• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.8 no.4
• /
• pp.532-538
• /
• 1998

Emerald ($3BeO{\cdot}Al_2O_3{\cdot}6SiO_2:Cr^{3+}$) single crystal was grown by temperature gradient reflux method with using Korean natural beryl. The flux of lithium-molibudenium-vanadium oxide system was made by means of mixing the 2 sort of flux which were differently melted $Mo_3-Li_2O$ and $V_2O_5-Li_2O$ each other. The optimum composition of flux was 3 mole ratio of molibudenium. vanadium oxides to lithium oxide ($(MoO_3+V_2O_5)/Li_2O$), flux additives were substituted more less then 0.2 mole% of $K_2O$ or $Na_2O$ to the $Li_2O$ amount. The melting concentration of mixing beryl material was 3~10% content to the flux, that of $Cr_2O_3$ color dopant was 1% to the beryl amount. In the crystal growing apparatus with temperature gradient in the 3 zone furnace which was separated into the block of melt, growth and return, the solution have got to circulate continuously between $1100^{\circ}C$ and $1000^{\circ}C$ in steady state. When thermal fluctuation was treated to during 2 hrs once on a day at 950~$1000^{\circ}C$ in growth zone, the supersaturation solution was maintained, controled and emerald single crystal can be grown large crystal which was prevented from the nucleation of microcrystallite. The preferencial growth direction of hexagonal columnar emerald single crystal was the c(0001) plane of botton side and vertical to the m(1010) plane of post side.

• Journal of Conservation Science
• /
• v.35 no.2
• /
• pp.117-129
• /
• 2019

In this study, black-glazed porcelain excavated from the Shinan shipwreck is analyzed to distinguish its characteristics. Glazes of Hong-Tang kiln are thin and exhibit little vitrification, whereas the Ci-Zhou-type and Cha-Yang kilns are similar in terms of their cross section. However, Raman mapping images reveal difference in the distribution area of magnetite. In this study, firing experiments are conducted to determine how iron oxides change properties in black glazes. The results show that when hematite is fired to a temperature greater than $1250^{\circ}C$, it becomes magnetite. Therefore, it is estimated that a firing temperature of approximately $1200^{\circ}C$ is suitable for the Hong-Tang kiln. In addition, glazes of the Ci-Zhou-type and Cha-Yang kilns are fired at approximately $1300^{\circ}C$. However, when the characteristics of firing in ancient kilns are considered, porcelain can be fired for a sufficiently long period to extend to glaze surfaces.

• Journal of Bio-Environment Control
• /
• v.20 no.2
• /
• pp.144-149
• /
• 2011

This research has been carried out to examine the effects of quality promoting agents on global quality and epidermal changes of Chamaecereus silvestrii 'Hee-mang' for quality maintenance of the transportation. D-sorbitol than D-mannitol treatment was effective in a lower reduction of fresh weight in C. silvestrii transportations. Application of diniconazole 200 ppm suppressed growth of C. silvestrii. However, it enabled the possibility of long-tenn plant transportation (up to 50 days) and color formation was also effective. As for epidermis structure of C. silvestrii, hypodermis development was lower compared to Gymnocalycium friedrichii and its long-term transportation became poor quality due to single layered, thin cell wall. Application of diniconazole 200 ppm + D-mannitol 10,000 ppm showed higher growth suppressing effects and diniconazole 200 ppm + wax treatment showed better color formation suitable for quality maintenance and storage purposes for C. silvestrii.

• Journal of the Korean Applied Science and Technology
• /
• v.38 no.5
• /
• pp.1273-1281
• /
• 2021

The purpose of this study was to increase the power of color and examine the long-lasting power, which is a disadvantage of one-pack acid hair dye by using chestnut shell pigment. For this, hair dyeing power was measured using a spectrophotometer, the optical density(O.D.) value was measured to examine the degree of fading of the hair, and the elasticity of the hair was analyzed by measuring the tensile strength. As a result of comparing the results of applying different leaving times and treatment methods to the hair samples of each level, the experimental group that was heat-treated for 20 minutes showed the highest dyeing power. Then, it was confirmed in the order of 40 minutes of natural exposure, 10 minutes of heat treatment, and 20 minutes of natural exposure. And it was also confirmed that the color expression visually improved as it went up to level 10. However, at level 10, it was confirmed that some water loss occurred even after 3 days and the tensile strength was low. These findings that indicated the beauty industry will popularize a one-step acid hair dye containing various natural dye ingredients to help maintain modern people's well-being and healthy mind and body.

