• The Journal of Engineering Geology
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• v.32 no.4
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• pp.661-670
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• 2022

In recent years, extreme rainfall and rainy seasons caused by climate change have caused river flooding and flooding damage, and it is urgent to solve economic and environmental problems in the city center due to the increase in the number of peak homes. The gap block, called the fitting block, is designed to facilitate rainwater pitching by forming a gap between the block and the block by forming a concave part and a protrusion of the block differently without the use of an existing spacer. In this study, for the production of such a gap block, the existing cement content was reduced and aramid fibers and exploration fibers, which are industrial by-products such as Goroslag fine powder and reinforcing fibers, were applied.

• Journal of the Mineralogical Society of Korea
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• v.28 no.1
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• pp.39-49
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• 2015

Recently, carbon capture and storage (CCS) techniques have been globally studied. This study was conducted to use waste cement powder as an efficient raw material of mineral carbonation for $CO_2$ sequestration. Direct aqueous carbonation experiment was conducted with injecting pure $CO_2$ gas (99.9%) to a reactor containing $200m{\ell}$ reacting solution and the pulverized cement paste (W:C = 6:4) having particle size less than 0.15 mm. The effects of two additives (NaCl, $MgCl_2$) in carbonation were analyzed. The characteristics of carbonate minerals and carbonation process according to the type of additives and pH change were carefully evaluated. pH of reacting solution was gradually decreased with injecting $CO_2$ gas. $Ca^{2+}$ ion concentration in $MgCl_2$ containing solution was continuously decreased. In none $MgCl_2$ solution, however, $Ca^{2+}$ ion concentration was increased again as pH decreased. This is probably due to the dissolution of newly formed carbonate mineral in low pH solution. XRD analysis indicates that calcite is dominant carbonate mineral in none $MgCl_2$ solution whereas aragonite is dominant in $MgCl_2$ containing solution. Unstable vaterite formed in early stage of experiment was transformed to well crystallized calcite with decreasing pH in the absence of $MgCl_2$ additives. In the presence of $MgCl_2$ additives, the content of aragonite was increased with decreasing pH whereas the content of calite was decreased.

• Applied Chemistry for Engineering
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• v.28 no.1
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• pp.101-111
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• 2017

Mineral carbonation is a technology in which carbonates are synthesized from minerals including serpentine and olivine, and industrial wastes such as slag and cement, of which all contain calcium or magnesium when reacted with carbon dioxide. This study aims to develop the mineral carbonation technology for commercialization, which can reduce environmental burden and process cost through the reduction of carbon dioxide using steel slag and the slag reuse after calcium extraction. Calcium extraction was conducted using NH4Cl solution for air-cooled slag and convert slag, and ${\geq}98%$ purity calcium carbonate was synthesized by reaction with calcium-extracted solution and carbon dioxide. And we conducted experimentally to minimize the quantity of by-product, the slag residue after calcium extraction, which has occupied large amount of weight ratio (about 80-90%) at the point of mineral carbonation process using slag. The slag residue was used to replace silica sand in the manufacture of cement panel, and physical properties including compressive strength and flexible strength of panel using the slag residue and normal cement panel, respectively, were analyzed. The calcium concentration in extraction solution was analyzed by inductively coupled plasma optical emission spectrometer (ICP-OES). Field-emission scanning electron microscope (FE-SEM) was also used to identify the surface morphology of calcium carbonate, and XRD was used to analyze the crystallinity and the quantitative analysis of calcium carbonate. In addition, the cement panel evaluation was carried out according to KS L ISO 679, and the compressive strength and flexural strength of the panels were measured.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.29 no.6
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• pp.315-325
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• 2017

This study aims to provide information for the design and use of structural lightweight concrete (SLWC) for floating concrete structures in a marine environment. An experimental program was set up and comprehensive experimental campaign were carried out to determine SLWC mix proportions that can satisfy specified concrete strength, density, and slump values all of them were determined from previous research. Comparisons with previous SLWC mix designs that have been utilized for actual floating concrete structures were made. Key aspects needed to be considered regarding to the use of SLWC for floating marine concrete structures were discussed.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.641-644
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• 2008

This paper investigated the plant and raw material of the ready-mixed concrete company which could supply to the second Lotte World on Pusan. the results were summarized as following. Almost plants were mainly using Twin shaft mixer which was 210m$^3$/hr and horizontal type. There was different the number of admixture silos at each plants, and they were separated by types. The mixtures mainly consisted of the ordinary portland cement, fly ash and blast furnace slag. For favorable quality control, each materials had to carry from same factories, and the monitering standard for quality control should be prepared. The coarse aggregates were used with many different producing districts, so they were only used from Y caused by exclusion of quality difference. The crushed, washed and river sands were generally used as fine aggregates, so the fine aggregates which could be possible to supply stable quality were chosen. This study used Poly Carbonic Acid Admixture which was developed to satisfy maintenance of performance till 2 hours and 10MPa at 15 hours.

