• Title/Summary/Keyword: 발화점

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폐목재 재활용 분진의 화재폭발위험성

  • Lee, Su-Hui;Han, U-Seop;Han, In-Su
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2013.04a
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    • pp.115-115
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    • 2013
  • 최근의 분진폭발은 플라스틱, 의약품, 목재, 곡물 저장고, 고체연료, 화학제품 제조공정 등을 포함하여 성형 및 가공 공정 등에서 화재폭발사고가 발생되고 있다. 폐목재를 재활용하여 PB(Particle board)를 생산하는 국내 제조사업장에서는 화재폭발 사고가 빈번히 발생하고 있어 예방대책이 요구되고 있다. 본 연구에서는 폐목재 제조공정의 사고예방과 목재분진 취급공정에 대한 안전대책 등을 제시하기 위하여 사고원인 물질인 폐목재 부유분진의 폭발특성실험을 실시하고 실험결과를 검토하였다. 또한 폐목재 분진의 화재폭발위험성을 상세히 평가하기 위하여 해당 물질의 자연발화점, 축열저장시험, 및 최소점화에너지 등의 화재폭발위험특성값을 실험적으로 조사하였다. 본 연구에서 사용한 폐목재 시료의 비구형 입자형태를 가지는데 입도분석기의 측정 결과 평균 입경은 $15.96{\mu}m$로 조사되었다. 또한 목재 분진의 함수율은 3.88%이며 중금속함유량은 1.73%이다. 자연발화점 측정결과 $225.5^{\circ}C$로서 비교적 낮게 측정되었고 퇴적분진에 대한 화재의 위험성은 높게 나타났다. 반면에 축열저장시험 결과를 통하여 공정관리 온도 및 보관온도를 $150^{\circ}C$ 이하로 관리하면 축열에 의한 자기분해 위험성은 낮은 것으로 판단되었다. 그러므로 축열에 의한 화재폭발 등의 위험성은 낮은 것으로 사료 된다. 최대폭발압력($P_{max}$)은 8.7 bar이며 폭발하한농도 (LEL)는 $60g/m^3$으로 나타났다. 부유분진의 폭발특성실험 결과 분진폭발지수(Kst)는 폭발등급 St 1 (0$bar{\cdot}m/s$)으로 나타났으며 폭발에 의한 위험성이 약한 분진으로 판정되었다. 최소점화에너지(MIE)는 10mJ < MIE <30mJ의 범위로 측정되었으며, 계산에 의해 추정된 최소점화 에너지(Es) 값은 14 mJ로서 일반적인 발화감도(Normal ignition sensitive)로 분류되었다. 이는 실질적인 점화원만 제거하여도 분진폭발을 예방할 수 있다는 것을 의미한다. 그러나 분진 폭발사고를 예방을 위하여 MIE값이 공정운전온도 $100^{\circ}C$ 초과 시에 급격히 낮아질 수 있으므로 운전 온도 설정에 있어서 주의가 필요하다.

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Experimental Study on Ignition and Explosion Hazard by Measuring the Amount of Non-volatile (NVR) and Explosion Limit of Biodiesel Mixture (바이오디젤 혼합물의 가열잔분측정과 폭발한계 측정을 통한 발화 및 폭발위험성에 대한 실험적인 연구)

