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Colorimetric Detection of Chelating Agents Using Polydiacetylene Vesicles (폴리다이아세틸렌 베시클을 이용한 킬레이트제의 색전이 검출)

  • Park, Moo-Kyung;Kim, Kyung-Woo;Ahn, Dong-June;Oh, Min-Kyu
    • Korean Chemical Engineering Research
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    • v.49 no.3
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    • pp.348-351
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    • 2011
  • In this research, we developed a sensor system which can easily detect several chelating agents using polydiacetylene(PDA) vesicles. In comparison to other sensors, PDA based sensor has several advantages. First, detection method is much simpler and faster because it does not require any labeling step in the experiment procedure. Second, significant color-transition from blue to red based upon external stimulus allows us the detection by naked eyes. Finally, it is also possible to perform quantitative analysis of the concentration of the chelating agent by measuring the colorimetric response. In this paper, five types of chelating agents were used, including EDTA, EGTA, NTA, DCTA and DTPA. Among them, EDTA and DCTA triggered especially strong color-transition. In conclusion, this study has led to a successful development of a color transition-based PDA sensor system for easy and rapid detection of chelating agents.

Decolorization of Azo Dyeing Wastewater Using Underwater Dielectric Barrier Discharge Plasma (수중 유전체장벽방전 플라즈마를 이용한 아조 염색폐수 색도제거)

  • Jo, Jin Oh;Lee, Sang Baek;Mok, Young Sun
    • Applied Chemistry for Engineering
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    • v.24 no.5
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    • pp.544-550
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    • 2013
  • This work investigated the environmental application of an underwater dielectric barrier discharge plasma reactor consisting of a porous hydrophobic ceramic tube to the decolorization of an azo dyeing wastewater. The reactive species generated by the plasma are mostly short-lived, which also need to be transferred to the wastewater right after the formation. Moreover, the gas-liquid interfacial area should be as large as possible to increase the decolorization rate. The arrangement of the present wastewater treatment system capable of immediately dispersing the plasmatic gas as tiny bubbles makes it possible to effectively decolorize the dyeing wastewater alongside consuming less amount of electrical energy. The effect of discharge power, gas flow rate, dissolved anion and initial dye concentration on the decolorization was examined with dry air for the creation of plasma and amaranth as an azo dye. At a gas flow rate of $1.5Lmin^{-1}$, the good contact between the plasmatic gas and the wastewater was achieved, resulting in rapid decolorization. For an initial dye concentration of $40.2{\mu}molL^{-1}$ (volume : 0.8 L; discharge power : 3.37 W), it took about 25 min to attain a decolorization efficiency of above 99%. Besides, the decolorization rate increased with decreasing the initial dye concentration or increasing the discharge power. The presence of chlorine anion appeared to slightly enhance the decolorization rate, whereas the effect of dissolved nitrate anion was negligible.

Photochemical Index Analysis on the Influence of LED Illumination Color Temperature on Donarium Cherry (도시야간조명의 LED 색온도별 겹벚나무의 광화학적 생리지표 해석)

  • Kim, Ji-Su;Yoo, Sung-Yung;Kim, Hway-Suh;Kim, Tae-Wan
    • Korean Journal of Environmental Biology
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    • v.36 no.2
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    • pp.117-123
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    • 2018
  • In this study, the efficiency of photosynthetic electron transfer according to LED color temperature was verified in order to find a way to efficiently grow trees under night illumination. The experiment was carried out with White treatment, Warmwhite treatment, and non-treatment with donarium cherry. The study uses to a method for analyzing and evaluating the color temperature of an LED light source by photochemical analysis. We found that all treatments 115 DAT of maximum fluorescence amount(P) had the lowest. In the treatment using white light and the Warm-white light, the T amount of florescence of the late stage during the transition of the J-I level was increased, and the photosystem I electron transfer efficiency was decreased. Therefore, the electron transport efficiency of $RE1_O/CS$ and RE1o/RC were reduced. Especially, compared to Warmwhite, the light intensity increased greatly in the white-light treatment, The $PI_{TOTALABS}$ of 7 DAT was the highest value, but it was decreased to the lowest value on 115 DAT. This study has shown that the white treatment was low in electron transfer efficiency and soundness. Warmwhite-light treatments showed lower stress.

