• Title/Summary/Keyword: 물투과

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투과증발 분리법에 의한 CMC/PVA blend막의 물/유기용제 혼합액의 분리특성

  • 홍영기;배기서;이정민
    • Proceedings of the Membrane Society of Korea Conference
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    • 1993.10a
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    • pp.52-53
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    • 1993
  • 투과증발 분리를 위하여 여러가지 막 소재와 공정을 개발하기 위한 노력이 다방면에서 이루어지고 있으며, 이에 관한 자료도 많이 제시되고 있으나 고분자 분리막의 개발은 아직도 미흡한 상태이다. 한편 투과증발 분리는 공정자체는 매우 간단하면서도 분리막의 투과성능에 따라 분리효율이 달라지기 때문에 여러종류의 막의 개발이 필요하다. 따라서 본 연구에서는 물/유기용제 혼합액에서 물을 분리하기 위하여 친수성이 강한 두 고분자 재료인 poly(vinyl alcohol)(PVA)와 carboxymehtylcellulose(CMC)를 브랜드하여 목적하는 분리기능을 갖는 새로운 막을 제조하여, 물/유기용제, 혼합액의 분리특성을 브랜드비와 온도 및 농도 그리고 분리시간에 따라 각각 검토하였다.

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Analysis of Ground Penetration Radar Technology Trend (지중탐지 레이더 기술동향 분석)

  • Kim, D.K.
    • Electronics and Telecommunications Trends
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    • v.30 no.5
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    • pp.22-27
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    • 2015
  • 도로함몰 사고 증가를 계기로 지하 구조물의 안전 관리 방법, 특히 비파괴 검사 장비에 대한 관심이 고조되고 있다. 지중투과 레이더 기술은 전자파의 투과, 반사 특성을 이용한 비파괴 검사 기술로써 투과 깊이, 투과 해상도 등 비파괴 검사 성능 측면에서 가장 주목받고 있는 기술이다. 본고에서는 지중투과 레이더 기술의 특징, 국외 제품 동향을 살펴본다.

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A Permeation Behavior for the Pervaporation of Aqueous Ethanol Solution (에탄올 수용액의 Pervaporation에서의 투과거동)

  • Bae, Seong-Youl;Lee, Han-Sun;Hwang, Seong-Min;Kim, Hee-Taik;Kumazawa, Hidehiro
    • Applied Chemistry for Engineering
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    • v.5 no.1
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    • pp.127-138
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    • 1994
  • In the process of pervaporation separation for aqueous ethanol solution through cellulose tai-acetate(CTA) membrane, the modelling on the solution-diffusion permeation mechanism was built up on the basis of sorption and permeation experimental results. Also its function type and parameter were examined. The composition of sorption equilibrium in three component system(Ethanol/Water/CTA) were compared with the calculated value by Flory-Huggins' equation using the pure component sorption data. In order to apply the thermodynamic equilibrium relationship between the membrane free composition in the membrane and the equilibrium composition in the liquid phase, the apparent activity this system, however, the results were not satisfied. Diffusion equations were expressed with the concentration gradient considering permeate alone, and a concentration-dependent diffusion coefficient which includes a parameter was used. And this model was fitted with the measured permeation rates. If the permeation rate and the amount of sorption of one component were much larger than those of the other, the bulk flow term could not be negligible. The flux and selectivity were increased with increasing temperature, and with decreasing downstream pressure.

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Pervaporation Characteristics of NaA Zeolite Membrane for Water/Ethanol Mixture (NaA 제올라이트 분리막의 물/에탄올 투과증발 특성)

  • Ahn, Hyoseong;Lee, Hyeryeon;Lee, Yongtaek
    • Korean Chemical Engineering Research
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    • v.43 no.2
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    • pp.243-248
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    • 2005
  • Membrane pervaporation processes could have advantages over distillation for separation of water/organics mixtures: a low energy demand and the ability to separate azeotropic mixtures or isomers. Zeolite membranes might show better thermal, mechanical and chemical stabilities than polymer membranes. Water could be effectively separated from water/organic mixtures using the NaA zeolite membrane because of its high hydrophilicity. In this study, water was separated by pervaporation using the NaA zeolite membrane from water/ethanol mixtures. As a mole fraction of ethanol increased, the total permeation flux and the water flux decreased while the separation factor increased, reached a maximum point, and decreased. As an experimental temperature increased, the total permeation flux increased while the separation factor increased at the lower mole fraction of ethanol than 0.8 and it decreased at the higher mole fraction of ethanol than 0.8. The total permeation flux and the separation factor could be maintained constant during the long term experiment longer than 160 hours. It was found that the NaA zeolite membrane synthesized in our study showed better performance on water/ethanol separation than that of a distillation process or PVA polymeric pervaporation membranes.