  • Kim, Ju Suk;Koh, Jae-Sun
    • Journal of the Society of Disaster Information
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    • v.18 no.1
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    • pp.182-193
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    • 2022
  • Purpose: By measuring and evaluating the risk of biodiesel through non-volatile residue (NVR) and flash point and explosion limit measurement at a specific temperature according to ASTM test standards, the risk of chemical fire causative substances is identified and a universal evaluation method By derivation and securing the risk-related data of the material, it can be used for the identification and analysis of the cause of the fire, and it can be applied to the risk assessment of other chemical substances Method: In order to measure the risk of biodiesel, it was measured using the non-volatile residue(NVR) measurement method, which measures how much flammable liquid is generated at a specific temperature. Heating was tested by applying KS M 5000: 2009 Test Method 4111. In addition, the flash point was measured using the method specified in ASTM E659-782005, and the energy supply method was measured using the constant temperature method. In addition, the explosion limit measurement was conducted in accordance with ASTM E 681-04 「Standard test method for concentration limits of flammability of chemicals(Vapors and gases)」 test standard. Result: As a result of checking the amount of combustible liquid by the non-volatile residue (NVR)measurement method, the non-volatile residue(NVR) of general diesel when left at 105±2℃ for 3 hours was about 30% (70% of volatile matter) and about 4% of biodiesel. In addition, similar results were obtained for the non-volatile residue(NVR)heating temperature of 150±2℃, 3 hours and 200±2℃ for 1 hour, and white smoke was generated at 200℃ or higher. In addition, similar values were obtained as a result of experimentally checking the explosion (combustion) limits of general diesel, general diesel containing 20% biodiesel, and 100% biodiesel. Therefore, it was confirmed that the flammability risk did not significantly affect the explosion risk. Conclusion: The results of this study suggested the risk judgment criteria for mixtures through experimental research on flammable mixtures for the purpose of securing the effectiveness, reliability, and reproducibility of the details of the criteria for determining dangerous substances in the existing Dangerous Materials Safety Management Act. It will be possible to provide reference data for the judgment criteria for flammable liquids that are regulated in the field. In addition, if the know-how for each test method is accumulated through this study, it is expected that it will be used as basic data in the research on risk assessment of dangerous substances and as a basis for research on the determination of dangerous substances.

The Study of the Fire Possibility of Sheath Heater without Safety Device in Use(Focused on the fire cases) (안전장치 없는 시즈히터에 대한 사용중 발화 가능성 연구(화재사례를 중심으로))

  • Mun, Yong-Su;Myeong, Jeong-Ho;Choe, Jin-Man;Kim, Yong-Su
    • Journal of Korean Institute of Fire Investigation
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    • v.4 no.1
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    • pp.62-69
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    • 2004
  • The purpose of this study on the sheath heater having high occurrence of fires in a small work place because of not having the safety device, was to find out the characteristics required in the field examination of the fires in the courses of investigation. The results of the experiments conducted and reviewed on the basis of the fire cases whose conditions of the ignition possibility were divided into A, E, C and D are as follows: When the sheath heater without safety device is left on the condition of the heat accumulation of which the temperature rapidly rise, and then ignite the inflammables of the surroundings. In such cases, it was characterized that the color change trace appeared even if no short trace was discovered in the power line.

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Design & Implementation of Speechreading System using the Face Feature on the Korean 8 Vowels (얼굴 특징점을 이용한 한국어 8모음 독화 시스템 구축)

  • Kim, Sun-Ok;Lee, Kyong-Ho
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2009.01a
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    • pp.135-140
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    • 2009
  • 본 논문은 한국어 8 단모음을 인식하는 자동 독화 신경망 시스템을 구축한 것이다. 얼굴의 특정들은 휘도와 채도 성분으로 인하여 다양한 색 공간에서 다양한 표현 값을 갖는다. 이를 이용하여 각 표현 값들을 증폭하거나 축소, 대비시킴으로서 얼굴 특정들을 추출되게 하였다. 눈과 코, 안쪽 입의 외곽선, 이의 외곽선을 찾았고, 그 후 한국어 8모음 발화시 구분되게 변화는 값들을 파라미터로 설정하였다. 한국어 8모음을 발화하는 2400개의 자료를 모아 분석하고 이 분석을 바탕으로 신경망 시스템을 구축하여 실험하였다. 이 실험에 정상인 5명이 동원되었고, 사람들 사이에 있는 관찰 오차를 정규화를 통하여 수정하였다. 5명으로 분석하였고, 5명으로 인식 실험하여 좋은 결과를 얻었다.

