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고무소재의 열응력

  • Gang, Sin-Yeong;Hong, Chang-Guk
    • Rubber Technology
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    • v.11 no.1
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    • pp.12-26
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    • 2010
  • 각종 산업제품의 주요 부품으로 사용되고 있는 고무재료는 사용 중 온도변화에 의해 체적 또는 길이 변화를 수반할 수 있어 결과적으로 고무제품의 성능이나 효율이 영향을 받게 된다. 특히 고온에서 고무제품의 치수변화를 제한하거나 일정치수를 강제할 경우 열수축이나 열팽창에 의해 응력이 발생하게 된다. 따라서 온도 변화에 따른 열응력의 측정은 고무제품의 정밀성과 성능을 평가하는 중요한 수단을 제공한다. 본 연구에서는 고무소재의 열응력 측정을 위한 새로운 측정방법을 개발하였고 이와 관련 새로운 시험장치를 설계, 제작하였다. 고무시편에 일정 변형의 인장을 준 상태에서 가열하면 열응력이 발생한다. 이 때의 열응력은 고무분자 사슬들의 운동성에 기인하며 배향된 고무분자 사슬들이 열역학적으로 랜덤 사슬형태로 돌아가려는 엔트로피적 힘이다. 따라서 온도가 높을수록 그 수축력은 증가하게 된다. 또한 고무분자 사슬의 사전 변형이 증가하면 그 열응력은 증가한다. 이때 열응력은 측정시간이 지남에 따라 최대치에 도달한 후 완화되며 그 완화속도는 설정온도에 의해 영향을 받는다. 여기서는 온도변화에 따른 고무시편의 열응력 측정결과를 소개하고, 고무분자 사슬의 엔트로피 변화와 점탄성적 흐름, 그리고 가열에 따른 고무 시편의 팽창 또는 수축이 열응력에 미치는 영향 등을 논의하였다. 특히 천연고무와 SBR 고무시편의 열응력 차이를 분자사슬의 운동과 연관하여 검토하였고, 가교밀도와 가교시스템이 각각 다른 고무시편에 대해 열응력 발생과에 따른 상관관계를 고찰하였다. 또한 시편의 형태와 두께가 열응력 발생에 미치는 영향도 검토하였다. 충전 배합고무의 경우 열응력에 영향을 미치는 인자로 고무분자 사슬의 운동성과 가교밀도 외에 고무재료와 충전제 사이의 물리 화학적 상호작용도 매우 중요한 요소가 된다. 배합고무에서 충전제의 영향을 검토하기 위해 실리카와 카본블랙을 선택하였고 배합고무의 열응력을 각각 측정하여 이들의 보강효과가 열응력에 미치는 영향에 대해 논하였다.

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Effects on the Inclusion of the Pigment in Performance of Color Asphalt Mixture (안료의 혼입이 유색 아스팔트 혼합물 싱능에 미치는 영향 연구)

  • Park, Tae-Soon;Jeon, Man-Sik
    • International Journal of Highway Engineering
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    • v.10 no.4
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    • pp.181-187
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    • 2008
  • This paper presents the results of the effects on the inclusion of the pigment in the color asphalt mixture. The particle size of the pigment is extremely finer than that of the filler and should be reduced the amount of the filler used. It was found in the present practise that the total weight of 2% of the pigment in the weight of the total aggregate was used during the mix design. The extra inclusion of the pigment in the mixture increased the amount of the filler and affected on the volumetric properties such as void ratio and VMA. It has related with the performance and distress of the pavement and found that the mechanical properties have decreased.

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An Experimental Study on the Manufacturing and Application of High-Workable Concrete (고유동콘크리트의 제조 및 현장적용을 위한 실험적 연구)

  • 윤재환;차태환;홍순조;권지훈
    • Magazine of the Korea Concrete Institute
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    • v.8 no.2
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    • pp.109-117
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    • 1996
  • Recently, High-Workable Concrete has been developed and began to be used to a great extent in foreign countries, but it is not familiar with and fully Introduced in Korea yet. Therefore the aim of this paper is to suggest a reference data. for the development of High-Workable Concrete according to the comparative analysis which were done on the effects of mix proportion(water-binder ratio, sand-aggregate ratio, unit water, a kind of superplasticizer) on the flowing characteristics. And also this paper aims to examine the compactability and segregation resistance of High-Workable Concrete in a mock-up test and in a field test. From the result, we concluded that it is possible to produce and to use the High-Workable Concrete at the construction site.

