• Title/Summary/Keyword: 발열 특성

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A Study on the Characteristics of the pyrolysis for the PE, PP, PVC, RPF by using TGA (PE, PP, PVC, RPF의 열중량분석들 이용한 열분해반응에 관한 연구)

  • Kim, Hi-Youl;Park, Sang-Shin;Che, Tae-Young;Park, Ju-Won;Yu, Tae-U;Yang, Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.637-641
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    • 2007
  • 화석연료의 고갈이 가시화됨에 따라 이를 해결하기 위한 대체에너지원의 확보를 위해 다양한 연구가 수행되어 왔다. 본 연구에서는 폐기물 특히 플라스틱 폐기물의 안정적인 처리 및 청정가스의 생산방법을 연구하기 위해서 선행적으로 플라스틱 폐기물의 열분해 특성을 조사하였으며, 그 반응모델을 제시하여 열분해로의 설계인자의 도출하고자 하였다. 대상 폐 플라스틱류로서 PE, PP, PVC, RPF 등을 이용하였고, 열중량분석기와 tube furnace를 통해서 온도에 따른 분해반응 특성을 확인하였다. 열분해 특성조사를 한 결과 PE, PP 등은 잔류 char가 없이 $400^{\circ}C$ 전후에서 완전 분해하였으며, PVC의 경우 $400^{\circ}C$ 이후에도 약 20% 이상의 char가 잔류함을 확인하였고, RPF의 경우에도 약 10%의 char이 잔류함을 확인하였다. 또한 각각의 열분해 특성을 DTG/TGA분석을 통해서 적정체류시간을 구할 수 있었고, 다단열분해 가스화기를 이용하여 합성가스를 제조한 결과 2500 kcal / $Nm^3$의 높은 발열량을 가진 합성가스를 제조할 수 있었다.

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Gasification Performance in the Dry-Feeding Gasifier with Variation of Feed Ingredients and Main Operational Problems (건식 가스화기 시료의 선정인자 및 변화에 따른 가스화 특성과 주요 운전상 문제점)

  • 윤용승;정석우;김원배
    • Journal of Energy Engineering
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    • v.10 no.2
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    • pp.90-104
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    • 2001
  • 일일 최대 석탄처리 용략이 3톤인 건식 석탄가스화기를 사용하여 가스화에 미치는 주요 변수들중 산화제내 산소농도와 증기 주입량을 변경시켜 가스화성능을 조사하였고, IGCC용 대성석탄을 선정하는 입장에서의 주요 인자 및 고온고압 조건에서의 가스화기 운전상 특성과 문제점을 파악하여 운전상 문제에 대한 대책을 제시하였다. 사용한 석탄은 유연탄인 중국 대동탄과 아영청탄인 미국 알라스카의 유시벨리탄에었는데, 두 탄중 모두 건식 가스화기의 운전상에는 문제가 없었다. 가스화를 위한 산소의 농도는 90%까지 그리고 석탄시료 무게 대비 증가량 10∼12%까지는 가스화의 온도 유지와 가스조성 측면에서 무리 없이 적용할 수 있다고 판단되었다. 이들 가스화 시험을 통하여 생성된 슬랙은 가스화기 슬랙탭의 조업 온도와 대상석탄 회재의 용융특성에 따라 침상 또는 알갱이 형태로 배출되었으며, 슬랙으로부터 중금속 성분이 유출되는지를 분석해 본 결과 침출수에 의한 2차 오염은 없는 것으로 확인하였다. IGCC용 석탄을 선정하는 석탄특성에서는 미분탄의 수분함량, 회재함량, 회재용융온도, 발열량 측면에서 검토하였는데, 건식가스화기의 경우 미분탄의 표면수분의 제거가 중요하고 회재의 함량과 회재의 용융온도를 같이 고려하여 적정한 시료 석탄이 선정되어야 한다는 결론을 얻었다. 가스화기 운전측면에서는 여러 기계적인 문제점들이 발견되었는데 시료공급노즐의 막힘문제, 역화문제, 고온가스 누출문제, 추운 겨울 운전시 오링(O-ring)문제 등에 대한 논의와 대책을 제시하였다.

