• Title/Summary/Keyword: 발포 폴리프로필렌

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Phase Morphology and Foaming of Polypropylene/Ethylene-octene Copolymer Blends (폴리프로필렌/에틸렌옥텐 공중합체 블렌드의 상분리 구조 및 발포 특성)

  • 서관호;임정철
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.707-718
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    • 2001
  • Polypropylene (PP) exhibits many beneficial properties such as low density high thermal stability, chemical resistance, good processability and recyclability. However, only limited research has been done on expanded polypropylene (EPP). In this study, we were trying to prepare EPP with chemical blowing agent. Ethylene-octene copolymer (mPE) was melt blended with PP to enhance melt fluidity of PP at processing temperature and to make more flexible foamed material. Prior to foaming, phase morphology of PP/mPE blends were investigated to examine the effect of phase morphology on the foaming ratio and cell structure of foams. Phase morphology of PP/mPE blends were affected by the content of mPE and mixing torque ratio. At the same composition, it was affected by mixing rpm. High blowing ratio and stable cell structure were obtained in the blend which has the continuous PP matrix with dispersed droplets of mPE.

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Production method for porous polypropylene sheet (발포 폴리프로필렌 시트의 제조방법)

  • Yu, Ho-Tak;Lee, Kee-Sun;Kim, Kee-Sun
    • Proceedings of the KAIS Fall Conference
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    • 2012.05b
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    • pp.677-679
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    • 2012
  • 다공질 폴리프로필렌 시트는 압전센서 및 VOC 발생이 적은 자동차 내장소재로 주목을 받고 있으며, 특히 경량화를 위한 다공질 폴리프로필렌 시트의 가공기술이 중요하다. 이 연구에서는 기존의 가교형 폴리프로필렌 시트를 활용하여 압출과 사출이 아닌 압연공정과 열처리 발포공정을 접목하였다. 발포를 위한 마스터배치와 폴리프로필렌의 혼합으로 제조된 두께 1mm의 폴리프로필렌시트를 $200^{\circ}C$온도에서 온간압연공정에 의해 0.1-0.2mm 두께로 제조하고, 이를 $200^{\circ}C$에서 5분동안 발포함으로써 기공률 65%의 시트를 제조함으로써 저가의 압전센서 소재로 활용 가능성을 확인하였다.

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Application of the EPU Constitutive Equation to expanded Polypropylene under Dynamic Loading (동하중을 받는 발포 폴리프로필렌에 대한 EPU 구성 방정식 적용)

  • Jeong, Kwang Young;Kim, Byeong-Jun;Cheon, Seong S.
    • Composites Research
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    • v.27 no.4
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    • pp.135-140
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    • 2014
  • A constitutive equation, which was suggested for describing the compressive deformation behaviour of the expanded polyurethane, was applied to the expanded polypropylene under dynamic loading. This equation consists of seven parameters, five of which are obtained by fitting the stress strain curve obtained from the quasi-static compression test at the lowest base strain rate. The remaining two parameters are able to be determined by fitting the curve from the compression test at different two stage strain rates. In order to check the eligibility of the equation at high strain rate, the impact test was performed and the results were compared to the analytical constitutive equation results for the expanded polypropylene with expansion ratios of 30 and 40 times, respectively.

An Experimental Study on the Absorbed Energy of Polymeric Foam According to Different Mass and Impact Velocity Based on the Constant Impact Energy (동일 에너지 조건하에 충격체 질량과 속도변화에 따른 발포 고분자의 흡수 에너지에 관한 실험적 연구)

  • Kim, Byeong-Jun;Kim, Han-Kook;Cheon, Seong S.
    • Composites Research
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    • v.27 no.2
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    • pp.42-46
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    • 2014
  • In the present study, impact tests were carried out to investigate the crashworthy behaviour of the expanded polypropylene under the constant incident energy (100 J and 200 J) with five different combinations of striker mass and velocity. Also, preliminary quasi-static test was performed to obtain basic characteristics of the expanded polypropylene. MTS 858 and Instron dynatup 9250 HV were used for the quasi-static test and impact tests, respectively. In consequence, it was found that the impact energy absorption characteristics of the expanded polypropylene was more influenced by the striker mass instead of the velocity of the striker.

A Study on the Extrusion Foaming of Polypropylene (폴리프로필렌의 압출발포 특성에 관한 연구)

  • 황대영;한갑동;홍다윗;이규일;이기윤
    • Polymer(Korea)
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    • v.24 no.4
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    • pp.538-544
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    • 2000
  • The characteristics of cell growth and foamed cell structures of PP were investigated by a continuous foaming process. The operating parameters were the contents of blowing agent and nucleating agent, nucleating agent contents, die temperatures and die dimensions. The foaming cells grew without collapse at less than 14.5 wt% of blowing agent, isopentane. But the cells were collapsed when the blowing agent content was more than 14.5 wt%. The foam density dramatically decreased when a very small amount of the nucleating agent, 1 wt%, was added. After the nucleating agent was added, the cell's weight plummeted to one-seventh of its previous weight. Stable foam cell structures were formed at the die temperature of 17$0^{\circ}C$. However, the effects of the pressure drop rate on the cell morphology were not serious.

