• Title/Summary/Keyword: 방사화분석

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Study on the Simulation of Crud Formation using Piping Materials of Nuclear Power Plant in High Temperature Water (원자력 발전소 배관재를 이용한 고온 수화학 조건에서의 방사화 부식생성물 모사에 관한 연구)

  • Kim Sang Hyun;Kim In Sup;Lee Kun Jai
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.1
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    • pp.31-40
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    • 2005
  • High temperature - high pressure apparatus was developed to simulate nickel fewite corrosion products which were main compositions of the radioactive crud in the nuclear power plant. Corrosion product similar to the crud was obtained by a tube accumulator system. Nickel alloy (Inconel 690) and carbon steel (SA106 Gr. C) were corroded at 270 $\^{circ}C$ in the corrosion product generator. Ni ions and Fe ions dissolved by corrosion reaction were able to be transported to the accumulator because the crud generation mechanism was the solubility change with temperature. To evaluate the properties of simulated corrosion products, scanning electron microscope (SEM) observation and EDAX analysis were performed. SEM observation of corrosion product showed the needlelike or crystal structure of oxide depending on precipitating location. The crystal oxide was the nickel ferrite, which was similar to the crud in nuclear power plants.

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Determination of Trace Elements in $PM_{2.5}/PM_{10}$ of Daejeon Region Using Neutron Activation Analysis(V) (중성자 방사화분석에 의한 대전지역 $PM_{2.5}/PM_{10}$의 미량원소농도의 측정(V))

  • 김선하;문종화;임종명;백성렬;정용삼
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.376-377
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    • 2003
  • 대기환경에 대한 정보의 파악은 환경연구의 기본이 된다. 유해원소 및 미량원소에 의한 환경오염과 그로 인한 인체건강에 대한 영향은 인간생활에 심각한 문제가 되므로 대기, 수질, 토양등의 환경시료 중의 농도를 정확히 측정하는 것은 매우 중요한 일이다. 중성자 방사화분석법은 핵반응을 통해 생성시킨 방사성동위원소로부터 방출되는 방사선을 검색하여 절대적으로 성분원소를 정량하는 핵분석기술(Nuclear Analytical Techniques)중의 하나로서 소량의 시료로부터 미소량원소의 비파괴, 동시다원소분석이 가능하고 분석감도($10^{-3}$ - $10^{-7}$$\mu\textrm{g}$)가 탁월한 분석기술이다. (중략)

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Determination of major and minor elements in low and medium level radioactive wastes using closed-vessel microwave acid digestion (밀폐형 극초단파 산분해법을 이용한 중${\cdot}$저준위 방사성폐기물의 성분 원소 분석)

  • Lee Jeong-Jin;Pyo Hyung-Yeal;Jeon Jong-Seon;Lee Chang-Heon;Jee Kwang-Yong;Ji Pyung-Kook
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.4
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    • pp.231-238
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    • 2004
  • The conditions are obtained for the decomposition of solid radioactive wastes, including ion exchange resin, zeolite, charcoal, and sludge from nuclear power plant. In the process of decomposing the radioactive wastes was used the microwave acid digestion method with mixed acid. The solution after acid digestion by the following method was colorless and transparent. Each solution was analyzed with ICP-AES and AAS and the recovery yield for 5 different elements added into the simulated radioactive wastes were over $94{\%}$. The elemental analysis of destructive low and medium level radioactive wastes by the proposed microwave acid digestion conditions concerning the chemical characteristics of each radioactive waste are expected to be useful basic data for development of optimal glass formulation.

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Determination of Impurities in Uranium Dioxide by Neutron Activation Analysis (중성자방사화분석법에 의한 이산화우라늄중의 불순물정량)

  • Nak Bae Kim;Hae-Ill Bak;Chul Lee
    • Nuclear Engineering and Technology
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    • v.13 no.4
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    • pp.237-244
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    • 1981
  • The preliminary concentration of trace elements in uranium dioxide using an anion exchange resin is presented for neutron activation analysis. The uranyl solution in sulfuric acid is adjusted to the acidity of about pH 2.7 and loaded on a column of the anion exchange resin. An appropriate volume of eluates obtained from the column shows good recoveries of trace elements. By combining this preconcentration with a radiochemical separation scheme, which was developed for the determinations of impurities in aluminum, it is possible to determine 21 trace elements in reactor grade uranium dioxide.

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Development of Low-activation Cement for Decreasing the Activated Waste in Nuclear Power Plant (원전 방사화 폐기물 저감을 위한 저방사화 시멘트의 개발)

  • Lee, Binna;Lee, Jong-Suk;Min, Jiyoung;Lee, Jang-Hwa
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.3
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    • pp.223-229
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    • 2017
  • When concrete is exposed to neutron rays for a long time, the concrete tends to become activated. If activated, it is classified as middle or low level radioactive waste. However, the great amount of the activated concrete is hard to dispose. In this study, low-activation cement was developed for decreasing the activated waste from shielding concrete around nuclear reactor. Furthermore, the manufactured low-activation was analyzed with activation nuclide Eu, Co. The low-activation cement showed great advantage for low-activation with detecting none of Eu and 3.75ppm of Co while ordinary portland cement showed 0.4~0.9ppm of Eu, 5.5~19.8ppm of Co content. As the results of physical properties of the low-activation cement, it is similar to type 1 ordinary portland cement and accords with type 4 low heat portland cement. Meanwhile, as for the chemical properties of the cement, it accords wite type 1 and 4 at the same time.

Radiological Impact Assessment for Radioactive Concrete in Dismantling of the Medical Cyclotron (의료용 사이클로트론 해체 시 발생되는 방사화 콘크리트의 방사선학적 영향평가)

  • Jang, Donggun;Shin, Sanghwa
    • Journal of the Korean Society of Radiology
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    • v.13 no.1
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    • pp.73-80
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    • 2019
  • Neutrons are generated by the nuclear reaction, which is absorbed into the concrete wall and causes the activation during cyclotron operation. The purpose of this study is to investigate the effect of neutron activation and radiative concrete on concrete type. This experiment used Monte Carlo simulation and RESRAD model. The results of the experiment showed that the higher the content of Fe in concrete, the greater the shielding rate. The effect of $^{56}Fe(n,\;2np)^{54}Mn$ reaction on workers is also increased. However, radioactive nuclides have low activity and have very low impact on workers. Radioactive concrete should be treated as general wastes with less than its self-disposal tolerance level, and it should be recycled to the surface such as road repair rather than landfill to minimize the effect of $^{14}C$.