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Characteristics of AC-DC Converter using Multilayer Piezoelectric Transformer (적층형 압전변압기를 이용한 AC-DC 컨버터 특성)

  • Shin, Hyun-Yong
    • The Journal of the Korea institute of electronic communication sciences
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    • v.7 no.6
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    • pp.1315-1320
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    • 2012
  • In this study, piezoelectric AC-DC converter using ring-dot type multilayer piezoelectric transformer with no anisotropic of polarization was developed. Considering the characteristics of piezoelectric transformer which is very narrow operating frequency range, piezoelectric converter was designed with mixed structure of PFM driving method for feedback control of oscillation frequency and PWM driving method for output control. Maximum power and allowed current of the developed piezoelectric converter showing stable driving with minimum heat was 25W and 900mA, respectively. The output voltage of the piezoelectric converter was controlled by the driving oscillation frequency and showed stable and efficient operating characteristics at the maximum power.

Characteristics of a nonmagnetic preplating leadframe (비자성 선도금 리드프레임의 특성)

  • Lee, D.H.;Jang, T.S.;Kim, H.D.;Hong, S.S.;Lee, J.W.;Yang, H.W.
    • Proceedings of the KAIS Fall Conference
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    • 2006.11a
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    • pp.162-166
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    • 2006
  • 기존의 Ni PPF를 대신하여 새롭게 Cu-Sn 합금을 barrier층으로 적용한 PPF를 제조하여, 그 제반 특성들을 조사하였다. Cu-Sn 합금도금층은 기존의 Ni PPF와 마찬가지로 반도체 substrate로서 지녀야 할 열적 안정성을 충분히 확보할 수 있음을 알 수 있었다. 또한 기지층 및 보호층과의 계면간 밀착성이 Ni PPF보다 더 우수했으며, 미세한 결정립들이 균일하게 분포한 도금층 구조를 나타내어, 이들이 Ni PPF보다 구조적으로 더욱 안정할 것임을 예상할 수 있었다. 한편 강자성 거동을 보이는 Ni PPF와는 달리 Cu-Sn PPF는 완벽한 상자성 특성을 보여, 점차 고집적, 고밀도화 되어가는 반도체 패키지의 동작중 발생할 발열 및 신호간섭의 위험이 원천적으로 제거될 수 있음을 보였으며, solderability, bondability 등의 field 특성 또한 Ni PPF와 거의 비슷함을 알 수 있었다.

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Characteristics of Transformer as a function of Coiling method (코일 형태에 따른 변압기의 특성)

  • Kim, Hyun-Sik;Kim, Jong-Ryung;Lee, Hae-Yon;Evgeniy, Ustinov;Oh, Young-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05b
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    • pp.161-164
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    • 2004
  • 변압기는 권선방법에 따라 많은 특성의 변화를 나타내게 되는데 일반적인 동선의 권선법과 코일형태로 동판을 가공하여 사용하는 평면 권선방법, 그리고 고전류용 변압기에 이용되는 것으로 코어의 권선창 표면을 감싸는 형태의 관형 권선방법의 3가지의 코일 형태 또는 권선방법에 따른 변압기의 특성 변화와 컨버터에 채용되었을 때의 전력효율에 대하여 고찰하였다. 평면 코일을 이용한 변압기는 높은 코일간의 결합도로 인해 가장 낮은 누설인덕턴스와 가장 높은 성능지수 및 결합계수를 나타내었고, 관형코일을 이용한 변압기는 높은 누설특성으로 인해 가장 낮은 성능지수와 결합계수를 나타내었다. 그리고 이들을 DC-DC 컨버터에 채용하여 분석한 결과 평면변압기가 가장 높은 효율을 발휘하였다. 관형변압기는 저전력에서는 높은 누설량으로 인해 효율이 상대적으로 낮지만 출력전력이 증가할수록 상승하는 발열량에 대한 방열효과가 높아 효율의 감소폭이 작아서 고주파 또는 대전류용 변압기 응용이 기대된다.

