• Title/Summary/Keyword: 반응성 산소기

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A Study on High Strength Nitrogen Wastewater Treatment and Sludge Granulation Characteristics in a Pilot-scale Air-lift Sequencing Batch Reactor (파일럿 규모의 공기 유동 연속회분반응기에서 고농도 질소제거 및 슬러지 그래뉼화 특성 연구)

  • Lee, Soochul;Kim, Dong-Jin
    • Clean Technology
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    • v.18 no.4
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    • pp.398-403
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    • 2012
  • Selective nitrification and granulation have been carried out in a pilot scale air-lift sequencing batch reactor (SBR) for stable and economical nitrogen removal from wastewater. The SBR showed about 100% nitrification efficiency up to 1.0 kg ${NH_4}^+-N/m^3{\cdot}d$, about 90% efficiency at 1.0-2.0 kg ${NH_4}^+-N/m^3{\cdot}d$, and it was less than 90% when the load was higher than 2.0 kg ${NH_4}^+-N/m^3{\cdot}d$. Nitrite accumulation was induced by selective inhibition of nitrite oxidizing bacteria by free ammonia inhibition and dissolved oxygen limitation. For the purpose, high nitrite ratio (> 0.95) was obtained by keeping the pH higher than 8.0 and dissolved oxygen lower than 1.5 mg/L. In addition, sludge granulation was achieved by keeping reactor settling time to 5 minutes to wash out poor settling sludge and to promote the growth of granulation sludge. The operation accelerated sludge granulation and the sludge volume index (SVI) decreased and stably maintained to less than 75 in 60 days.

Removal of Ammonia-N by Immobilized Nitrifier Consortium (고정화된 질화 세균군에 의한 암모니아성 질소 제거)

  • 서근학;김병진;조문철;조진구;김용하;김성구
    • KSBB Journal
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    • v.13 no.3
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    • pp.238-243
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    • 1998
  • Nitrifier consortium immobilized in Ca and Ba-alginate beads were packed into two bioreactors and the performances of bioreactors were evaluated for the removal of ammonia nitrogen from synthetic aquaculture water. The total ammonia nitrogen (TAN) concentration of the influent was continually kept about 2g TAN/㎥. At the HRT of 0.6hr, ammonia nitrogen removal rate of two bioreactors were about 52.6 and 51.0g TAN/$\textrm{m}^3$/day, respectively. At the respect of ammonia nitrogen removal, two bioreactor showed the similar abilities. The second trial with nitrifier consortium immobilized in Ca-alginate bead was carried out to evaluate the ammonia nitrogen removal rate for 35 days. The highest ammonia nitrogen removal rate was 82g TAN/$\textrm{m}^3$ when HRT was about 0.3hr.

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The surface modification on the inner wall of PTFE tube using micro plasma (마이크로 플라즈마 방전을 이용한 PTFE 튜브 내벽의 표면개질)

  • Jo, Yong-Gi;Kim, Hun-Bae;Jeong, Dong-Geun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2013.05a
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    • pp.104-104
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    • 2013
  • 고분자이면서 유전체인 Poly-Tetra-Fluoro-Ethylene (PTFE) 튜브에 AC형 고전압을 인가하여 유전체 장벽 방전 (dielectric barrier discharge, DBD)를 유도하고, 발생된 마이크로 플라즈마에 의한 PTFE 튜브 내벽의 표면 개질에 관한 연구이다. 가스인입과 진공배기가 가능한 장치에 PTFE 튜브를 연결하고, 튜브내부를 진공상태를 유지하면서 반응가스를 이용하여 튜브 내벽을 표면개질 하였다. 반응가스를 아르곤, 수소, 아세틸렌, 산소, 질소를 반응 단계에 맞게 혼입하여 마이크로 플라즈마를 발생시켜 플라즈마에 의한 표면변화를 관찰하였다. 표면은 반응성 가스 플라즈마에 의해 물리 화학적 반응이 일어나 고분자 표면의 반응성 활성화를 통한 표면개질의 방식으로 진행되었다. 표면 개질된 튜브 내벽 표면에 대해 XPS, FT-IR, SEM, 접촉각 측정과 분석 실시함으로써 표면변화를 관찰하였다.

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Citric Acid Production and Scale-up in Dual Hollow Fiber Bioreactor (이중실관 생물 반응기에서의 구연산 생산과 Scale-up)

  • 장호남;지동진;심상준
    • Membrane Journal
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    • v.2 no.2
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    • pp.122-128
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    • 1992
  • A study on the citric acid production was performed in various size dual hollow fiber bioreactors with immobilized Aspergillus niger (KCTC 1232). The final dry cell mass density reached 300g/l based on the space volume available for cell growth. Under air and oxygen aeration the volumethe productivity reached 0.63 and 1.02g/l.h, which cormsponded to 10 and 16 fold over those of batch fermentation, respectively. The initial pH of the medium was a critical factor and the lower value resulted in higher citric acid yield. The increase in the feeding rate of medium or the number of reactor unit resulted in the improvement of the productivity due to higher consumption rate of substrate.

