• Journal of the Korean Wood Science and Technology
• /
• v.29 no.2
• /
• pp.126-132
• /
• 2001

This research is carried out to investigate the formation and preservative effectiveness of inorganic substance, calcium carbonate($CaCO_3$), in wood. The specimens were prepared by the impregnation with saturated solutions of potassium carbonate($K_2CO_3$) into the wood followed by precipitation in saturated solutions of calcium chloride($CaCl_2$) for 24h, 72h and 120h, and then they were leached in instrument flowing with water for 24h. The weight percent gains of $K_2CO_3$ solution impregnated specimens reached approximately a maximum value (108.1%) by 72h precipitation in $CaCl_2$ solutions. Inorganic substances were observed to he produced in the lumina of tracheids of specimens. From these inorganic substances filling in the tracheids, characteristic X-rays of calcium(Ca-$K_{\alpha}$) were detected by energy dispersive X-ray analyzer. Moreover, it was shown from a leaching treatment that these substances could not he leached easily from the specimens. Therefore, they were could he considered to be insoluble calcium carbonates. The weight losses of the prepared specimens were hardly occurred by test fungi attacks. Thus inorganic substances in specimens can be said to have preservative effectiveness.

• Journal of the Korean Wood Science and Technology
• /
• v.21 no.4
• /
• pp.7-28
• /
• 1993

본 총설에서는 새로운 방부제와 방부처리 기술의 현재 발전 동향을 요약, 보고한다. 많은 새로운 방부제들이 약제의 독성 측면에서 환경적인 충격을 완화시킬 수 있는 잠재성을 가지고 있지만, 방부제로서 상업화되기 위해서는 이러한 약제들은 약제의 효능과 환경 안전성 간의 몇 가지 상호 조정 관계가 반드시 해결되어야 한다. Ammoniacal copper 계통의 방부제들이 지접부 사용에 적합한 새로운 수용성 방부제들의 주종을 이루고 있으며, 기존의 유용성 방부제들을 물에 용해한 emulsion 형태도 지접부 사용의 가능성을 보여 준다. 새로운 유용성 방부제 중에서 copper naphthenate, substituted isothiazolones, chlorothalonil, oxine copper가 지접부 사용을 위한 최상의 후보로 평가되고 있다. 유용성 방부제를 emulsion 형태로 사용하는 것은 유용성 방부제에 사용되는 석유 계통 용제의 소비를 감소시키기 때문에 중대한 의미를 가진다. 방부제들의 효능을 개선하고 강화시키기 위해 사용되는 첨가제들도 본 총설에서 거론된다. 재질개량을 위해 사용되는 비통상적인 방법(nonconventional system)들도 생물학적 열화 및 기상열화에 대한 저항성을 부여하여 목재의 사용수명을 증가시킨다. 전처리 공정에서 침상 자상처리(Needle incising)와 레이져 자상처리는 난주입 수종의 처리도를 개선시킬 수 있는 잠재성을 가지고 있다. 처리기술에 있어서 여러 가지 혁신적인 변화들은 기존의 처리 schedule을 조성함에 그 기본을 두고 있다. 난주입 수종의 처리도 개선은 pulsation법이나 고압 약제 분사법 (high energy liquid jets) 같은 고압을 적용하는 처리법에 의해서 달성된다. 미래의 처리공장들은 방부제를 기체상태로 또는 물질의 임계점 이상에서 방부제를 처리할 수도 있다. 이러한 새로운 접근은 외관이 깨끗하고, 처리도도 매우 양호한 처리재를 생산하는데 일조하리라 기대한다. 환경에 대한 대중적인 지대한 관심은 앞으로 목재 방부산업에 큰 영향을 미칠 것으로 보인다. 결과적으로 방부제의 처리목재내 가속 정착에 관한 연구에 상당한 노력이 투자될 것이다. 처리 후 가공에 관한 다른 주요한 연구는 방부제 처리 후 실시되는 재건조가 처리재의 역학적 성질에 미치는 영향에 대한 것이다.