Effects of the Combination of Oxygen and Color Light on Stress Relaxation: Psychological and Autonomic Responses (산소와 색채 조명 자극의 조합이 스트레스 완화에 미치는 효과: 심리 및 자율신경계 반응을 중심으로)

  • Jang, Eun-Hye;Kim, Ah-Young;Jang, Yongwon;Kim, Bo-Seong;Choi, Yong-Bok;Kim, Seung-Chul;Lee, Sang-Kone;Kim, Seunghwan
    • Science of Emotion and Sensibility
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    • v.22 no.1
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    • pp.55-64
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    • 2019
  • Stress is accompanied by changes in the responses of the autonomic nervous system, and the heart rate variability (HRV) index is a quantitative marker that reflects autonomic responses induced by stressors. In this study, we observed changes in the autonomic responses induced by combinations of 30% oxygen administration and color light for stress relaxation. In all, 42 participants produced stress symptoms over the preceding two weeks, as rated on the stress response scale. After stress assessment, they were exposed to three therapeutic conditions, and electrocardiogram (ECG) signals were recorded before, during, and after therapy. The three therapy conditions consisted of only 30% oxygen administration with white light, a combination of 30% oxygen and orange light, and a combination of 30% oxygen and blue light. The HRV indices extracted from ECG signals were heart rate (HR), the standard deviation of the RR interval (SDNN), the mean square root of consecutive RR interval difference values (RMSSD), the low frequency component of HRV (LF), the high frequency component (HF), and the LF/HF ratio. These indicators were used to compare mean values before and after therapy. The results showed that HR and the LF/HF ratio were significantly lower after therapy than before it. In particular, the condition with 30% oxygen and blue light yielded significantly greater RMSSD and HF increases, as well as decreases in LF/HF ratio than in other two conditions. Our results suggest that therapy with 30% oxygen and blue light is the most effective for the relaxation of stress, which implies autonomic balance by parasympathetic activation.

Sensibility Evaluation on the Correlated Color Temperature in White LED Lighting (백색 LED 조명의 색온도에 관한 감성평가)

  • Jee, Soon-Duk;Lee, Sang-Hyuk;Choi, Kyoung-Jae;Park, Joung-Kyu;Kim, Chang-Hae
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.4
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    • pp.1-12
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    • 2008
  • The aim of this study is to investigate the sensitivity evaluation of human beings in reacting to the correlated color temperature of the optical properties of white LED lighting. For the sake of this study, white light-emitting diode modules have been fabricated their correlated color temperature have been measured, test cabinets for the sensitivity evaluation have been constructed with the white LED modules, and their sensitivity reactions on the test cabinets have been evaluated and analyzed. The sensitivity reaction has been evaluated by the semantic differential method with 15 selected questions, and the reliability and the content validity of their lighting have been analyzed to 3 factors which foe the activity as the first factor, the stability as the second one, the potency as the third one, respectively. For the data analysis on the sensitivity reaction, the dependent variable is the score of the sensitivity evaluation and the independent one is the correlated color temperature of the test module. The results of this study is as follows: In the case of the sensitive evaluation on the activity and the potency in the white LED lighting compared with the fluorescent lamp, the subjects have made higher mark on $MA_3$ with 8,300[K], and in the factor of the stability, they have made higher mark on $MA_1$ with 3,800[K].