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Experimental Study for the Impact Characteristics of Expanded EPP/EPS Foams (발포 EPP/EPS의 충격특성에 관한 실험적 연구)

  • Kim, Han-Kook;Kim, Byeoung-Jun;Jeong, Kwang-Young;Cheon, Seong S.
    • Composites Research
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    • v.26 no.6
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    • pp.343-348
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    • 2013
  • In the present study, quasi-static tests and impact tests were performed for investigating the mechanical behaviour of EPP (Expanded polypropylene) and EPS (Expanded polystyrene). Four different density cylindrical type specimens were prepared for EPP and EPS and 0.001 $s^{-1}$ and 0.1 $s^{-1}$ of strain rate conditions for quasi-static tests and 100 J, 200 J and 300 J of incident energy conditions for the instrumented impact tests were considered.

A Constitutive Equation Including Strain Rate Effect for the Expanded Polypropylene (변형률 속도가 고려된 발포 폴리프로필렌의 구성방정식)

  • Kim, Han-Kook;Cheon, Seong S.
    • Composites Research
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    • v.27 no.4
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    • pp.130-134
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    • 2014
  • The purpose of this paper is to build DB in order to Propose new constitutive equations by redefining constitutive equations for Polyurethane presented by Jeong et al. [12] based on Quasi-static test and Impact test DB of Expanded polypropylene using cylindrical specimens with 4 different densities presentsd by Kim et al. [7] for EPP foam and combining the impulse-momentum theory.

Structural Changes of Homopolymer Polypropylene Foam with Molecular Weights and Rheological Properties : (1) In Batch Process (분자량 및 유변 특성에 따른 단일 중합체 폴리프로필렌의 발포체 변화 : (1) 회분식 공정)

  • 홍다윗;윤광중;이기윤
    • Polymer(Korea)
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    • v.26 no.1
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    • pp.61-70
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    • 2002
  • The effects of molecular weights and rheological properties of polypropylene (PP), on its foam structures in batch process were investigated. The effects of crosslinking process were also considered in this study. The rheological properties of polypropylene, such as storage modulus(G'), loss modulus(G"), zero shear viscosity($\eta_O$), and relaxation time($\lambda$), increased with the increase of molecular weights, and these increases in rheological properties directly affected the stability improvements of the PP foam. The increase of crosslinked PP's gel content stopped at the irradiation dose of 3.2 Mrad. The development of foam structures was more enhanced as the irradiation dose increased up to 3.2 Mrad. When the irradiation dose exceeded 3.2 Mrad, however, it negatively affected the structural development of the foam by diminishing gel contents of the foaming material, which resulted in instability of the foam structure.ture.

최근 완충재 개발동향

  • 한국포장협회
    • The monthly packaging world
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    • s.6
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    • pp.46-51
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    • 1993
  • 최근 대표적인 완충재로 사용되어 오던 EPS(발포폴리스티렌)의 사용이 규제됨에 따라 환경적응형 완충재의 중요성이 더욱 강조되고 있다. 완충재는 수송시 제품에 가해지는 충격을 줄여 제품을 최대한 보호하는 역할을 한다. 일반적으로 사용되고 있는 플라스틱 완충재로는 폴리에틸렌 폼(polyethylene foam), 폴리프로필렌 폼(polypropylene foam), 폴리우레탄 폼(polyuretane)등이 있고 종이를 소재로 한 형태도 있다. 이 글에서는

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Effects of Irradiation Crosslinking and Molecular Weight Properties on Crosslinked PP Foaming Process (전자선 조사량과 분자량 특성이 전자선 가교 PP 발포 가공에 미치는 영향)

  • 홍다윗;윤광중;백운선;정영헌;이준길
    • Polymer(Korea)
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    • v.26 no.4
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    • pp.508-515
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    • 2002
  • The effects of the crosslinking caused by irradiation dose, molecular weights of the foaming materials, and various foaming processes on the foam structure of the polypropylene (PP) were investigated. The maximum gel content of the PP was 48% when the sheet was irradiated with 3.2 Mrad. This high gel content improved the cell structures by providing high thermal stability. The increase of both the gel content and structural development were stopped at the irradiation dose exceeding 3.2 Mrad. The increase of the molecular weights served to help produce a foam with particularly fine and even cell structures, along with improved thermal stability as well.