• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.22 no.6
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• pp.127-133
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• 2008

This paper presents the battery management system(BMS) for the optimum conditions of the lead-Acid battery in UPS. The proposed system control the currents and voltages of battery for optimum conditions to estimate the State Of Charge(SOC) in charge or discharge mode. It proved the performance and the algorithm for the estimation of SOC, through the experiments which using the charge and discharge tester and the field tests.

• Proceedings of the KIPE Conference
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• 2018.07a
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• pp.474-475
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• 2018

본 논문은 충 방전 실험을 통해 온도와 C-rate에 따른 24S1P 배터리팩 내부 저항 변화와 용량을 비교분석하였다. 충전 및 방전 전류의 크기와 온도의 변화에 따라 변하는 내부 저항과 용량의 변화를 비교분석하기 위해 다양한 온도 조건($-5^{\circ}C$, $25^{\circ}C$, $55^{\circ}C$)에서 SOC별(0.04C, 1/3C) HPPC 테스트를 진행하였다. 실험을 통해 얻은 데이터로 1차 RC 등가모델을 통하여 온도와 C-rate에 따른 저항, 용량 변화를 분석하였다.

• Clean Technology
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• v.24 no.4
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• pp.332-338
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• 2018

Currently graphite is used as an anode active material for lithium ion battery. However, since the maximum theoretical capacity of graphite is limited to $372mA\;h\;g^{-1}$, a new anode active material is required for the development of next generation high capacity and high energy density lithium ion battery. The maximum theoretical capacity of Si is $4200mA\;h\;g^{-1}$, which is about 10 times higher than the maximum theoretical capacity of graphite. However, since the volume expansion rate is almost 400%, the irreversible capacity increases as the cycle progresses and the discharge capacity relative to the charge is remarkably reduced. In order to solve these problems, it is possible to control the particle size of the Si anode active material to reduce the mechanical stress and the volume change of the reaction phase, thereby improving the cycle characteristics. Therefore, in order to minimize the decrease of the charge / discharge capacity according to the volume expansion rate of the Si particles, the improvement of the cycle characteristics was carried out by pulverizing Si by a dry method with excellent processing time and cost. In this paper, Si is controlled to nano size using vibrating mill and the physicochemical and electrochemical characteristics of the material are measured according to experimental variables.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2014.11a
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• pp.199-199
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• 2014

좁은 관경을 갖는 상대 유전율 3 이하인 PTFE와 PE 고분자 튜브 내부에 플라즈마 방전을 일으켜 고분자 튜브 표면 그래프팅 기술을 개발 하고자 하였다. 스텐트 및 인공혈관 등에 적용이 가능한 내부지름 3 mm 이하의 원통형 고분자 생체 식립체 내부 표면을 그래프팅하는 기술이다. 좁은 고분자 튜브 내부에 생성되는 방전은 고분자의 관경에 의해 방전개시 전압이 결정되었다. 방전개시 이후 DC glow discharge 에서 나타나는 전압과 전류의 특징들이 나타났다. 전압과 전류의 파형 분석에서는 고분자 표면과 가스 간의 새로운 용량성 임피던스가 형성되는 것을 관찰하였다. 고분자 내부 표면에 플라즈마의 방전 형태는 면 방전 (surface discharge)의 형태로 나타났다.

• 한국전기화학회:학술대회논문집
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• 2000.04a
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• pp.32-32
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• 2000

• Journal of the Korean Professional Engineers Association
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• v.15 no.3
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• pp.12-18
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• 1982

Preliminary investigation have been made on what the capacity of high rate pulsed discharge of Ago-Zn button cells were associated with the changes of cathode construction feature, mix formulation, separator and electrolyte concentration.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 1998.11a
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• pp.92-92
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• 1998

