• Applied Chemistry for Engineering
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• v.22 no.5
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• pp.532-539
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• 2011

The physical and chemical properties of the dried low rank coals (LRCs) before and after the surface treatment using ozone and ammonia were characterized in this study. The contents of moisture, volatiles, fixed carbon and ash consisting of dried LRCs before the surface treatment were about 2.0, 44.8, 44.9 and 8.9%, respectively. Also, it was composed of carbon of 62.66%, hydrogen of 4.33%, nitrogen of 0.94%, oxygen of 27.01% and sulfur of 0.09%. The dried LRCs was surface-treated with the various dry methods using gases such as ozone at room temperature, ammonia at $200^{\circ}C$ and then the dried LRCs before and after the surface treatment were characterized by the various analysis methods such as FT-IR, TGA, proximate and elemental analysis, caloric value, ignition test, adsorption of $H_2O$ and $NH_3-TPD$. As a result, the oxygen content increased and the calorific value, ignition temperature and the contents of carbon and hydrogen relatively decreased because the oxygen-contained functional groups were additionally generated by the surface oxidation with ozone which plays a role as an oxidant. Also, its $H_2O$ adsorption ability got higher because the hydrophilic oxygen-contained functional groups were additionally generated by the surface oxidation with ozone. On the other hand, it was confirmed that the dried LRCs after the surface treatment with $NH_3$ at $200^{\circ}C$ have the decreased oxygen content, but the increased calorific value, ignition temperature and contents of carbon and hydrogen because of the decomposition of oxygen-contained functional groups the on the surface. In addition, the $H_2O$ adsorption ability was lowered bucause the surface of the dried LRCs might be hydrophobicized by the loss of the hydrophilic oxygen-contained functional groups. It was concluded that the various physico-chemical properties of the dried LRCs can be changed by the surface treatment.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2008.11a
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• pp.423-427
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• 2008

지하수 중에 함유된 불소이온을 제거하기 위한 흡착제로 상용의 음이온교환수지(PA), 란탄산화물(La) 및 수산화아파타이트(HAp)를 선정하고 각각의 흡착특성을 회분식 실험을 통해 검토하였다. 그 결과를 요약하면 다음과 같다. 1) PA, La 및 HAp의 불소흡착은 Fruendlich isodtherm model 및 Pseudo-second-order kinetics model과 일치하는 거동을 보였다. 2) D-R model로부터 구한 흡착에너지는 9.66$\sim$12.90 kJ/mol로 이온교환메커니즘을 나타내는 흡착에너지 6$\sim$16 kJ/mol의 범위에 속하였다. 3) Van't Hoff 식에 이용하여 구한 ${\Delta}H^{\circ}$ 및 ${\Delta}G^{\circ}$값은 각각 3.40$\sim$89.28 kJ/mol과 -12.26$\sim$-13.76 kJ/mol의 범위를 보여 모두 흡착과정이 발열반응이며 자발적으로 일어나는 조건임을 알 수 있었다. 4) PA는 pH 6$\sim$8인 중성영역에서 가장 높은 불소 제거율을 보였으며, La과 HAp는 산성영역으로 갈수록 불소 제거율이 증가하는 특성을 나타내었다. 5) 불소에 대한 흡착선택성은 La$\geq$HAp>PA 순으로 높았으며, La의 경우 불소를 제외한 모든 음이온에 대한 흡착능이 없을 정도로 불소에 대한 흡착 특이성을 보였다.

• Proceeding of KASS Symposium
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• 2008.05a
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• pp.3-8
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• 2008

The purpose of this study is to provide fundamental cooling design data for the large public enclosures as gymnasium. This study executed indoor thermal environment verification of the existing gymnasium by measuring temperature distribution with cooling the space in summer. Cooling loads from human body was not considered. We examined various indoor thermal environment factors of the large enclosed space in this study which include vertical and horizontal temperature distribution, supply and return air flow feature, thermal comfort environment feature, amount of ventilation and etc.

