• Journal of the Korean Electrochemical Society
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• v.15 no.4
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• pp.222-229
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• 2012

We studied the electrochemical phenomena and increase of capacity according to the polymer composite electrode of two different polymeric materials with different the voltage range and capacity. Polyaniline (PANI) with relatively high voltage and small capacity and poly [1,2] bis-thio[1,8]-naphthylidine (PTND) with slightly low voltage and large capacity were used as polymer composite electrode materials. After PTND was synthesized, PANI was synthesized on the surface of PTND. The synthesis and the fine structure were analyzed by FT-IR, XPS, FE-SEM, and FE-TEM. Charge/discharge capacity and cyclic voltammetry measurements were carried out for the electrochemical performance as a polymer cathode active material for lithium secondary batteries. The discharge capacities of PANI/PTND after 1,5, and 10 cycles at 1.3~4.0 V voltage range and room temperature 167 mAh/g, 90 mAh/g, and 81 mAh/g. When we compared with PANI (80, 67, and 62 mAh/g), the discharge capacity after 10 cycles was improved about 30%. After 50 cycles, the discharge capacity of PANI/PTND was 67 mAh/g.

• Journal of the Korean Applied Science and Technology
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• v.30 no.2
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• pp.362-370
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• 2013

The coconut shell based activated carbon was applied for EDLC (electric double layer capacitor) electrode with the post treatments. The electrochemical properties were evaluated with a coin cell using the activated carbon as electrode. The initial gravimetric and volumetric capacitance of the coconut shell based activated carbon electrode s were 66 F/g and 39 F/cc, and these values decreased to 54 F/g and 32 F/cc after 100 cycles, respectively showing 82% of charge-discharge efficiency. The properties of CV graph with the commercial activated carbon electrodes showed the serious polarization as the result of additional reaction between electrolyte and impurities of the electrode materials. In order to remove impurities efficiently, the commercial activated carbon was treated by alkali and acid solutions consecutively, and then heat treated to control the pore size distribution and the content of surface functional groups. The surface functional groups decreased with the increased heat temperature and the specific capacitance increased with the decreased surface functional groups. The initial capacitance of coconut shell based activated carbon elec trode which was treated with NaOH and HNO3, and then heat treated at $800^{\circ}C$ was 44 F/cc, and the value turned out to be 42 F/cc after 100 cycles, showing over 95% of charge-discharge efficiency.

• Applied Chemistry for Engineering
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• v.25 no.2
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• pp.161-166
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• 2014

In this study, effects of pyrite ($FeS_2$) particle sizes on the electrochemical characteristics of thermal batteries are investigated using unit cells made of pulverized pyrite by ball-milling. At $450^{\circ}C$ unit cell discharge test, the electrochemical capacity of $1.46{\mu}m$ pyrite-cell largely increases compared to $98.4{\mu}m$ pyrite-cell, and their internal resistances also decrease. These results are attributed to the increase in the active reaction area of pyrite by ball milling. However, at $500^{\circ}C$ unit cell discharge test, a $1.46{\mu}m$ pyrite cell shows lower internal resistance than that of $98.4{\mu}m$ pyrite cell only at Z-phase region ($FeS_2{\rightarrow}Li_3Fe_2S_4$). After that, a $1.46{\mu}m$ pyrite cell shows a decrease in the cell voltage and an rapid increase of the internal resistance in J-phase region ($Li_3Fe_2S_4{\rightarrow}LiFe_2S_4$) is observed compared to those of $98.4{\mu}m$ pyrite cell. It can be concluded that at the higher temperature, the thermally unstable pulverized pyrite is decomposed thermally as well as self discharged, simultaneously, which causes the higher resistance and lower capacity at $500^{\circ}C$ in J-phase than that of $98.4{\mu}m$ pyrite cell.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.4
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• pp.357-364
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• 2018

Fly ash is a material used as a concrete admixture. When fly ash is used for concrete manufacturing, it is expected to improve the performance such as reduction of cement usage and increase of chemical resistance. However, fly ash have some problems such as unburned carbon content and amorphous film on the surface of fly ash particles. When concrete is manufactured using fly ash containing a large amount of unburned carbon, there is a problem that the slump is lowered due to adsorption of AE agent. In addition, the amorphous film on the surface of the particles prevents the reactive substances from leaching out of the fly ash. Therefore, a method of surface treatment of fly ash using plasma has been studied to remove such unburned carbon and amorphous films. However, plasma has the problem that $O_3$ is generated when $O_2$ is used as an active gas. $O_3$ is a harmful substance and adversely affects the health of the experimenter. In this study, the surface of fly ash was treatment by arc discharge. Experimental results show that the unburned carbon is removed when the surface of fly ash is treatment by arc discharge and the amorphous film was broken and the reactivity was improved. Therefore, it is considered that arc discharge can treatment the surface of fly ash and improve the quality of fly ash.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.6 no.7
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• pp.1055-1061
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• 2002

