• Title/Summary/Keyword: 방출강도

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Factors Associating Major Burn in Chemical Injury Patients due to Industrial Place Incident : A Retrospective study (산업장 화학 손상 환자에서 중증 화상에 영향을 미치는 요인)

  • Shin, Hee-Jun;Oh, Se-Kwang;Lee, Han-You
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.4
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    • pp.332-339
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    • 2016
  • This study examined the intensity of the association of factors affecting major burns by statistical analysis for patients injured by the release of chemical hazards. A total of 446 patients were evaluated as chemical injury patients, who had visited the emergency room from 1/Jan/2010 to 31/Dec/2014. The major burn was used as a dependent variable representing the severity of chemical injury. A chi-square test (CST) and binary logistic regression test (BLRA) were used as the statistical analysis method for determining the association between major burns and the independent variables. In CST, female and their presence at an incident scene, multiple site injury were associated with major burn (p<0.05). In BLRA, the presence at an incident scene and spills (comparing explosion), discharge (comparing admission) were associated with major burns (p<0.05). In this study, the presence at an incident scene was the most significant factor concerning major burns. Furthermore, gender and injury number, exposure mechanism (spill comparing explosion), and disposition (discharge comparing admission) were also associated with major burns.

The Study on the Corrosion Property of the Zn/Mg/Zn Multilayer Coatings with Various Mg layer thicknesses (Mg 중간층 두께에 따른 Zn/Mg/Zn 다층 박막의 내식특성에 관한 연구)

  • Bae, Gi-Tae;Ra, Jeong-Hyeon;Lee, Sang-Yul
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.177-177
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    • 2016
  • 우수한 내식성을 가지는 Zn 박막은 자동차, 가전제품, 전자제품 등에 사용되는 철 생산품의 수명 연장을 위하여 널리 사용되어 왔다. 최근 개발된 Zn-Mg 합금 박막은 Zn나 Mg에 비해 우수한 내식성을 나타내는 Zn-Mg 합금상을 형성하기 때문에 순수한 Zn 박막이나 다른 Zn 계 합금 박막에 비해 우수한 내식성을 가진다고 보고된 바 있다. 본 연구에서는 다양한 합금상의 형성을 위해 Mg 중간층 두께를 제어하며 Zn/Mg/Zn 다층 박막들을 합성하였으며 열처리를 통한 합금상의 변화, 그에 따른 박막의 내식성에 관해 연구하였다. Zn/Mg/Zn 다층 박막은 총 $4{\mu}m$의 두께로 Mg 중간층의 두께를 변화하였으며 비대칭 마그네트론 스퍼터링 공정을 이용하여 냉연강판 위에 합성하였다. 합성된 다층 박막은 다양한 Zn-Mg 합금상을 형성하기 위하여 진공로를 이용하여 $200^{\circ}C$에서 1시간 동안 어닐링 열처리를 실시하였다. 열처리 전, 후 Zn/Mg/Zn 다층 박막의 미세조직과 조성은 X선 회절 분석기 (XRD)와 전계방출형 주사전자현미경 (FE-SEM)과 글로우 방전 분광분석기 (GDEOES)를 사용하여 분석하였다. 어닐링 열처리를 통한 Zn-Mg 합금상 형성이 Zn/Mg/Zn 다층 박막의 내식성에 미치는 영향을 평가하기 위하여 동전위 분극시험과 EIS(Electrochemical impedance spectroscopy) 분석 실시하였다. FE-SEM과 GDOES 분석 결과, Zn/Mg/Zn 다층 박막들 각각의 중간층 Mg 두께는 1.5, 2.0, $2.5{\mu}m$ 였으며, 어닐링 열처리 후 중간층의 Mg이 상, 하부의 Zn 층으로 확산되면서 박막을 치밀한 구조로 변화시키는 것으로 확인되었다. XRD 분석 결과, 열처리를 하지 않은 Zn/Mg/Zn 다층 박막들에서는 Mg 상의 피크의 강도 차이만 존재할 뿐 Zn-Mg 합금상은 형성되지 않았다. 그러나 열처리를 후 Zn/Mg/Zn 다층 박막들에서 $MgZn_2$ 합금상이 형성되었으며, 중간층 Mg 두께가 $1.5{\mu}m$ 이하인 박막에서는 Zn 상이, 초과하는 박막에서는 Mg 상이 잔존하는 것을 확인하였다. EIS 분석 결과, 열처리 후 박막의 전하이동저항 값은 증가하며 박막의 어드미턴스 값이 감소하였으며 Bode phase plot을 통해 열처리 후 시정수(time constant)가 높은 주파수 영역에서 형성 되는 것을 확인하였다. 이는 열처리 후 Zn/Mg/Zn 다층 박막이 치밀해지고 내식성이 향상되었음을 나타낸다. 동전위 분극시험 결과에서도 마찬가지로 열처리 한 Zn/Mg/Zn 다층 박막들은 열처리 전 대비 내식성이 향상되는 것을 확인하였다. 열처리를 통한 Zn/Mg/Zn 다층 박막의 내식성의 향상은 우수한 내식성의 합금상의 형성과 박막 미세구조의 치밀화에 기인한다고 판단하였다. 또한 열처리 한 Zn/Mg/Zn 다층 박막들에서는 Zn와 $MgZn_2$ 상들이 공존 할 경우 가장 우수한 내식성을 나타내었으며, 이는 $MgZn_2$와 Zn 사이의 적은 전위 차이로 인해 갈바닉 부식 효과가 감소되었기 때문으로 판단된다.

