• Journal of Korean Society of Environmental Engineers
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• v.22 no.10
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• pp.1833-1841
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• 2000

Microelectrode probe was made and applied to the biofilm in the biological treatment process as the state-of-art technology in order to actually measure the biofilm thickness, ionic concentration gradient, and material transport, etc. instead of classical theoretical approach. The working microelectrode, one of the main components of microelectrode probe, was easily contaminated and broken when determining the differences in the ionic concentrations through the measurement of biofilm's EMF (electromotive force). As a demonstration, two microelectrode probes were constructed in our lab for the measurement of the pH and $NO_3{^-}$ concentration in denitrifying biofilm. The microelectrode probe through the inner biofilm ($350{\mu}m$ from the surface of biofilm) showed that the pH was increased from pH 8 in the bulk solution to pH 8.3, on the other hand, the $NO_3{^-}$ concentration was decreased from 30 fig N/L in the bulk solution to 4 fig N/L.