토양세정기법의 유류 오염토양 적용을 위한 기초 연구

  • 소정현;최상일;조장환
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.283-286
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    • 2002
  • 유류로 오염된 부지에 토양세정기법을 적용하기 위한 전 단계로, 실험실 규모의 컬럼실험을 통하여 pilot 규모 현장 적용을 위한 설계인자 및 최적 운전조건을 규명하고자 적정 세척제 종류와 농도, 배합비 및 세정용액 주입유량을 고찰하였다. 회분식실험 결과 POE$_{14}$와 SDS(1:1)를 1%로 적용한 흔합계면활성제의 효율이 가장 우수하였으나, 예비실험 결과 음이온계 계면활성제인 SDS는 미생물에 독성을 끼치는 경향이 있는 것으로 나타나 같은 농도에서 효율이 거의 유사한 POE$_{5}$와 POE$_{14}$ 혼합계면활성제를 이용하여 실험하였다. 선정된 혼합계면활성제를 적용하여 디젤 오염토양 세척능력을 검토한 결과 세척제 농도 1%까지는 효율이 증가하다가 1% 이상의 농도에서는 다시 감소하는 경향을 나타내었으며, 계면활성제 배합비는 1:1로 혼합하였을 경우 세척효율이 가장 우수하였다. 따라서 POE$_{5}$와 POE$_{14}$ (1:1) 1% 혼합계면활성제를 세척제로 선정하였다. 컬럼실험 결과, 주입 flux가 클수록 세정 제거된 총 유류의 양이 증가하였으며, 같은 pore volume의 세정용액 통과 시에는 flux가 작을수록 제거효율이 좋았다.

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A Study on the Optimal Mixture Ratio for Stabilization of Surface Layer on Ultra-soft Marine Clay (초연약 해성점토의 표층고화처리를 위한 최적배합에 관한 연구)

  • 천병식;고경환;김진춘
    • Journal of the Korean Geotechnical Society
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    • v.18 no.4
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    • pp.33-43
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    • 2002
  • Recently, as large constructions on the coast increase, an application of a surface layer stabilization method which is one of the improvement methods for dredged soft clay has increased. However, there are few studies about this. The purpose of this study is clarifying characteristics of ultra-soft marine clay and hardening agent. Also, it is verifying an optimal mixture ratio of hardening agent through the laboratory tests according to designed experiments and proving by statistical analysis and pilot tests. Laboratory tests were performed with proper hardening agent and test soil in accordance with the design of experiments. Regression equations between hardening agents materials and unconfined compressive strength were derived from the tests. The applicability of regression equations were also verified by pilot tests. From the test results, it was found that hardening agent materials(cement, slag, fly-ash, inorganic salts, arwin, gypsum etc.) have some effect upon compressive strength. The optimal mixture ratio which satisfies the required compressive strength was derived from the statistical analysis. The effect of ground improvement by cements and hardening agents was confirmed through the pilot tests. This study will suggest data for design or construction criteria of stabilization of surface layer on ultra-soft marine clay.

Optimized Mixing Design of Lightweight Aerated Concrete by Response Surface Analysis (반응표면분석법에 따른 경량기포콘크리트 최적배합 도출에 관한 연구)

  • Lee, Sang-An;Jung, Chan-Woo;Kim, Wha-Jung;Ahn, Jung-Hyun
    • Journal of the Korea Concrete Institute
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    • v.21 no.6
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    • pp.745-752
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    • 2009
  • This paper presents the optimized mixing design of lightweight aerated concrete using hydrogen peroxide. Design of experiments in order to the optimized mixing design was applied and commercial program (MINITAB) was used. Statistical analysis was used to Box-Behnken (B-B) method in response surface analysis. The influencing factors of experimental are unit cement content, water ratio and hydrogen peroxide ratio. According to the analysis of variance, at the hardened state, water ratio and hydrogen peroxide ratio affects on dried density, compressive strength and bending strength of lightweight aerated concrete, but unit cement content affects on only dried density. In the results of response surface analysis, to obtain goal performance, the optimized mixing design for lightweight aerated concrete using hydrogen peroxide were unit cement content of 800 kg/$m^3$, water ratio of 44.33% and hydrogen peroxide ratio of 10%.

