• Journal of the Earthquake Engineering Society of Korea
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• v.7 no.2
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• pp.39-48
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• 2003

This paper present a summary of the results of statistical study of the ductility factor which is key component of response modification factor(R). To compute the ductility factor, a group of 1,860 ground motions recorded from various earthquake was considered. Based on the local site conditions at the recording station, ground motions were classified into four groups according to average shear wave velocity. Inleastic spectrum were computed for elastic perfectly plastic SDOF systems undergoing different level of inelastic deformation and period. Ductility factors were calculated by deviding elastic response spectrum by inelastic response spectrum. The influence f displacement ductility ratio, site condition, magnitude and epicentral distance on ductility factors were studied. The coefficient of variation was computed to evaluated the dispersion of ductility factors as the defined ratio of the standard deviation to the mean.

• Journal of the KSME
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• v.55 no.7
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• pp.37-41
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• 2015

이 글에서는 초임계 유체 이용기술의 일환으로서 바이오매스의 초임계수 가스화 기술을 소개하였다. 초임계수 가스화 기술의 원리와 특징, 가스화 반응조건, 그리고 기술개발 현황을 정리한 다음, 향후 이 기술의 상용화를 위하여 극복해야 할 과제를 제시하였다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.2
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• pp.90-96
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• 2018

Tracer experiments were carried out on two laboratory modes, "without media mode" and "with media mode", to examine the hydraulic characteristics of the anaerobic fluidized bed bioreactor (AFBR). For both configurations, a formula was derived for the hydraulics and data interpretation to obtain the actual characteristics of the reactor. The dispersion model is based on the assumption that carriers are non-reacting and the dispersion coefficient is constant. The model represents the one-dimensional unsteady-state concentration distribution of the non-reacting tracer in the reactors. The experimental results showed that the media increased the mixing conditions in the reactor considerably. For the reactor without media, in the range tested, the dispersion coefficient was at least an order of magnitude smaller than that of the reactor with media. Advective transport dominates and the flow pattern approaches the plug flow reactor (PFR) regime. The dispersion coefficient increased significantly as us, the superficial liquid velocity, was increased proportionally to 0.82cm/s. On the other hand, for the reactor with media, the flow pattern was in between a PFR and a completely mixed flow reactor (CMFR) regime, and the dispersion coefficient was saturated at us=0.41cm/s, remaining relatively constant, even at us=0.82cm/s. The dispersion coefficient depends strongly on the liquid Reynolds number (Re) or the particle Reynolds number (Rep) over the range tested.

• Applied Chemistry for Engineering
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• v.10 no.1
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• pp.173-176
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• 1999

The production of fine metal oxide particles in supercritical water has been studied. Cobalt nitrate solution and manganese nitrate solution have been selected as model solutions for metal salt aqueous solution and the particles of cobalt oxide and manganese oxide have been produced. It was observed that the production of fine metal oxide particles in supercritical water was feasible and the dehydration rate was remarkably high in supercritical water. In spite of a short residence time (3~100 seconds), fine particles ($0.5{\sim}2{\mu}m$) have been produced. In the supercritical water process, the temperature of mixer had a significant effect on particle size and size distribution. It was observed that a change in reaction temperature resulted in the control of particle size.

• Polymer(Korea)
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• v.28 no.2
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• pp.121-127
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• 2004

The instantaneous removal of ethylene glycol is very important fur obtaining high molecular weight polymer because of the reversibility of the polycondensation reaction of poly(ethylene naphthalate)(PEN). In this study, we investigated the mass transfer phenomena in the thin film of PEN oligomer where the polycondensation reaction took place at 280$^{\circ}C$ and under 0.1mmHg. In case of less than 0.025cm film thickness the mass transfer resistance through the thin film of the polymer melt was not so high that the overall reaction rate was governed only by the polycondenstion reaction. Both the mass transfer model and the diffusion model predicted the experimenatal data well but the diffusion model showed faster reaction rate in the low molecular weight range than the mass transfer model . It was estimated from the two models that the diffusivity was 4.7${\times}$10$\^$-6/$\textrm{cm}^2$/sec and the mass transfer coefficient was 1.4 ${\times}$10$\^$-4/cm/sec both of which were smaller than In case of poly(ethylene terephthalate).

• Journal of the Korean Society of Hazard Mitigation
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• v.11 no.1
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• pp.7-13
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• 2011

Accurate response analysis of long span bridges subjected to seismic excitation is important for earthquake hazard mitigation. In this paper, the performance of a typical four span continuous reinforced concrete bridge model subjected to asynchronous multiple seismic excitations at the supports is investigated in both the time and frequency domains and the results are compared with that from a relevant uniform support excitations. In the time domain analysis, a linear modal superposition approach is used to compute the peak response values. In the frequency domain analysis, linear random vibration theory is used to determine the root mean square response values where the cross correlation effects between the modal and the support excitations on the seismic response of the bridge model are included. From the two sets of results, a practical range of peak factors which are defined to be the ratio of peak and the root mean square responses are suggested for displacements and forces in members. With reliable practical values of peak factors, the frequency domain analysis is preferred for the performance based design of bridges because of the computational advantage and the generality of the results as the time domain analysis only yields results for the specific excitation input.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2006.04a
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• pp.217-219
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• 2006

• Proceedings of the Korea Water Resources Association Conference
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• 2018.05a
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• pp.361-361
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• 2018

