey siltstone and dark grey mudstone, alternately. As an analysis for the same rocks of the fossil site, physical properties show on mean values for 0.62% of absorption rate, 1.64% of porosity and 2.63 of specific gravity. Rock-forming minerals composed mainly of plagioclase, quartz, calcite, chlorite and mica. Meanwhile, we executed an experiments based on the petrography and weatherings to find a proper consolidants. In the experiments, the OH 100 reagent proved stable aspect and the lowest transition rate in terms of weight and chromaticity. Also, it showed the highest increase in ultrasonic velocity, improving the physical properties of the rocks. In the case of applying the OH 100 with antihygro, an swelling inhibitors on the sedimentary rocks, the chromaticity indicated an stable transition aspect. When it comes to the physical properties, the antihygro also decreases the porosity effectively. Thus, the most proper method for the fossil site of Haman Formation is to apply antihygro and OH 100 reagents since the rocks includes clay minerals that show swelling characteristics. However, this result is deduced from an indoor application experiments, leaving the necessity of verification how these reagents would affect the bird tracks site under the field condition.

Effect of Consolidation using Artificial Porous Material for Stone Cultural Property (인공 다공질체를 이용한 석조문화재 강화제의 처리효과)

  • Lee, Jae-Man;Lee, Myeong-Seong;Kim, Jae-Hwan;Lee, Mi-Hye
    • Journal of Conservation Science
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    • v.26 no.3
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    • pp.325-334
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    • 2010
  • In order to clarify the effect of consolidant, the artificial porous material with low intensity was manufactured using granite powder and Portland cement. We have prepared four kinds of alkoxysilane system consolidants, a acrylic resin and a epoxy resin and investigated about characteristics before and after consolidation. As a result of the research, Silres BS OH 100 was effective for density and surface hardness. SS-101 with hydrophobicity and Site SX-RO with hydrophilicity had the good durability over salts weathering. On the other hand, Syton HT-50 and Paraloid B72 were easily destructed by salt weathering because they were concentrated on surface area by the low penetration depth. Araldite 2020 was the most effective consolidant for improvement of physical properties.

In vitro Long Term Conservation of Potato Germplasms (감자 유전자원의 기내 장기보존 방법)

  • Yi, Jung-Yoon;Cho, Hyun-Mook;Park, Kuen-Woo
    • Horticultural Science & Technology
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    • v.16 no.4
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    • pp.508-510
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    • 1998
  • This study was carried out to establish the in vitro culture system of potato germplasms for minimizing the occurrence of variation and maximizing the culture period. We used osmoticum such as sorbitol or mannitol with sucrose in the absence of plant growth regulators. The growth of potato germplasms in the medium containing osmoticum was increased when the growth temperature was lowered. After six months storage in low temperature, plant heights of tetraploid was somewhat higher than those of diploid with the exception of stn-16 and the difference due to media was not observed. But after twelve months storage, survival rates of plants cultured in LSM 1(sucrose and sorbitol) was higher than those of plants cultured in LSM 2(sucrose and mannitol). The survival rate of stn-16, diploid wild species, was approximately 75% and it was considerably high. In Atlantic, tetraploid cultivated variety, every individual was survived.

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Petrological and Conservational Scientific Deterioration Assessment of the Chungung-dong 5-Storied Stone Pagoda, Hanam City, Korea (하남시 춘궁동 오층석탑의 암석학적 및 보존과학적 훼손도 평가)

  • 이찬희;서만철;채상정;정연삼;이효민
    • Economic and Environmental Geology
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    • v.37 no.2
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    • pp.225-234
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    • 2004
  • The Chungung-dong 5-storied pagoda (Treasure No. 12) in the nnm, Korea was studied on the basis of petrological weathering and deterioration diagnosis. Frontal part of the pagoda is looked out on the N30$^{\circ}$W. Constitution rocks of this pagoda show augen gneiss and biotite granite. Host rock of the pagoda was highly exfoliation and discoloration, therefore most rock-forming minerals were altered to the clay minerals due to the mineralogical and chemical weathering. Open cavity and rock surface occur partly green and black patchs because of contamination by algae, lichen and moss, and the lower part of the pagoda is transition to the some weeds. This biological problems are need for cleaning and chemical treatments. For the structural stability, the pagoda is rebuilt without open gap between the each rock materials. All iron plates eliminate from the difference gap of the rock materials, and properly conservation treatments need to be repaired petro-filler for stone cultural properties and water curtain for the humidity attenuation of the ground.

Effect of Talc Content on the Physical Properties of the Epoxy Resins in Conservation Treatment of Stone Monument (석조문화재 보존처리용 에폭시수지 물성에 미치는 탈크 함량의 영향)

  • Kim, Da-Ram;Do, Jin-Young
    • Journal of Conservation Science
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    • v.25 no.1
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    • pp.77-86
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    • 2009
  • The physical properties of the epoxy resins were studied with an addition of filler content and the application of artificial weathering test. When talc as a filler was added to the epoxy resin (L-30), the water resistance seemed to be increased because of the results of the reducing of water absorption rate and the increasing of contact angle. Although the adhesive strength of epoxy resins was not affected by the increasing amount of talc, its compressive strength was reduced. The physical properties of the epoxy resins had different trends according to the site environments. The artificial weathering test with the change of temperature and humidity showed that the changes of water absorption rate and colour differences of the epoxy resins containing talc were lower than the pure epoxy resin itself. However, the contact angle was higher. The artificial weathering test with ultraviolet irradiations showed the opposite result; the damage of epoxy resins was increased with the increasing of talc content. These mean the site environment of the stone monuments should be considered to determine the content of talc added to increase the durability of epoxy resin.

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