Optimization Model for the Mixing Ratio of Coatings Based on the Design of Experiments Using Big Data Analysis (빅데이터 분석을 활용한 실험계획법 기반의 코팅제 배합비율 최적화 모형)

  • Noh, Seong Yeo;Kim, Young-Jin
    • KIPS Transactions on Computer and Communication Systems
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    • v.3 no.10
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    • pp.383-392
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    • 2014
  • The research for coatings is one of the most popular and active research in the polymer industry. For the coatings, electronics industry, medical and optical fields are growing more important. In particular, the trend is the increasing of the technical requirements for the performance and accuracy of the coatings by the development of automotive and electronic parts. In addition, the industry has a need of more intelligent and automated system in the industry is increasing by introduction of the IoT and big data analysis based on the environmental information and the context information. In this paper, we propose an optimization model for the design of experiments based coating formulation data objects using the Internet technologies and big data analytics. In this paper, the coating formulation was calculated based on the best data analysis is based on the experimental design, modify the operator with respect to the error caused based on the coating formulation used in the actual production site data and the corrected result data. Further optimization model to correct the reference value by leveraging big data analysis and Internet of things technology only existing coating formulation is applied as the reference data using a manufacturing environment and context information retrieval in color and quality, the most important factor in maintaining and was derived. Based on data obtained from an experiment and analysis is improving the accuracy of the combination data and making it possible to give a LOT shorter working hours per data. Also the data shortens the production time due to the reduction in the delivery time per treatment and It can contribute to cost reduction or the like defect rate reduced. Further, it is possible to obtain a standard data in the manufacturing process for the various models.

Compaction Characteristics of Reactive Material for Absorption of Underground Oil Contaminant (지중 유류 오염물 흡수를 위한 반응재료의 다짐 특성)

  • Hong, Gigwon;Lee, Jai-Young;Oh, Seung-Jin;Kim Su-Hee;Park, Jeong-Jun
    • Proceedings of the Korean Society of Disaster Information Conference
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    • 2023.11a
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    • pp.337-338
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    • 2023
  • 본 논문에서는 유류 오염물의 흡수 반응이 가능한 반응재료에 대하여 지중 구조 재료로서의 적용성 검토를 목적으로 배합조건에 따른 다짐시험을 실시하였다. 다짐시험 결과, 주요 반응물질이 최적함수비에 미치는 영향은 미미하였으나, 최대건조단위중량의 영향인자로 평가되었다.

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A Study on the Factors Affecting Cigarette Weight (II) (담배의 중량변화 요인에 판하여 (제2보))

  • 진학용;김남원;안기영;이태호
    • Journal of the Korean Society of Tobacco Science
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    • v.1 no.2
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    • pp.127-137
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    • 1979
  • Three factors affecting cigarette weight, tobacco shreds length(cut width 0.9mm), moisture content and filling grower were studied for domestic brands. The results were obtained as follows. 1. When the moisture contents war법 changed by one per cent consecutively. filling power of tobacco shreds and cigarette weight were changed by 3.9 - 7.9 per cent for the former and by 5.7 - 7.6 per cent for the later. The longer the length of tobacco, shreds, the wider are the changing radios, and vice versa. 2. At constant moisture content (12 %), filling Power and cigarette weight were varied by 3.8- 22.8 per cent and by 2.9-29.4 per cent respectively due to the fluctuation of tobacco shreds length, The range of this variation was increased by reducing moisture content , and was decreased by increasing the moisture content. 3. The higher the blending ratio of shreds longer than 2 mm, the lower are the cigarette weights. 4. The operation standard weight of domestic brands was found 1- 9 per cent higher compared with the observed optimal cigarette weight in this study.

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An Experimental Study on Compressive Strength and the Chloride Content of Concrete with Substitution Ratio of Recycled Fine Aggregate and Limestone Power (순환잔골재 및 석회석 미분말 치환율에 따른 콘크리트 강도와 염화물량에 관한 실험적 연구)

  • Lee, Soo-Hyung;Kong, Tae-Woong;Jang, Jae-Hwan;Lee, Han-Baek
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.597-600
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    • 2008
  • Correspond in chloride content increase by sea sand uses of bad quality using recycled fine aggregate in this research. together, examined basic properties of matter for activation of been using recycled fine aggregate use definitely. Also, super fundamental principles that is shortcoming that blast furnace slag differential speech has prevents problem of decline and change of countenance limestone power differential speech by purpose to contribute in early age strength as Filler role special quality examine. As experiment result, compressive strength at recycled fine aggregate 10%, limestone power 20% metathesis the highest compressive strength value appear, According to recycled fine aggregate metathesis rate increase, the chloride content reduced by 0.127 ㎏/m$^3$s(metathesis rate 0%), 0.119 ㎏/m$^3$s (metathesis rate 10%), 0.112 ㎏/m$^3$s (metathesis rate l20%), 0.097 ㎏/m$^3$s (metathesis rate 30%).

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