• Title/Summary/Keyword: 반응영역

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폐슬러지를 이용한 SiC를 합성하기 위한 열역학적인 고찰

  • 최미령;김영철
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2002.11a
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    • pp.18-19
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    • 2002
  • Si 웨이퍼제조 시 나오는 페슬러지에서 SiC 연마재와 절삭유를 분리해내면 Si 분말을 얻을 수 있다. 본 연구에서의 SiC는 폐슬러지 Si 분말에 C 분말을 혼합하여 제조할 수 있다. Si-C-O 3성분계는 Si, $SiO_2$, SiC, C 4개의 응축상과 CO, SiO, $CO_2$, $O_2$ 4개의 기체상이 가능하고 생성물들 간의 평형관계를 깁스 자유에너지에 의해 평형 반응식이 계산되어질 수 있다. 계산된 평형 반응식은 2개의 SiO, CO 분압이 각각 X, Y 좌표평면에 나타나는 상안정도를 그려볼 수 있다. 상안정도에서 자유도가 2인 경우는, $SiO_2$가 불안정하므로 SiC와 C가 공존하는 영역에서 온도를 독립 변수로 놓으면 나머지 독립 변수는 SiO 나 CO 기체 분압 둘 중 하나가 되어 하나의 직선으로 나타낼 수 있다. 직선을 경계로 각 응축상들의 안정영역을 하나의 좌표평면에 나타낸 후 온도에 따른 SiC의 안정영역을 알아본다.

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Deinterlacing based on the local frequency characteristic of image (영상의 국부 주파수 특성에 기반을 둔 deinterlacing)

  • 우동헌;강현민;엄일규;김유신
    • Proceedings of the IEEK Conference
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    • 2003.07e
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    • pp.1735-1738
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    • 2003
  • 영상은 주파수 분포로 볼 때, 크게 에지 영역과 평탄 영역으로 구분할 수 있다. 또한 각 영역 안에서도 다양한 주파수 분포를 가지고 있다. 기존의 가중치 합(weighted-sum)기반의 방법으로는 다양한 주파수 변화를 포괄하기가 어렵고, 특히 고주파 성분을 효과적으로 보전할 수 없다. 이런 문제를 해결하기 위해서 본 논문에서는 영상의 국부 영역의 주파수 특성에 기반을 둔 deinterlacing 방법을 제안한다. 제안 방법에서는 우선 영상을 에지 영역과 평탄 영역으로 구분하였다. 그런 다음, 각 영역에 대해 신경 회로망을 할당하였다. 또한 각 영역에 대해서 저주파 성분과 고주파 성분으로 모듈화된 신경 회로망을 사용하여 각 영역 안에서의 주파수 특성의 변화에 잘 반응할 수 있게 하였다. 모의 실험에서 제안 알고리즘은 단일 신경 회로망의 경우나 기존의 다른 알고리즘들보다 개선된 성능을 보여주었다

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Pyrolysis Characteristics of Sawdust and Rice Husk (톱밥과 왕겨의 열분해 특성 연구)

  • Park, Dong Kyoo;Seo, Myung Won;Goo, Jeong Hoi;Kim, Sang Done;Lee, See Hoon;Lee, Jae Goo;Song, Byung-Ho
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.415-423
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    • 2007
  • Pyrolysis characteristics of sawdust and rice husk as biomass resources in a thermogravimetric analysis were determined. Experiments were carried out with a linear heating rate under inert atmosphere of $N_2$ gas. Pyrolysis of the biomass can be classified as a lower temperature reaction zone where the major component of holocellulose is thermally decomposed and a high temperature reaction zone where lignin is thermally decomposed. The obtained data was analyzed by the two-step consecutive reaction model. Activation energies of sawdust and rice husk are found to be respectively 82.5 kJ/mol and 85.1kJ/mol in the low temperature zone according to the first order reaction model and 19.7 kJ/mol, 22.0 kJ/mol in the high temperature zone according to the three-way transport model. The reaction rate constant with variation of heating rate can be well predicted by the kinetic compensation relation of Gaur-Reed.

Daily Hassles, Self-Efficacy, and Stress Responses of Adult Learners of Distance Education in Digital Convergence Era -Based on RN-BSN Students (디지털 융복합시대 원격대학 성인학습자의 일상생활스트레스, 자기효능감 및 스트레스반응 -간호학사 특별편입과정 학생을 중심으로)

  • Park, Young-Suk;Kim, Jeong-Hee
    • Journal of Digital Convergence
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    • v.13 no.9
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    • pp.397-407
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    • 2015
  • The purpose of this study was to investigate the relationships among daily hassles, self-efficacy, and stress responses of RN-BSN (Registered Nurses-Bachelor of Science in Nursing) students in juggling both their jobs and learning as an adult learner of distance education in digital convergence era. The data were collected by a questionnaire from 229 nurses in a RN-BSN course of an open university from October to November, 2013. The mean score of facing task dimension was much higher than the interpersonal dimension score among daily hassles. The academic problem of the facing task and the family relationship of the interpersonal were the highest respectively. The mean score of self-efficacy was slightly higher than the median. Multiple regression showed that perceived health status, workload, occupation satisfaction, and values problem of daily hassles explained 44.2% of stress reponses and values problem was the main factor influencing stress responses. The distance education policies and strategies were required to manage their stress for the adult learners of distance education in digital convergence era.

