• Title/Summary/Keyword: 배출농도

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Removal of Volatile Organic Silicon Compounds (Siloxanes) from Landfill Gas by Adsorbents (흡착제에 의한 매립가스 중 휘발성 유기규소화합물(실록산) 제거특성)

  • Seo, Dong-Cheon;Song, Soo-Sung;Won, Jong-Choul
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.9
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    • pp.793-802
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    • 2009
  • Adsorption properties were estimated for the organic silicon compounds (siloxanes) in an actual landfill gas (LFG) using adsorbents such as coconut activated carbon, coal activated carbon, silica gel, sulfur adsorbent, carbonized sludge, and molecular sieve 13X. Coconut activated carbon showed the highest removal efficiency of more than 95%. The desorption of hexamethyldisiloxane (L2) from the adsorbent, however, resulted in the remarkable concentration variation of the compound in the treated gas. Silica gel, which had high adsorption capacity for L2 in single substance adsorption experiment in the other study, could not remove the component in the actual landfill gas while it adsorbed well octamethylcyclotetrasiloxane (D4) and decamethylcyclopentasiloxane (D5) in the LFG. Therefore the elimination of hexamethyldisiloxane is an important factor to determine the level of total organosilicon compound in pretreated landfill gas. Moreover, the L2 from the actual landfill gas was effectively adsorbed by the serial adsorption test using two columns packed with coconut activated carbon which has the great capacity of siloxanes removal among others. In order to utilize efficiently LFG as a renewable energy, the emission and adsorptive characteristics of the substance to be treated should be considered for the organization, operation, and management of pretreatment process.

Performances of Anaerobic Sequencing Batch Reactor for Digestion of Municipal Sludge at the Conditions of Critical Solid-liquid Separation (혐기성 연속 회분식 공정에 의한 도시하수슬러지 소화시 고액분리 특성에 따른 처리효율평가)

  • Hur, Joon-Moo;Park, Jong-An
    • Journal of Environmental Health Sciences
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    • v.28 no.5
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    • pp.77-85
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    • 2002
  • The objective of this study was to evaluate the performances of the ASBR under critical conditions of solid-liquid separation, caused by extremely high solids concentration, for wider application of the ASBR to various wastes. The ASBRs and completely-mixed daily-fed control runs were operated using a municipal mixed sludge at 35$^{\circ}C$ and 55$^{\circ}C$. Conversion of completely-mixed daily-fed reactor to sequencing batch mode and changes in HRT of all ASBRs were easily achieved without adverse effect, regardless of digestion temperature. Solids accumulation was remarkable in the ASBRs, and directly affected by settleable solids concentration of the feed sludge. Noticeable difference in solids-liquid separation was that flotation thickening occurred in the mesophilic ASBRs, while gravity thickening was a predominant solid-liquid separation process in the thermophilic ASBRS. Solids profiles at the end of thickening step dramatically changed at solid-liquid interface, and slight difference in solids concentrations was observed within thickened sludge bed. Organics removals based on subnatant or supernatant after thickening always exceeded 80% in all reactors. Thickened sludge volume and gas production of the ASBRs affected mutually. Gas production increased as thickened sludge accumulated, and continuous gas evolution during thickening could cause thickened sludge to expand or resuspend. Thickened sludge volume exceeding a predetermined withdrawal level resulted in loss of organic solids as well as biomass during withdrawal step, leading to decrease in gas production ind SRT. Such an adverse mutual effect was significant in gravity thickening, while it was not sensitive in flotation thickening. Changes in organic loading had no significant effect on organic removals and gas production after build-up of solids in the ASBRs.