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Adhesion improvement between metals and fluoropolymers by ion assisted reaction (이온보조반응에 의한 금속과 불소계 고분자의 접착력 증진)

  • Han, Sung;Cho, Jun-Sik;Choi, Sung-Chang;Yoon, Ki-Hyun;Koh, Seok-Keun
    • Journal of the Korean Vacuum Society
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    • v.10 no.1
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    • pp.37-43
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    • 2001
  • Polyvinylidenefluoride and Polytetrafluoroethylene have been irradiated by 1 keV Ar+ ion beam in an $O_2$ environment. Hydrophilic functional groups (such as -(C-O)-,-(C=O)-,-(C=O)-O- and so on) were formed on fluoropolymers. Contact angles of water to PVDF were reduced from $75^{\circ}$ to $31^{\circ}$. Re-increase of contact angle was originated from carbonization phase in case of high dose irradiation above $1{\times}10^{16} Ar^+cm^2$. Contact angles to PTFE decreased at low dose irradiation and were exaggerated to about $140^{\circ}$ due to cone type surface at high dose irradiation. Hydrophilic functional groups have played an important role on adhesion between metal and fluoropolymers by acid-base interaction and chemical bond formation. Adhesion of Pt/PVDF was enhanced by acid-base interaction because Pt is inert metal. Chemical bond formation between Cu and PTFE could enlarge the adhesion strength of Cu/PTFE.

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Photocatalytic Activities of Titania Deposited Beads by FB-CVD as Operation Variables (유동층 화학기상증착(FB-CVD)으로 제조한 광촉매 박막증착 비드의 조업변수에 따른 반응성)

  • Lim, Nam-Yun;Lee, Seung Yong;Park, Jaehyeon;Kwak, Jini;Park, Hai Woong
    • Korean Chemical Engineering Research
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    • v.44 no.3
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    • pp.300-306
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    • 2006
  • Photocatalyst deposited beads were prepared by fluidized bed chemical vapor deposition (FB-CVD) under various operating conditions of substrates, bed temperature, pressure, and oxygen concentration. Photocatalytic degradation of acetaldehyde was carried out to determine the optimum operating condition of prepared photocatalysts. They were characterized by using FE-SEM, XRD, and XPS. From the FE-SEM photographs, it was found that the surfaces of titania-coated beads were covered with crystal form, particle form, and slick form of titania on alumina, silica-gel, and glass beads, respectively. From the result of photocatalytic degradation of acetaldehyde, it was found that prepared titania/ alumina beads at $600^{\circ}C$, 5 torr showed superior performance to others, and oxygen flow rate has no significant effect.

Comparative Bioreactor Studies in Terms of Oxygen Transfer between Suspended and Immobilized Fungal Systems for Cyclosporin A Fermentation (Cyclosporin A 생산을 위한 액체배양과 고정화배양의 생물반응기에서의 산소전달 비교 연구)

  • 전계택
    • KSBB Journal
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    • v.9 no.2
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    • pp.211-223
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    • 1994
  • In fermentations with a 4-liter stirred tank bioreactor, a better than two-fold enhancement of the gas-liquid mass transfer coefficient$(k_La)$ in the celite-immobilized fungal cultures of Tolypocladium in flatum over the parallel conventional free-cell was observed at identical biomass concentrations, despite the higher specific oxygen uptake rate of the immobilized fungi during exponential growth. As a result oxygen sufficient conditions, i. e., dissolve oxygen(D.O.) concentrations exceeding 75% air saturation, could be maintained throughout exponential growth period of the immobilized culture, in contrast to the suspended fungal culture, whose D.O. levels fell below 50% air saturation. A linear monotonic dependence of $k_La$ upon impeller agitaion rate was found for both immobilized and conventional cultivation modes over a range of 250 to 550rpm, the slope being a function of biomass concentration for the free but not for the immobilized cell system In contrasts oxygen transfer rate was a much weaker function of aeration rate up to about 2.5 vvm for both culture configurations. Above this level, aeration rate had no further effect on the mass transfer. In addition, the immobilized cultures sustained good morphological and physiological states, leading to almost two times higher cyclosporln A (CyA) productivity overt the parallel free cell system. These experiments suggest that the celite-immobilized fungal system in a stirred tank reactor has considerable promise for scaling up cyclosporin A production in terms of high-density cultivation.