Acoustic Characteristics of Sand Sediment with Circular Cylindrical Pores in Water (수중 원통형 다공성 모래퇴적물의 음향특성)

  • 윤석왕;이용주;노희설
    • The Journal of the Acoustical Society of Korea
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    • v.21 no.2
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    • pp.110-119
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    • 2002
  • Acoustic characteristics of water sediment were experimentally studied in laboratory. Water saturated sand sediment less than the grain size of 0.5 mm diameter is uniformly distributed in an acryl box (100 mm×100mm×42mm) with material thickness 1 mm. Pores in the acryl box are modeled as the structure of cylindrical pore tubes (diameter 3 mm and length 42 mm) filled with water. Cylindrical pore tubes have porosities 0%, 5%, 11%, 18% and 26 % controlled by the tube numbers. Transmitted acoustic waves through sand sediment specimen are analyzed as the functions of porosity and frequency from 0.3 MHz to 4 MHz. Transmitted acoustic waves are mixed with the first-kind wave from whole specimen and the second-kind wane from cylindrical pore tubes. For the center frequency 1 MHz, the first kind wave is dominant but for the center frequency 2.25 MHz, the second kind wave is dominant. In the case of the first-kind wave, as the porosity increases, the transmission coefficient decreases and the sound speed decreases to the sound speed of water. As the frequency increases, the transmission coefficient decreases but the sound speed is almost constant. In the case of the second-kind wave, as the porosity increases, the transmission coefficient increases but the sound speed is almost constant. The transmission coefficient and the sound speed are almost constant as a function of frequency.

Evaluation of Tidal Flow around the Pile-supported Pier Structures (잔교식 항만구조물 주변에서 해수유동의 평가)

  • Park Il Heum
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.7 no.2
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    • pp.82-88
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    • 2004
  • To evaluate the tidal flow around the transmission type harbour structures, the numerical models considering hydraulic resistance are used. The traditional governing equations of depth-integratef hydrodynamics are modified by using of the drag force term. As a numerical model to evaluate the rate of tidal exchange, the Random-walk method is used. The models are applied in a design of the pile-supported pier structures in Busan harbour site, Korea, where the flow speed and the tidal exchange are more promotive than the case of non-transmission structure. The developed model will be applied usefully to design the transmission type structure in the ocean space.

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Low Reflection and High Hardness Coatings for Polymer Windows (고분자 윈도우를 위한 저반사.고경도 박막 코팅)

  • Yang, Ji-Hun;Jeong, Jae-In;Lee, Yeong-Min;Jang, Seung-Hyeon;Park, Yeong-Hui;Heo, Gyu-Yong;Lee, Gyeong-Hwang;Park, Jong-Won
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.10a
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    • pp.113-113
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    • 2009
  • 휴대형 정보기기의 표시창으로 사용되는 투명한 고분자 소재의 표면을 보호하고 광특성을 유지하기 위해 산화물 다층 박막과 비정질 탄소 박막을 코팅하였다. 산화물 다층 박막은 소재 표면에서 빛의 반사율을 낮춰 투과율을 향상시키는 특성을 가지고 있다. 산화물 다층 박막으로 실리콘 산화물과 티타늄 산화막이 사용되었으며 전자빔 증착법을 이용하여 코팅되었다. 비정질 탄소 박막을 산화물 다층 박막의 최상층에 코팅하여 보호막으로 이용하였다. 고분자 윈도우에 산화물 다층 박막을 코팅하면 투과율이 향상되었으며 보호막으로 코팅된 비정질 탄소 박막에 의해서 일어나는 투과율 저하를 낮추는 효과를 보였다.

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Experimental Study on Fracture Pressure, Permeability Enhancement and Fracture Propagation using Different Fracture Fluids (다양한 파쇄 유체별 파쇄압력, 투과도 증진 및 균열전파에 관한 실험적 연구)

  • Choi, JunHyung;Lee, Hyun Suk;Kim, Do Young;Nam, Jung Hun;Lee, Dae Sung
    • Tunnel and Underground Space
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    • v.31 no.1
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    • pp.41-51
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    • 2021
  • The hydraulic fracturing developed to improve permeability of tight reservoir is one of key stimulation technologies for developing unconventional resources such as shale gas and deep geothermal energy. The experimental study was conducted to improve disadvantage of hydraulic fracturing which has simple fracture pattern and poor fracturing efficiency. The fracturing experiments was conducted for tight rock using various fracturing fluids, water, N2, and CO2 and the created fracture pattern and fracturing efficiency was analyzed depending on fracturing fluids. The borehole pressure increased rapidly and then made fractures for hydraulic fracturing with constant injection rate, however, gas fracturing shows slowly increased pressure and less fracture pressure. The 3D tomography technic was used to generate images of induced fracture using hydraulic and gas fracturing. The stimulated reservoir volume (SRV) was estimated increment of 5.71% (water), 12.72% (N2), and 43.82% (CO2) respectively compared to initial pore volume. In addition, permeability measurement was carried out before and after fracturing experiments and the enhanced permeability by gas fracturing showed higher than hydraulic fracturing. The fracture conductivity was measured by increasing confining stress to consider newly creating fracture and closing induced fracture right after fracturing. When the confining stress was increased from 2MPa to 10MPa, the initial permeability was decreased by 89% (N2) and 50% (CO2) respectively. This study shows that the gas fracturing makes more permeability enhancement and less reduction of induced fracture conductivity than hydraulic fracturing.