A Study on the Moderating Factors of the Relationship between Artwork Color Series and Visitor Satisfaction in Commercial Spaces (상업공간에서 미술품 색 계열과 방문객 만족도 관계의 조절요인에 관한 연구)

  • Wang, YeunJu;Lee, SeungHyun;Bae, JiHye;Kim, SunYoung
    • Korean Association of Arts Management
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    • no.58
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    • pp.121-152
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    • 2021
  • This study attempted to analyze the effect of the color series of artworks installed as environmental stimuli in commercial spaces on the satisfaction of visitors and the moderating effect of the relationship. To this end, based on the SOR model of Stimulate-Organism-Response applied to burial environment research in the field of environmental psychology, and the preceding research using the SOR model, artwork color series(S)-mood and spaace amenity(O)-A research framework for satisfaction(R) was developed. In the experiment, an online questionnaire was conducted for domestic college students and graduate students by producing images with two conditions depending on the case where warm colors and cold colors were installed for the color series of artworks. As a result of verifying the difference in satisfaction of respondents corresponding to the two conditions through regression analysis, it was found that the warm color(vs. cold color) of the artwork color series induces higher visitor satisfaction. In addition, as a result of verifying the controlling factors of mood and space amenity variables in this relationship of influence, a significant moderating effect was found when the positive mood of warm colors(vs. cold colors) in the artwork color series was felt higher than the average. And, of the four types of space amenity, it was found that a significant moderating effect appeared when only comfort and aesthetics were measured as moderating variables. The result of this study proves that the warm color series of artworks that stimulate the physical environment of commercial spaces has a more positive effect on the satisfaction of visitors than the cold color series, and this is reinforced by positive mood, comfort, and aesthetics. It adds understanding and provides useful implications for marketing strategies for building an effective spatial image.

Application of Response Surface Methodology for Optimization of Nature Dye Extraction Process (천연색소 추출공정 최적화를 위한 반응표면분석법의 적용)

  • Lee, Seung Bum;Lee, Won Jae;Hong, In Kwon
    • Applied Chemistry for Engineering
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    • v.29 no.3
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    • pp.283-288
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    • 2018
  • As the use of environmentally friendly and non-disease natural pigments grows, various methods for extracting natural pigments have been studied. The natural color was extracted from parsley, a vegetable ingredient containing natural dyes. Target color codes of green series of natural dyes extracted as variables #50932C (L = 55.0, a = -40.0, b = 46.0) were set with the pH and temperature of extracted natural color coordinates (of the extracted), and the quantitative intensities of natural dyes were analyzed. During the colorimetric analysis predicted by the reaction surface analysis method, a color coordinate analysis was conducted under the optimal conditions of pH 8.0 and extraction temperature of $60.9^{\circ}C$. Under these conditions, predicted figures of L, a, and b were 55.0, -36.3, and 36.8, respectively, while actual experimental ones confirmed were 69.0, -35.9, and 31.4, respectively. In these results, the theory accuracy and actual error rate were confirmed to be 73.0 and 13.8%, respectively. The theoretical optimization condition of the color difference (${\Delta}E$) was at the pH of 9.2 and extraction temperature of $55.2^{\circ}C$. Under these conditions the predicted ${\Delta}E$ figure was 12.4 while the experimental one was 13.0. The difference in color analysis showed 97.5% of the theoretical accuracy and 4.5% of the actual error rate. However, the combination of color coordinates did not represent a desired target color, but rather close to the targeted color by means of an arithmetic mean. Therefore, it can be said that when the reaction surface analysis method was applied to the natural dye extraction process, the use of color coordinates as a response value can be a better method for optimizing the dye extraction process.