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Temperature Rise of the MV Class Transformer Filled with a Vegetable Fluid (식물성 절연유를 사용한 배전용 변압기의 온도변화 특성)

  • Lee, Byung-Sung;Park, Chul-Bae;Song, Il-Keun;Han, Sang-Ok
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.2060-2061
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    • 2008
  • 식물성 절연유는 기존 광유계 절연유에 비해 친환경성과 안전성이 부각되어 전력용 변압기에 사용을 검토하고 있다. 우수한 생분해성 및 높은 인화점, 발화점을 갖는 반면, 점도가 높아 냉각 효과가 줄어드는 단점이 있다. 변압기 절연유의 역할이 절연과 냉각이므로 광유에 비해 약 3배 정도 높은 점도를 갖는 식물유를 사용할 경우 변압기 권선 내부 온도 상승을 검토하여야 한다. 본 연구에서는 배전급에 사용되는 변압기에 광유 대체로 식물유를 사용하였을 때 권선 및 유온도 상승을 측정하였다. 변압기 권선 구조 설계에 있어서 정확한 권선온도 상승 값을 활용하여야 적정 수명 유지가 가능해 진다.

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Study on combustion characteristics of the Wood (Pinus rigida, Castanea sativa, Quercus variabilis and Zelkova serrala) grew up in Korea (한국에서 자란 목재(리기다 소나무, 밤나무, 굴참나무, 느티나무)의 연소특성에 관한 연구)

  • Shi, Nan;Jin, Eui;Oh, Jung-Kyoo;Chung, Yeong-Jin
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2011.04a
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    • pp.321-324
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    • 2011
  • 건자재로서 나무 결함 중의 하나는 화재에 대한 취약성이다. 본 연구의 목적은 한국에서 자란 리기다 소나무, 밤나무, 굴참나무, 느티나무의 연소성질을 시험하는 것과 건자재로서의 사용에 대한 바람직한 특성을 알아내는 것이며 연소억제를 위해 실온에서 3종류의 암모늄염 즉, ammonium sulfate, monoammonium phosphate, 그리고 diammonium phosphate를 20 wt% 수용액에 각각 리기다 소나무를 함침시켜 건조시킨 후 재료의 난연성을 시험하였다. 콘칼로리미터(ISO 5660-1)를 이용하였고 분석 결과로는 열방출랑을 비롯하여, 가스방출량, 발화점 등을 측정하여 비교분석하였다.

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Information Extractive Dialog State Tracking for Consulting (상담 대화를 위한 사용자 정보 추출 대화 상태 추적 시스템)

  • Jang, Yunjeong;Lee, Geunbae
    • Annual Conference on Human and Language Technology
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    • 2021.10a
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    • pp.625-628
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    • 2021
  • 정보 추출이 가능한 대화 상태 추적(Information-Extractive Dialog State Tracking)은 상담 목적에 맞는 대화를 시스템이 유도하여 사용자로 부터 정보를 추출할 수 있도록 대화 상태를 추적하는 연구로써, 사용자에게 적합한 상담이 이루어지도록 하기 위해 제안되었다. 이 논문에서는 상담 대화에서는 내담자의 발화는 상담자에 의해 유도되는 점을 착안하여 시스템이 대화를 주도하는 모델을 제안한다. 시스템 액션과 사용자 발화를 이용해 슬롯, 밸류로 구성된 대화 상태를 추적하고 이를 대화 정책에 반영하여 이어질 대화를 주도한다. 추적한 대화 상태와 기존 대화 상태를 비교하여 대화 시스템의 성능을 보인다.

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Orthographic Influence in the Perception and Production of English Intervocalic Consonants: A Pilot Study (영어 모음사이 자음의 인지와 발화에서 철자의 영향: 파일럿 연구)

  • Cho, Mi-Hui;Chung, Ju-Yeon
    • The Journal of the Korea Contents Association
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    • v.9 no.12
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    • pp.459-466
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    • 2009
  • While Korean allows the same consonants at the coda of the preceding syllable and at the onset of the following syllable, English does not allow the geminate consonants in the same intervocalic position. Due to this difference between Korean and English, Korean learners of English tend to incorrectly produce geminate consonants for English geminate graphemes as in $su\underline{mm}er$. Based on this observation, a pilot study was designed to investigate how Korean learners of English perceive and produce English doubleton graphemes and singleton graphemes. Twenty Korean college students were asked to perform a forced-choice perception test as well as a production test for the 36 real word stimuli which consist of (near) minimal pairs of singleton and doubleton graphemes. The result showed that the accuracy rates for the words with singleton graphemes were higher than those for the words with doubleton graphemes both in perception and production because the subjects misperceived and misproduced the doubleton graphemes as geminates due to orthographic influence. In addition, the low error rates of the word with voiced stops were accounted for by Korean language transfer. Further, spectrographic analyses were provided where more production errors were witnessed in doubleton grapheme words than singleton grapheme words. Finally, pedagogical implications are provided.