Field Applicability Evaluation Using Effective Microorganism Brewing Cycle for Contaminated Soil in Water Retention Basin (복합발효미생물을 이용한 하천유수지 오염토의 현장적용성 평가)

  • Shin, Eunchul;Jung, Minkyo;Kim, Kyeongsig;Kang, Jeongku
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.11
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    • pp.35-43
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    • 2016
  • In this study, by using a Effective Microorganisms Brewing Cycle, it confirmed the purification effect of pollutants that are adsorbed on the basins stench removal and retarding soil. On the basis of on-site application test, a soil decontamination system will be suggested. Using a Effective Microorganisms Brewing Cycle, the odor concentration is reduced 2.5 times than that of natural purification treatment method. It was measured and found that the quality of the pore water discharged from the soil is improved. In addition, it was found that a composite of copper and lead with the fermentation microorganisms adsorbed on soil particles from the surface of the stirred experiments lagoon mixed soil is reduced to 65% and 66%, respectively, The TPH organic component was confirmed that the reduction effect of 85%. Restoration of reservoir contaminated soils using the effective microorganism brewing cycle needs to be more developed and implemented as a long-term purification system. This study may be a good reference of developing more complete microorganism brewing system which will efficiently reduce the odor and soil contamination based on optimal stirring and mixing ratio of the compound solutions and contaminated soils in reservoir.

키토산 분자량 변화에 따른 수중의 여러 중금속들의 제거에 관한 연구

  • 이승원;김동석
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.05a
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    • pp.292-296
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    • 2003
  • Autoclaving처리를 하지 않은 키토산과 autoclaving처리한 키토산과의 중금속 흡착실험을 해 본 결과 다음과 같은 결과를 도출 할 수 있었다. 1) 먼저 중금속간의 흡착능을 고찰하기 위하여 Langmuir와 Freundlich 흉착등온식에 적용시켜 본 결과 Freundlich 흡착등온식 보다는 Langmuir 흡착등온식이 보다 적합한 것으로 나타났다. 2) 시간에 따라서 autoclaving 처리한 키토산의 중금속 제거 가능성과 그 효율을 검토하기 위하여 각 중금속간의 Langmuir 흡착등온식을 이용하여 $q_{max}$를 나타냈다. 15 min > 60 min > 0 min 순으로 모든 중금속 제거 실험에서 15 min 동안 autoclaving 처리한 키토산의 중금속 흡착량이 가장 높은 것으로 나왔다. 그러므로 기존의 키토산 보다는 15 min동안 autoclaving 처리한 키토산이 중금속 제거에 더 좋은 흡착제로써 역할을 할 수 있을 것으로 판단된다. 3) 키토산을 이용한 중금속 제거에서는 $Pb^{2+}$ > $Cd^{2+}$ > $Cu^{2+}$ > $Cr^{3+}$순서로 제거가 되었다. 여러 연구자들의 실험 결과를 종합해 볼 때 Pb$^{2+}$가 중금속 중에 제거가 잘 된다는 연구 결과가 많이 발표 되었으며, $Cd^{2+}$, $Cu^{2+}$, $Cr^{3+}$의 경우에는 흡착제의 종류에 따라서 제거되는 순서가 다르다는 연구 결과들이 보고 되고 있다. 그러나 어떠한 이유로 중금속의 제거에 차이가 있는지에 대해서는 명확한 결론이 내려져 있지 않는 실정이다. 이러한 중금속간의 경쟁적인 관계에 대해 더 많은 세밀한 연구가 이루어져야 할 것 같다.는 0.52mg/$\ell$~0.99mg/$\ell$~의 범위이었다. 신천에 금호강물을 혼합한 이후에도 부유물질, 생화학적산소요구량, 암모니아태 질소, 총인 등의 농도가 개선되지 않았다. 즉 금호강물의 혼합은 신천수질환경사업소에서 배출되는 방류수에 함유되어 있을 2차 오염물질의 희석이라는 이점외의 수질개선효과는 확인되지 않았다.l years and a new type of transfer crane has been developed. Design concepts and control methods of a new crane will be introduced in this paper.and momentum balance was applied to the fluid field of bundle. while the movement of′ individual material was taken into account. The constitutive model relating the surface force and the deformation of bundle was introduced by considering a representative prodedure that stands for the bundle movement. Then a fundamental equations system could be simplified considering a steady state of the process. On the basis of the simplified model, the simulation was performed and the results could be confirmed by the experiments under various conditions.뢰, 결속 등 다차원의 개념에 대한 심도 깊은 연구와 최근 제기되고 있는 이론

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Comparison of Discharge Characteristics of NPS Pollutant Loads from Urban, Agricultural and Forestry Watersheds (유역으로부터 배출되는 비점원 오염부하의 토지이용에 따른 특성 비교)

