• Title/Summary/Keyword: 배기온도

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RF Magnetron Sputtering 및 Evaporation을 이용하여 증착한 CdTe 박막의 물성평가

  • Kim, Min-Je;Jo, Sang-Hyeon;Song, Pung-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.345-345
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    • 2012
  • 최근 의료산업에서는 고해상도 및 동영상 구현이 가능한 직접 방식의 X-선 검측센서에서 X-ray 흡수효율이 좋은 반도체 센서(CdTe, CdZnTe 등)와 성숙된 기술, 집적효율이 뛰어난 CMOS 공정을 이용한 제품을 출시하여 대면적화 및 고집적화가 가능하게 되어 응용분야가 점차 확대되고 있는 추세이다. 하지만 이 역시 고 성능의 X-선 동영상 구현을 위해서는 고 해상도 문제, 검출효율 문제, 대면적화의 어려움이 있다. 기존의 X-선 광 도전층의 증착은 증착 속도와 박막 품질에서 우수한 Evaporation 법이 사용되고 있다. 한편, 대면적에 균일한 박막형성이 가능하기 때문에 양산성에서 우월성을 가지는 sputtering법의 경우, 밀도가 높은 소결체 타겟의 제조가 힘들뿐만 아니라 증착 속도가 낮아 장시간 증착 시 낮은 소결밀도로 인한 타겟 Particle 영향으로 인해서 대 면적에 고품질의 박막을 형성하기가 어렵다. 하지만 최근 소결체 타겟 제조기술 발달과 함께, 대면적화와 장시간 증착에 대한 어려움이 해결되고 있어 sputtering 법을 이용한 고품질 박막 제조 기술의 연구가 시급한 실정이다. 본 연구에서는 $50{\times}50$ mm 크기의 non-alkali 유리기판(Corning E2000) 위에 Evaporation과 RF magnetron sputtering을 사용하여 다양한 기판온도 (RT, 100, 200, 300, $350^{\circ}C$)에서 $1{\mu}m$의 두께로 CdTe 박막을 증착하였다. RF magnetron sputtering의 경우 CdTe 단일 타겟(50:50 at%)을 사용하였으며 Base pressure는 약 $5{\times}10^{-6}$ Torr 이하까지 배기하였고, Working pressure는 약 $7.5{\times}10^{-3}$ Torr에서 증착하였다. 시편과 기판 사이의 거리는 70 mm이며 RF 파워는 150 W로 유지하였다. CdTe 박막의 미세구조는 X-ray diffraction (XRD, BRUKER GADDS) 및 Field Emission Scanning Electron Microscopy (FE-SEM, Hitachi)를 사용하여 측정하였다. 또한, 조건별 박막의 조성은 Energy Dispersive X-ray Spectroscopy (EDS, Horiba, 7395-H)을 사용하여 평가하였다. X-선 동영상 장치의 구현을 위해서는 CdTe 다결정 박막의 높은 흡수효율, 전하수집효율 및 SNR (Signal to Noise Ratio) 등의 물성이 요구된다. 이러한 물성을 나타내기 위해서는 CdTe 박막의 높은 결정성이 중요하다. Evaporation과 RF magnetron sputtering로 제작된 CdTe 박막은 공정 온도가 증가함에 따라 기판상에 도달하는 스퍼터 원자의 에너지 증가로 인해서 결정립이 성장한 것을 확인할 수 있었다. 따라서 CdTe 박막이 직접변환방식 고감도 X-ray 검출기 광도 전층 역할을 수행할 수 있을 것으로 기대된다.

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Synthesis of iron disilicide single crystal by chemical vapour transport (기상성장법(CVT)에 의한 Iron disilicide단결정의 합성)

  • 이충효;홍대석;이상진;최종건;김판채
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.2
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    • pp.68-72
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    • 2002
  • The $\beta$-$FeSi_2$ and $\alpha$-$FeSi_2$ single crystals were synthesized by chemical vapour transport (CVT) using iodine as a transporting agent from the commercially available $FeSi_2$ powder. The $FeSi_2$ powder together with iodine were sealed in an evacuated quartz ampoule and the ampoule then being placed in two-zone electrical furnace for growing crystal. The CVT of $FeSi_2$ with iodine yielded $\beta$-$FeSi_2$ and $\alpha$-FeSi$_2$ single crystals at deposition temperature of 750 and $950^{\circ}C$ respectively. The source temperature was $1050^{\circ}C$ in both cases. The crystals of the $\alpha$-FeSi$_2$ phase were typically plate shaped with dimensions of about $10\times 10 \textrm{mm}^2$, whereas the crystals of orthorhombic $\beta$-$FeSi_2$ phase grew predominantly in the fonts of thin needle of about 10 mm in length. The composition of$\alpha$-FeSicrystal determined by electron probe microanalysis (EPMA) resulted in Si-rich $FeSi_{2.58}$ . 57. Furthermore, the CVT $\beta$-$FeSi_2$ crystal was found to be transformed to the high temperature $\alpha$-$FeSi_2$phase above $930^{\circ}C$.

