• Title/Summary/Keyword: 밀폐용기

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Simultaneous Determination of UV Absorbers Migrated from Polyethylene and Polypropylene Food Packaging Materials into Food Simulants by HPLC-UVD (HPLC-UVD를 이용한 폴리에틸렌, 폴리프로필렌 기구 및 용기·포장 유래 자외선흡수제 동시분석법)

  • Choi, Heeju;Choi, Jae Chun;Bae, In-Ae;Lee, Chanyong;Park, Se-Jong;Kim, MeeKyung
    • Journal of Food Hygiene and Safety
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    • v.32 no.5
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    • pp.434-442
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    • 2017
  • The UV light in sunlight breaks down the chemical bonds in a polyolefin polymer through a process called photodegradation, ultimately causing cracking, chalking, colour changes, and loss of physical properties such as impact strength, tensile strength, elongation, and others. UV absorbers are used to prevent or terminate the oxidation of plastics by UV light. They are receptive to UV radiation and dissipate the energy harmlessly as heat. Benzotriazoles and benzophenones are used mainly in polyolefins such as polyethylene and polypropylene. In this study, we have developed a method for the analysis of 12 UV absorbers, which are Uvinul 3000, Cyasorb UV 24, Uvinul 3040, Tinuvin 312 and P, Seesorb 202, Chimassorb 81, Tinuvin 329, 234, 326, 328 and 327, migrated from the food packaging materials into four food simulants for aqueous, acidic, alcoholic and fatty foods. The UV absorbers in food simulants were determined by reversed-phase high performance liquid chromatograph-ultraviolet detector with 310 nm after solid-phase extraction with a hydrophilic-lipophilic balance (HLB) cartridge or dilution with isopropanol. The analytical method showed a good linearity of coefficient ($R^2{\geq}0.99$), limits of detection (0.049~0.370 mg/L), and limits of quantification (0.149~1.120 mg/L). The recoveries of UV absorbers spiked to four food simulants ranged from 70.05% to 110.13%. The developed method would be used as a reliable tool to determine concentrations of the migrated UV absorbers.

Effect of UV-LED Irradiation on Respiration and Ethylene Production of Cherry Tomatoes (방울토마토의 호흡 및 에틸렌 발생에 미치는 자외선 LED의 효과)

  • Kim, Nam-Yong;Lee, Dong-Sun;Lee, Hyuk-Jae;An, Duck-Soon
    • Food Science and Preservation
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    • v.19 no.1
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    • pp.47-53
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    • 2012
  • UV light irradiation is known to give beneficial effects on fresh produce preservation. A container system equipped with UV-LED was fabricated for storing cherry tomatoes under computer-controlled conditions of intermittent on-off cycles (1 hour on/1 hour off). Wavelength (365 and 405 nm) and physical location of the LED (2 and 5 cm above fruit) were studied as variables affecting the respiration, ethylene production and quality preservation of the fruits at 10 and $20^{\circ}C$. 365 nm wavelength gave much higher radiation intensity than 405 nm, and intensity on surface decreased in inverse proportion to square of distance from LED. When compared to non-irradiated control, UV-LED irradiation decreased the respiration by 5-10% at $10^{\circ}C$ while there was no obvious effect at $20^{\circ}C$. Ethylene production was reduced when the fruits were placed at 5 cm distance, while there was no significant difference from control at 2 cm location. The reduction of ethylene production at 5 cm was more pronounced at $20^{\circ}C$. UV-LED irradiation was shown to have delayed increase or lower concentration in carotenoids compared to control treatment. Any negative effect of UV-LED irradiation on ascorbic acid content and firmness was not observed.

Self-Decomposition Characteristic of Concentrated Hydrogen Peroxide with Temperature and Stabilizer (저장 온도와 안정제 양에 따른 고농도 과산화수소의 자연 분해 특성)

  • Chung, Seung-Mi;An, Sung-Yong;Kwon, Se-Jin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.13 no.4
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    • pp.16-21
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    • 2009
  • This paper introduces the methods of hydrogen peroxide storage test and storability of concentrated hydrogen peroxide is estimated. Using the method of simple concentration measuring, storability was evaluated. Experiment variables were the amount of stabilizer in hydrogen peroxide, storage temperature, and caps of vessels. The experiments were performed during 8 months to 24 months. High purity hydrogen peroxide had much better storability than hydrogen peroxide with much stabilizer. In addition, the case using paraffin film which did not react with hydrogen peroxide for covering showed better storability. The temperature is very important variable in hydrogen peroxide storage. So, when hydrogen peroxide was under $10^{\circ}C$ storability of hydrogen peroxide is much improved.

