• Korean Chemical Engineering Research
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• v.62 no.1
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• pp.99-104
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• 2024

In this study, a carbon coated hollow silicon (HSi/C) composite material was prepared for anode material of high-capacity lithiun-ion battery. Hollow silica (HSiO₂) was synthesized by the Stöber method with CTAB (N-Cetyltrimethylammonium bromide). The HSi/C anode composite was manufactured by carbon coating after magnesiothermic reduction of HSiO₂. The physical and electrochemical characteristics of the prepared anode materials were investigated based on CTAB amount. In the FE-SEM analysis, it was found that the HSiO₂ particle size increased as CTAB amount decreased, but shell thickness decreased. The HSi/C composites exhibited high initial discharge capacities of 1866.7, 2164.5 and 2188.6 mAh/g with various CTAB ratios (0.5, 1.0, 1.5), respectively. After 100 cycles of charge-discharge, 0.5-HSi/C demonstrated a high reversible capacity of 1171.3 mAh/g and a capacity retention of 70.9%. Electrochemical impedance spectroscopy (EIS) was employed to analyze the impedance characteristics, and it revealed that 0.5-HSi/C showed more stable resistance characteristics than HSi/C composites with other CTAB amount over 20 cycles.

• KEPCO Journal on Electric Power and Energy
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• v.5 no.3
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• pp.209-213
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• 2019

Recently, demand for high energy density and long cycling stability of energy storage system has increased for application using with frequency regulation (F/R) in power grid. Supercapacitor have long lifetime and high charge and discharge rate, it is very adaptable to apply a frequency regulation in power grid. Supercapacitor can complement batteries to reduce the size and installation of batteries. Because their utilization in a system can potentially eliminate the need for short-term frequent replacement as required by batteries, hence, saving the resources invested in the upkeep of the whole system or extension of lifecycle of batteries in the long run of power grid. However, low energy density in supercapacitor is critical weakness to utilization for huge energy storage system of power grid. So, it is still far from being able to replace batteries and struggle in meeting the demand for a high energy density. But, today, LIC (Lithium Ion Capacitor) considered as an attractive structure to improve energy density much more than EDLC (Electric double layer capacitor) because LIC has high voltage range up to 3.8 V. But, many aspects of the electrochemical performance of LIC still need to be examined closely in order to apply for commercial use. In this study, in order to improve the capacitance of LIC related with energy density, we designed new method of pre-doping in anode electrode. The electrode in cathode were fabricated in dry room which has a relative humidity under 0.1% and constant electrode thickness over $100{\mu}m$ was manufactured for stable mechanical strength and anode doping. To minimize of contact resistance, fabricated electrode was conducted hot compression process from room temperature to $65^{\circ}C$. We designed various pre-doping method for LIC structure and analyzing the doping mechanism issues. Finally, we suggest new pre-doping method to improve the capacitance and electrochemical stability for LIC.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.48 no.6
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• pp.455-466
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• 2020

In this study, we built a thermal model for SNIPE 6U nano-satellite which has scientific mission for measuring science data in near Earth space environment and described thermal design based on the thermal model. And the validity of the thermal design was verified through the on-orbit thermal analysis. The thermal design was carried out mainly on the passive thermal control techniques such as surface finishes, insulators, and thermal conductors in consideration of the characteristics of the nano-satellite. However, the components with narrow operating temperature range and directly exposed to the orbital thermal environments, such as a battery and thrusters, are accomodated with heaters to satisfy the temperature requirements. On-orbit thermal analysis conditions are based on the basic orbital conditions of the satellite, and thermal analysis was performed for Normal mode, Launch & Early Orbit Phase (LEOP), Safehold mode, and Maneuver mode which are classified by the power consumption and the attitude of the satellite according to the mission scenario. The analysis results for each mode confirmed that every component satisfies the temperature requirement. In addition, the heater capacity and duty cycle of the battery and thruster were calculated through the analysis results of the Safehold mode.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.3
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• pp.320-326
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• 2017

Multistage deep-drawing technology is used widely in the production of mobile phone battery cases to improve productivity and economy. To ensure adequate capacity and rigidity, such cases are fabricated as a rectangular cup with a high slender ratio. The multistage deep-drawing of a rectangular cup entails a high slender ratio, and the heights of the product sides may be non-uniform because of the complicated deformation mechanisms. This causes problems in product assembly that affects the surface quality of the case. This study examined a blank shape that minimizes the height variations of the product to resolve the aforementioned problems. Optimization design and analysis were performed to identify the shape that yields the least variation. The long and short sides of an oval blank were set as the design variables. The objective function was set to yield the lowest height difference, and the thickness reduction rate of the product was set to the target range. In addition, the height of the final shape was set as a constraint. The height difference was minimized successfully using the optimized design. The design process of the initial blank for all rectangular shapes can be automated in the future.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.45 no.1
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• pp.42-50
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• 2008

Unlike a cellular network, a mobile ad hoc network(MANET) is constructed only by mobile nodes without access point. Mobile nodes in MANET operate with scarce resources and restricted battery. If battery of intermediate node is exhausted, overall network might be diverged. Therefore, power-aware is really important. An on-demand multipath routing protocol which is proposed to compensate for shortcoming of on-demand single path routing protocol can reduce mute discovery overhead because route discovery starts only when all routes are disconnected. AOMDV(Ad hoc On-demand Multipath Distance Vector) which is on-demand multipath routing protocol based on AODV, reduces 40% of route discovery frequency. However, AOMDV have none of power-aware. So AOMDV have problem that route discovery for power exhaustion is not reduced at all. This paper proposes new power-aware path selection algorithm for AOMDV and scheme that broadcast REER packets when mobile node's battery can be gone. Performance comparison of proposed algorithm with AOMDV using ns-2 simulator shows that route discovery of proposed algorithm is reduced maximally 36.57% than AOMDV's.