• Journal of Yeungnam Medical Science
• /
• v.1 no.1
• /
• pp.49-58
• /
• 1984

The differential diagnosis of atypical mycobacteriosis caused by atypical mycobacteria (with the exception of Mycobacterium tuberculosis, Mycobacterium bovis, and Mycobacterium leprae) which are widly distributed in soil and water, from pulmonary tuberculosis is possible only when atypical mycobacteria are isolated and identified. In this investigation, attempts were made to isolate atypical mycobacteria from persons registered as tuberculosis patients in the Anyang Health Center in Anyang City, Kyungki province, Korea. Biological and biochemical tests were performed for the atypical mycobacteria isolated from these patients, also retrospective analysis of clinical and X-ray findings of the patients with bacteriologically confirmed atypical mycobacteriosis were done. The results can be summarized as follows: 1. 103 strains of mycobacteria were isolated among 334 sputum samples from patients. 2. Among the isolated mycobacteria, 10 strains (9.7%) were found to be a atypical mycobacteria and 93 strains (90.3%) were tubercle bacilli of human type. 3. On the basis of Runyon's grouping of atypical mycobacteria, there were 3 strains (30.0 %) of scotochromogen and nonphotochromogen respectively, 4 strains (40.0%) of rapid grower, and no photochromogen. 4. By biochemical tests, 3 strains of scotochromogen were identified as Mycobacterium scrofulaceum (2 strains) and Mycobacterium szulgai (1 strain) 3 strains of nonphotochromogen were Mycobacterium avium-complex (2 strains) and Mycobacterium terriae (1 strain), and 4 strains of rapid grower were Mycobacterium fortuitum (3 strains) and Mycobacterium chelonei. 5. In drug sensitivity tests, all 10 strains isolated atypical mycobacteria showed resistance to various concentration of INH and SM and low concentration (10mcg, 40mcg and 50mcg) of EB, TH, and CS, and were sensitive to only high concentration (20mcg and 100mcg) of EB, TH, CS, and RFP. 6. In analysis of clical findings by the patients with bacteriologically confirmed atypical mycobacteriosis, it was found that clinical symptoms of these patients appeared not to be mild than those of patients with pulmonary tuberculosis. The patients with atypical mycobacteriosis had been treated for pulmonary tuberculosis for a long time and they showed no improvement.

• Journal of Conservation Science
• /
• v.37 no.5
• /
• pp.606-616
• /
• 2021

From the collection of the National Kimhae Museum, qualitative analyses using microscopic observation, SEM-EDS, Raman spectroscopy, FT-IR-ATR spectroscopy, and GC-MS were conducted on three burnished red potteries-Jeoksaekmaoyeonwa burnished red pottery (Neolithic age red pottery), Dandomaoyeonwan burnished red pottery(Bronze age red pottery) and Jeoksaekmaoyeongajimun burnished red pottery(Bronze age red pottery)-to investigate the components of the red pigments and the binder. After the layers of the primer were separated from the red surface, crystals of red pigment particles and minerals were found on the red surface. Through SEM-EDS, Raman estimates that the red pigment is Among soil pigments with iron oxide(Fe₂O₃) as the main color development source, Red Ocher(Fe₂O₃). A band characteristic of the Urushiol polymer was detected in the FTIR-ATRspectra(4000~600cm^-1), GC-MS analysis confirmed the presence of the benzenemethanol-2-prophenyl, 4-heptylphenol, 1-tetracecanol, heptafluorobutyric texidecane, all of which are the ingredients of the directional structure of the lacquer present in the red layer. Therefore, it seemed that the three burnished red pottery: Jeoksaekmaoyeonwan pottery(Neolithic age burnished red pottery), Dandomaoyeonwan pottery(bronze age burnished red pottery) and the Jeoksaekmaoyeongajimun pottery(bronze age burnished red pottery) made by mixing minerals and Red Ocher(Fe₂O₃), with lacquer.