• Proceedings of the Korean Society for Agricultural Machinery Conference
• /
• 2003.07a
• /
• pp.469-477
• /
• 2003

삼림에서 벌채된 목재는 대부분 건조공정을 거쳐 산업용 재료가 되므로 건조정도에 따라 목질 재료의 품질이 결정된다. 목재에 포함된 과도한 수분을 제거하여 운송비용을 줄일 수 있으며 목재를 적절하게 건조하게 되면 목재 사용 중에 발생할 수 있는 수축 및 팽윤을 제한할 수 있을 뿐만 아니라 건조과정을 통해 비틀림, 갈라짐, 할열 등과 같은 결함의 발생을 크게 줄일 수 있다. 또한 건조된 목재는 생재에 비해 기계 가공이 보다 용이하기 때문에 정확한 치수로 재단이 가능하며, 각각의 부품으로 재단한 부재를 못이나 나사못, 볼트, 접착제 등을 사용하여 견고하게 짜 맞출 수 있다. 그리고 도장성능이 향상되어 기능성을 증진시킬 수 있으며, 건조 후의 방부처리를 통해 장기간의 사용이 가능하다. (중략)

• Journal of the Korean Wood Science and Technology
• /
• v.18 no.1
• /
• pp.24-30
• /
• 1990

This study was attempted to propose a method evaluating fixation of active ingredients in Copper-Chromium-Arsenic preservatives treatment. Fixated amount of active ingredients on wood was obtained by measuring the density of surface electric charge based on $\varsigma$ potential. Data accumulated from density of surface electric charge showed that the fixated amount of preservatives on wood increased linearly as concentration of treating solution increaced, which indicatied quantitative reactions in fixation of preservatives.

• Journal of the Korean Wood Science and Technology
• /
• v.36 no.3
• /
• pp.85-92
• /
• 2008

Strength of logs and round posts is compared and analyzed to estimate the strength of the incised Larix round posts treated with CCA in this paper. There is no significant difference in MOR of logs and round posts. However, in the incised Larix round posts treated with CCA MOE is decreased to about 9%, and there is 29% reduction in MOR as strength ratio is 0.71. When calculating the allowable bending stress of incised round type round posts, not in nominal 2-in timbers, an adjustment factor for MOE and bending strength is proposed as 0.91 and 0.71, respectively. Logs, round posts and the incised Larix round posts treated with CCA do not show significant difference in nail withdrawal load. There is almost no difference between incised Larix round posts treated with CCA and round posts in the shear strength of bolted joint. When calculating the allowable shear stress of bolted joint, it is conformed that considering the application of incising factor is not necessary.

• Journal of the Korean Wood Science and Technology
• /
• v.30 no.2
• /
• pp.151-157
• /
• 2002

The removing copper from CCA, CCFZ treated wood were tested with Tyromyces palustris. The shacking culture, solid culture, and stationary culture methods were tested to removal of copper in CCA, CCFZ treated wood. The steam pressure method and oxalic acid method were tested as pretreatment. To investigate of copper removal mechanism, the oxalic acid that produced by T. palustris and combination with copper was examined on stationary culture that contained CCA and CCFZ treated wood chips. Oxalic acid increased copper removing rate of T. palustris as pretreatment. Stationary culture had most removal effectiveness among the culturing methods. The removal rate of copper on bioreactor was 61% on 7 days. Copper-oxalate was detected on liquid culture, which show the oxalate from liquid of culture combined with copper from treated wood. It would be related to the removal of copper from treated wood by T. palustris.

• Resources Recycling
• /
• v.18 no.5
• /
• pp.52-62
• /
• 2009

This research was carried out to formulate environmentally friendly wood preservatives with okara and to investigate the effects of the acid concentration used for the hydrolysis of okara and salt type on the decay resistance of the preservatives. Okara-based preservatives were formulated with okara hydrolyzates, which were prepared with 0, 1%, and 2% sulfuric acid at $25^{\circ}C$ for 1 hr, and salts such as copper chloride and/or sodium borate. The preservatives were treated into wood blocks by vacuum-pressure method, and then the treated wood blocks were leached in $70^{\circ}C$ hot water for 72 hrs. The fungal treatments of the leached wood blocks were conducted by brown-rot fungus, Tyromyces palustris, and white-rot fungus, Trametes versicolor, to examine the decay resistance of the preservatives. As the acid concentration used for hydrolysis of okara increased, the treat-ability and decay resistance of the preservatives were improved, which the leachability was decreased. Wood blocks treated with the okara/copper or okara/copper/borax, showed very good decay resistance against T. palustris and T. versicolor. However, wood blocks treated with the okara/borax and okara-free preservative solutions, were observed the fungal decay by T. palustris. The optimal conditions for the preparation of okara-based wood preservatives were formulated with okara hydrolyzed with 1% sulfuric acid, copper chloride and borax.