  • Yur, Joong-Hyun;Kim, Geon-Ha;Kim, Jeong-Kon
    • Proceedings of the Korea Water Resources Association Conference
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    • 2005.05b
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    • pp.1214-1218
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    • 2005
  • 지금까지 국내에서의 수질개선을 위한 노력은 점오염원에 대한 저감만을 중심으로 진행되어 왔기 때문에, 보다 획기적인 수질개선을 위해서는 비점오염에 대한 연구와 관리가 진행되어야 한다. 그러므로 본 연구에서는 도시지역, 농촌지역, 임야지역의 토지이용특성이 다른 3유역을 대상으로 현장연구를 실시하여 비점오염물질의 발생특성 및 유역별 비교를 실시하였다. 측정은 도시지역의 가장 큰 오염원인 CSOs(Combined Sewer Overflows)에 대하여 측정을 실시하였고, 농촌지역 및 임야지역의 경우 각 유역의 출구 지점에서 측정을 실시하였다. 강우특성이 다른 15개의 강우사상을 대상으로 유량 및 SS, TCOD, TN, TP의 항목에 대하여 한 강우사상당 $15\~20$회의 측정을 실시하였다. 각각의 강우사상에 대하여 EMCs(Event Mean Concentrations)를 산출하여 도시지역, 농촌지역, 임야지역의 각 유역에 대한 확률별 EMCs를 산정한 결과 3개 유역의 EMCs는 도시지역>농촌지역>임야지역 순으로 나타났다. $EMC_{TCOD}$는 도시지역과 농촌임야지역간에 가장 큰 차이를 보이는 것으로 나타났으며, $EMC_{TN}$에서 가장 작은 차이가 나타났다. 각 유역별 EMCs의 로그-정규 확률그래프의 분산계수를 비교한 결과 농촌임야지역은 도시지역에 비하여 오염물질의 농도 변화가 강우특성에 따라 보다 큰 변화를 보이는 것으로 나타났다. 연구유역에서 $EMC_{TN}$의 발생확률 $50\% 값이 도시지역은 17.0mg/L, 농촌임야지역은 4.5mg/L로 나타났으며, 이는 유사한 유역특성을 나타내는 타 지역에서의 연구자료를 분석 값과 매우 유사한 크기를 가지는 것으로 나타났다.를 분석하였다. 실험을 수행하여 보다 정밀한 공식으로 개선할 수 있었다.$10,924m^3/s$ 및 $10,075m^3/s$로서 실험 I의 $2,757m^3/s$에 비해 통수능이 많이 개선되었음을 알 수 있다.함을 알 수 있다. 상수관로 설계 기준에서는 관로내 수압을 $1.5\~4.0kg/cm^2$으로 나타내고 있는데 $6kg/cm^2$보다 과수압을 나타내는 경우가 $100\%$로 밸브를 개방하였을 때보다 $60\%,\;80\%$ 개방하였을 때가 더 빈번히 발생하고 있으므로 대상지역의 밸브 개폐는 $100\%$ 개방하는 것이 선계기준에 적합한 것으로 나타났다. 밸브 개폐에 따른 수압 변화를 모의한 결과 밸브 개폐도를 적절히 유지하여 필요수량의 확보 및 누수방지대책에 활용할 수 있을 것으로 판단된다.8R(mm)(r^2=0.84)$로 지수적으로 증가하는 경향을 나타내었다. 유거수량은 토성별로 양토를 1.0으로 기준할 때 사양토가 0.86으로 가장 작았고, 식양토 1.09, 식토 1.15로 평가되어 침투수에 비해 토성별 차이가 크게 나타났다. 이는 토성이 세립질일 수록 유거수의 저항이 작기 때문으로 생각된다. 경사에 따라서는 경사도가 증가할수록 증가하였으며 $10\% 경사일 때를 기준으로 $Ro(mm)=Ro_{10}{\times}0.797{\times}e^{-0.021s(\%)}$로 나타났다.천성 승모판 폐쇄 부전등을 초래하는 심각한 선천성 심질환이다. 그러나 진단 즉시 직접 좌관상동맥-대동맥 이식술로 수술적 교정을 해줌으로써 좋은 성적을 기대할 수 있음을 보여주었다.특히 교사들이 중요하게 인식하는 해

