• Title/Summary/Keyword: 미량금속

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득량만 표층퇴적물내 미량금속원소의 지리적 분포특성

  • 김성수;이재성;김귀영;정래홍;고태승
    • Proceedings of the Korean Society of Fisheries Technology Conference
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    • 2002.10a
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    • pp.152-153
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    • 2002
  • 남해안의 서쪽에 위치한 득량만은 면적이 374$\textrm{km}^2$로 비교적 넓으며, 평균 수심이 약 7.5m(최고수심 40m)로서 남북방향 장축의 길이가 약 50km, 동서방향 폭이 4.6~11.0km이다. 만 남쪽에는 금당도, 거금도, 소록도 등의 섬들 사이의 3개 수로에 의해 해수교환이 이루어지고 있어 남해안의 다른 만에 비해 외해와의 해수교환이 비교적 원활한 편이다. (중략)

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Effect of Asian Dust for Airborne Trace Elements at Roadside (도로변 대기입자중 미량원소의 황사영향 평가)

  • 임종명;이현석;장미숙;이진홍
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.11a
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    • pp.197-198
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    • 2002
  • 황사는 장거리를 이동해 한반도 둥에 영향을 미치는데, 호흡기 질환, 눈 질환, 알레르기 등 각종 질환을 유발하고, 최근에는 중국의 산업화에 따라 납, 카드뮴 같은 독성금속과 발암물질 둥 유해 오염물질까지 포함하고 있어 건강에 위협을 주고 있다. 나아가 황사에 포함된 미세 입자들이 대기 중에서 화학반응을 일으켜 각종 산화물을 생성하는 까닭에 만성기관지염을 악화시키고, 노인과 영아의 호흡기 질환을 유발하기도 한다 그밖에 황사는 햇빛을 차단해 시정거리를 감소시키고 항공기 운항에도 영향을 미친다. (중략)

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Studies on the Micro-determination of Metals by Spetrophotometry (II) Micro-determination of pb by Dithizone Method (Spectrophotometer에 의한 금속의 최상정량법에 관한 연구 (제 2 보) Dithizone에 의한 Pb의 미량정량법)

  • 노일협
    • YAKHAK HOEJI
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    • v.5 no.1
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    • pp.24-26
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    • 1960
  • Micro-determination of Lead by Dithizone Method was studied as follows: 1) Max. absorption wave length of Dithizone-pb complex in CC $l_{4}$ soln. is 510m.mu., 2) at the range of 5.gamma.-120.gamma. pb content, Bourguer-Beer's law hold good, 3) co-existence of F $e^{++}$ Z $n^{++}$, and C $u^{++}$ interfere.rfere.

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Effect of Silver Nano-particle Concentration on the Optical and Electrical Characteristics of Organic-based Nano-composite Electrodes (금속 나노입자 함량에 따른 유기나노복합체의 광학 및 전기전도성 특성변화)

  • Kim, Y.H.;Park, S.K.;Han, J.I.
    • Proceedings of the KIEE Conference
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    • 2008.10a
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    • pp.125-126
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    • 2008
  • 본 연구에서는 금속 나노입자 함량에 따른 유기나노복합체에서의 광학 및 전기전도도 특성변화를 분석하였다. 유기나노복합체 전극은 전기전도성을 가리고 있는 PEDOT : PSS(poly(3,4-ethylenedioxythio- phone):poly(styrenesulfonate))나노 입자를 기반으로 하며 이 복합제에 미량의 Ag nano-particle을 첨가하여 전기전도도 특성을 향상시키는 연구를 진행하였다. Ag nano-particle은 전체 중량 대비 01 - 0.4%의 범위에서 첨가하였으며 실험결과 0.1%의 첨가 비율에서 약 5% 정도의 전기전도도 특성 향상이 확인되었다. 또한 광투과도 변화를 분석해본 결과 0.4%까지의 Ag nano-particle 첨가 비율에서는 광투과도의 비율이 크게 감소되지 않는 것으로 파악되었다.