• The KIPS Transactions:PartD
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• v.18D no.3
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• pp.179-184
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• 2011

Current mobile devices have surpassed its boundaries as a more communication tool to a smart device which provides additional features. These features have supported the smart life of its users, but have reached its limit from low-performance processors and short-battery time. These issues can be resolved b implementing higher performing hardware, but they come with a burden of high cost. This paper introduces a new way of managing computing resources in a mobile device by enhancing the quality of human-computer interaction. The real-speed felt by users are mainly influenced by the time it takes form a user's input to the device to display the completed result on the screen. Since the size of the screen for mobile devices are small, if the processor only fetch data to be used for displaying on screen, the time can be significantly reduced. MVC+Prefetch Controller pattern accomplished this goal by using the minimum amount of data from DB to fetch display and still manages to support high-speed data transfer to achieve seamless display. This idea has been realized by practice using Samsung mobile phone S8500, which demonstrated the superior performance on user's perspective.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.10
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• pp.86-92
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• 2016

A high-capacity battery installed in a hybrid vehicle or electric vehicle is used to power, or as a power supply for, electric sub-assemblies. In order to use a high-capacity battery as a power supply for electric sub-assemblies, such as an electronic control unit or for lighting, radio, and navigation, there is a need for a DC converter that changes a high voltage of 240-400V to a low voltage of 12-14V, which is done with a low-voltage DC-DC converter (LDC). An LDC undergoes long-term aging so as to reduce latent defects in the production process. With regard to the usual aging method, an LDC is a DC-DC converter. So, a DC power supply is connected and used as input, and a programmable DC electronic load is the output. For stable operation, a product having a larger capacity by 10% (compared to an LDC) is used, and has a structure where electric power is dissipated into 100% heat. So, there is a problem with volume, based on the use of two pieces of equipment to test the LDC, and another problem based on the generation of heat in the programmable DC electronic load. Hence, this paper suggests a load test method as a way of recycling, where a significant portion of the electricity dissipated as heat in a load tester is returned as input. The method realizes savings of 80% or more in the electricity dissipated as heat through improvement in the efficiency of the recycling load tester.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.9
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• pp.42-51
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• 2017

This paper deals with the power supply facility providing wireless power transmission for a type of electric vehicles called the on-line electric vehicle(OLEV) and proposes optimal protection coordination methods which analyze the faultsin the 60Hz and 20kHz bands using PSCAD/EMTDC, which is the typical commercial software for the distribution system. The simulation results show that the proposed methods can reduce the fault current by introducing an NGR (Neutral Ground Resistor) in the 60Hz band and prevent the malfunctioning of the protection device by installing a CT in the neutral wire in the 20kHz band when a ground fault occurs.

• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.593-599
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• 2017

In order to enhance ultra battery performances, the electrochemical characteristics of nano Pb/AC anode composite was investigated. Through nano Pb adsorption onto activated carbon, nano Pb/AC was synthesized and it was washed under vacuum process. The prepared anode materials was analysed by SEM, BET and EDS. The specific surface area and average pore size of nano Pb/AC composite were $1740m^2/g$ and 1.95 nm, respectively. The negative electrode of ultra battery was prepared by nano Pb/AC dip coating on lead plate. The electrochemical performances of ultra battery were studied using $PbO_2$ (the positive electrode) and prepared nano Pb/AC composite (the negative electrode) pair. Also the electrochemical behaviors of ultra battery were investigated by charge/discharge, cyclic voltammetry, impedance and rate capability tests in 5 M $H_2SO_4$ electrolyte. The initial capacity and cycling performance of the present nano Pb/AC ultra battery were improved with respect to the lead battery and the AC-coated lead battery. These experimental results indicate that the proper addition of nano Pb/AC into the negative electrode can improve the discharge capacity and the long term cycle stability and remarkably suppress the hydrogen evolution reaction on the negative electrode.

• Journal of the Korean Applied Science and Technology
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• v.34 no.2
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• pp.280-288
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• 2017

Nanocarbon base materials such as, graphene and graphene hybrid with high electrochemical performances have great deal of attention to investigate flexible, stretchable display and wearable electronics in order to develop portable and high efficient energy storage devices. Battery, fuel cell and supercapacitor are able to achieve those properties for flexible, stretchable and wearable electronics, especially the supercapacitor is a promise energy storage device due to their remarkable properties including high power and energy density, environment friendly, fast charge-discharge and high stability. In this study, we have fabricated flexible supercapacitor composed of graphene/conductive polymer composite which could improve its electrochemical performance. As a result, specific capacitance value of the flexible supercapacitor (unbent) was $198.5F\;g^{-1}$ which decreased to $128.3F\;g^{-1}$ (65% retention) after $500^{th}$ bending cycle.