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A STUDY ON THE FLUORIDE RELEASING AND FLEXURAL STRENGTH OF ACRYLIC RESIN BLENDED WITH FLUORIDE (불소를 포함시킨 가철성 교정장치용 Resin의 불소 방출과 굴곡강도에 관한 연구)

  • Jang, Ki-Taeg;Lee, Sang-Hoon;Kim, Chong-Chul;Hahn, Se-Hyun;Shon, Dong-Soo
    • Journal of the korean academy of Pediatric Dentistry
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    • v.24 no.2
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    • pp.428-435
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    • 1997
  • For the purpose of investigating the continuous fluoride releasing from acrylic resin using removable appliances by incorporating fluoride into polymethylmethacrylate during the construction of the appliances, two kinds of fluoride were blended with acrylic powder and devided into five groups as follows. Group 1 : no fluoride (control) Group 2 : NaF 5 wt% Group 3 : NaF 10 wt% Group 4 : $CaF_2$ 5 wt% Group 5 : $CaF_2$ 10 wt% Resin specimens were tested in vitro for fluoride release with fluoride electrode and flexural strength with Instron. The results were as follows ; 1. After 24 hrs, released fluoride concentration(ppm) was the most in group 3($126.5{\pm}14.15$) then, next, group 2($49.5{\pm}4.92$), group 5($2.67{\pm}1.08$), group 4($0.81{\pm}0.30$), group 1($0.03{\pm}0.01$) in order, but after 28 days, group 3($3.37{\pm}0.31$), group 5($1.25{\pm}0.25$), group 4($0.74{\pm}0.19$), group 2($0.68{\pm}0.07$), group 1($0.03{\pm}0.01$). 2. Fluoride releasing of NaF groups were faster and more amount than $CaF_2$ groups initially but decreased significantly, later. 3. Flexural strength ($kg/cm^2$) was the biggest in group 1($602.90{\pm}69.32$), and then group 4($568.98{\pm}20.16$), group 5($556.19{\pm}5.26$), group 2($536.12{\pm}30.35$), group 3($508.44{\pm}26.16$) in order, the differences between control group and NaF groups were statistically significant (p<0.05).

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Prediction of Transmission Error Using Dynamic Analysis of a Helical Gear (헬리컬기어의 동적해석을 통한 전달오차 예측)

  • Lee, Jeongseok;Yoon, Moonyoung;Boo, Kwangsuk;Kim, Heungseob
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.12
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    • pp.1005-1011
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    • 2016
  • The fundamental reason for gear noise is transmission error. Transmission error occurs because of STE (static transmission error) and DTE (dynamic transmission error), while a pair of gears is meshing. These errors are generated by the deflection of the teeth and the friction on the surface of the teeth. In addition, the vibration generated by transmission error leads to excited bearings. The bearings support the shafts, and the noise is radiated after exciting the gear casing. The analysis of the contact stress in helical gear tooth flanks indicates that it is due to impact loading, such as the sudden engagement and disengagement of a gear. Stress analysis is performed for different roll positions, in order to determine the most critical roll angle. Dynamic analysis is performed on this critical roll position, in order to evaluate variation in stresses and tooth contact force, with respect to time. In this study, transmission error analysis was implemented on a spur and helical gear with involute geometry and a modified geometry profile. In addition, in order to evaluate the intensity of impact due to sudden engagement and significant backlash, the impact factor was calculated using the finite element analysis results of static and dynamic maximum bending stresses.

