• 제목/요약/키워드: 물질-장 분석

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Development of Methodology for Fracture Network Analysis in the Unsaturated Zone using MINC Approach in TOUGH2 Code (TOUGH2 전산코드의 MINC 기법을 이용한 불포화 암반 내 단열 해석 방법론 개발)

  • Ha, Jaechul;Cheong, Jae-yeol;Kim, Soogin;Yoon, Jeonghyoun
    • The Journal of Engineering Geology
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    • v.26 no.3
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    • pp.325-330
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    • 2016
  • The second phase of low- and intermediate-level waste (LILW) disposal facility is under planned on the sedimentary rock in unsaturated zone. In this study, we created two meshes which were a matrix continuum mesh and a fracture continuum mesh to carry out 2 dimensional numerical modeling for groundwater flow in the unsaturated zone containing fractures focused on the second phase of LILW disposal facility. Two continuum meshes were developed using MINC in meshmaker module of TOUGH2 code. A fracture continuum mesh was included the k-field distribution of the permeability derived from the Discrete Fractured Network (DFN) modeling. To apply the unsaturated zone for the modeling, the gridding steps to generate mesh were developed. Each step to generate a mesh consisted of definition of materials, setting the initial conditions and creating grids using MINC. The methodology development of meshes in this study will be applied for more precise modeling of groundwater flow and mass transport.

Preparation and Performance of Synthetic Organo-beidellite (유기 바이델라이트의 합성 및 거동 연구)

  • Ryu, Gyoung-Won;Jang, Young-Nam;Cho, Sung-Jun;Choi, Sang-Hoon
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.2 s.48
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    • pp.123-128
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    • 2006
  • Beidellite, a member of the dioctahedral smectite group, was synthesized hydrothermally from dickite. Organophilic [DEACOOH]-beidellite intercalation complex was formed by the cation exchange reaction between synthetic Na-beidellite and [DEACOOH]Br. The products dried in high vacuum were treated with various organic solvent such as methanol, ethanol, acetone, ether, acetonitrile and caprolactam in order to determine the swelling behaviour of the prepared complexes. After drying under high vacuum, basal spacing of [DEACOOH]-beidellite shows 15.1 ${\AA}$, and it changed to 19.4, 29.9, 15.9, 16.8, 14.8, 26.5 and 14.8 ${\AA}$ under distilled water, methanol, ethanol, acetone, ether, acetonitrile and caporlactam, respectively. Especially, the characteristics of the intercalation complexes and their swelling behavior of the synthetic beidellite and natural montmorillonite were compared.

Analysis of Annual Emission Trends of Air Pollutants by Region (권역별 대기오염물질의 연도별 배출 특성 분석)

  • Lim, Jun Hyun;Kwak, Kyeong Kyu;Kim, Jeong;Jang, Young Kee
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.1
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    • pp.76-86
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    • 2018
  • Using the CAPSS emissions data, we analysed changes and reasons in the annual air pollutant emission trends from 1999 to 2014. The CO emissions in the metropolitan area decreased steadily since 2001, when the latest model year of automobiles and high efficiency fuel were applied. However, other regions have not changed significantly in annual emissions. $NO_x$ emissions continued to increase since 2003, and unchanged after the decline in 2007. $SO_x$ emissions are steadily declining due to the supply of low sulfur oil. The $PM_{10}$ and $PM_{2.5}$ emissions were repeatedly affected by the influence of motor vehicles activities in the metropolitan area. In Gangwon and Chungcheong Provinces, emissions are increasing according to the use of coal in the manufacturing sector. And VOC and $NH_3$ emissions are increasing steadily every year. The major CO emission sources was automobiles in the metropolitan area. However, agricultural residue burning was the biggest CO sources in the Chungchong, Honam and Yeongnam Provinces. The major sources of $NO_x$ emissions differ from region to region. In the Metropolitan area, Honam and Yeongnam region, the truck was the largest emitter of $NO_x$. However, the cement kiln was the largest producer of $NO_x$ in Gangwon region, and the power plant is the largest emitter in Chungcheong Provinces.