The Microbiological Assessment of a University Foodservice Establishment, and Hazard Analysis for Quality Control of Fried Fish Cake Soup Preparation (대학 급식시설의 위생 실태조사 및 품질관리를 위한 연구 - 제 1 보 : 오뎅국을 중심으로 -)

  • Rew, Kyung;Kim, Jeong-Mi;Kwak, Tong-Kyung
    • Journal of Nutrition and Health
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    • v.18 no.4
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    • pp.283-292
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    • 1985
  • A sanitary quality of a university foodservice establishment was assessed in terms of time and temperature, pH and Aw, and microbiological evaluation. Critical control points during various phases in product flow of fried fish cake soup were identified using hazard analysis concept. The results are summarized as follows : 1) Time and temperature data indicated that phases of holding ingredients at room temperature after cooking, and hot - holding of soup before assembly were critical. 2) pH and Aw values were in favorable for microbial growth. 3) Microbiological data indicated that microbial quality of ingredients was in poor condition. A holding practice of cooked ingredients at room temperature might provide the chance for microbial contamination and multiplication. Hot - holding time and temperature of soup should be strictly controlled to assure the food safety, since the microbial quality of serving food can be directly influenced by the hot - holding temperature of soup. 4) Microbiological test results for food containers, equipments, working surfaces, and supplies indicated that sanitary conditions of earthenware, gloves, wiping cloths and cutting board should be improved promptly. 5) Critical control points identified were : ingredients, pre - preparation, post - preparation, and holding before assembly and service. 6) Guidelines for the effective quality control program for this operation were suggested.

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Fire Modeling and Smoking Control Characteristic Analysis of Electric Room by Using FDS (FDS를 이용한 전기실의 화재모델링 및 연기제어 특성 분석)

  • Choi, Jeong-A;Lee, Min-Gu;Lee, Dae-Dong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.3
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    • pp.662-668
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    • 2018
  • Most electric rooms are located in the underground spaces of buildings. When a fire occurs in electrical equipment, the fire expands to cable insulation material, resulting in toxic smoke and combustion products. If the smoke and combustion products quickly move vertically and horizontally, the evacuation of occupants and firefighting activities will be hindered. Therefore, it is necessary to design optimal equipment for smoke control in cases of fires in electric rooms. This study analyzes the characteristics of smoke and combustion products in fires in a cubicle-type switchboard in an electric room using PyroSim, which is based on the program Fire Dynamics Simulator (FDS). The fire modeling consists of four scenarios according to the operation mode of the mechanical ventilation equipment, the amount of air supply and exhaust, and the location of the air supply slot. The analysis shows that the mechanical ventilation equipment improves the smoke density, visibility, carbon monoxide concentration, and temperature characteristics. The visibility and temperature characteristics were improved when the air flow rate and the location of the air supply slot from fire defense regulations were applied.

Development of Direct DME Synthesis Process (DME 직접 합성공정 기술개발)

  • Mo, Yong-Gi;Cho, Won-Jun;Baek, Young-Soon
    • Journal of the Korean Institute of Gas
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    • v.14 no.3
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    • pp.41-45
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    • 2010
  • The physical properties of DME(Dimethyl Ether) are very similar to LPG and well-mixed. As cetane number of DME is similar to diesel fuel that can replace diesel fuel and alternative energy. DME is a clean energy source that can be manufactured from various raw materials such as natural gas, CBM(Coal Bed Methane) and biomass. DME has no carbon-carbon bond in its molecular structure and its combustion essentially generates no soot as well as no SOx. The development of DME process in KOGAS have 4 section. First, syngas section can be manufactured various syngas ratio. This completes the tri-reforming process for the synthesis gas ratio of approximately 4.0 to 1.0 range can be adjusted. Second, $CO_2$ is removed from the $CO_2$ removal section of about 92~99%, so the maximum concentration of $CO_2$ entering the DME synthesis reactor should not exceed 8%. Third, in the DME synthesis section, if the temperature of DME reactor increases, the activity of DME catalyst increased. but for the long-term activity is desirable to maintain the proper temperature. Finally, the purity of DME in the DME purification section is over 99.6%.

