• Title/Summary/Keyword: 발열 특성

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Study on Hydration Heat of Blended Belite Binder (벨라이트계 혼합 결합재의 수화열 특성에 관한 연구)

  • Lee, Kewn-Chu;Cho, Jae-Woo;Jung, Sang-Hwa;Kim, Jang-Ho Jay
    • Journal of the Korea Concrete Institute
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    • v.23 no.2
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    • pp.145-150
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    • 2011
  • Presently, mass concrete structures are being built in federal and private projects of civil infrastructures and building structures. The hydration heat of mass concrete structures is the most important factor in the quality of concrete matrix and construction period. Moreover, internal cracks caused by hydration heat degrades durability, water tightness, and strength of concrete. To reduce hydration heat, it is necessary to blend belite cement (${\beta}-C_2S$) with industrial by-products (i.e. granulated slag and fly ash). In this experiment, 14 levels of binary binders and 4 levels of ternary binders were used to understand the effect of different replacement ratio on hydration heat, strength and microstructure (i.e. SEM and XRD) of mortar. Cumulative hydration heat at 28 days for the binary and ternary binders was affected by replacement ratio of fly ash and/or granulated slag. As fly ash content increased, hydration heat decreased. As granulated slag content increased, reduction rate of the hydration heat was lower than when fly ash was used. Especially, the hydration heat of ternary binder blended with 40% flyash and 30% granulated slag showed about 50% of hydration heat from using belite cement (P). The study results showed that the temperature rise of concrete matrix can be decreased by using blended belite binders producing low hydration heat and reasonable strength.

Surface Treatment of Al(OH)3 using Dilute Hydrofluoric Acid Aqueous Solution (저농도 HF 수용액을 이용한 Al(OH)3의 표면처리)

  • Kim, Do-Su;Lee, Churl-Kyoung;Yang, Dong-Hyo
    • Journal of the Korean Ceramic Society
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    • v.39 no.3
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    • pp.315-320
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    • 2002
  • Treatment effects of dilute hydrofluoric acid (6 wt% HF) on the surface properties of $Al(OH)_3$ were investigated at the molar ratio of F/Al(fluoride/aluminum)=0.15. Temperature and pH variations in the reaction system were recorded to analyze reaction mechanism between $Al(OH)_3$ and aqueous Hf. The reaction of HF to the surface of $Al(OH)_3$ accompanied with a quantity of heat evolution, resulting in increasing temperature of a reactionsystem. And also the reaction was proceeded as transitional state which metastable ${\alpha}-form\;AlF_3{\cdot}3H_2O$ was transferred to insoluble ${\beta}$-form. The resulting ${\beta}-form\;AlF_3{\cdot}3H_2O$ formed by a surface treatment was identified by FT-IR and X-ray diffractormetry. The formation of ${\beta}$-form aluminum fluoride hydrates with diameter less than $1{\mu}m$ on the surface of $Al(OH)_3$ could be visulaized by SEM imgae, making up a coating layer as precipitate-like. The surface whiteness of $Al(OH)_3$ treated with aqueous HF was furthermore increased approximately 6.6% due to the formation of surface hydrates.

Effect of Hardening Accelerators on the Adiabatic Temperature property Properties of Precast Concrete and FEM analysis for Evaluating the Crack Performance (경화촉진제를 사용한 프리캐스트 콘크리트의 단열온도특성 및 FEM해석에 의한 균열성능 평가에 관한 연구)

  • Min, Tae-Beom;Cho, In-Sung;Mun, Young-Bum;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.1
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    • pp.25-33
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    • 2015
  • In this study, initial crack index was evaluated by FEM analysis to find the crack propagation from hydration heat in precast concrete. As results, as the usage of hardening accelerator increased, initial compressive strength increased and setting time was shortened. Additionally, as amounts of hardening accelerators increased, the central temperature of concrete increased and the time to reach the highest temperature was shortened. It was demonstrated that the hardening accelerators accelerated the hydration reaction of cement, and caused the increase of hydration heat within the short period of time. Furthermore, the crack index for evaluating the heat level was performed by FEM. As results, there was no problem about the cracks, despite of the growth of initial high hydration heat. This is because of the increased tensile strength that is large enough to sustain the thermally induced-stress.

Measurement of Thermophysical Properties of Various Starches in the Freezing Processes (동결 과정중의 전분의 열역학적 특성에 관한 연구)

  • Kong, Jai-Yul;Kim, Min-Yong;Cheong, Jin-Woong
    • Korean Journal of Food Science and Technology
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    • v.20 no.6
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    • pp.820-826
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    • 1988
  • The freezing point$(t_f)$, latent heat of freezing$({\triangle}\;H_f)$ and kinetic constant of fleering$(k_f)$ were determined from DSC thermogram at cooling rate $-2.5^{\circ}C/min{\sim}-10.0^{\circ}C/min$. The freezing point of various starches was decreased with an increase in cooling rate, and that of whole starches were lower than defatted starches. Changes of the latent heat of freezing was not observed at above cooling rate $-2.5^{\circ}C/min$. The latent heat of freezing$({\triangle}\;H_f)$ could be deduced as a function of water content(W) as follows: ${\triangle}\;H_f=0.700W-13.048$, (Kcal/kg) $(35%{\leqq}W{\leqq}70%)\;{\triangle}\;H_f=1.569W-73.861,\;(Kcal/kg)\;(W{\geqq}70%$) In the water content range $35{\sim}90$(wt %), the activation energy of various starches in freezing process was determined $126{\sim}270$ Kcal/mol.