반도체 기술의 경이적인 발전에 힘입이 최근 휴대용 이동통신기기, 노트북 컴퓨터 등 무선전자제품의 폭발적인 수요와 함께 이들의 소형화, 경량화가 요구되어 전원인 2차전지의 경량화, 고용량화, 장수명화의 필요성이 절실해졌다. Ni-MH 전지는 Ni-Cd전지에 비해 에너지밀도가 1.5~2배에 이르고 충방전 cycle이 길며 오염물질이 없어 환경 친화적이라는 장점이 었다. Ni-MH 전지의 성능은 음극재료인 수소저장합금에 의해 좌우되므로 수소저장능력이 크고 내식 성이 우수한 합금개발이 중요하다. $CaNi_5$는 수소저장능력이 크고 매장량이 많아 값이 싸다는 장점이 있지만 KOH 용액에서 내구성이 떨어진다는 단점이 있어 주로 Heat Pump 재료에만 사용이 제한되어왔다. 본 실험에서는 결정 구조의 nanocrystalline 및 amorphous화함으로써 해리압의 변화, 방전용량의 변화 등 새로운 전극 특성을 나타낸다고 보고되고 있는 MG (Mechanical Grinding)방법을 통해 CaNis 합금의 전극특성의 변화를 살펴보았고, 아울러 고상-기상반응에서 표면에 형성된 산화피막을 제거하여 안정한 불화물을 표면에 형성시킴으로써 불순물 가스에 대한 내구성을 높이고 활성화특성을 향상 시킨다고 보고되고있는 불화처리 방법을 이용하여 불화처리 시간을 달리하면서 용액 속에서의 pH의 변화, ICP분석, 전극의 성능 및 표면 특성변화를 충방전 test, SEM 등을 통해 고찰하였다.

• Korean Chemical Engineering Research
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• v.47 no.1
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• pp.84-88
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• 2009

Al doped $LiMn_2O_4$ cathode powders with fine size were synthesized by an ultrasonic spray pyrolysis method from the spray solution with citric acid and ethylene glycol. The as-prepared powders with spherical shape, porous structure and micron size turned into $LiMn_{11/6}Al_{1/6}O_4$ powders with micron size and regular morphology after post-treatment above $800^{\circ}C$. The $LiMn_{11/6}Al_{1/6}O_4$ powders had low initial discharge capacity of 94 mAh/g at a post-treatment temperature of $700^{\circ}C$. As the post-temperature increased from $750^{\circ}C$ to $1,000^{\circ}C$, the initial discharge capacities of the $LiMn_{11/6}Al_{1/6}O_4$ powders changed from 103 to 117 mAh/g. The $LiMn_{11/6}Al_{1/6}O_4$ powders had the maximum discharge capacity at a post-treatment temperature of $750^{\circ}C$. However, the $LiMn_{11/6}Al_{1/6}O_4$ powders post-treated at a temperature of $900^{\circ}C$ had the good cycle properties. The discharge capacities of the $LiMn_{11/6}Al_{1/6}O_4$ powders dropped from 107 to 100 mAh/g (93% capacity retention) by the 70th cycle at a current density of 0.1 C.

• Journal of the Korean Electrochemical Society
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• v.4 no.2
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• pp.53-57
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• 2001

When an EV is parked for a long period time, the battery capacity naturally decreases due to selfdischarge. Therefore, this effect must be considered for the accurate measurement of the state of charge of EV battery. Battery selfdischarge simulations using the design of experiments among computer simulation methods are compared with experimental data for Ni/MH batteries for electric vehicles. The motivation is to predict the selfdischarge rate of the battery for electric vehicle at all temperature conditions and standing time when electric vehicle could be operated. We developed a general equation representing the seudischarge rate of the electric vehicle battery using design of experiments, and the equation is determined by temperature and standing time of the battery. We selected Ni/MH battery, 12 V-95 Ah, for pure electric vehicle for this study. ID develop the equation using design of experiments we selected temperature range of $-20^{\circ}~30^{\circ}C$ and standing time of 1 day$\~15$ days. We conducted several selfdischarge tests of Ni/MH battery to verify the integrity of the equation. The results showed that the computation values were in good agreement with experimental data.

• Journal of the Korean Electrochemical Society
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• v.11 no.4
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• pp.297-303
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• 2008

$LiNiO_2$ cathode powders with fine size have been synthesized by spray pyrolysis from the spray solution with citric acid and ethylene glycol. The as-prepared powders with spherical shape, porous structure and micron size turned into $LiNiO_2$ powders with micron size and regular morphology after post-treatment at $800^{\circ}C$. The initial discharge capacities of the $LiNiO_2$ powders changed from 199 to 171mAh/g when the concentrations of the citric acid and ethylene glycol added to the spray solutions were changed from 0 to 1 M. The maximum initial discharge capacity of the $LiNiO_2$ powders obtained from the spray solution with citric acid and ethylene glycol was 198 mAh/g when the lithium component added to the spray solution was 6 mol% excess of the stoichiometric amount. The discharge capacities of the fine-sized $LiNiO_2$ powders dropped from 198 to 163 mAh/g by the 30 th cycle at a current density of 0.1 C.