• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.157-157
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• 2010

우리나라는 기후변화협약에 대응하기 위한 교토의정서를 비준한 국가로서, 아직 온실가스의 의무감축 대상 국가는 아니다. 그러나 2012년부터 시작될 교토의정서 2차 공약기간 중에 브라질, 중국 및 인도와 같이 2차 의무감축대상이 가장 유력시 되는 국가로 지목되고 있으므로, 이러한 변화에 능동적으로 대처할 수 있는 기술적, 사회적, 정책적 방안이 신속히 마련될 필요가 있다. CCS(carbon capture & storage)란 화석연료로 부터 연소시 대기 중으로 배출되는 온실가스($CO_2$)를 포집하여 재생 또는 지중, 해양에 저장하는 기술로서 국가녹색성장 핵심기술중의 하나로 분류되며, 대료적인 $CO_2$ 발생대상인 석탄화력발전소로 부터 $CO_2$ 회수방안, 회수, 처리관련 연구를 포함하여 국내외 적으로 활발한 연구가 이루어 지고 있다. 순산소 연소기술을 통한 $CO_2$ 회수, 처리기술은 연료(천연가스, 석탄, 석유)의 산화제를 공기대신 순도 95% 이상의 고농도 산소를 이용하여 순산소연소를 하며, 이때 발생하는 배가스의 대부분은 $CO_2$와 수증기로 구성되어 있다. 발생된 배가스의 약 70~80%를 다시 연소실로 재순환시켜 연소기의 열적 특성에 적절한 연소가 가능하도록 최적화함과 동시에 배가스의 $CO_2$ 농도를 80% 이상으로 농축시켜 회수를 용이하게 하며, 특히 공해물질은 NOx 발생량을 10ppM 이하로 줄일 수 있다. 천연가스가 생산되는 LNG기지에서 LNG를 기화시키기 위하여 해수식 기화기(ORV : Open Rack Vaporizer와 수중연소식 기화기(SMV ; Submerged Combustion Vaporizer)를 사용하고 있으며, 특히 SMV는 버너를 이용하여 $-162^{\circ}C$ LNG를 $10^{\circ}C$의 LN로 기화시키는 설비로서 이때 연소시 $CO_2$를 상당량 발생시킨다. 본 논문에서는 SMV에서 순산소 연소방식을 적용하여 연료인 천연가스를 연소시키고, 이때 발생되는 $CO_2$와 수분이 주 성분인 배가스를 연소기에 재순환시켜, 연소실내 고온문제를 해결하며, 최종적으로 배가스중 $CO_2$는 $-162^{\circ}C$의 LNG 냉열을 이용하여 고순도의 액체 $CO_2$로 액화시키므로서 $CO_2$의 회수, 처리문제를 해결하는 방식을 소개하고자 한다. 이러한 방식은 천연가스에서 발생되는 $CO_2$ 회수를 LNG 냉열을 활용하므로서 폐열을 활용하는 에너지 효율적인 문제와 사용가능한 고순도 $CO_2$로 회수하므로서 환경적인 문제를 처리하는 기술이라 할 수 있다.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2001.11a
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• pp.177-182
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• 2001

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2006.04a
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• pp.59-59
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• 2006

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2005.05a
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• pp.218-222
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• 2005

• Journal of the Korean Applied Science and Technology
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• v.34 no.1
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• pp.183-188
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• 2017

This study deals with $de-SO_X$ and $de-NO_X$ process of a wet scrubber for small size ship engines. The experiment was conducted according to the E3 mode of the $NO_X$ technical code. In order to discharge the sulfur containing flue gas, ditertiarybutyldusulfide was added to the diesel fuel to increase the sulfur content. NO gas, which occupies most of the nitrogen oxides in the exhaust gas, was oxidized into $NO_2$ and absorbed by a wet scrubber. The developed equipment of this work achieved 100% of removal efficiency for highly soluble $SO_2$ gas in an aqueous solution.

