• Title/Summary/Keyword: 배가스

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Study on Separation Characteristics of Flue Gas Using Hydroquinone Clathrate Compounds (하이드로퀴논 크러스레이트를 이용한 배가스 분리 특성 연구)

  • Lee, Jong-Won;Choi, Ki-Jong
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.865-868
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    • 2011
  • An organic substance, hydroquinone is used to form clathrate compounds in order to identify separation characteristics of carbon dioxide in flue gas. Formed samples were analyzed by means of the solid-state $^{13}C$ nuclear magnetic resonance (NMR) and Raman spectroscopic methods to examine enclthration behaviors of guest species. In addition, elemnetal analysis was also performed in order to evaluate separation efficiency of $CO_2$ in a quantitative way. Based on the experimental results obtained, $CO_2$ molecules are found to be captured into the clathrate compound more readily than $N_2$ molecules. Moreover, because such preferential enclathration is even more significant at low pressure conditions, $CO_2$ separation/recovery from flue gas can be achieved with minimizing additional energy cost for the technique. Experimental results obtained in this study can provide useful information on separation techniques of flue gas or selective separation of gas mixtures in the future.

Oxy-Fuel and Flue Gas Recirculation Combustion Technology: A Review (순산소 및 배가스 재순환 연소 기술)

  • Kim, Hyeon-Jun;Choi, Won-Young;Bae, Soo-Ho;Shin, Hyun-Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.10
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    • pp.729-753
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    • 2008
  • Oxy-fuel combustion is a reliable way for the reduction of pollutants, the higher combustion efficiency and the separation of carbon dioxide. The review of recent research trends and the prospects of oxy-fuel combustion were presented. The difference in characteristics among oxy-fuel combustion, conventional air combustion, oxy-fuel combustion with flue gas recirculation (FGR) technique was investigated. Recent experiments of oxy-fuel combustion with/without FGR were surveyed in various ways which are optimized burner design, flame characteristics, the soot emission, the radiation effect, the NOx reduction and the corrosion of combustor. Numerical simulation is more important in oxy-fuel combustion because flame temperature is so high that conventional measurement devices have a restricted application. Equilibrium and non-equilibrium chemical reaction mechanisms for oxy-fuel combustion were investigated. Combustion models suitable for the numerical simulation of non-premixed oxy-fuel flame were surveyed.

Study on Formation Behaviors of Hydroquinone Clathrates with CO2 and N2 for Application to Selective CO2 Separation/Recovery from Flue Gases (배가스 중 CO2 분리/회수로의 응용을 위한 CO2 및 N2 하이드로퀴논 크러스레이트의 형성 거동 연구)

  • LEE, DONGWON;YOON, JI-HO;LEE, JONG-WON
    • Journal of Hydrogen and New Energy
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    • v.30 no.3
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    • pp.289-295
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    • 2019
  • Effects of various reaction factors such as pressure, time, and temperature on clathrate formation were investigated for hydroquinone with $CO_2$ and $N_2$. Experimental and spectroscopic results indicate that $CO_2$ plays more preferential role in forming hydroquinone clathrates than $N_2$. These results can be used in application of selective $CO_2$ separation from flue gases with the formation of clathrate compounds.