• Fire Science and Engineering
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• v.25 no.5
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• pp.62-68
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• 2011

A series of fire tests involving realistic solid combustible materials was conducted to quantify the heat release rate and investigate the fire growth characteristics during the initial fire growth stage. For these tests, single/double wood cribs, urethane cushion having polypropylene covers and wood crib on nylon carpet with urethane carpet padding were used as a fuel source. The fire growth coefficient of the solid combustible materials was quantified and the fire growth characteristics were compared with the $t^2$ fire scenario. The mean effective heat of combustion was evaluated by the total mass loss of fuel and total energy release concept and examined the effect of the ventilation and fire condition. The present study provides the practical information on the fire growth characteristics of solid combustible material to design to a set of fire scenarios for the fire risk analysis.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2012.04a
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• pp.66-69
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• 2012

Field Model에 의한 화재해석방법은 화재현상을 지배하는 망정식윤 직접 해석하기 때문에 Zone model에 비해 공간내의 상세 정보를 제공함과 동시에 다양한 화재형태에 내해 보편적인 적용이 가능하다. Field model은 해석영역을 구성하는 격자점에 대해 이산화된 지배 방정식을 해석하는 과정에서 차분방법이나 격자의 크기에 따라 수치오류가 발생할 수 있다. 특히 격자수는 계산시간에 영향을 미치는 가장 중요한 인자이기 때문에 효율적인 계산을 위해서는 격자크기의 최적화가 이루어져야 한다. 본 연구에서는 구획공간 화재의 최적 격자크기 선정을 위해 격자해상도(Grid Resolution)에 따른 해석결과의 독립성을 비교분석하고 이를 통해 구획공간화재에 대한 격자 최적화 방법에 대해 논의하고자 한다. 화재크기 및 특성 길이에 따른 격자의존성을 파악하기 위해 ISO-9705 표준화재실에 내해 적용된 격자크기는 최소 3 cm에서 최대 30 cm까지 총 7 종류의 격자크기에 대해 FDS 해석이 수행되었다. 해석결과, 환기량이 충분한 화재에 대해서도 격자해상도가 16보다 작은 경우 출입구의 유동은 격자에 따른 독립성을 확보하지 못하는 것으로 나타났으며 화재발열량이 증가함에 따라 독립적인 해석해를 얻기 위해서는 더 큰 격자해상도를 요구하는 것으로 나타났다. 따라서 현재 실무에서 격자최적화를 위해 사용되고 있는 격자선정법에 대한 재검토가 필요하며 화재특성 및 구획공간 조건에 따른 최적격자 조건을 도출하기 위한 추가적인 연구가 필요하다.

• Proceedings of the KIEE Conference
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• 2005.07c
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• pp.1903-1905
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• 2005

다중 코어를 이용한 대전류용 고효율 변압기 개발을 위해 고주파 손실이 작고, 전기 비저항이 큰 자성재료와 최적의 코어 형상 및 권선 방법에 대한 연구개발과 최종적으로 고효율 다중 코어를 이용한 변압기를 개발하고 전원장치에 적용하여 동작특성을 평가하였다. 최소 손실 온도를 $90^{\circ}C$ 이하로 감소시켜 100 kHz에서 250kW/m3의 낮은 전력손실을 갖는 다중 코어를 이용하여 변압기를 제조하고, 제조된 변압기가 채용된 컨버터의 50A 출력 전류에서 측정된 변압기의 발열특성은 30분 이후 약 $58^{\circ}C$까지 증가하였으며, $30{\sim}80A$의 출력 전류에서 85% 이상의 고효율을 얻었다.