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Taurine exerts neuroprotective effects via anti-apoptosis in hypoxic-ischemic brain injury in neonatal rats (신생 흰쥐의 저산소성 허혈성 뇌손상에서 항세포사멸사를 통한 taurine의 신경보호 효과)

  • Jeong, Ji Eun;Kim, Tae Yeol;Park, Hye Jin;Lee, Kye Hyang;Lee, Kyung Hoon;Choi, Eun Jin;Kim, Jin Kyung;Chung, Hai Lee;Seo, Eok Su;Kim, Woo Taek
    • Clinical and Experimental Pediatrics
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    • v.52 no.12
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    • pp.1337-1347
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    • 2009
  • Purpose:Taurine (2-aminoethanesulfonic acid) is a simple sulfur-containing amino acid. It is abundantly present in tissues such as brain, retina, heart, and skeletal muscles. Current studies have demonstrated the neuroprotective effects of taurine, but limited data are available for such effects during neonatal period. The aim of this study was to determine whether taurine could reduce hypoxic-ischemic (HI) cerebral injury via anti-apoptosis mechanism. Methods:Embryonic cortical neurons isolated from Sprague-Dawley (SD) rats at 18 days gestation were cultured in vitro. The cells were divided into hypoxia group, taurine-treated group before hypoxic insult, and taurine-treated group after HI insult. In the in vivo model, left carotid artery ligation was performed in 7-day-old SD rat pups. The pups were exposed to hypoxia, administered an injection of 30 mg/kg of taurine, and killed at 1 day, 3 days, 1 week, 2 weeks, and 4 weeks after the hypoxic insult. We compared the expressions of Bcl-2, Bax, and caspase-3 among the 3 groups by using real- time polymerase chain reaction (PCR) and western blotting. Results:The cells in the taurine-treated group before hypoxic insult, although similar in appearance to those in the normoxia group, were lesser in number. In the taurine-treated group, Bcl-2 expression increased, whereas Bax and caspase-3 expressions reduced. Conclusion:Taurine exerts neuroprotective effects onperinatal HI brain injury due to its anti-apoptotic effect. The neuroprotective effect was maximal at 1-2 weeks after the hypoxic injury.

Thioredoxin Peroxidase Manifestation in Radiation-Induced White Rat Lung Tissues (방사선 조사후 손상된 백서 폐조직에서의 Thioredoxin Peroxidase의 발현)

  • Chong, Seong-Cheoll;Park, Joon-Seong;Park, Jee-Won;Lee, Sun-Min;Park, Kwang-Joo;Hwang, Sung-Chul;Lee, Yi-Hyeong;Hahn, Myung-Ho;Oh, Young-Taek;Kim, Hyung-Joong
    • Tuberculosis and Respiratory Diseases
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    • v.47 no.5
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    • pp.650-659
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    • 1999
  • Background/Aims: It is well recognized that all aerobic cells have the protective mechanisms in order to minimize the tissue damage induced by various reactive oxygen species(ROS). Thioredoxin peroxidase(TPX) which has been recently identified and characterized functions to convert peroxide to water. The protein is also found in various subtypes(TPX-A & B, MER5, HS22 and HORF-06) and is known to be ubiquitous in most human cells. Especially, ischemic brain injuries, partial hepatectomy and radiation induced DNA damages. In treating lung cancer, radiation therapy has a major place in the local control and the relief of symptoms, but radiation induced free radical injury and resulting pulmonary fibrosis has been the major drawback of the therapy. However, little is known about the protective mechanisms and biologic modulations against radiation-induced tissue damages. Methods: Eighteen mice were divided into six groups, 3 in each group, and fifteen had received 900cGy of radiation. The mice were sacrificed according to the pre determined time schedule; immediate, 1, 2, 3 and 6 weeks after irradiation. Extracts were made from the lungs of each mice, Western blot analysis of various subtypes of TPX were done after SDS-P AGE. Examination of H & E stained slides from the same irradiated specimens and the control specimens were also performed. Results: No difference in the intensity of the immunoreactive bands in the irradiated lung samples of the mice compared to the unirradiated control was observed regardless of the time intervals, although H & E examination of the sample specimens demonstrated progressive fibrotic changes of the irradiated lung samples. Conclusion: In conclusion, according to our data, it is suggested that various thioredoxin peroxidase subtypes and catalase which are known to be increased in many repair processes may not be involved in the repair of the radiation injury to the lung and subsequent fibrosis.

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Comparison of Reactivity of Oxygen Carrier Particles by TGA (TGA를 이용한 매체순환식 가스연소기 산소공여입자의 반응성 비교)

  • 임남윤;류호정;진경태;배성렬
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2003.05a
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    • pp.621-625
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    • 2003
  • 최근 지구온난화 문제와 관련하여 국제적으로 이슈가 되고 있는 $CO_2$ 저감 및 처리기술 중에서 연소 후 처리가 아닌 신개념 연소기술로서 NO$_{x}$가 배출되지 않고 $CO_2$의 고농도 원천분리가 가능하여 새로운 연소 및 발전기술로 부상하고 있는 매체순환식 가스연소기술(Chemical-Looping Combustion Technology, CLC)에 대한 연구가 국내외적으로 활발하게 진행되고 있다.(중략)

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