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Recent Research Trend in Oxide Semiconductor Gas Sensors for Indoor Air Quality Monitoring (산화물 반도체를 이용한 실내 공기질 가스 센서 연구동향)

  • Lee, Kun Ho;Lee, Jong-Heun
    • Prospectives of Industrial Chemistry
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    • v.23 no.3
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    • pp.32-41
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    • 2020
  • 사람들은 대부분의 시간을 실내에서 보내고 있으며, 실내에 존재하는 유해가스는 미량의 농도에도 불구하고 심각한 질환을 일으킬 수 있다. 금속산화물 반도체 가스센서는 감도가 우수하고, 구조가 간단하며, 초소형화가 가능한 장점이 있어 고가의 대형 장비를 사용하지 않고 실내 유해가스를 측정하는 데 효과적으로 이용될 수 있다. 본 기고문에서는 금속산화물 반도체를 이용한 가스 센서의 검지 원리를 고찰하고, 나노 구조 조절, 마이크로 리액터 및 이중층 구조를 이용한 가스 개질 등 실내 유해가스 측정을 위한 다양한 센서 설계방법을 소개하고자 한다.

Determination of Mn, Co, Ni and Cu in Iron Oxide Ore by Atomic Absorption spectroscopy. Utilization of APDC-MIBK Extraction System (원자흡수 분광법에 의한 철광석중의 Mn, Co, Ni 및 Cu 의 정량. APDC-MIBK 추출계의 이용)

  • Misun Park;Youn-Doo Kim;Kwanghee Koh Park
    • Journal of the Korean Chemical Society
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    • v.33 no.3
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    • pp.315-320
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    • 1989
  • A method was presented for the analysis of trace metals in iron oxide ore. The method utilized ammonium pyrrolidinedithiocarbamate (APDC)-methyl isobutyl ketone (MIBK) extraction procedure and analysis by atomic absorption spectroscopy (AA). Citrate at pH $8{\sim}10$ for the determination of Co, Ni and Cu or tiron at pH $6{\sim}7$for the determination of Mn and Cu was added as a masking agent to prevent extraction of Fe(III) into the organic phase. Reduction of solubility of MIBK in water was achieved by addition of NaCl as a salting-out agent. Back extraction of the MIBK extracts with aqueous $HNO_3$ was also studied to increase the stability of metal extracts.

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Technology for the Recovery of Os and Ru from Primary/Secondary Resources (1차(次)/2차(次) 자원(資源)으로부터 Os과 Ru 회수기술(回收技術))

  • Sun, Pan-Pan;Lee, Man-Seung
    • Resources Recycling
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    • v.21 no.6
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    • pp.3-11
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    • 2012
  • Some methods used for the recovery of osmium and ruthenium from primary/secondary sources are reviewed. Both Ru and Os could form volatile oxides which enable their separation from the other PGMs by distillation as a traditional method. In hydrochloric acid solution, they also form chloro-complexes with different valence states. Amines or amine based mixture have been used to extract Ru. Solvating extractants are employed to separate Ru and Os. The detailed extraction and stripping conditions of several solvent extraction processes have been reviewed. As an alternative to solvent extraction, solid-liquid method can be applied to recover trace amount of these metals.

Environmental Characteristics of Seawater and Sediment in Mariculture Management Area in Ongjin-gun, Korea (옹진군 어장관리해역의 수질 및 퇴적물 환경 특성)

  • Kim, Sun-Young;Kim, Hyung-Chul;Lee, Won-Chan;Hwang, Dong-Woon;Hong, Sok-Jin;Kim, Jeong-Bae;Cho, Yoon-Sik;Kim, Chung-Sook
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.19 no.6
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    • pp.570-581
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    • 2013
  • To improve productivity of aquaculture animals with management of culturing grounds, survey of mariculture management area in Ongjin-gun about water quality and sedimentary environment had been conducted on June, August and November in 2011. Water temperature in surface and bottom waters ranged from 9.49 to $24.14^{\circ}C$. Salinity and dissolved oxygen concentrations were in the range of 23.19~31.49 and 5.48~9.36 mg/L, respectively, depending on the variation of water temperature. The average concentration of COD was 1.57 mg/L and the concentrations of DIN and DIP showed entirely low level. As the result of grain size analysis, sand(56.66 %) and silt(34.60 %) were predominated. The Mz of sediment showed a variation of 2.59 to $6.62{\O}$ and sorting appeared to be poorly sorted. The concentrations of COD and IL in surface sediment ranged from 1.00 to $11.03mg/g{\cdot}dry$ and 0.72 to 5.29 %, respectively, which showed relatively good positive correlations. On the environmental assessment of trace metals in surface sediment, geoaccumulation index ($I_{geo}$) class indicated that sediments were not contaminated by most of metallic elements except Cr and As. Our result implies that this study area showed good water quality and sediments were not polluted by organic matters and metallic elements.