This paper deals with a design and fabrication of an electronic ballast for 70[W] ceramic discharge metal halide lamps. The proposed ballast is composed of a rectifier, an active power factor correction circuit (PFC), a half-bridge inverter, a LC resonant circuit and a microprocessor. The developed ballast also includes a specially designed time circuit which provides reignition signal of lamps. Running frequency of the ballast is .jet at 40[kHz] to avoid acoustic-resonance and flickering. From the experimental results, input power factor and efficiency of the ballast are estimated 99.8[%] and 93.1[%], respectively.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.16 no.2
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• pp.1-8
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• 2002

The electronic ballast have much more shaking of arc than magnetic ballast because of acoustic resonance phenomenon. but it has used mare than before. In this paper, we made metal halide lamp modeling by modifying modeling of mercury lamp. To avoid acoustic resonance phenomenon, We calculated acoustic resonance frequency band. We proposed design of LCC circuit. Also, electronic ballast simulator for metal halide lamp was developed by simulink LCC parameters of inverter was decided on the basis of simulation results. After development of prototype ballast, it was verified the characteristics of simulator.

• Korean Journal of Materials Research
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• v.5 no.2
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• pp.178-183
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• 1995

Piezoelectric properties of sintered specimen having a tetragonal phase of $Pb_{0.9888}Sr_{0.012}(Zr_{0.52}Ti_{0.48})O_{3}$ were comparatively studied with two different poling methodes, i.e., DC field and corona discharge technique. Internal stress of poled specimens by indentation fracture toughness was analyzed to evaluate degradation phenomenon. As the results, it was confirmed that corona discharge poling technique is practicable and has merits such as low-temperature poling, slow degradation and no electric breakdown comparing to DC field poling. However, corona discharge technique showed lower Kp value than DC field poling.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2002.11a
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• pp.435-439
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• 2002

This paper describes a design and fabrication of an electronic ballast for 70[W] ceramic discharge metal halide lamps. The proposed ballast is composed of a rectifier, an active power factor correction circuit (PFC), a half-bridge inverter, a LC resonant circuit and a microprocessor. The developed ballast also includes a specially designed time circuit which provides reignition of lamps. Running frequency of the ballast is set at 40[kHz] to avoid acoustic-resonance and flickering. From the experimental results, input power factor and efficiency of the ballast are estimated 99.8[%] and 93.1[%)] respectively.

• JOURNAL OF ELECTRICAL WORLD
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• no.2 s.110
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• pp.92-98
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• 1986

과학의 현저한 발달과 산업의 발전은 고도의 풍부한 인간사회를 만들어 냈는데 반면에 사람과 건강이나 생활에 장해가 되는 여러 가지의 환경문제가 생겼다. 가령 화학공장, 화력발전소, 자동차 등에서의 배기가스에 의한 대기오염, 각종 공장에서의 배액, 가정의 배수 등으로 인한 수질오염 및 폐기물 등에 의한 토양오염, 제트기, 고속철도, 자동차 및 공장 등에서 발생하는 소음, 원자력 이용에 의한 방사능 등의 환경문제가 발생한 것이다. 이들 환경문제에 대해서는 원인의 규명, 특성의 해명, 실태조사 등 그 해명에 노력이 경주되고 있으며 사람의 건강보존과 생활의 안정에 의하여 고도의 문화생활을 할 수 있도록 대책을 강구하는 노력을 하고 있다. 현재는 공업의 현저한 발달에도 불구하고 매우 좋은 생활환경으로 되어 있다. 전자환경문제란 전기가 원인으로 발생하는 여러 가지의 현상, 가령 전계, 자계, 대전, 방전, 전자파 등의 각종 현상을 명백히 하고 그것이 사람의 건강이나 생활에 미치는 영향의 유무를 조사하여 영향이 있는 경우에는 대책을 강구하는 것이다. 우리들 인류를 포함한 생물은 본래 자연에 존재하는 전자환경 속에서 생존하고 있다. 또한 생물 체내에는 전기가 존재하여 통전이 용이하며 통전의 전기의 크기에 따라서는 심하게 반응하거나 마비되거나 토사하거나 하는 수가 있다. 따라서 인공의 전자환경이 이상상태에 있으면 어떤 영향을 받을 지도 모른다. 따라서 강한 전자계를 발생하거나 전자파를 발생하는 전자설비나 기기에 대해서는 영향의 유무를 고려하여 어떤 경우에는 대책이 필요해진다. 고전압가공송전선은 그같은 종류의 하나의 설비이다. 자연 및 각종 인공의 전자환경을 보면서 송전선의 전자환경에 대하여 고찰해본다.

• Journal of computational fluids engineering
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• v.13 no.4
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• pp.58-65
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• 2008

In the present study, a numerical analysis on electrohydrodynamics (EHD) of the flow and the collection mechanisms inside a electrostatic precipitator with a spiral spike electrode were investigated. The phenomena of the electrostatic precipitator include complex interactions between the electric field, the fluid flow and the particle motion. To validate the numerical method, the numerical computation for the electric field of a simple wire-pipe type electrostatic system having an analytic solution were performed. Using this numerical method, the electric field of the spiked electrostatic precipitator was simulated. And the fluid flow and the particle motion inside the spiked electrostatic precipitator were numerically analyzed.