Relationship of Favorite Color and Human Character (좋아하는 색채와 인간의 성격의 관계)

  • Shin, Seong-Yoon;Jang, Dai-Hyun;Shin, Kwang-Seong;Lee, Hyun-Chang;Pyo, Seong-Bae
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2011.06a
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    • pp.313-314
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    • 2011
  • 우리가 사는 세계에는 무수히 많은 색들이 존재한다. 이 수많은 색들은 인간에게 항상 의미있는 지시나 신호를 보내고 있다. 본 논문에서는 이러한 인간이 좋아하는 색과 인간의 성격에 대해 자세히 알아본다. 우리 인간은 거의 무의식적으로 색채에 반응하고 색채의 영향을 받고 있다. 색채들이 우리 인간에게 주는 효력은 무시할 수 없을 정도로 엄청나게 크다. 인간은 어떠한 색채를 보고 무드가 좋아지거나 가라앉기도 하고 또는 밝아지거나 나아지기도 한다. 이것은 인간은 빛으로부터 색이 주는 지시나 신호를 알아듣는 것이다. 색채의 지시나 신호를 인식하거나 자각하여 받아들인다면 색채가 지닌 일반적인 뜻을 알 수 있으며 효율적으로 색채를 사용할 수 있다.

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A Development of a Color Tracking System based on the Central Value of the Object (객체 면적중심 기반의 색 추적 시스템 개발)

  • Ji, Yu-na;Kang, Yu-Kyung;Lee, Hyun
    • Proceedings of the Korea Information Processing Society Conference
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    • 2013.11a
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    • pp.1324-1327
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    • 2013
  • 최근 무인로봇 시장이 커지면서 국방관련, 민간, 상업적으로 무인로봇의 수요가 증가하고 있다. 이는 사람이 직접 접근할 수 없는 재난발생지역, 환경오염지역, 방사능위험지역, 국가 간 분쟁지역 등에 무인항공기나 무인지상로봇을 투입하여 실시간 원격으로 재난피해 정도를 관찰하고 인명구조작업, 생존자 위치파악, 국경지대 순찰 등에 효과적인 시스템으로 활용할 수 있다. 하지만, 제한적인 환경에서 가지고 있는 부품들이 기능을 제대로 동작하지 않을 때, 하나의 센서 또는 부품을 활용한 위치추적, 원격제어 및 자율주행 등이 가능해야 한다. 따라서 본 논문에서는 1개의 이미지 센서를 통해, 객체의 색을 인식하고 추적하는 시스템을 개발하고자 한다. 특히, 기존의 거리감지 센서 기반의 색 객체 추적 알고리즘에 비교하여, 면적중심 값의 변화량에 따라 객체추적의 반응속도를 증가시켜 쉽게 객체를 추적할 수 있는 시스템을 개발하고자 한다.

Studies on the Interaction of Biocides and Ethylsilicate Consolidants for Stone Monument (석조문화재 살생물제와 에틸실리게이트 강화제의 상호작용에 관한 연구)

  • Do, Jin-Young;Yun, Yun-Kyung;Lee, Tae-Jong;Kyung, Hye-Sun
    • Journal of Conservation Science
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    • v.21
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    • pp.73-88
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    • 2007
  • In this paper, the interaction between five biocides(commercial) and two ethylsilicate consolidants for stone monuments, reacted in different sequence, has been studied. Through the structures, weight and gelation time of mixture of biocides and consolidants have been evaluated the reactivity of biocide alone, the reactivity of consolidants and biocides, the reactivity of consolidants and dried biocide, and the reactivity of ethylsilicate gel and biocides. The tested biocides show quite different properties from those of consolidants; after evaporation, some biocides are remained white salt crystals, another need the long time for evaporation and one biocide shows pale brown color. The results have shown an interaction of the tested products each other in some application sequences of the products. When the application of liquid state biocides with consolidants, it was noted that some biocide seem to interfere with the formation of gel due to reaction of consolidants and water and salts in biocides. In the reaction of ethylsilicate with dried biocides have shown a heterogenous gel(transparent layer with ethylsilicate alone and white layer which is mixed biocide and ethylsilicate) and many cracks in product due to the different shrinkage, thus the products don't play a role as consolidants. There is no change in structures and color in reaction of the gas state biocide and ethylsilicate gel.

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