• Title/Summary/Keyword: 발포체

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Foaming Properties and Flame Retardancy of the Foams Based on NBR/GTR Compounds (니트릴고무/타이어고무분말(GTR)를 이용한 발포체의 발포 및 난연 특성에 관한 연구)

  • Moon, Sung-Chul;Jo, Byung-Wook;Choi, Jae-Kon
    • Elastomers and Composites
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    • v.37 no.3
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    • pp.159-169
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    • 2002
  • The improvement of flame retardancy of the foams based on NBR/GTR compounds was conducted by formulating various materials i.e. NBR, GTR, inorganic and phosphorus containing flame retardants, foaming agent, cross-linking agent and activator. The foaming properties, morphology, smoke density and flame retardancy of the specimens were investigated using SEM, LOI tester, smoke density control system and cone calorimeter. The phosphorus containing flame retardant reduces heat release rate, increases the limiting oxygen index and a char formation. The inorganic flame retardant increases the limiting oxygen index and reduces heat release rate with an increased CO yield by char formation, and smoke suppressing effect. The formed char seemed to intercept the oxygen transport and heat transfer into the core area. When the composition ratios of the compounds of NBR/GTR were $100{\sim}80/0{\sim}20 wt.%$, and the ratios of the rubbers/flame retardants were $1/1.55{\sim}3.60 wt.%$, we could developed foams with low heat release rate, high limiting oxygen index($28.0{\sim}39.3$), closed or semi-closed cell of uniformity and reasonable expandability($225{\sim}250 %$).

Flame Retardancy and Foaming Properties of the NBR/Ground Tire Rubber Foams Containing Expandable Graphite (팽창 흑연을 포함한 NBR/GTR 발포체의 난연 및 발포특성)

  • Moon Sung-Chul;Choi Jae-Kon;Jo Byung-Wook
    • Polymer(Korea)
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    • v.28 no.5
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    • pp.412-425
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    • 2004
  • The influence of expandable graphite (EG) on flame retardancy and foaming properties of the NBR/GTR foams was studied. The foaming properties were similar to those of NBR/GTR foams without EG when the EG contents were 10$\~$30 phr. The LOI values were increased with the EG content. For cone-calorimeter test, the data showed the trend similar to that from experiment. When the composition ratios of the compounds of NBR/GTR were 100$\~$0/80$\~$20 (w/w), and the EG contents were 10$\~$30 phr, we obtained high flame retardancy foams with low heat release rate (HRR), total heat release (THR), effective heat of combustion (EHC) and carbon monoxide yield (COY). The smoke density is similar to CO yield values obtained by the cone-calorimeter test. TGA analysis also showed the results approximately similar to those from the LOI and cone-calorimeter experiments.

Effect of Waste Ground Tire Rubber on Flame Retardancy and Foaming Properties of the NBR foams (폐타이어 고무분말(GTR)이 니트릴고무(NBR) 발포체의 난연 및 발포 특성에 미치는 영향)

  • Moon, Sung-Chul;Lee, Jae-Chul;Choi, Jae-Kon;Jo, Byung-Wook
    • Elastomers and Composites
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    • v.38 no.3
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    • pp.251-261
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    • 2003
  • The flame retardancy and foaming properties of NBR foams containing waste ground tire rubber (GTR) were studied. When the composition ratios of NBR/GTR were ranged in $100/0{\sim}80/20$ (w/w) and rubbers/flame retardants were in the range of $1/1.95{\sim}3.70 wt%$, the considerably optimized foam for flame retardancy was obtained with high limiting oxygen indices (LOI, $29.4{\sim}40.0$), low heat release rate(HRR), closed/semi-closed cell of uniformity, and reasonable expandability ($215{\sim}300 %$). The LOI was increased and the heat release rate was decreased with increasing the amount of GTR content.

Ceramic Foams by the Self-Blowing of Polymer (고분자의 자체발포를 이용한 세라믹 다공질체)

  • 백종원;김득중
    • Journal of the Korean Ceramic Society
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    • v.41 no.7
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    • pp.555-559
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    • 2004
  • Ceramic foams were prepared by a self-blowing process of a polysiloxane with A1$_2$O$_3$ as a filler. The release of water and ethanol vapor during the condensation reaction of the polymer triggered the pores in the polymer melt. The size. interconnectivity and shape of the pores in the ceramic foams were strongly dependent on the viscosity of the polymer melt, which could be varied by the content and size oi the filler. When the content of the filler inceased and the size of the filler decreased. the size of the pores were decreased and the thickness between the pores were increased. In the addition, the viscosity of polymer melt increased by the pretreatment at 130$^{\circ}C$ for Ire intermolecular cross linking thereby stabilizing the foam structure. The density and compressive strength of the ceramic foams were affected by the heating rate during the blowing process.

난연 및 전기전도성 폐PET/PE 복합 발포체의 제조 및 특성

  • 송종혁;강영구
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2001.11a
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    • pp.242-247
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    • 2001
  • Foam Plastics, cellular plastics, expanded plastics, plastic foam 등 여러 가지 이름으로 불리우고 있는 발포플라스틱은 plastic matrix 내에 무수한 cell이 open 형태 혹은 closed 형태로 존재하는 플라스틱 재료이며/sup 1)/ 원료플라스틱 보다 경량성, 열전도성, 충격흡수성 등 제반물성이 우수하여 포장재료, 보온재, 완충재 및 각종 구조재료로써 널리 사용되고 있으며 소재 plastic의 특성에 따라 PE, PP, PVC, PS, ABS 등 다양하게 개발되어 있다.(중략)

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The Relationship between Blowing Agents and Inner Temperature at the Preparation of Flexible Polyurethane Forams (연질 폴리우레탄 발포체 제조에서 발포제와 내부 온도와의 관계)

  • Lee, S.W.;Kim, J.H.;Kim, K.H.;Yang, Y.K.;Ahn, C.I.;Myong, Y.C.
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.2
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    • pp.179-185
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    • 1999
  • The effect of blowing agents and inner temperature on the machanical properties of the flexible polyurethane foams were investigated. In the study used that chemical blowing agents is $H_2O$ and support blowing agents. CFC-11, HCFC-114b, dichloromethane, n-penthane, iso-pentane, cyclopentane. The flexible polyurethane foams were foamed by the density of $0.015{\pm}0.002g/cm^3$ and $0.024{\pm}0.002g/cm^3$ which were used in mechanical properties measurements. Inner temperature was measure as long as the preparation of the flexible polyurethane foams of each blowing agents. The density, tensile strength, elongation, tear strength, compression strength and compression set were measured after 48 hours hardening. The result of the study was optimized dichloromethane and cyclopentane at the support blowing agents.

전분 발포체의 제조 및 물성에 관한 연구

  • 유웅렬;이대훈;이영목;안재상
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.501-504
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    • 1998
  • 최근에 환경을 오염시키는 쓰레기, 특히 많은 양의 플라스틱 완충재의 처리에 대한 관심이 고조되고 있다. 포장재 분야에서는 부피가 크고 환경 친화적이지 않은 플라스틱 제품들이 많이 사용되므로 환경 보호의 차원에서 이의 대체 재료에 대한 연구가 활발히 이루어지고 있다. 포장재로 많이 사용되는 재료로 약 70%의 회복성(resilience)을 갖는 expanded polystyrene(EPS)가 있다. (중략)

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