A Study on Analysis of vortex and Wave Screening Performance for Fixed-Floating Breakwater According to Cross section (단면형상 변화에 따른 고정된 부유식방파제의 유동장 분석과 소파성능에 관한 연구)

  • Kim, Heun;Yoon, Jae Seon;Cho, Yong-Sik
    • 한국방재학회:학술대회논문집
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    • 2011.02a
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    • pp.54-54
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    • 2011
  • 기존의 착저식 방파제를 보완하기 위하여 부유식 방파제가 개발되었고, 많은 연구가 선행되어 왔다. 부유식 방파제의 최대 장점은 경제성과 친환경성이다. 그러나 부유식 방파제는 소파성능이 떨어진다는 단점이 있으며, 이를 개선하기 위해 잠재와 혼용, 배열형에 관한 연구등이 선행되어왔다. 그러나 이것은 경제성이라는 강점을 고려하지 못하였다. 그래서 본 연구에서는 부유식 방파제의 중요한 장점중 하나인 경제성을 고려해, 단면현상 변화만을 이용하여 부유식 방파제의 소파성능 개선하고자 하였다. RANS(Reynolds averaged Navier-Stokes) 방정식에 기초하여 VOF법과 $k-{\varepsilon}$ 난류모델을 결합한 수치모델인 CADMAS-SURF를 이용하였으며, 구조물 단면형상 변화를 이용해 와의 상호 간섭을 유도하였고, 이에 따른 투과율 변화를 관찰 하였다. 결과를 살펴보면 요철1 단면에서는 구조물 전면 하단부분과 구조물 후면 하단부분에서 와의 간섭이 일어났으며 가장 아래 요철 부분에서 유속의 전달현상이 보인다. 투과계수는 일반적인 부유식 방파제와 마찬가지로 L/B가 1~4사이 값인, 비교적 단주기에서는 0.3~0.4의 투과율을 보였으나 L/B가 5를 넘어가면서 0.45~0.55의 투과율을 보였고, 요철2 단면에서는 전면과 후면에서 발달한 와가 전, 후면 돌출부에 의해 바닥까지 전파되지 못하는 양상을 보였으며, 돌출부 사이 중앙부분에서 가장 활발한 와의 간섭을 관찰 할 수 있었다. 돌출부 아래에서 역시 강력한 와의 간섭을 보이고 있다. 투과율 역시 가장 낮은 값을 보였으며 비교적 단주기 구간인 B/L 1~4 에서는 0.2~0.35 사이의 값을 가졌으며 5~10사이구간에서는 0.35~0.34의 값을 보이고 있다. 이 같은 결과는 와의 간섭이 가장 활발하게 나타난 결과로 보인다. 그리고 요철 3단면에서는 전면 돌출부 끝단에서의 활발한 와의 간섭을 관찰 할 수 있었다. 투과율은 세 단면 중 가장 높은 값의 투과율을 보이지만 B/L 3~4 구간에서 요철1 경우보다 낮은 값의 투과율을 보이고 있다. 결과에서 보듯이 도출부의 적절한 조합과 배치를 통해 언급한 연구목표(와의 생성과 간섭, 방파효율 개선)를 달성하였고 추후에 돌출부의 크기와 배치, 흘수의 영향, 수심의 영향 등을 고려한 연구가 진행된다면 더욱 우수한 단면형상을 개발 할 것이라 예상된다.

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Vibration Intensity Analysis of Penetration Beam-plate Coupled Structures (관통보와 평판의 연결 구조물에 대한 진동인텐시티 해석)

  • 홍석윤;강연식
    • The Journal of the Acoustical Society of Korea
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    • v.21 no.1
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    • pp.73-81
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    • 2002
  • The transmission of vibration energy through beam-plate junctions in vibration intensity analysis called power new analysis (PFA) has been studied. PFA is an analytic tool for the prediction of frequency averaged vibration response of built-up structures at medium to high frequency ranges. The power transmission and reflection coefficients between the semi-infinite beam and plate are estimated using the wave transmission approach. For the application of the power coefficients to practical complex structures, the numerical methods, such as finite element method are needed to be adapted to the power flow governing equation. To solve the discontinuity of energy density at the joint, joint matrix is developed using energy flow coupling relationships at the beam-plate joint. Using the joint matrix developed in this paper, an idealized ship stem part is modeled with finite element program, and vibration energy density and intensity are calculated.