An Experimental Study on melting phenomena of PCM affected by Ultrasonic Vibration in a square cavity (밀폐용기내에서 초음파 진도에 따른 상변화물질의 용융현상 연구)

  • Youn, Joung-Hwan;Joung, Dae-Hun;Oh, Yool-Kwon
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.246-251
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    • 2001
  • Solid-liquid phase change (i.e. melting or solidification) occurs in a number of situations of practical interest. Some common examples include the melting of edible oil, metallurgical process such as casting and welding, and materials science applications such as crystal growth. Therefore, due to the practical importance of the subject, there have been a large number of experimental and numerical studies of problems involving phase change during the past few decades. Also, this study presented the effective way to enhance phase change heat transfer.

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Numerical Study of Double Diffusive Convection of a Stratified Fluid in an Annulus Due to Lateral Heating (환형밀폐용기내 성층화된 유체의 옆면가열에 의한 이중확산대류에 관한 수치해석)

  • 강신형;전창덕;이진호
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.7
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    • pp.1720-1730
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    • 1995
  • Finite-difference analysis was conducted to study the natural convection of a stably stratified salt-water solution in an annulus due to lateral heating. The main purpose of this study is to examine in detail the multi-layered flow structure. Calculation was thus made for R $a_{\eta}$=2*10$^{5}$ and 6.5*10$^{5}$ . Formation of layered flow structure, merging process of layers, the corresponding temperature and concentration distributions, Nusselt number variations with time are examined. Numerical results show that in each layer, the temperature profile looks 'S`-shaped and the concentration profile is uniform due to the convective mixing. The formation of the roll and the layer is governed by natural convection due to the temperature gradient and the merging process of the layer by diffusion of the concentration.ation.

Enhancement of Mass Transfer of an Enclosed Fluid by Time-periodic Thermal Forcing (간헐 열전달을 이용한 밀폐용기내의 물질전달 향상)

  • Kwak H. S.
    • Journal of computational fluids engineering
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    • v.7 no.1
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    • pp.36-43
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    • 2002
  • A numerical investigation is made of unsteady double-diffusive convection of a Boussinesq fluid in a rectangular cavity subject to time-periodic thermal excitations. The fluid is initially stratified between the top endwall of low solute concentration and the bottom endwall of high solute concentration. A time-dependent heat flux varying in a square wave fashion, is applied on one sidewall to induce buoyant convection. The influences of the imposed periodicity on double-diffusive convection are examined. A special concern is on the occurrence of resonance that the fluctuations of flow and attendant heat and mass transfers are mostly amplified at certain eigenmodes of the fluid system. Numerical solutions illustrate that resonant convection results in a conspicuous enhancement of time-mean mass transfer rate.

A Case Study on the Boring-Hole Blasting for Offering of the Ground Vibration Source (지진동 Source 제공을 위한 심부 시추공발파 기술사례)

  • 조영곤;김희도;조준호
    • Tunnel and Underground Space
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    • v.13 no.3
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    • pp.187-195
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    • 2003
  • This case study which is to make 2-Dimension earth's crust structures clearly is about the great boring-hole blasting to provide ground vibration source of the reflected wave research on the Korean Peninsula earth's crust structures research. For this study we've done blasting twice-500 ㎏/charge per delay, 1,000 ㎏/charge per delay, and the specifications of blasting are the following - dia.: 300 ㎜, boring-depth : 100m, besides, we used the explosives and electric detonators which have sufficient detonating velocity and very excellent safety, capacity of detonating, accurate delay time. We charged explosives into steel pipe with bulk type to avoid dead pressure by ground water. And then we tested about pipe airtight and blasting to certificate which has no problem by using on this study. In the results, we succeeded each blasting in Seosan, Youngdong. For the Peak Sum Vector(PSV) around the blasting at the main points, its real measured PSV is higher 180 % than estimated PSV with USBM. In this study we can't to be analysis of vibration velocity, but to be key providing vibration source.