• Analytical Science and Technology
• /
• v.7 no.2
• /
• pp.173-179
• /
• 1994

The point of present study was focused on developing the method for the determination of dissociation constant by means of FIA conjunction with Diode Array Spectrphotometry or spectrophotometry along with small amount of Bromocresol Green(mg order) within short time. On the calculation with computer, the indicator with pK=7 has been shown the most sensitive reaction when little amount of base or acid has been added. The pKa of Bromothymol Blue and Bromocresol Green were measured as 7.31 and 4.82 respectively with spectrophotometry after activity correction by Kielland method (Reported value by Bishop, 7.30 and 4.79). The pKa of Bromocresol Green by FIA was obtained as 4.78 and was comparable with other values determined by other methods.

• Journal of the Korean Applied Science and Technology
• /
• v.30 no.4
• /
• pp.592-601
• /
• 2013

This work, which was about the synthesis of 3-(1,8-Naphthalimido) propyl methacrylate and GMA copolymers and their physical properties, investigated the compositions of the copolymer, the reactivity ratios of the monomer, resonance effect(Q), polar effect(e) and fluorescence effect of 1,8-naphthalicanhydride. Azobisisobutyronitronitryl(AIBN) as an initiator was employed at $60^{\circ}C$ with dimethylformamide(DMF) of solvent for the copolymerization of NIPM. $r_1$ was found to be higher than $r_2$ from the reactivity ratios of the monomer obtained from F-R and K-T methods. NIPM was found to be more copolymerized than GMA. The fluorescence spectrums of these polymers showed a weak monomer fluorescence band at 380 nm and a strong excimer fluorescence band at about 460 nm.

• Applied Biological Chemistry
• /
• v.19 no.1
• /
• pp.24-30
• /
• 1976

Rhizomes of the common reed (Phragmites communis Trin.) were incubated for three days in the dark. Methanol extract of the shoots was thin layer chromatographed with several solvent systems and visualized with five reagents. The results may be summarized as follows: 1. Serotonin, tryptophan, and tryptamine were identified by cochromatography with the respective authentic compounds. Bufotenine, N-methylserotonin, and N,N-dimethyltryptamine were tentatively identified by their Rf values and colour reactions. The presence of skatole and gramine was suggested. 2. It was esteemed that the common reed might have an active methylation/hydroxylation system of indole compounds at least for a period of time. 3. The presently devised 'overlap' thin layer chromatographic technique may be a useful tool for the identification of a compound whose Rf value was diverse from that of the authentic one by the interferance containing in a sample material.

• Journal of Conservation Science
• /
• v.28 no.2
• /
• pp.101-112
• /
• 2012

The Donggwanwangmyo Shrine was built in the period of Joseon Dynasty in 1602. There are Clay Statues (Gwanwo, Jangbi, Woojanggun, Juchang, Jojaryoung and so on) enshrined in the inside of the main hall. Original color of these Clay Statues are deteriorated by inorganic pollutant like dust. And the origanal forms were damaged during several process of restorations and repaintings. This study carried out XRD, SEM-EDS, P-XRF and chromaticity measurement for characterization of pigments which painted on Clay Statues. As a result, cinnabar, hematite and red lead were used to paint in pigments for the red and brown colors. Light red pigment was made by gypsum with these minerals that make colors. Graphite and gold were used to color of black and gold pigment, respectively. Green pigment is identified of malachite, atacamite and glauconite. Blue pigment which is clearly painted on Clay Statues is interpreted a morden industrial pigment that were painted at repair work. White pigments are detected calcite, gypsum and silver white. Orpiment and litharge were used to color of yellow and light yellow pigment.