Change of PET Image According to CT Exposure Conditions (CT 촬영 조건에 따른 PET 영상의 변화)

  • Park, Jae-Yoon;Kim, Jung-hoon;Lee, Yong-Ki
    • Journal of the Korean Society of Radiology
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    • v.13 no.3
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    • pp.473-479
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    • 2019
  • PET-CT improves performance and reduces the time by combining PET and CT of spatial resolution, and uses CT scan for attenuation correction. This study analyzed PET image evaluation. The condition of the tube voltage and current of CT will be changed using. Uniformity phantom and resolution phantom were injected with 37 MBq $^{18}F$ (fluorine ; 511 keV, half life - 109.7 min), respectively. PET-CT (Biograph, siemens, US) was used to perform emission scan (30 min) and penetration scan. And then the collected image data were reconstructed in OSEM-3D. The same ROI was set on the image data with a analyzer (Vinci 2.54, Germany) and profile was used to analyze and compare spatial resolution and image quality through FWHM and SI. Analyzing profile with pre-defined ROI in each phantom, PET image was not influenced by the change of tube voltage or exposure dose. However, CT image was influenced by tube voltage, but not by exposure dose. When tube voltage was fixed and exposure dose changed, exposure dose changed too, increasing dose value. When exposure dose was fixed at 150 mA and tube voltage was varied, the result was 10.56, 24.6 and 35.61 mGy in each variables (in resolution phantom). In this study, attenuation image showed no significant difference when exposure dose was changed. However, when exposure dose increased, the amount of dose that patient absorbed increased too, which indicates that CT exposure dose should be decreased to minimum to lower the exposure dose that patient absorbs. Therefore future study needs to discuss the conditions that could minimize exposure dose that gets absorbed by patient during PET-CT scan.

Lacquer as Adhesive : Its Historical Value and Modern Utilization (접착제로서의 옻; 역사성과 현대적 활용)

  • Jang, Sung Yoon
    • Korean Journal of Heritage: History & Science
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    • v.49 no.4
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    • pp.114-125
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    • 2016
  • Lacquer is one of the most widely used natural resin in East Asia since Neolithic Age. As a major ingredient of lacquerware, lacquer is waterproof, insect-proof and rot-proof to be durable and anti-abrasion, generally utilized for mainly painting purpose. According to lacquerware excavated from several sites of Japan and China, lacquerware seems to appear in Neolithic Age. On the other hand in case of excavation research in Korea, lacquerwares are found after the Bronze Age. The initial purpose of lacquer is estimated to be adhesive, regarding the literatures mentioning bitumen(Yeoksceong ), animal glue(Kyeo) and egg alumen(Nanbaek). Especially piece of jar coffin unearthed in Pyeongtaek Daechu-ri site had trace of restoration by lacquer and hemp as an evidence of lacquer for adhesion in Pre-Three Kingdoms period. Since then a trend to restore the broken ceramics with lacquer and decorate with golden foil lasted especially in Joseon Dynasty. In the field of gold plated lacquer method, mother-of-pearl inlaying technique for lacquerware and restoration of buildings, lacquer is still used as adhesive. Due to matter of reversibility lacquer is being avoided for conservation and restoration of cultural heritage. Lacquer as a traditional material for adhesive since ancient times, however, has advantage in adhesion strength and durability. Because synthetic resin adhesive has problem of emission of volatile organic compounds and aging over time, lacquer receives attention recently. On the contrary, by combination adhesive from mixing lacquer and animal glue, already proved the possibility of applicability and chemical modification. A research to utilize lacquer as modern paint or functional material is also conducted continuously also in China and Japan. To put traditional material into practical use and modernize, chemical research from the molecular level of the lacquer is necessary in the near future.

A Study on the Blue Fluorescence Characteristics of Silica Nanoparticles with Different Particle Size (실리카 나노 입자의 크기에 따른 청색 형광 특성 연구)

  • Yoon, Ji-Hui;Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.5
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    • pp.1-6
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    • 2019
  • Organic dye-doped silica nanoparticles are used as a promising nanomaterials for bio-labeling, bio-imaging and bio-sensing. Fluorescent silica nanoparticles(NPs) have been synthesized by the modified $St{\ddot{o}}ber$ method. In this study, dye-free fluorescent silica NPs of various sized were synthesized by Sol-Gel process as the modified $St{\ddot{o}}ber$ method. The functional material of APTES((3-aminopropyl)triethoxysilane) was added as an additive during the Sol-Gel process. The as-synthesized silica NPs were calcined at $400^{\circ}C$ for 2 hours. The surface morphology and particle size of the as-synthesized silica NPs were characterized by field-emission scanning electron microscopy. The fluorescent characteristics of the as-synthesized silica NPs was confirmed by UV lamp irradiation of 365 nm wavelength. The photoluminescence (PL) of the as-synthesized silica NPs with different size was analyzed by fluorometry. As the results, the as-synthesized silica NPs exhibits same blue fluorescent characteristics for different NPs size. Especially, as increased of the silica NPs size, the intensity of PL was decreased. The blue fluorescence of dye-free silica NPs was attributed to linkage of $NH_2$ groups of the APTES layer and oxygen-related defects in the silica matrix skeleton.