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Development of Separation System with Rotating Rakes for Recovery of Film-based Plastics (기계식(機械式) 회전(回轉)레이크를 이용(利用)한 생활계(生活界) 폐기물(廢棄物) 필름류(類) 선별장치(選別裝置) 개발(開發)에 관(關)한 연구(硏究))

  • Lee, Byung-Sun;Na, Kyung-Duk;Han, Sang-Kuk;Choi, Woo-Zin;Park, Eun-Kyu
    • Resources Recycling
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    • v.19 no.3
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    • pp.24-32
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    • 2010
  • In the present work, a new separation system with rotating rakes has been developed to separate the film-based plastics from the recyclable materials, and environment assessment is also carried out during operation of the device. Capacity of the device was about 5.3 ton/hr at a rakes rotation speed of 26.0 rpm (the number of rakes in the 1st, 2nd and 3rd trials were 39, 52 and 48, respectively) and a belt conveyor speed of 38.5m/min, which satisfied the initial design capacity (5.0 ton/hr). Recovery ratio and purity of the plastic films were 92.6% and 96.5%, respectively at a rotation speed of 28 rpm. The levels of noise, vibration and particulate emission were below material standard regulatory limits. Plastic refused fuel (RPF) was also prepared with the recovered films. The calorific value and chlorine content of the prepared RPF were 9,740 kcal/kg and 0.18%, respectively which satisfy the first grade quality specification of the Korean RPF standard. As a result of this work, recovery of energy resources from the municipal solid waste is possible by adopting the developed separation device.

Nitrogen, Phosphorus, and Organic Carbon Discharges in the Imgo Small Agricultural Watershed Catchment (임고천상류 소규모 농업유역에서 하천으로의 질소, 인 및 유기물의 부하)

  • Chung, Jong-Bae;Kim, Min-Kyeong;Kim, Bok-Jin;Park, Woo-Churl
    • Korean Journal of Environmental Agriculture
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    • v.18 no.1
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    • pp.70-76
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    • 1999
  • Since high concentrations of N, P, and organic C cause the excessive eutrophication in water systems, the control of nutrient export from agricultural nonpoint sources has become important. This study was conducted to estimate discharges of N, P, and organic C from a small agricultural watershed of the upper Imgo stream in Youngchun, Kyongbuk. Of the total area(1.420ha), 25% was agricultural land including paddy, upland and orchards and most of the remainder was forest. The resident population in the watershed was 194 in 80 households and relatively small numbers of livestocks including cow were raised. Mean concentrations of nutrients in the stream water were 4.95, 0.80, 6.72, 0.07 and 2.52mg/L for $NO_3-N$, $NH_4-N$, Total N, Total P and COD respectively. Annual discharges in 1997 were 28,991kg of $NO_3-N$. 3,010kg of $NH_4-N$, 37,006kg of Total N. 590kg of Total P, and 29,138kg of COD. There was a strong positive relationship between stream flow and precipitation, and also most of the nutrient discharges occurred in the rainy season (May to August). Since there was no any other industries in the watershed, agricultural practices and sewage from the resident households, forest runoff and livestock wastes were the major sources of NPS discharges. A combination of management options, including management of soil erosion and fertilizer application, could lead to reductions in nutrient exports.

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The Analysis of PM10 Concentration and Emission Contribution in the Major Cities of Korea (한반도 주요 대도시의 PM10 농도 특성 및 배출량과의 상관성 분석)