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Combustion Characteristics of Landfill Gas in Constant Volume Combustion Chamber for Large Displacement Volume Engine (I) - Fundamental Characteristics - (대형기관 모사 정적연소실에서 매립지 가스의 연소특성에 대한 연구 (I) - 기초 특성 -)

  • Ohm, Inyong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.8
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    • pp.733-741
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    • 2013
  • This is the first paper on the combustion characteristics of landfill gas in a constant volume combustion chamber for a large displacement volume commercial engine, and it discusses the fundamental characteristics of fuel from the viewpoint of thermochemistry and thermodynamics and compares these results with experimental ones. The results show that the final pressures obtained from theoretical analysis vary under the same heating value owing to the change in the constant volume specific heat owing to the difference in the burned gas composition according to the fuel gas compositions; furthermore, the stoichiometric ratios and trends of analytical and experimental pressures coincide very well, although some minor differences are observed between the two. The root cause of the difference is the heat transfer, which changes the specific heat and lowers the temperature considerably, in the real combustion process. In addition, the large chamber volume and ignition position promote the heat transfer to the wall. Finally, the fuel conversion efficiency increases as the methane mol fraction decreases, and it is maximum when the stoichiometric ratio ranges from 0.8 to 0.9. These increases due to the composition and stoichiometric ratio could sufficiently compensate the decrease due to the specific heat ratio drop, LFG might be more advantageous than pure methane in a real engine.

A Study on Heat Dissipation Characteristics of PMMA Composite Films with Phase Change Material (상변화물질을 이용한 PMMA 복합필름의 방열 성능 향상에 관한 연구)

  • Kwon, Junhyuk;Yoon, Bumyong;Cho, Seung-hyun;Lee, Stephanie K.;Kim, Hyung-ick;Kim, Donghyun;Park, Kyungui;Suhr, Jonghwan
    • Composites Research
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    • v.30 no.5
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    • pp.288-296
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    • 2017
  • The focus of this study is to experimentally investigate the heat dissipation characteristics of poly (methyl methacrylate) (PMMA) composite films with phase change materials (PCM) to resolve heat build-up problems encountered in various electronic devices. In this study, two different types of phase change materials were used to fabricate the composite films by compression molding method and PCM paste sealing method then compared. It was observed in this study that the heat dissipation capability of PCM/PMMA composite films was remarkably enhanced by applying graphite sheet or graphene film into the composite due to their high thermal conductivity. These PCM/ PMMA composite films were attached on the hot spot inside smart phone and tested its surface temperature change according to time. The heat dissipation capability of PCM/PMMA composite film incorporated smart phone was increased 154% and hybrid PCM/PMMA composite film incorporated smart phone was increased 286% over the reference, respectively.

Preparation of crosslinkable imide oligomers and Applications in Polyether Imides for Dual-ovenable Packaging (가교형 이미드 올리고머 제조 및 듀얼 오브너블 용기(Dual-Ovenable Packaging) 용 폴리에테르이미드에 대한 적용 연구)