Risk of Smoke Occurring in the Combustion of Plastics (플라스틱의 연소 시 발생하는 연기 위험성에 관한 연구)

  • You, Jisun;Chung, Yeong-jin
    • Fire Science and Engineering
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    • v.33 no.1
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    • pp.69-75
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    • 2019
  • In this study, the combustibility of five types of plastic plates, fiber reinforced plastic (FRP), polystyrene (PS), polycarbonate (PC), polypropylene (PP), and polyvinyl chloride (PVC), were tested using a cone calorimeter (ISO 5660). The PVC plate showed a $44.65kW/m^2$ lower peak heat release rate (HRR) and a $30.97kW/m^2$ lower maximum average rate of heat emission than the other four types of plastics, whereas the PS plate showed a $773.44kW/m^2$ higher peak HRR and $399.14kW/m^2$ higher maximum average rate of heat emission. The PC plate and PS plate showed the highest HRR by a maximum of 3.88 times in $CO_{mean}$ yields, while the PS pate and PP plate showed the highest HRR by a maximum 4.88 times in $CO_{2mean}$ yields. In addition, the smoke performance index (SPI) of the PS plate decreased by 74.81%~95.99%; the smoke growth index (SGI) increased to 76%~300%; the smoke intensity (SI) also increased to 917.73% ~ 9607.57%, and the danger of smoke increased. The PS plate was found to have the highest risk of life damage due to smoke on the thermal and smoke sides.

Examination about evaluation method of odor active compounds in evaporator by using condensed water (응축수를 이용한 냉각기의 냄새원인물질 평가방법 검토)

  • Kim, Sun-Hwa;Kim, Kyung-Hwan;Jung, Young-Rim;Kim, Man-Goo;Kim, Jae-Ho;Park, Ha-Young;Ji, Yong-Jun
    • Analytical Science and Technology
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    • v.20 no.5
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    • pp.361-369
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    • 2007
  • Uncomfortable odor emitted from air conditioning system is the main cause of indoor air quality deterioration. To solve evaporator odor problems, odor active compounds, have to be identified then the quality of the product can be improved its quality. Because evaporator odor in exhaust gas has low odor intensity and discontinuity, it is very difficult to collect and analyze sample. In this study through the identification of odor compounds in condensed water, the evaluation of the eraporator was tested. Odor compounds were extracted from water by headspace-solid-phase microextraction (HS-SPME) method. The single odor was separated by GC/FID/Olfactometry (GC/FID/O) and odor active compounds were identified by GC/AED and GC/MS. Compared to air sample, result of sensory evaluation and the single odor compound appeared similarly. It was identified that odor active compounds have functional group containing oxygen such as alcohols and acids. Evaluation method of odor active compounds using condensed water in evaporator appeared effective on the side of simplicity of collection, low expanse and rapid analysis.

Analysis of Applicability of Rapid Hardening Composite Mat to Railway Sites (초속경 복합매트의 철도현장 적용성 분석)

  • Jang, Seong Min;Yoo, Hyun Sang;Oh, Dong Wook;Batchimeg, Banzragchgarav;Jung, Hyuk Sang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.44 no.1
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    • pp.109-116
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    • 2024
  • The Rapid Hardening Composite Mat (RHCM) is a product that improves the initial strength development speed of conventional Geosynthetic Cementitious Composite Mats (GCCM). It offers the advantage of quickly securing sufficient strength in railway slopes with insufficient formation level, and provides benefits such as preventing slope erosion and inhibiting vegetation growth. In this study, an analysis of the practical applicability of RHCM in railway settings was conducted through experimentation. The on-site applicability was assessed by categorizing it into fire resistance, durability, and stability, and conducting combustibility test, ground contact pressure test, and daily displacement analyses. In the case of South Korea, where a significant portion of the territory is composed of forested areas, the prevention of slope fires is imperative. To analyze the fire resistance of RHCM, combustibility tests were conducted as an essential measure. Durability was assessed through ground contact pressure tests to analyze the deformation and potential damage of RHCM caused by the inevitable use of small to medium-sized equipment on the construction surface. Furthermore, daily displacement analysis was conducted to evaluate the structural stability by comparing and analyzing the displacement and behavior occurring during the application of RHCM with railway slope maintenance criteria. As a result of the experiments, the RHCM was analyzed to meet the criteria for heat release rate and gas toxicity. Furthermore, the ground contact pressure was observed to be consistently above 50 kPa during the curing period of 4 to 24 hours under all conditions. Additionally, the daily displacement analyzed through field site experiments ranged from -1.7 mm to 1.01 mm, confirming compliance with the criteria.