• Journal of the Korean Wood Science and Technology
• /
• v.18 no.3
• /
• pp.34-41
• /
• 1990

본 연구는 CCA로 방부(防腐)처리된 Lodgepole pine 각재(角材)의 재건조(再乾燥)시 고온건조법(高溫乾燥法)의 적용이 건조속도(乾燥速度) 및 건조결함(乾燥缺陷)의 발생에 어떻게 영향하는가를 고찰하고자 수행되었다. 고온건조시 건조속도는 통당(通常) 열기건조(熱氣乾燥)시보다 약(約) 2.5배 증가되었으며, 방부처리재의 재건조 속도는 처리전(前)의 전건조속도보다 약간 감소됨을 보였다. 표면할열(表面割裂)의 발생정도(程度)은 전건조시의 경우, 고온건조시 보다 심(甚)하였으나 재건조시에는 건조방법간에 큰 차이가 없었다. 방부제의 침투(浸透)를 도모(圖謀)하기 위하여 자상(自傷)처리(Incising)된 각재의 경우에는 재건조시 절개부(切開部)의 연장(延長)에 의해 할렬의 정도가 증가됨을 보였다. 뒤틀림(Warping)의 발생정도는 고온건조시가 통상 열기건조에 비해 심하지 않았으며, 전(全) 건조과정을 통하여 발생된 뒤틀림은 WWPA가 정(定)해놓은 Lodgepole pine 2등급(等級)(No. 2 grade)의 뒤틀림 허용치(許容値)의 범위내(範圍內)에 있음을 보였다. 결론적(結論的)으로, 고온건조시 증가되는 건조속도와 건조재의 질(質)에 큰 영향을 주지않는 범위내에서 발생되는 건조결함을 고려할 때, Lodgepole pine의 전건조및 CCA 처리후 재건조를 위해 큰 문제없이 고온건조법이 적용될 수 있음을 보였다.

• Journal of the Korean Wood Science and Technology
• /
• v.38 no.6
• /
• pp.532-540
• /
• 2010

The strength properties of wooden model retaining wall made of pitch pine (Pinus rigida Miller) was evaluated. Three different types of wooden model retaining wall were made of the 11cm square timber treated with CUAZ-2 (Copper Azole). The retaining wall was made into the 4 layers of crossbar and the 3 layers of vertical-bar, of which the size was 86 cm high, 200 cm long and 96 cm wide. Type I was control and in Type II 20 cm vertical-bars and 93 cm vertical-bars were arranged alternately to decrease wood usage. TypeIII was similar to TypeII except that the connection between crossbars was reinforced with the wooden armature. In each type, the strength properties of retaining wall were investigated by horizontal loading test and the deformation of structure by image processing (AICON 3D DPA-PRO system). In horizontal loading test of Type I, Type II and Type III was 63.17, 57.80, and 60.97 kN/m, respectively. The deformation of the top layer in Type II was 1.5 times larger than in Type I and Type III. Consequently, the economic efficiency and strength performance were better in Type III than in Type I and Type II.

• Journal of Applied Biological Chemistry
• /
• v.55 no.1
• /
• pp.55-59
• /
• 2012

We designed a new rapid detection method for volatilized formaldehyde from wood. The process was installed with volatilizing and collecting parts in an incubator. For rapid sampling of formaldehyde from wood, we pulverized the wood to sawdust, and used 0.15-2.0 mm particles for the tests. The highest sampling rate (94.8%) was obtained at 40 mL/min flow rate and $100^{\circ}C$. Under the optimized condition, we could collect the volatilized formaldehyde with good recovery rate. The developed method was applied to the monitoring of the formaldehyde from wood, and the measured concentrations were 0.7-4.6 ${\mu}g/g$ from natural wood, 5.9-12.3 ${\mu}g/g$ from preserved wood, and 5.9-211.5 ${\mu}g/g$ from chemical adhesive processed wood. From the results, we identified natural wood sawdust and chemically processed wood (medium density fiberboard, high density fiberboard, particle board) by the formaldehyde contents except preserved wood.