강우패턴이 유출반응에 미치는 영향을 분석하는 것은 수문연구에서 중요한 주제 중 하나이며 댐유역에 대해 기상 및 유출자료를 사용하여 이를 상세히 분석함으로써 이수기에 필요한 수자원을 예측 및 확보하는 것은 중요하다. 강우패턴이 유출반응에 미치는 영향을 상세히 분석하기 위해서는 댐유역의 상류부터 하류까지 많은 유출관측지점의 자료를 사용해야 하지만 상류의 소유역들은 대부분 미계측유역이라는 문제점이 있다. 본 연구에서는 자료공간확장 방법을 사용하여 미계측유역의 유출자료를 생성하고 이 자료들을 분석함으로써 강우패턴이 유출반응에 미치는 영향을 자세히 분석하였다. 먼저 안동댐유역내 관측유역인 안동댐, 도산, 소천유역을 대상으로 1989년부터 2009년까지의 기간 중 20개의 사상에 대하여 분포형 모형인 GRM 모형의 적용성을 조사하였으며 전반적으로 0.5 Nash-Sutcliffe 계수 이상의 타당한 모형효율성 결과를 얻었다. 그 후 자료공간확장 방법을 사용하여 안동댐 상류에 위치한 47개의 미계측 소유역들의 유출자료를 생성하였으며 세 관측유역을 포함한 총 50개 유역의 유출자료를 연구에 사용하였다. 그리고 총 50개 유역의 평균강우량 시계열 자료를 생성하고 이동평균방법을 사용하여 이 평균강우량 자료를 강우강도-지속시간 곡선으로 변환하였다. 강우패턴과 유출반응간의 관계를 분석하기 위해 합리식의 유출계수와 강우강도비율을 사용하였으며 유출계수와 강우강도비율을 계산하기 위해 유역별 도달시간을 사용하였다. 여기서 강우강도비율은 강우강도지속시간 곡선을 사용하여 첨두강우강도를 도달시간에 해당하는 평균강우강도로 나눠준 값이다. 그리고 이 유출계수와 강우강도비율을 유역면적에 대해 도시함으로써 그 경향을 조사하였다. 그 결과 20개 사상은 유출계수, 강우강도비율과 유역면적을 사용하여 물리적으로 타당한 네 가지의 타입으로 분류될 수 있었다. 이 네 가지 타입은 강우의 이동 및 분포와 상관이 있었는데 첫번째 타입은 안동댐 유역전체에 강우가 거의 등분포하는 경우, 두 번째는 강우가 유역의 상류방향으로 이동하는 경우, 세 번째는 강우가 유역의 하류방향으로 이동하는 경우, 그리고 네 번째는 강우가 유역에 무작위로 분포하는 경우였다. 이것은 어떠한 사상에 대해서도 유출계수와 강우강도비율을 유역면적에 대해 도시함으로써 강우패턴과 유출간의 관계를 분석할 수 있다는 것을 나타낸다. 그리고 이 네 가지 타입에 대한 강우사상들의 비율은 각각 65%, 20%, 10%, 그리고 5% 였다. 이 타입별 강우사상의 비율은 향후 강우-유출관계에 의한 수자원 예측 및 확보에 활용될 수 있다.

• Korean Chemical Engineering Research
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• v.44 no.6
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• pp.636-643
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• 2006

Supercritical water oxidation of DMMP using continuous flow reactor was studied at temperature ranging from 440 to $540^{\circ}C$ and a fixed pressure of 242 bar. The range of residence times in the reactor was from 10 to 26 s, and oxygen excess value varied from -40 to 200%. Destruction efficiencies (DE) of DMMP were greater than 99.7% at $540^{\circ}C$, and increased as the DMMP concentrations were increased. DE of DMMP were significantly affected by oxygen concentration under stoichiometric amount, but showed little difference over stoichiometric amount. On the basis of 30 data with conversions greater than 85%, kinetic correlations for the DE of DMMP were developed. The pre-exponential factor was $(1.10{\pm}0.76){\times}10^6$, and the activation energy was $90.66{\pm}3.87kJ/mol$, and the reaction orders for DMMP and oxygen were $1.02{\pm}0.03$, $0.32{\pm}0.03$, respectively. The model predictions agreed well with the experimental data.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2002.05a
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• pp.2-2
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• 2002

Quartz Crystal Microbalance(QCM)은 표면에 묻은 물질의 미량의 무게변화도 간단히 측정 할 수 있어 반웅기 내에서 일어나는 현상올 in-situ로 즉시 알 수 있는 장점을 가진 장치이 다. 이 장치를 이용하면 초엄계 이산화탄소 내에서 용해도를 알 수 있고, 대상물질이 녹아냐 가는 속도를 측정하면 확산계수를 구할 수 있다. 그리고, 초음파 혼을 반응용기 내에 설치하 고, 초음파 효과를 알아보았다. 먼저 static system에서 초음파 효과를 알아보았다. Cu(acac)2를 대상으로, 밀폐된 용기에서 수행한 실험에서, 액체와 초임계 이산화탄소 내에서 용해속도를 QCM으로 구할 수 있었다. 용해속도로부터 Cu(acac)2의 확산계수를 측정할 수 있었다. 액체 내에선 $10^{-4}{\;}cm2/sec$, 초임계상태에서 $10^{-2}{\;}cm2/sec$의 값을 갖는 것으로 나타 났다. 그리고, 초음파를 사용할 경우 이 확산계수값이 4-5배정도 증가하는 것으로 냐타났다. 이어서 dynamic system에서 반응을 알아보았다. Cyanex를 함유한 C02를 반응용기에 흘리 면서 QCM표면에 묻은 Co이온의 용해속도를 측정하였다. 초음파는 용해도에 아무 역활을 안하는 것으로 나타났다. 주어진 조건에서 13 microgram/gram-cyanex의 용해도를 갖는 것 으로 나타났다.