Effects of Pot Soil and humidity on Growth for Transparent Cup Cultivation of Climacium japonicum Lindb (나무이끼의 투명컵 재배시 용토 및 습도가 생육에 미치는 영향)

  • Suh, Jong-Taek;Ryu, Seung-Yeol;Yoo, Dong-Lim;Nam, Chun-Woo;Hur, Youn-Young
    • Korean Journal of Plant Resources
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    • v.23 no.4
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    • pp.379-385
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    • 2010
  • This study was carried out to develop cultivation techniques of Climacium japonicum in transparent pot. We analyzed effect of different soil moisture content, air exposure degree, bed soil and ground cover moss on the growth of Climacium japonicum. The best humidity condition in transparent pot culture was 60~80% and a mixture of bed soil with peatmoss : perlite as 7:3 ratio was effective to growth. Two holes(each diameter is 4 mm) in the cover were also effective to the growth and control moisture in the transparent pot. The best mixture of bed soil was moss with peatmoss : pelite(7:3) in the pot culture but price of moss is expensive, the moss treatment was not practical. Total of 10 moss species were selected as ground cover plant; Hypnum erectiusculum Sull. et Lesq., Thuidium kanedae Sak., Hypnum plumaeforme Wils., Trachycystis microphylla Lindb., Bryum argenteum Hedw., Hypnum oldhamii Jaeg., Funaria hygrometrica Hedw., Leucobryum glaucum Aongstr., Polytrichum commune Hedw. and Weissia controversa Hedw. The plant height of selected moss was smaller than that of Climacium japonicum so these moss were very effective to cover the ground.

Preparations and Antistatic/UV Blocking Properties of Dual Functional Phthalocyanine Materials (기능성 프탈로시아닌 물질의 제조 및 대전방지/UV 차단 특성)

  • Kang, Young-Goo;Ihm, Dae-Woo;Kim, Shi-Surk;Park, Byoung-Ki
    • Journal of the Korean Society of Safety
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    • v.23 no.1
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    • pp.66-71
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    • 2008
  • A new route to phthalocyanine complexes were developed to synthesize these products by fusion in the absence of solvent. This new method of synthesis without using solvent has advantages over the conventional synthetic methods since there are no risk of explosion and formation of harmful vapor from organic solvent. Reaction of PcFe with axial ligands such as $PcFe(4-VP)_2$[Pc: Phthalocyanine, 4-VP: 4-Vinylpyridine] and $PcFe(VIM)_2$[VIM: 1-Vinylimidazole] afforded powderlike, pure dark greenish blue colored products. The resulted products are soluble in $CH_2Cl_2$ and found to be complexes of the type $PcFeL_2$. Spectral properties were studied with ATR-FTIR and UV/Vis. Thermal and electrical characterization was also performed. Phthalocyanine complexes exhibit useful properties such as UV/Vis blocking, antistatic characteristics and excellent thermal stability and we anticipate various applicability in numerous products.

High prandtl number natural convection in a low-aspect ratio rectangular enclosure (종횡비 가 낮은 직각밀폐용기내 의 Prandtl 수 가 큰 유체 의 자연대류 에 관한 실험적 연구)

  • 이진호;황규석;현명택
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.9 no.6
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    • pp.750-756
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    • 1985
  • Experimental investigation was carried out to study the natural convection of water and silicon oil due to end temperature differences in a horizontally insulated rectangular enclosure of aspect ratio 0.1 with a special attention on the core configuration in the laminar boundary-layer flow regime. Rayleigh number ranges covered herein are Ra=4.40 * 10$^{6}$ -9.64 * 10$^{7}$ for water and Ra=1.69*10$^{5}$ -3.80*10$^{6}$ for silicon oil, respectively. In the case of water, for Ra.geq.2.21 * 10$^{7}$ there appeared distinct horizontal thermal layers adjacent to the horizontal boundaries in the core and the temperature distribution outside the horizontal thermal layers, i.e., in the mid-core region, is vertically stratified. The core flow pattern was shown to be nonparallel with a weak back flow in the mid-core for Ra.geq.3.63 *10$^{7}$ . In the case of silicon oil, distinct horizontal thermal layers appeared along the core horizontal boundaries for Ra.geq.1.27 * 10$^{6}$ with a stratified temperature distribution in the mid-core, but the core flow pattern in this case was shown to be parallel. In addition, secondary flow appeared near the hot wall for Ra.geq.3.80 * 10$^{6}$ . Nusselt number, Nu, was found to be proportional to R $a^{0.3}$ for water and R $a^{0.28}$ for silicon oil in the boundary-layer flow regime. There also in an indication from the comparison with other results that Nu is independent of aspect ratio for water in the boundary-layer flow regime in low aspect ratio enclosures.res.