• Polymer(Korea)
• /
• v.25 no.2
• /
• pp.240-245
• /
• 2001

The effect of additives on the orientation of magnetic Sr-ferrite powders has been studied during powder injection molding under applied magnetic field for fabricating multi-pole anisotropic sintered Sr-ferrite magnets. The orientation of the Sr-ferrite powders depends sensitively on the fluidity of powder-binder mixture, related to the binder additives and the injection molding temperature, and the magnetic field intensity. The orientation of Sr-ferrite powders is good for the compacts with stearic acid added in the binder system of paraffin wax/carnauba wax/HDPE, but it is poor for the compacts with silane coupling agent added. The orientation of Sr-ferrites higher than 80% is achieved at the following useful conditions; apparent viscosity lower than 2500 poise in 1000 sec$^{-1}$ shear rate and applied magnetic field higher than 4 kOe.

• Polymer(Korea)
• /
• v.30 no.4
• /
• pp.362-366
• /
• 2006

It was found by polarized FTIR spectroscopic studies that pentacene molecules are arranged with their molecular axes perpendicular to the substrate surface when pentacene films are deposited on a polyimide alignment layer. The ring plane in a pentacene molecule is arranged parallel to the rubbing direction of the polyimide alignment film while no specific arrangement of vertically deposited pentacene molecules was found for the film without rubbing. The pentacene band at $1296cm^{-1}$ which has a transition dipole moment parallel to the ring plane is much stronger in a polarized IR spectrum of parallel to the rubbing direction, whereas the band at $908cm^{-1}$ whose transition dipole align normal to the ring plane shows much stronger intensity in a spectrum of perpendicular to the rubbing direction. These findings indicate that orientation of polyimide chains affects the arrangement of pentacene molecules when they are deposited on a polyimide alignment film.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.02a
• /
• pp.78-78
• /
• 2011

수열합성법을 이용하여 Si(111) 기판에 ZnO 박막을 성장하였다. ZnO 박막의 성장을 위한 씨앗층은 plasma-assisted molecular beam epitaxy (PA-MBE)를 이용하였다. 씨앗층의 표면 거칠기(root-mean-square roughness)는 2.5 nm이고, 씨앗층 위에 성장된 ZnO 박막은 다양한 크기의 입자들로 이루어져 있었으며 두께는 약 $1.8{\mu}m$로 매우 일정하였다. 배향성을 알아보기 위하여 texture coefficient (TC)를 계산해 보았다. TC(100)과 TC(200)은 a-축 배향성을, TC(002)는 c-축 배향성을 나타내는데, c-축으로 더 우세한 배향성(99.5%)을 보였다. TC 비율(TCa-axis/TCc-axis)은 열처리 온도를 $700^{\circ}C$까지 올렸을 때, 점차적으로 증가하였고, 그 이상의 열처리 온도(< $900^{\circ}C$)에서는 급격히 감소하였다. 잔류응력과 Zn와 O의 bond length도 유사한 경향을 보였다. $700^{\circ}C$까지 열처리 온도가 증가함에 따라, 잔류응력은 증가하였고 bond length는 감소하였다. Near-band-edge emission (NBE)의 피크 강도는 열처리 온도가 $700^{\circ}C$까지 증가함에 따라 점차적으로 증가하였다. 열처리 온도가 $800^{\circ}C$ 이상 증가함에 따라 deep-level emission (DLE)가 적색편이(red-shift)하였다. $700^{\circ}C$로 열처리를 한 ZnO 박막이 가장 우세한 (002)방향의 배향성을 보였을 뿐만 아니라 가장 큰 발광효율 증가를 보였다.

• Journal of the Korean Ceramic Society
• /
• v.37 no.10
• /
• pp.981-986
• /
• 2000

Er(NO$_3$)$_3$.5$H_2O$, Mn($CH_3$$CO_2$)$_2$.4$H_2O$를 출발원료로 사용하여 졸-겔법으로 제조한 ErMnO$_3$박막의 열처리 온도 및 기판 배향성에 따른 박막 배향성과 누설 전류 특성에 관하여 연구하였다. ErMnO$_3$박막은 75$0^{\circ}C$ 이하의 온도에서 1시간 열처리 시비정질상태였으나, 78$0^{\circ}C$ 이상의 온도에서 hexagonal pahse인 ErMnO$_3$로 결정화되었다. 열처리 온도가 증가할수록 기판 배향성과 무관하게 모든 방향으로 결정이 성장함을 알 수 있었다. 결정화 정도와 결정 성장 축에 따라 누설 전류 값이 변화함을 알 수 있었고, 80$0^{\circ}C$에서 열처리한 시편에서는 누설 전류 변화가 비선형적인 경향으로 증가하였으며, $10^{-5}$ A/$ extrm{cm}^2$ 이하로 유지되었다.