• Fire Science and Engineering
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• v.20 no.4 s.64
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• pp.65-71
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• 2006

Some major properties such as a heat release rate have been measured experimentally for the validation of fire model and the clarification of fire phenomena as the study is more rigorous recently. Although the reduced-scale experiment also provides the basic data and the physical understanding in fire study, it is not enough to explain real fire problem directly because there is no exact analogy theory between a real fire and the reduced scale model. Therefore, large cone calorimeter have been built and used in a few foreign countries for the measurement of large scale fire. This paper addressed the theoretical background and the description of key features in the design of the facility. It will be a useful guide for implementation of the large scale cone calorimeter in the future.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2010.10a
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• pp.231-234
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• 2010

본 연구는 화재조건에 따른 화재실 바닥면에서의 열유속특성을 파악하기 위해 ISO-9705 표준화재실의 40% 축소모형공간에 대하여 화재실험을 수행하고 화재성상에 따른 열유속변화와 공간적 분포를 분석한다. 또한 모형실험에서 계측된 열유속을 Scaling Law를 적용하여 실규모 크기의 결과로 환산하고 이를 기존의 다른 연구결과와 비교분석함으로써 화재발생으로 인한 공간내 열유속의 축소법칙의 적용성을 파악하고자 한다. 실험에 사용된 연료는 천연가스, 메탄올, 에탄올, 헵탄, 톨로엔, 폴리스틸렌등이며 모형실험의 최대발열량은 450 kW 정도로 실규모로 환산시 약 4.4 MW이다. 실험결과 화재실바닥면의 열유속은 연층의 온도와 연료의 종류에 따라 차이를 보였으나 측정위치별 차이는 크지 않았으며 Scaling Law를 적용한 결과 화재실 상층부 온도가 약 $500{\sim}600^{\circ}C$ 정도에서 바닥면의 열유속은 약 $20kW/m^2$ 정도로 기존연구와 유사한 경향을 보였다. 본 연구는 화재공간 내 열유속 측정을 통해 전실화재로의 화재성장을 파악하고 화재실내부의 열적특성을 분석하기 위한 기초적인 자료를 제공하고자 한다.

• Journal of Aerospace System Engineering
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• v.13 no.3
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• pp.9-14
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• 2019

Liquid and solid fuels currently in use have various pros and cons. As a result, researches are dedicated to produce a new form of fuel that utilizes the advantages and overcomes weakness of conventional fuels. In the present study, a new method for making solidified ethanol fuel is introduced, and its preliminary properties and combustion characteristic are observed. The solidified ethanol fuel was made through the production of agarose hydrogel, and its subsequent soaking into pure ethanol. The properties of the solidified ethanol fuel were quantitatively and qualitatively observed, and its validity and applicability discussed.

• Childhood Kidney Diseases
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• v.8 no.2
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• pp.223-228
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• 2004

Purpose and Methods: Urinary tract infection(UTI) is one of the most important diseases of childhood, especially for young infants. To characterize the patients diagnosed with febrile UTI in their first 6 months of life and to explore the risk factors of recurrent UTI, a retrospective study was performed. Results: Among the 90 patients studied, 77 were boys(86%). First episodes of UTI were diagnosed at the age of $2.5{\pm}1.4$ months. These patients underwent ultrasonographic evaluation of urinary tract(n=90) and voiding cystourethrography(n=81) where 53 and 35 studies showed abnormal findings respectively, and a total of 45 cases of urinary tract anomaly including vesicoureteral reflux(VUR, n=35) were diagnosed. Normal findings on ultrasonography indicated decreased risk of VUR in boys of 1-3 months of age(n=30). 53 patients were followed up more than 6 months and 45 episodes of subsequent UTI developed in 29 patients during the first 6-month period. Patients with relapse were older than patients without relapse at the diagnosis of first UTI, but other clinical parameters including abnormal findings on the imaging studies and prophylactic antibiotics prescription were not different between the two groups. Conclusion: UTI in early infancy occurred mainly in male infants and half of the patients had structural anomalies. USG was of clinical value in detecting anomalies requiring surgical intervention, and to rule out high grade VUR in 1-3 months old boys. Results of the imaging study or prophylactic antibiotics could not modify the risk of recurrent UTI. (J Korean Soc Pediatr Nephrol 2004;8:223-228)