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Influenza A Outbreak in a Neonatal Intensive Care Unit During the 2011-2012 Influenza Season in Korea (2011-2012년 인플루엔자 국내 유행시기에 신생아 중환자실에서 발생한 A형 인플루엔자 바이러스 집단발병)

  • Son, Ok Sung;Oh, Chi Eun;Kong, Seom Gim;Jung, Yu Jin;Hong, Yoo Rha
    • Pediatric Infection and Vaccine
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    • v.23 no.2
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    • pp.87-93
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    • 2016
  • Purpose: An outbreak of influenza virus is uncommon in neonatal intensive care unit (NICU). The clinical presentation of influenza virus infection in neonates is diverse. This study was aimed to report an outbreak of influenza A in a NICU and to investigate the clinical characteristics of influenza virus infection in neonates especially preterm infants during the 2011-2012 influenza season in Korea. Methods: We reviewed the medical records of 29 patients who were evaluated by respiratory virus multiplex reverse transcriptase-polymerase chain reaction (RT-PCR) at NICU of Kosin University Gospel Hospital during the 2011-2012 seasonal influenza outbreak in Korea. Results: Eleven patients (37.9%) were influenza A virus RT-PCR positive during the survey periods. They were all preterm infants and three of them had no symptoms. Eight patients had symptoms and it was fever (18%, 2/11), respiratory difficulty (72.7%, 8/11) without symptoms of upper respiratory infection, and gastrointestinal symptoms (27.3%, 3/11). The median duration of symptom was 5 days. There were differences of duration of admission at the test of respiratory RT-PCR, Clinical Risk Index for Babies (CRIB) score, use of mechanical ventilation, and use of dexamethasone before infection between influenza A virus RT-PCR positive and negative group. All 11 patients with influenza A were discharged without any complications. Conclusions: The symptoms of influenza A virus infection in the preterm infants is nonspecific. Influenza A virus should be considered as a possible cause of infection in NICU during the influenza season in the community.

Adsorption Behaviors of Nickel ton on the Waste Pulp Produced in the Paper Recycling Process (고지(古紙) 재생(再生) 과정(過程)에서 발생(發生)하는 폐(廢)펄프를 흡착제(吸着劑)로 이용(利用)한 니켈 폐수(廢水) 처리(處理) 특성(特性))

  • Baek, Mi-Hwa;Shin, Hyun-Young;Kim, Dong-Su
    • Resources Recycling
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    • v.15 no.3 s.71
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    • pp.58-65
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    • 2006
  • The applicability of the waste pulp which produced in the paper recycling process as an adsorbent for the treatment of $Ni^{2+}$ ion in wastewater has been investigated taking the initial concentration of adsorbate, temperature, the amount of adsorbent, and solution pH as the experimental variables. In addition, the effect of the concentration of coexisting solute and pre-treatment of adsorbent on the adsorbability of $Ni^{2+}$ ion were also examined. The electrokinetic potential of waste pulp was observed to be positive below pH 7.8 and negative above this pH. The adsorption reaction of $Ni^{2+}$ ion reached its equilibrium within 4 hours after the reaction was initiated and the adsorbed amount of adsorbate was found to increase with its initial concentration. The adsorbability of $Ni^{2+}$ was raised with temperature so that its adsorption reaction was considered to be exothermic, which was substantiated by thermodynamic calculation. Also, the adsorbed amount of $Ni^{2+}$ was raised with the amount of waste pulp and with pH in the range of pH $3{\sim}6$. This behavior of the adsorption of $Ni^{2+}$ according to the solution pH was well agreed with the electrokinetic characteristics of waste pulp in solution. The amount of coexisting solute was observed to reversely affect on the $Ni^{2+}$ adsorption onto waste pulp under the experimental conditions. With regard to the pre-treatment of adsorbent with NaOH, the adsorbability of $Ni^{2+}$ was increased with the concentration of NaOH to a certain extent. However, it was found to decrease contrarily when the concentration of NaOH became too high.