Non-isothermic Analysis of Reaction Rate for the Thermal Decomposition of Na2B4O7·10H2O (Na2B4O7·10H2O 열분해 반응속도의 비등온해석)

  • Choi, Ho-Sang;Park, Young-Tae;Lee, Soo-Kag
    • Applied Chemistry for Engineering
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    • v.8 no.6
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    • pp.1029-1033
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    • 1997
  • Fundamental research of non-isothermic analysis of reaction rate has been carried out for the heat storage system using the thermal decomposition of $Na_2B_4O_7{\cdot}10H_2O$. It was found that the equilibrium temperature of the thermal decomposition reaction was lowered less than 373K in $Na_2B_4O_7{\cdot}10H_2O/Na_2B_4O_7{\cdot}5H_2O$ system, but the heat efficiency was unchanged. The initiation temperature of the reaction was varied from low to high temperature region with heating rate. The reaction order of the dehydration reaction by the thermal decomposition was appeared to be 0.67 by non-isothermic analysis, thereby $Na_2B_4O_7{\cdot}10H_2O$ may be used as a hemical heatstorage material.

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The Impact of Brand's Backstage Information Disclosure via Social Media Contents on Consumer Responses: Adoption of Dramaturgical Theory (브랜디드 콘텐츠를 통한 브랜드 무대후면영역(backstage) 정보 노출이 소비자 반응에 미치는 영향: 연극적 접근이론의 적용)

  • Moon, Jang Ho
    • The Journal of the Korea Contents Association
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    • v.15 no.4
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    • pp.139-152
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    • 2015
  • One of the most latest trends in today's marketing practice is to create branded contents for interacting with online consumers. Marketers are increasingly adopting behind-the-scene contents which disclose a brand's backstage information in their contents marketing efforts. The current study conceptualizes this behind-the-scene storytelling based on dramaturgical theory and investigates its impacts on consumer responses. The study also examines how consumers advertising skepticism level would influence on the evaluation of branded contents. In addition, the moderating role of advertising skepticism in evaluating brand's backstage information is investigated. The findings suggests that consumers who are exposed to brand's backstage indicate greater information attitude, brand attitude, and purchase intention than those who are not exposed to brand's backstage. Also consumers who have lower advertising skepticism evaluated branded contents more positively than high ad skepticism consumers. Lastly, the moderating role of advertising skepticism on the impact of brand's backstage disclosure is reported.

MMA계의 환경친화적인 광중합에 관한 연구

  • 주영배;이내우;최재욱;설수덕
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2000.11a
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    • pp.361-366
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    • 2000
  • 최근 광화학반응(photochemical reaction)을 이용해서 새로운 무기, 유기 및 고분자의 재료개발을 위한 연구가 매우 활발히 진행되고 있으며, 이중 광범위하게 환경친화적 조업으로 작업환경적인 독성영향을 최소화시킬 수 있는 연구영역이 필요한 것은 광중합반응을 이용한 소재개발이다.(중략)

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혼합물실험을 위한 평행좌표그림의 활용

  • Jang, Dae-Heung
    • Proceedings of the Korean Statistical Society Conference
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    • 2003.10a
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    • pp.167-172
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    • 2003
  • 혼합물실험에서 성분의 개수가 많고 성분에 대하여 제한조건이 있는 경우 흥미영역을 도시하는 작업은 성분의 개수가 4개 이상일 때 힘든 작업이 된다. 또한 반응변수가 여러 개인 경우 최적화문제도 까다롭게 된다. 이때, 탐색적 자료분석의 한 도구로서 평행좌표그림을 이용하면 통계자료분석시 많은 도움을 받을 수 있다.

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Hydrodynamic and Oxygen Effects on Corrosion of Cobalt in Borate Buffer Solution (Borate 완충용액에서 코발트의 부식에 대한 대류와 산소의 영향)

  • Kim, Younkyoo
    • Journal of the Korean Chemical Society
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    • v.58 no.5
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    • pp.437-444
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    • 2014
  • The electrochemical corrosion and passivation of Co-RDE in borate buffer solution was studied by Potentiodynamic and electrochemical impedance spectroscopy. The mechanisms of both the active dissolution and passivation of cobalt and the hydrogen evolution in reduction reaction were hypothetically established while utilizing the Tafel slope, the rotation speed of Co-RDE, impedance data and the pH dependence of corrosion potential. Based on the EIS data, an equivalent circuit was suggested. In addition, the electrochemical parameters for specific anodic dissolution regions were carefully measured. An induction loop in Nyquist plot measured at the open-circuit potential was observed in the low frequency, and this could be attributed to the adsorption-desorption behavior in the corrosion process.

Numerical Study on Fluid Flow Characteristics in Taylor Reactor using Computational Fluid Dynamics (CFD를 이용한 테일러 반응기의 유동 특성에 관한 수치적 연구)

  • Lee, Seung-Ho;Shim, Kyu Hwan;Jeon, Dong Hyup
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.1
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    • pp.9-19
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    • 2016
  • This study investigated the variations of Taylor flow and particle residence time in a Taylor reactor according to the changes of angular velocity and inlet velocity using computational fluid dynamics technique. The results showed that the fluid in a reactor became unstable with an increase of angular velocity. The flow moved to the regions of CCF, TVF, WVF and MWVF resulting in an increase of Reynolds number. Accordingly, the flow characteristics were different for each regions. We confirmed that the inlet velocity influences the Taylor flow. The particle residence time and standard deviation increased with an increase of angular velocity and a decrease of inlet velocity.