Trace Metal Contents and Safety Evaluation of Major Edible Seaweeds from Korean Coast (한국산 주요 식용해조류의 미량금속 함량 및 안전성 평가)

  • Mok, Jong-Soo;Park, Hee-Yeon;Kim, Ji-Hoe
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.9
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    • pp.1464-1470
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    • 2005
  • To assure the safety of the major edible seaweeds, we collected the 176 samples of seaweeds such as laver(Porphyra sp.), sea mustard (Undaria pinnatifida), sea tangle (Laminaria japonica) and sea lettuce (Enter-omorph sp.) from Korean coast. We investigated the contents of the trace metals in the edible seaweeds, and the values were expressed as the dry weight of sea weeds. The mean levels of the trace metals were high in the oder of Zn ($36.19{\pm}27.14 \;{\mu}g/g$), Mn ($28.75{\pm}28.03\;{\mu}g/g$), and Cu ($6.82{\pm}7.62\;{\mu}g/g$), which are necessary metals in the human body, and then followed by Cr ($1.54{\pm}2.07\;{\mu}g/g$), Ni ($1.29{\pm}2.57\;{\mu}g/g$), Pb ($0.89{\pm}1.11\;{\mu}g/g$), Cd ($0.72{\pm}0.80\;{\mu}g/g$) and Hg ($0.01{\pm}0.02\;{\mu}g/g$). The contents of Cd and Zn were high in the laver, Cr, Ni and Pb were detected highly in sea lettuce, and Hg was detected highly in sea tangle. Significant linear correlations were obtained among 28 different pairs of metals, some of them highly correlated (r>0.5, p<0.05),such as Ni-Mn, Zn-Ni, Cu-Pb and Cu-Zn in laver, Ni-Zn in sea mustard, Cu-Pb, Cu-Zn and Mn-Pb in sea tangle, and Ni-Cr in sea lettuce. And, the trace metal contents of seaweeds varied with parts and kinds of samples. The average weekly intakes of Hg, Cd and Pb from seaweeds were about $0.07{\~}3.57\%$ of PTWI (Provisional Tolerable Weekly Intakes) which has set by FAO/WHO to evaluate the safeties of trace metals in food. Therefore, it was found that they showed very safe levels in the edible seaweeds.

Chemical Speciation of Trace Metals in Airborne Particles at An Industrialized Site (공업지역 대기 중 입자에 함유된 미량금속의 화학종별 분석)

  • Jeong Gi-Ho;Lee Ji-Young;Moon Ji-Yong;Lee Sung-In
    • Journal of Environmental Science International
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    • v.15 no.6
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    • pp.503-511
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    • 2006
  • Airborne particles collected from a heavily industrialized site were analyzed by chemical speciation of seven trace metals: Pb, Cd, Cr, Cu, Ni, Zn, and As. The average concentrations were as follows: $Zn,\;502.0{\pm}230.7;\;Pb,\;176.5{\pm}310.9;\;Cu,\;111.9{\pm}82.7;\;As,\;38.0{\pm}31.0;\;Cr,\;21.5{\pm}24.4;\;Cd,\;20.8{\pm}17.4;\;and\;Ni,\;11.4{\pm}8.4\;ng/m^3$. The median enrichment factor (EF) values of Cd (7,280), As (1,030), Cu (215), Zn (214), and Pb (143), with respect to iron, were much larger than 100. We observed that Cd was found in the soluble and exchange- able form (56.9%), and that Pb and Cr were found in carbonates, oxides and the reducible form (69.8% and 61.1%, respectively). These two forms, which are the most easily absorbed into human body tissue, predominated in most of the trace metals investigated in this study.