  • Kang, Minsung;Kim, Yoo-Keun;Kim, Taehee;Kang, Yoon-Hee;Jeong, Ju-Hee
    • Journal of Environmental Science International
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    • v.25 no.8
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    • pp.1065-1076
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    • 2016
  • This study analyzes the $PM_{10}$ characteristics (particulate matter with aerodynamic diameter less than $10{\mu}m$), concentration, and emissions in eight large South Korean cities (Seoul, Incheon, Daejeon, Daegu, Gwangju, Ulsan, Busan, Jeju). The annual median of $PM_{10}$ concentration showed a decline of $0.02{\sim}1.97{\mu}g/m^3$ in the regions, except for Incheon, which recorded an annual $0.02{\mu}g/m^3$ increase. The monthly distribution levels were high in spring, winter, fall, and the summer, but were lower in summer for all regions except for Ulsan. These differences are thought to be due to the dust in spring and the cleaning effect of precipitation in summer. The variation in concentrations during the day (diurnal variation) showed that $PM_{10}$ levels were very high during the rush hour and that this was most extreme in the cities (10.00 and 18.00-21.00). The total annual $PM_{10}$ emissions analysis suggested that there had been a general decrease, except for Jeju. On-road mobile (OM) sources, which contributed a large proportion of the particulates in most regions, decreased, but fugitive dust (FD) sources increased in the remaining regions, except for Daegu. The correlation analysis between $PM_{10}$ concentrations and emissions showed that FD could be used as a valid, positive predictor of $PM_{10}$ emissions in Seoul (74.5% (p<0.05)), Dajeon (47.2% (p<0.05)), and Busan (59.1% (p<0.01)). Furthermore, industrial combustion (IC) was also a significant predictor in Incheon (61.7% (p<0.01)), and on-road mobile (OC) sources were a valid predictor in Daegu (24.8% (p<0.05)).

Performance and Emission Characteristics of a CNG Engine Under Different Natural Gas Compositions (천연가스 조성 변화에 따른 CNG 엔진 성능 및 배기가스 특성)

  • Ha, Young-Cheol;Lee, Seong-Min;Kim, Bong-Gyu;Lee, Chang-Jun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.7
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    • pp.749-755
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    • 2011
  • The performance and emission characteristics of a CNG (compressed natural gas) engine were experimentally investigated under different natural gas compositions. The engine specifications were as follows: 6606 cc, turbo, lean-burn-type; its ignition timing was fixed for the fuel gas with a HHV (higher heating value) of 10454 kcal/$Nm^3$. The experimental results showed that when the HHV of the fuel gas was changed from 10454 kcal/$Nm^3$ to 9811 kcal/$Nm^3$ and 9523 kcal/$Nm^3$, the average power reductions were 3.2 % and 3.4 % (1.5 % and 2.1 %, respectively, with A/F control switched off), respectively, and the average thermal-efficiency reductions were 1.1 % and 1.5 % (1.5 % and 2.1%, respectively, with A/F control switched off), respectively. The emissions of $CO_2$, CO, and $NO_x$ decreased as the HHV of the fuel gas was lowered. On the other hand, the emissions of THC (total hydrocarbon) were not consistent, and the extent of change in their emissions was small.

A Study of Nonpoint Source Pollutants Loads in Each Watershed of Nakdong River Basin with HSPF (HSPF 모델을 이용한 낙동강유역의 유역단위별 비점오염부하량 산정)

  • Kwon, Kwangwoo;Choi, Kyoung-sik
    • Journal of Environmental Impact Assessment
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    • v.26 no.1
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    • pp.68-77
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    • 2017
  • In order to estimate the non-point pollution loads from each watersheds among 209 watersheds, the calibration and validation of HSPF model were carried out based on 2012 in 2013 years. In the case of flow rate, R2 of calibration and validation were 0.71~0.93 and 0.71~0.79, which were relatively good values. With the respect to calibration of water quality, % differences between measured and simulated values were 0.4 ~ 9.7 of DO, BOD 0.5 ~ 30.2% and TN 1.9~28.6% except for Hwhangkang B site. In case of validation, DO was 0.2 ~ 13.7%, BOD 1.3~23% and TN 0.5~24.3% excluding Hwhangkang B. However, since the concentration of TP was very small compared with other items, the range of difference was large as 0.8~55.3%. level. As the result of calculating annual accumulative BOD loads for each watershed, it was found that RCH 123 (Uryeong, Gyeongsangnamdo), RCH 121 (Jinju, Gyeongsangnamdo) and RCH 92 (Daegu) were the high ranked. The unit watersheds including various landuse type susch as forest and agricultural sites in mainstream areas have a higher BOD nonpoint pollution load than those in dam regions. However, the results of the annual cumulative loading of the basins for nutrients did not appear to be consistent with the BOD annual cumulative loading ranks. Other factors that represent watershed characteristics such as landslope and soiltypes, including landuse pattern, have been found to be closely related to nonpoint pollutant loads.