  • Seo, Jongchul;Park, Su-Il;Choi, Seunghyuk;Jang, Wongbong;Han, Haksoo
    • Korean Chemical Engineering Research
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    • v.48 no.1
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    • pp.45-52
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    • 2010
  • Two different imide oligomers(6FDA-ODA/APA and 6FDA-MDA/MA) having crosslinkable end groups were prepared by using a solution imidization method and their properties were investigated. Also, semi-interpenetrating polymer networks(semi-IPN) were prepared using the blends of imide oligomers with polyetherimide $Ultem^{(R)}$, which is used in dual-ovenable packaging materials. The characteristic properties of semi-IPN films were interpreted by using TGA, Thin Film Diffusion Analyzer, and WAXD. Molecular weights of imide oligomers were successfully controlled utilizing 2-aminophenylacetylene(APA) and maleic anhydride(MA) as an endcapping agent. Exotherm reactions by crosslinking appeared and the amount of exthotherm heat was linearly increased as the content of imide oligomers was increased. For semi-IPNs of $Ultem^{(R)}$ and imide oligomers, 5% and 10% weight loss temperatures increased as the contents of imide oligomers were increased. Diffusion coefficient and water uptake of semi-IPNs decreased as the content of imide oligomers was increased, which might be resulted from hydrophobic fluorine group and high packing density. It was concluded that relatively low thermal stability and hydrolytic stability of polyetherimide $Ultem^{(R)}$ were improved by incorporating new developed imide oligomers.

Explosion Properties and Thermal Stability of Reactive Organic Dust (반응성 유기물 분진의 폭발특성과 열안정성)

  • Han, Ou-Sup;Han, In-Soo;Choi, Yi-Rac;Lee, Keun-Won
    • Journal of the Korean Institute of Gas
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    • v.15 no.4
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    • pp.7-14
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    • 2011
  • Using 20 L spherical explosion vessel and differential scanning calorimeter (DSC), an experimental investigation was carried on explosion characteristics and thermal decomposition of some reactive organic dust. As the result, the minimum explosion concentration of Benzoyl peroxide (BPO), Phthalic anhydride (PA) and 1-Hydroxybenzotriazol (HBT) exist between 10 and 15 g/$m^3$, which indicates that their explosion sensitivity are high. The maximum Kst values of HBT, PA and 97 % BPO are 251, 146 and 80 [$bar{\cdot}m/s$], respectively and the explosion severity of HBT is the explosion class of St-2. The flame velocity was also calculated from the combustion time of dust and flame arrival time to estimate the flame propagation characteristics in a closed vessel. The decomposition temperature and heat of decomposition reaction for 97 % BPO and HBT are $107^{\circ}C$ (1025 J/g), $214^{\circ}C$ (1666 J/g), respectively and it was found that these low decomposition temperature and high released heat affect the explosion characteristics.

Greenhouse Gas Reduction and Marine Steel Plate Tensile Properties When Using Propylene Flame in the Cutting Process (프로필렌 화염을 이용한 선박용 철판 가공 시 온실가스 감소 효과 및 재료의 인장 특성에 미치는 영향 연구)

  • Kim, Do Hyeon;Kim, Dong Uk;Seo, Hyoung-Seock
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.4
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    • pp.639-647
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    • 2022
  • The use of flames is essential in cutting, bending, and welding steel during a ship's construction process. While acetylene fuel is commonly used in steel cutting and the manufacturing process in shipyards, the use of propane as an alternative fuel has recently been increasing, due to the lower risk of explosion and propane's relatively low calorific value. However, propane fuel has a relatively slow processing speed and high slag generation frequency, thereby resulting in poor quality. Propylene is another alternative fuel, which has an excellent calorific value. It is expected to gain wider use because of its potential to improve the quality, productivity, and efficiency of steel processing. In this study, the combustion characteristics of propane and propylene fuel during steel plate processing were analyzed and compared. The reduction of greenhouse gases and other harmful gases when using propylene flame was experimentally verified by analyzing the gases emitted during the process. Heat distribution and tensile tests were also performed to investigate the effects of heat input, according to processing fuel used, on the mechanical strength of the marine steel. The results showed that when propylene was used, the temperature was more evenly distributed than when propane fuel was used. Moreover, the mechanical tests showed that when using propylene, there was no decrease in tensile strength, but the strain showed a tendency to decrease. Based on the study results, it is recommended that propylene be used in steel processing and the cutting process in actual shipyards in the future. Additionally, more analysis and supplementary research should be conducted on problems that may occur.