Environmental Efficiency Analysis of an Enclosed Experimental Broiler House (실험 무창육계사의 환경효율 분석)

  • Hwangbo, J.;Song, J.I.;Cho, S.B.;Chung, K.H.;Lee, B.S.;Nam, B.S.;Chung, C.S.;Chung, I.B.
    • Journal of Animal Science and Technology
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    • v.44 no.4
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    • pp.475-482
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    • 2002
  • The experiment was conducted to evaluate a ventilation system, which was devised to encourage farmers to use the enclosed poultry housing system. The study was observed in the National Livestock Research Institute from May 9 to May 30 in 2002. The main results of the experiment are as follows: 1. Although the outside temperature of the enclosed poultry house was 9.6 ${\sim}$ 21.2$^{\circ}C$ with 11.6$^{\circ}C$ variation, the house with an excellent heat insulation was maintained at 32${\sim}$33$^{\circ}C$ in a variation of 2$^{\circ}C$ which is within the range of the optimal temperature for broiler, being aided with two small electric heaters. 2. The average of air flow rates of the upper, middle and low parts of the room in the broiler house were detected at 0.57, 0.22 and 0.04 m/sec, respectively. The air flow in the whole room was distibuted uniformly by a perforated duct. In conclusion, heat and humidity could be controlled without any problem in this enclosed housing system. Especially, air flow in all parts of the room was detected in uniform rates, resulting in the better ventilation performance with air inhalation through the duct and air exhaust through the side walls of the house.

Thermal behavior of $PrCl_3$ in an oxidizing condition (산화조건에서 $PrCl_3$의 열적거동)

  • Eun, Hee-Chul;Yang, Hee-Chul;Cho, Yong-Zun;Lee, Han-Soo;Kim, In-Tae
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.4
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    • pp.207-212
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    • 2009
  • In this study, a thermal behavior of $PrCl_3$ as one of the lanthanide chlorides in LiCl-KCl molten salts was investigated in an oxidizing condition. First, a thermo-gravimetric analysis (TGA) of $PrCl_3$ was carried out by an injection of $O_2$ gas. Based on the results, an oxidation of $PrCl_3$ in the molten salts was performed by sparging $O_2$ gas with changing temperatures. According to the TGA data of $PrCl_3$, a dissociation of $PrCl_3$ occurred rapidly by about $380^{\circ}C$ and a conversion of $PrCl_3$ to $PrCl_3$ was completed at about $600^{\circ}C$. The thermal behavior of $PrCl_3$ in LiCl-KCl molten salts by sparging $O_2$ gas was similar to that of $PrCl_3$ in the TGA test, and PrOCl as a insoluble compound in the molten salts was precipitated into the bottom of the molten salts. A conversion of $PrCl_3$ to PrOCl in the molten salts occurred actively at a higher temperature than $650^{\circ}C$. And it would be possible to estimate a conversion status of $PrCl_3$ to PrOCl by measuring a $Cl_2$ concentration in a flue gas generated from an oxidation test of $PrCl_3$ in LiCl-KCl molten salts.

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Fundamental Heat Analysis about the Thermoelectric Generation System Using the Waste Heat of Exhaust Gas from Ship (선박의 배기가스 폐열을 활용한 열전발전시스템에 관한 기초 열해석)

  • Kim, Myoung-Jun;Ga, Gwang-Jin;Chea, Gyu-Hoon;Kim, In-Seup
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.5
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    • pp.583-592
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    • 2016
  • IMO (International Maritime Organization) in the UN (United Nations) set up that aim at reducing $CO_2$ emission from ship by up to 30 percent until 2030. The final purpose of this study is the development of marine thermoelectric generation system using waste heat from vessel of internal combustion engines. Before the development of marine thermoelectric generation system, this paper carried out the fundamental heat analysis of marine thermoelectric generation system. It was able to obtain the valuable results about the efficiency improvement of the thermoelectric generation system. The results is as follows : 1) It was confirmed that the efficiency of thermoelectric generation system improves to 8.917 % with increasing the temperature difference of peltier module by reducing the temperature difference between peltier module and heat source at the hot side. 2) System efficiency according to change in the external load resistance was confirmed that the change width of about 6 % which does not significantly occur. 3) System efficiency in the case stainless steel at the same condition is 8.707 %. System efficiency could be confirmed that the stainless steel is higher than duralumin (8.605 %), copper (8.607 %).

