• 대한치과보철학회:학술대회논문집
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• 2004.11a
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• pp.50-50
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• 2004

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2001.05a
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• pp.111-118
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• 2001

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2001.05a
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• pp.169-172
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• 2001

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2000.04a
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• pp.317-320
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• 2000

• Proceedings of the Safety Management and Science Conference
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• 2013.04a
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• pp.109-121
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• 2013

• Proceedings of the Korean Fiber Society Conference
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• 1997.10a
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• pp.445-450
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• 1997

• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.269-269
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• 2010

$SnO_2$ 나노선은 n-type의 전기적 특성과 우수한 광 특성을 보이며, 전자소자, 광소자 뿐 아니라 다양한 종류의 가스 센서 등에 응용되고 있다. 그러나 $SnO_2$ 나노선은 공기중에서 전기적으로 불안정한 특성을 보이며, 도핑을 하지 않은 나노선 소자에서는 전자의 모빌러티가 높지 않다는 단점을 갖고 있다. 이를 개선하고자 본 연구에서는 화학기상증착법 (Chemical Vapor Deposition)으로 Sb을 도핑한 $SnO_2$ 나노선을 성장하여 전계방출효과 트랜지스터 (field effect transistor: FET)를 제작하여 전기적 특성과 UV 반응성의 변화를 측정하였다. Sb 도핑 양을 늘려감에 따라 전기적 특성이 반도체 특성에서 점점 금속 특성으로 변하는 것과 게이트 전압의 영향을 적게 받는 것을 확인하였다. 또한 도핑을 해준 $SnO_2$ 나노선의 경우 UV 반응과 회복 시간이 기존에 비하여 크게 감소하여 UV 센서에 더욱 적합해진 것을 확인하였다. 또한, 슬라이딩 트랜스퍼 공정을 이용하여 나노선을 원하는 기판에 정렬된 상태로 전이할 때 도핑한 나노선은 표면특성의 변화로 정렬도가 크게 감소하는 것을 확인하였고, 기판에 윤활제를 사용하여 정렬도를 높일 수 있었다.

• Applied Chemistry for Engineering
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• v.9 no.6
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• pp.901-906
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• 1998

Gas and liquid flow characteristics were investigated in an internal circulation airlift reactor using a single nozzle for a gas distributor. In three reactors with different diameters of the downcomer and heights of the riser, the gas holdup in the individual flow zone and the impulseresponse curve of tracer for an air-water system were measured for various gas velocities and reactor heights. Experimental results showed that the flow behavior of bubbles in the riser was the slug flow due to strong coalescences of bubbles and that the bubble flow pattern in the downcomer was the transition bubble flow for the smaller diameter of the downcomer, however, it was the homogeneous bubble flow for the larger one. And mean gas holdups in the individual flow zone and the reactor were greatly increased with decreasing the diameter of the downcomer for the equal ratio of height of the top section to that of the riser. Also, the mixing time was much effected by the height of the top section of reactor and for the equal ratio of height of top section to that of the riser, it was increased with increasing the diameter of the downcomer and the height of the riser. Flow characteristics of liquid were mainly varied with the bubble flow pattern in the downcomer and the size of the top section of reactor. And circulation velocities of liquid in the riser were increased with increasing gas velocities and the size of the top section of reactor, and for the equal ratio of height of top section to that of the riser, they were increased with increasing the diameter of the downcomer and the height of the riser.

• Resources Recycling
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• v.18 no.6
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• pp.30-37
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• 2009

Silica sol was prepared from the mixture of sodium silicate solution and oxidized silicate solution in which sodium had been removed by sol-gel process. The properties of sodium silicate solution and silicate solution thus prepared were characterized by yellow silicomolydate method. Moreover, the formation and growth of silica sol from sodium silicate solution was investigated. Sodium silicate solution with 2% of $SiO_2$ contains 95% of reactive silicate, and 50% of reactive silicate participates sol-gel reaction. From the results of FT-IR analysis, it was found that the intensity of silanol bond decreased and the intensity of siloxane bond increased with increasing reaction temperature. Zeta potential of silica sol prepared at each condition was -40~-60 mV and it could be known that silica sol in this study was well dispersed. The silica sol with 5~10 nm size could be prepared by heating the mixed solution of sodium silicate and silicate solution. And the silica sol grew into about 20 nm as silicate solution was added to silica sol solution.

• Korean Chemical Engineering Research
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• v.60 no.4
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• pp.620-629
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• 2022

By varying various experimental conditions such as heating rate, molar hourly space velocity (MHSV), and nitridation reaction temperature, vanadium oxynitride was prepared through temperature programmed reduction/nitridation reaction (TPRN) of vanadium pentoxide and ammonia, and characterization were performed. In order to investigate the physico-chemical properties of the prepared catalyst, N₂ adsorption-desorption analysis, X-ray diffraction analysis (XRD), hydrogen temperature programmed reduction (H₂-TPR), temperature programmed oxidation (TPO), ammonia temperature programmed desorption (NH₃-TPD), transmission electron microscopy (TEM) was performed. Transformation of V₂O₅ with 5 m² g^-1 low specific surface area by reduction at 340 ℃ to V₂O₃ showed a high specific surface area value of 115 m² g^-1 by micropore formation. As the nitridation temperature increased beyond that, the specific surface area continued to decrease due to sintering. The nitridation reaction variable that had the greatest influence on the specific surface area was the reaction temperature, and the x + y value of VN_xO_y of a single phase approached from 1.5 to 1.0 as the nitridation reaction temperature increased. At a high reaction temperature of 680 ℃, the cubic lattice constant a was VN. close to the value. At 680 ℃, the highest nitridation temperature among the experimental conditions, the ammonia conversion rate was 93%, and no deactivation was observed.