• Plant Journal
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• v.16 no.1
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• pp.34-37
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• 2020

The need to improve the performance of the dust collector by increasing the fine dust pollution in Korea is eminent. In this study, electrostatic spray wet electrostatic precipitator is used to remove Particulate Matter (PM). In order to enter the Cone-jet mode, which is the most stable spray mode among the various modes of electrostatic spraying, an appropriate voltage-flow condition must be satisfied, and a voltage-flow interval enabling this can be expressed as Stability Island. The voltage at which the conduit mode starts in the Stability Island section is referred to as the electrostatic spray minimum voltage (Onset Voltage). However, the conventional electrostatic spray is uses a very low flowrate, at most few millilitres per minute. The use of much higher flowrates has introduced different patterns of electrospray modes. In this study, the different spray modes will be studied in detail.

• Journal of Energy Engineering
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• v.12 no.3
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• pp.223-230
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• 2003

A study was performed to measure and analyze the gas-side fouling of heat exchanger to cool the exhaust gas from sludge incinerator at ironworks. The incinerator gas passes through inside of the vertical tubes of heat exchanger to preheat the combustion air. This kind of fouling occurs at the entrance region of the heat exchanger and thus the perforated fouling plate was designed to measure the gas-side fouling and to analyze the particulate deposit. As a result of analysis, the particulate deposition rate was influenced by temperature, particulate composition and size and also the deposition patterns were different according to the location of perforated fouling plate. The computational analysis was performed to obtain the deposition rates at the perforated fouling plate and the calculation showed that the deposition rate was varied with the hole size and particulate size. It was proved that the fouling at the entrance region of heat exchanger could be measured by the perforated fouling plate designed in this study.

• Journal of Korea Soil Environment Society
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• v.4 no.3
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• pp.25-33
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• 1999

The recent emergence of biofiltration as a cost effective waste-gas control technology has stimulated in European countries and the USA. Biofiltration of soil vapor extraction off-gas from gasoline contaminated site was simulated in lab-scale in this study. A filling material used was a compost. This study was conducted to evaluate biofiltration characteristics of the compost material for gasoline off-gas. TPH elimination capacity at the gas loading rate of about 50g/$\textrm{m}^3$((filling material)/hr was circa 40g/$\textrm{m}^3$((filling material)/hr. Removal rate of xylene was the highest among BTEX. while it was the lowest in case of bezene. The maximum elimination capacity of the compost was about 1.5g/$\textrm{m}^3$((filling material)/hr for benzene. More than 95% of trimethylbenzene and naphtalene were removed below the loading rate of 0.7g/㎥(filling material)/hr. About 80% of total TPH and BTEX were removed by biodegradation.

• Korean Chemical Engineering Research
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• v.50 no.1
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• pp.128-134
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• 2012

The pilot scale experiments can handle the flue gas up to 1,000 $Nm^3/hr$ for separation of carbon dioxide included in real flue gas at coal-fired power plant. The operational characteristics was analyzed with the main experimental variables such as flue gas flow rate, absorbent circulation rate using chemical absorbents mono-ethanolamine( MEA) and 2-amino-2-methyl-1-propanol(AMP). The more flue gas flow rate decreased in 100 $m^3/hr$ in the MEA 20 wt% experiments, the more carbon dioxide removal efficiency was increased 6.7% on average. Carbon dioxide removal efficiency was increased approximately 2.8% according to raise of the 1,000 kg/hr absorbent circulation rate. It also was more than 90% at $110^{\circ}C$ of re-boiler temperature. Carbon dioxide removal efficiency of the MEA was higher than that of the AMP. In the MEA(20 wt%) experiment, carbon dioxide removal efficiency(85.5%) was 10% higher than result(75.5%) of ASPEN plus simulation.

• Clean Technology
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• v.18 no.1
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• pp.22-30
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• 2012

Separation of $SO_2$ from the flue gases of fossil fuel power plants are important issue because of its strong environmental impact. Industrially, $SO_2$ is being removed with a slurry of limestone, lime or aqueous caustic soda. However, these scrubbing processes possess several drawbacks such as the generation of huge amount of wastewater and the production of metal salts. Recently, ionic liquids have gained increasing interest as an absorbent for acid gas, $CO_2$ and $SO_2$. In this review, we have introduced the recent progress of ionic liquids as a $SO_2$ absorbent.