• Journal of the Korea Concrete Institute
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• v.28 no.1
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• pp.59-65
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• 2016

Commercial synthetic resins with great amount of hydrogen atoms were investigated for neutron shielding aggregates. Total three types of resins were considered in this study: high density polyethylene (HDPE), polypropylene (PP), and ultra molecular weight polyethylene (UPE). When these resins replaced 20, 40, 60 vol% of fine aggregates, mechanical properties were first evaluated including compressive and tensile strengths, and then image/microstructure analyses such as cross-section analysis, SEM, and X-ray CT were performed. The results showed that the compressive and tensile strengths decreased with the increase of replacement ratio of HDPE and PP, which was found through image analysis that it was closely related to the distribution of resins at the failure surface of test specimens. The strength reduction of UPE was quite small compared to HDPE and PP but it abruptly increased when the replacement level exceeded 60 vol%. The results of microstructure analyses indicated that the replacement level significantly affected the amount of air void so that it is critical to determine the reasonable amount of UPE to make cementitous materials for neutron shielding.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.375-381
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• 2017

Recently, due to the increasing of interest about the eco-friendly concrete, it is being increased to use concretes containing by-products of industry such as fly ash, ground granulated blast furnace slag, silica fume, and etc. Especially, these are well known for improving the resistance to reinforcement corrosion in concrete and decreasing chloride ion penetration. The purpose of this experimental research is to evaluate the resistance to corrosion of reinforcement and critical chloride content of high volume fly ash concrete(HVFAC) which is replaced with fly ash for approximately 50% cement content. For this purpose, corrosion monitoring of reinforcement by half cell potential method was carried out for the cylindrical test specimens that the upper of reinforcement in concrete was exposed to detect the time of corrosion initiation for reinforcement. It was observed from the test result that the the time of corrosion initiation for reinforcement of HVFAC by the accelerated corrosion tests increased 1.2~1.3 times than plain concrete and the critical chloride contents of plain concrete and HVFAC were found to range $0.80{\sim}1.20kg/m^3$, $0.89{\sim}1.60kg/m^3$, respectively.

• Magazine of the Korea Concrete Institute
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• v.11 no.1
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• pp.183-190
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• 1999

This paper investigated the possibility of appling to concrete through fundamental experiment for garnet, which was industrial wastes generated in kyung pook region, in aspects of development of new materials and recycling of industrial wastes due to shortage of natural resources. Consequently, garnet powder showed the possibility of admixture as showed in the chemical composition because the content of silica and alumina in relation to pozzolanic activity was about 50%. The time of setting was more or less diminished as the increasing of replacement ratio of garnet. In flow test, flow values tended to increase to some degree as the increasing of replacement ratio of garnet. Therefore, application of garnet was expected to improve the workability of concrete. The compressive strength of mortar replaced by garnet was respectively increased as compared with plain mortar and the maximum strength was showed in replaced by 10%, however a little different to the change of W/B ratio. Also, the possibility of admixture to reduce the amount of cement and to improve the property of concrete was showed as the strength of mortar replaced by garnet was comparable to that by existing admixture(silica fume, fly-ash).

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.2
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• pp.63-69
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• 2012

Recently, the cement industries brought very severe environment problems such as resource depletion and global warming with massive carbon dioxide during its production. The number of cases using industrial by-products such as the ground granulated blast furnace slag (GGBFS) in concrete mixtures is increasing to resolve the environmental issue. GGBFS is mainly used in the range between 20 to 50% to replace cement, but nowadays lots of researches are carried out to develop the alkali-activated slag (AAS) concrete with no cement. In this study, the early age properties of alkali activated slag (AAS) mortar are investigated to obtain the fundamental data for AAS concrete application to structural members. The experimental variables were the water-binder ratios of 0.3, 0.4, and 0.5 and NaOH as the alkali activator of 4%, 8%, and 12% by the mass of GGBFS, and compressive strength, flow, setting time, and ultrasonic pulse velocity of AAS mortars were measured and analyzed. It is found from the test results that as the normal concrete the lower W/B, the higher compressive strength. However, superplasticizer has to be used for producing high strength AAS concrete because the workability of AAS mortar are significantly lowered.

• Journal of the Korea Concrete Institute
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• v.21 no.5
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• pp.573-580
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• 2009

This paper presents the mix composition, production method, and curing condition applied to the extruded ECC(Engineered Cementitious Composite) panel which are able to exhibit multiple cracking and potential pseudo strain-hardening behavior. In addition to the production technique of extruded ECC panel, the effect of fiber distribution characteristics, which are uniquely created by applying extrusion process, on the flexural behavior of the panel is also focussed. In order to demonstrate fiber distribution, a series of experiments and analyses, including image processing/analysis and micro-mechanical analysis, was performed. The optimum mix composition of extruded ECC panel was determined in terms of water matrix ratio, the amount of cement, ECC powder, and silica powder. It was found that flexural behavior of extruded ECC panel was highly affected by the slight difference in mix composition of ECC panel. This is mainly because the difference in mix composition results in the change of micro-mechanical properties as well as fiber distribution characteristics, represented by fiber dispersion and orientation. In terms of the average fiber orientation, the fiber distribution was found to be similar to the assumption of two dimensional random distribution, irrespective of mix composition. In contrast, the probability density function for fiber orientation was measured to be quite different depending on the mix composition.