• Proceedings of the KIEE Conference
• /
• 2003.07c
• /
• pp.1439-1441
• /
• 2003

전기절연재의 구조재로 많이 사용되고 있는 FRP(fiber reinforced plastics)는 열경화성 수지를 접착성 결합제(binder)로 하고 고강도 섬유를 보강재로 한 복합재료로서 기계적, 화학적, 전기적 특성이 매우 우수하다. FRP의 기계적 강도는 유리섬유에 의존 하고 있으므로 유리섬유의 방향과 힘을 가하는 방향에 따라서 그 강도의 차이는 매우 크게 나타난다. 본 연구에서는 섬유의 배향에 따른 강도의 변화를 이해하기 위하여 시편을 제작하여 압축강도를 측정하고 압축강도와 응력의 분포를 유한요소법으로 시뮬레이션하였다. FRP rod에 압축응력이 가해졌을 때 섬유의 배향에 따른 파괴강도와 응력의 분포를 유한요소법을 이용하여 시뮬레이션하였고 모델링에는 3-D Shell과 3-D Brick 요소를 사용하였다. 제작된 시편의 강도특성과 시뮬레이션을 통한 응력의 분포를 서로 비교하여 시편의 파괴에 미치는 응력을 고찰하였다.

• Composites Research
• /
• v.32 no.6
• /
• pp.403-407
• /
• 2019

Long-fiber-reinforced composites have the advantages of cost-competitiveness and high degree of freedom of molding compared to continuous-fiber-reinforced composites. On the other hand, it is difficult to ensure uniform characteristics due to the randomly distributed fiber orientation incurred from the process of manufacturing intermediate materials. In this study, the effect of the directionality of LFPS (Long Fiber Prepreg Sheet) materials on the mechanical properties was analyzed. The eddy current measurement method was used to analyze fiber orientations, and tensile and compression tests on LFPS materials were performed according to ASTM standards. In addition, the test results and theoretical values of LFPS materials were verified using the ROM (rule-of-mixtures) theory. These results confirmed the effect of fiber orientation on mechanical properties of discontinuous-fiber-reinforced composites.

• 기계와재료
• /
• v.23 no.3
• /
• pp.82-95
• /
• 2011

다결정압연판재는 열가공공정을 거쳐서 생산되므로 공정의 특성을 반영하는 미세조직/집합조직 특성을 가지게 된다. 결정립들은 특정방향으로 배향하고 결정립의 형상과 크기도 변화한다. 이러한 변화는 거시적으로 다결정판재의 이방성으로 귀결이 되는데, 근본적으로 판재를 구성하는 단결정들의 기계적 물성이 각각의 방향별로 이방성을 띄기 때문이다. 본 자료에서는 압연공정시 다결정판재의 수직/평면이방성의 발생원인을 집합조직과 결정소성학을 이용하여 제시하고자 하였다.

• Journal of the Korean Ceramic Society
• /
• v.41 no.7
• /
• pp.513-517
• /
• 2004

Porous alumina ceramics with aligned plate-shaped pores were fabricated by using thermoplastic microsphere in order to show the anisotropy in thermal conductivity. The mixed powder of alumina and microsphere was pressed under 15 MPa till 20$0^{\circ}C$ to deform polymer into platelet-shape and sintered at 1,00$0^{\circ}C$ for 1 h. The sintered specimen with 10 wt% microsphere has 45.3% porosity and the bending strength of 44 MPa. The microstructural investigation confirmed the pore structure of platelet-shape, the thermal conductivities for vertical and parallel directions are 3.803 W/mK and 7.818 W/mK, respectively, the ratio between two directions exceeds 2.

• Journal of the Korean Wood Science and Technology
• /
• v.29 no.1
• /
• pp.22-30
• /
• 2001

Composites with various layer constructions involving the ratio of S/P were produced from wood strands(S) and particles(P) (Cryptomeria japonica D.Don) to measure various Young's moduli and anisotropy by ultrasonics. As a result, static Young's moduli of composites were almost same as dynamic Young's moduli obtained from natural frequency. However, these were smaller than those evaluated from ultrasonic wave propagation velocity. The differences between propagation velocity of the parallel(${\parallel}$) and perpendicular(${\bot}$) in-plane direction resulted in a tendency of anisotropy. The tendency of anisotropy was larger in three-layer constructions than in seven-layer constructions. The differences of strand surface layers showed larger values than those of particle surface layers. Also, composites with higher weight ratio of strand had a tendency to propagate rapidly in each direction. In contrast to these results, the propagation velocity in the thickness direction had a tendency to propagate rapidly in composites with particle surface layers and the lower weight ratio of strand.

• Journal of the Korean Ceramic Society
• /
• v.25 no.3
• /
• pp.268-276
• /
• 1988

Ba or La-Substituted lead niobate $(Pb_{1-x}Ba_x)_{1-y}La_{2y/3}Nb_2O_6$(PBLN), powders having needle shape are prepared by flux method using KCl and the effect of Ba or La substitution on morphology of obtained powders is examined. From these needle shape powders, grain-oriented ceramics are made by doctor-blade method and two-stage hot-pressing technique. The dielectric, piezoelectric and optical properties of the ceramics are also investigaated. Heating condition and the amount of substituted Ba or La have remarkable effects have large anisotropy in both permittivity and coupling factor depending on the pressing direction.