Synthesis and Magnetic Properties of $Fe-TiO_2$ Nanocomposite Powders by Mechanical Alloying (기계적 합금화법에 의한 $Fe-TiO_2$ Nanocomposite의 합성 및 자기적 성질)

  • 홍대석;이성희;이충효;김지순;권영순
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2002.11a
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    • pp.63-63
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    • 2002
  • 현재 기계적 합금화법에서는 주로 합금을 구성하는 성분원소 분말을 불활성분위기에서 볼밀처리 함으로써 함금화를 시키거나 모합금에 산화물을 분산시켜 복합화시키는 공정을 통하여 각종 화합물, 비정질상 및 과포화고용체등의 준안정상의 합성 뿐만이 아니라 초미세조직의 생성에 관한 폭 넓은 분야의 연구가 행하여지고 있다. 한편 MA에서는 볼멀처리중 기계적 에너지의 투여에 의하여 실제 반응온도보다 낮은 온도에서 발생하는 특이한 화학반응 즉 Mechanochemical 반응을 일으키 기도 한다. 본 연구에서는 헤마타이트($Fe_20_3$)와 금속윈소인 Ti의 MA처리에 의하여 고상환원반응 을 유기시켜 $Fe-TiO_2$계 nanocomposite 분말재료를 제조하고자 한다. 특히 MA 공정에 있어서 자기 물성의 변화와 X선 회절을 통하여 고상환원반응에 의한 복합분말의 생성과정을 조사하였다. 출발원료는 $Fe_20_3$(고순도화학제,99.9%, 평균입경 0.1$\mu\textrm{m}$)와 금속원소인 Ti(99.9%, 명균업경 150$\mu\textrm{m}$)을 몰비 2:3의 조성이 되도록 하여 MA를 실시하였다. 볼멀은 고에너지 유성형 볼밀장치(독일 제, Fritsch P-5)를 이용하였으며 진공치환형 용기에 원료분말을 장입하여 2회정도 진공배기한 후 아르곤 가스를 충전하여 볼밀을 행하였다. 얻어진 분말시료에 대하여 x-선 회절장치, 전자현미경 (SEM) 및 진동시료형자력계(VSM)를 통하여 결정구조, 미셰조직 빛 자기특성을 조사하였다. $Fe_2O_3-Ti$ 혼합분말의 MA처리 에 의하여 초기단계부터 환원반응과 함께 $Fe_3TIO_{lO}$ 중간상이 관찰 되었으나 30hrs의 MA처리 후 Fe와 산화물 $TiO_2$로 모두 환원되어 $Fe-TiO_2$계 나노복합분말이 얻어짐을 알 수 있었다. 이 때 X션 회절피크의 line broadening으로부터 복합분말의 Fe 명균 결정립 크기는 24nm로 초미세 결정럽의 분말합금이었다. 포화자화값은 볼밀처리에 따라 점점 증가하여 MA 30시간에는 20.3emu/g로 포화됨을 알 수 있었다. 또한 보자력 Hc는 MA초기단계에 350e로 매우 낮으나 30시간 후에는 Hc값이 2600e로 매우 큰 값을 나타내었다. 이것은 환원반응결과 초기에 생성된 Fe의 결정립이 비교적 크고 결정결함이 적으나 볼밀처리를 30시간까지 행하면 Fe 결정렵의 미세화 빛 strain 증가로 magnetic hardening이 일어나기 때문인 것으로 사료된다.

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Study on the Performance Factors of Two Stage Turbo-Charging System and Maximization of the Miller Cycle (2단 과급시스템의 성능 인자 영향과 밀러 효과 극대화에 관한 연구)

  • Beak, Hyun-min;Seo, Jung-hoon;Lee, Won-ju;Lee, Ji-woong
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.7
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    • pp.953-960
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    • 2019
  • The Miller cycle is a diesel engine that has been developed in recent years that it can reduce NOx and improve fuel consumption by reducing the compression ratio through intake valve closing (IVC) time control. The Miller cycle can be divided into the early Miller method of closing the intake valve before the bottom dead center (BDC) and the late Miller method of closing the intake valve after the BDC. At low speeds, the late Miller method is advantageous as it can increase the volumetric efficiency; while at medium and high speeds, the early Miller method is advantageous because of the high internal temperature reduction effect due to the expansion of the intake air during the piston lowering from IVC to BDC. Therefore, in consideration of the ef ects of the early and late Miller methods, it is necessary to adopt the most suitable Miller method for the operating conditions. In this study, a two-stage turbo charge system was applied to four-stroke engines and the process of enhancing the Miller effect through a reduction of the intake and exhaust valve overlap as well as the valve change adjustment mechanism were considered. As a result, the ef ects of fuel consumption and Tmax reduction were confirmed by adopting the Miller cycle with a two-stage supercharge, a reduction of valve overlap, and an increase of suction valve lift.