Effect of Dry Surface Treatment with Ozone and Ammonia on Physico-chemical Characteristics of Dried Low Rank Coal (건조된 저등급 석탄에 대한 건식 표면처리가 물리화학적 특성에 미치는 영향)

  • Choi, Changsik;Han, Gi Bo;Jang, Jung Hee;Park, Jaehyeon;Bae, Dal Hee;Shun, Dowon
    • Applied Chemistry for Engineering
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    • v.22 no.5
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    • pp.532-539
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    • 2011
  • The physical and chemical properties of the dried low rank coals (LRCs) before and after the surface treatment using ozone and ammonia were characterized in this study. The contents of moisture, volatiles, fixed carbon and ash consisting of dried LRCs before the surface treatment were about 2.0, 44.8, 44.9 and 8.9%, respectively. Also, it was composed of carbon of 62.66%, hydrogen of 4.33%, nitrogen of 0.94%, oxygen of 27.01% and sulfur of 0.09%. The dried LRCs was surface-treated with the various dry methods using gases such as ozone at room temperature, ammonia at $200^{\circ}C$ and then the dried LRCs before and after the surface treatment were characterized by the various analysis methods such as FT-IR, TGA, proximate and elemental analysis, caloric value, ignition test, adsorption of $H_2O$ and $NH_3-TPD$. As a result, the oxygen content increased and the calorific value, ignition temperature and the contents of carbon and hydrogen relatively decreased because the oxygen-contained functional groups were additionally generated by the surface oxidation with ozone which plays a role as an oxidant. Also, its $H_2O$ adsorption ability got higher because the hydrophilic oxygen-contained functional groups were additionally generated by the surface oxidation with ozone. On the other hand, it was confirmed that the dried LRCs after the surface treatment with $NH_3$ at $200^{\circ}C$ have the decreased oxygen content, but the increased calorific value, ignition temperature and contents of carbon and hydrogen because of the decomposition of oxygen-contained functional groups the on the surface. In addition, the $H_2O$ adsorption ability was lowered bucause the surface of the dried LRCs might be hydrophobicized by the loss of the hydrophilic oxygen-contained functional groups. It was concluded that the various physico-chemical properties of the dried LRCs can be changed by the surface treatment.

The changes of Students through Technological problem solving Hands-on Activity in Technology Education of Middle School (중학교 기술교육에서 기술적 문제해결 체험활동을 통해 나타나는 학생들의 변화)

  • Kim, Ji-Sook;Yi, Sang-Bong
    • 대한공업교육학회지
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    • v.40 no.2
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    • pp.175-195
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    • 2015
  • This study is aimed at exploring the educational meaning of cooperative hands-on activity in the technology subject from the perspective of a student who is an education consumer. For this purpose, this study selected 12 first year student of a middle school located at G City of Gyeonggi-do Province as research participants through purposeful sampling, and conducted an in-depth interview and group discussion based on stimulated recall questionary techniques. This study utilized area analysis, classification analysis and component analysis as a data analysis method, and secured the verity of the research through the examination between research participants and triangulation. As a result of this research work, it was found that the cooperative hands-on class in the technology subject had the meaning of 'Space between a burden and excitement about the technical making', 'Clue and ignition point of technological problem solving', and 'Self-discovery through Technical capability'. To be more concrete, 'Space between a burden and excitement about the technical making' means that students, whose usual school record is excellent, felt great psychological burdens of performance assessment, but their pre-experience and interest in 'Making' induced them to feel exhilaration of hands-on activity. 'Clue and ignition point of technological problem solving' means that students get to make much of the understanding & formation of the relationship with teammates in the process of resolving an unfamiliar hands-on activity task and to have the continuous problem-solving ability. 'Self-discovery through Technical capability' means that students get to realize the importance of learning experience of one's own making through hands-on activity learning, which could be the opportunity to meet the operant demands of the inner side. This study hopes that such results could be utilized as the basic data needed for designing the hands-on activity education in the technology subject more meaningfully and systematically for the time to come.