Development of the Dryer with a Heat Source of Carbon Nanofibers (탄소나노섬유를 열원으로 적용한 세탁물 건조기의 개발)

  • Lee, Jung-Hwan;Won, Sang-Yeon
    • Journal of Korea Society of Industrial Information Systems
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    • v.23 no.3
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    • pp.25-34
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    • 2018
  • This paper presents a heating source of carbon nanofibers for the efficiency and the drying performance of laundry dryer, and focuses on the applicability-evaluation of its source. To design the proposed heating module, experiments were conducted in terms of surface temperature and surface temperature distribution characteristics of carbon nanofiber lamps. The surface temperature of the lamps increased linearly with increment of a current to flow a lamp and revealing the increasing pattern as the length of the ramps is shorter. The proposed heating source was evaluated based on drying efficiency, moisture evaporation rate at laundry, and internal temperature of a drum during drying process. The drying efficiency satisfied a 45% which is specified in KS C 9319. The moisture evaporation rate and the internal temperature of the drum were respectively 98.88% and $61.1^{\circ}C$, which are similar to that of S's company dryer. From the evaluation and actual drying test results, the proposed carbon nanofiber lamp heating module is considered to be applicable as a heat source for laundry dryer in terms of drying efficiency and drying performance. it is possible to obtain a heat source at a high temperature, an excellent calorific value, an improvement in drying performance, and an effect of sterilizing laundry due to the emission of far-infrared rays. In addition to the applicability, the difference of the drying efficiency between the dryers was analyzed in detail based on the power consumption of the heat sources.

The Primary Research on oil Conversion Technology of biomass by Pyrolysis (열분해에 의한 바이오매스의 유류자원화 기술에 관한 기초 연구)

  • Chio, Hyuk-Jin;Yoo, Sun-Kyoung;Oh, Sang-Woo;Lee, Seung-Guk;Lee, Seung-Hoon
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.10 no.2
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    • pp.112-117
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    • 2007
  • This study aims to develop an alternative energy like oil made from marine organic waste by marine products waste, spent fishing nets. There are already many commercial examples and case studies based on the petroleum industry-refuse plastic or refuse tire, however, it is rare that a research developing alternative energy from food waste and organic waste. Therefore, this study investigated the oil made from thermal decomposition under the high temperature and high pressure condition, and examined the possibility for commercial use by testing its own characteristics. A bio-oil from thermal decomposition at $250^{\circ}C$ and 40 atm was hard to remove impurities because of its high viscosity, showed lower caloric value than heavy oil, and generated various gases which were not appropriate for the use of fuel. It is noticeable that thermal decomposition was occurred at $250{\pm}5^{\circ}C$ using steam pressure, which much lower compared to the existing method of thermal decomposition, more than $500^{\circ}C$. Since the high viscosity of bio-oil, it is necessary a further study to use as liquid fuel.

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Adsorption Kinetic and Thermodynamic Studies of Tricyclazole on Granular Activated Carbon (입상 활성탄에 대한 트리사이크라졸의 흡착동력학 및 열역학적 연구)

  • Lee, Jong-Jib;Cho, Jung-Ho;Kim, H.T.
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.9
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    • pp.623-629
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    • 2011
  • The adsorption characteristics of tricyclazole by granular activated carbon were experimently investigated in the batch adsorption. Kinetic studies of adsorption of tricyclazole were carried out at 298, 308 and 318 K, using aqueous solutions with 250, 500 and 1,000 mg/L initial concentration of tricyclazole. It was established that the adsorption equilibrium of tricyclazole on granular activated carbon was successfully fitted by Freundlich isotherm equation at 298 K. The pseudo first order and pseudo second order models were used to evaluate the kinetic data and the pseudo second order kinetic model was the best with good correlation. Values of the rate constant ($k_2$) have been calculated as 0.1076, 0.0531, and 0.0309 g/mg h at 250, 500 and 1,000 mg/L initial concentration of tricyclazole, respectively. Thermodynamic parameter such as activation energy, standard enthalpy, standard entropy and standard free energy were evaluated. The positive value for enthalpy, -66.43 kJ/mol indicated that adsorption interaction of tricyclazole on activated carbon was an exothermic process. The estimated values for standard free energy were -5.08~-8.10 kJ/mol over activated carbon at 200 mg/L, indicated toward a exothermic process.

A Study on the RDF making Process of Heat-dried Sludge from Cheonan by using Oil-drying Method (유중건조를 이용한 천안시 열건조물의 고형연료화 공정 연구)

  • Park, So-yeon;Kim, Sang-bin;Ha, Jin-wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.2
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    • pp.660-667
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    • 2018
  • This study examined the optimal manufacturing conditions of RDF using heat-dried sludge from sewage treatment plant in Cheonan with the oil-drying method. The amounts of oil evaporation and oil drying of the heat-dried sludge were measured at different temperatures to evaluate the value of the product. The performance of the product was then measured using a calorimeter and TGA. In addition, the concentration of odor, NH3, H2S, and TVOC during drying was determined using a portable odor-meter. Ingredient analysis was performed by EDS. Considering mass-production, the oil to heat-dried sludge weight ratio was fixed to 4:1. At $130^{\circ}C$, only physical mixing occurred after the instantaneous drying of internal water. Considering the eco-friendly aspects, there was no significant difference in the drying efficiency between $160^{\circ}C$ and $190^{\circ}C$. Therefore, the optimal conditions were a drying temperature of $160^{\circ}C$ within 5 minutes. Finally, the RDF manufactured in this study and fuel used in the thermal power plants were compared. The calorific value was 4,449kcal/kg, the water content was 2% and the ash content was 34%, which is higher than the fuel of thermal power plants. Therefore, it is believed that coal energy as well as wood pellets can be replaced.