Characteristic analysis of a thermochromic material based fiber-optic temperature sensor for measuring temperature of subsurface water (열변성 물질을 이용한 지하수 온도 측정용 광섬유 온도센서의 특성분석)

  • Seo, Jeong-Ki;Yoo, Wook-Jae;Cho, Dong-Hyun;Jang, Kyoung-Won;Heo, Ji-Yeon;Lee, Bong-Soo;Koh, Yong-Kwon
    • Journal of Sensor Science and Technology
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    • v.18 no.6
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    • pp.467-474
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    • 2009
  • In this study, we describe the feasibility of developing a fiber-optic temperature sensor using a thermochromic material such as 2,4,5-triphenylimidazole or also called Lophine. A sensor-tip is fabricated by mixing of a Lophine powder, which has a non-toxic and hydrophobic characteristics, and an epoxy resin. The temperature change in the sensor-tip gives rise to a change in the optical absorbance of the Lophine, and the transmittance of a light through the Lophine is also changed. We have measured the intensities of modulated lights due to the change of optical absorbance of the Lophine by using of a photo-multiplier tube(PMT). The relationships between the temperatures and the output voltages of PMT are determined to measure the temperature of water. The measurable temperature range of the fiber-optic sensor is from 5 to $30^{\circ}C$.

Syntheses and Characterizations of Position Specific Functionalized Graphenes (위치 선택적 관능기화 그래핀의 합성과 특성분석)

  • Heo, Cheol;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.37 no.2
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    • pp.218-224
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    • 2013
  • Graphene oxide (GO) was prepared by the Hummers and Offeman method from graphite. Two different types of functionalized graphene sheets (FGSs) were synthesized by using GO. Hexamethylamine (HDA) substituted vertically to the graphene sheet (Ver-HDA-GS) was synthesized from HDA and epoxy group in GSs. Whereas, horizontally substituted hexadecanol (HDO) to the GS(Hor-HDO-GS) was synthesized from HDO and alcohol groups via reduced GO (RGO), respectively. The structures of the GO, RGO, Ver-HDA-GS, and Hor-HDO-GS were identified by Fourier transform infrared (FTIR). In addition, we examined the thermal stability and morphology. Atomic force microscope (AFM) disclosed that Ver-HDA-GS consisted of one- or two-layer graphene regions. However, the Ver-HDA-GS layers showed average thickness of 1.76 nm. The thermal stabilities of the FGSs were better than those of the GO and RGO. The Ver- HDA-GS was well dispersed in common solvents such as dimethyl sulfoxide (DMSO), toluene, chloroform, and decalin.

An Experimental Study on Factors Affecting the Leachability of Cs-137 in Cement Matrix and Leaching Model with Backfill (시멘트 고화체내 Cs-137의 침출능에 영향을 미치는 인자에 대한 실험적 연구와 뒷채움재를 고려한 침출 모델)

  • Park, Jong-Kil;Lee, Kun-Jai
    • Nuclear Engineering and Technology
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    • v.23 no.4
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    • pp.374-386
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    • 1991
  • Various factors affecting the teachability of Cs-137 in cement matrix have been investigated. Factors investigated include such as pressure curing, vibration curing, pressure leaching, the effect of the clay addition, ion-exchange resin(IRN-77) addition, and $CO_2$or air injection. Leaching experiments were conducted by the method recommended by IAEA. To analyze the experimental results, pore structure analysis of cement matrices was carried out by BET method. Cement matrices may not contact directly with underground water in real repository, since the surroundings of disposed drums are filled with backfill. Thus, the effect of backfill to the teachability has been investigated. The well-known diffusion theory was utilized to predict long term leach rate and cumulative fraction leached of Cs-137 or non-radioactive species.

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Synthesis and Characterization of Molybdenum(V)-Iminodiaceticacid Derivatives Complexes (몰리브덴(V)와 이미노디아세틱액시드계 착물 합성과 그 성질)

  • Sang-Oh Oh;Sik-Young Choi
    • Journal of the Korean Chemical Society
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    • v.31 no.6
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    • pp.520-526
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    • 1987
  • A new series of $dioxo-di-\mu-oxo-dimolybdate(V)$, has been prepared by reaction of pyridinum oxoisothiocyantomolybdate (V) with iminodiacetic acid derivatives containing amine carboxyl groups. The properties and possible molecular structure of these complexes were discussed by elemental analysis, spectroscopic studies and magnetic susceptibility measurements. The infrared spectra of these complexes all show two strong $Mo=O_t$ stretching bands in the 900∼$980cm^{-1}$, $MoO_2Mo$ very prominent strectching bands at around 410~425 and 735~$750cm^{-1}$ to symmetrical and asymmetrical O-bridge stretching, a coordinated $coo^-$ asymmetrical band in the 1585∼$1,640cm^{-1}$. Also, d-d transition of molybdenyl complexes corresponding to $^2B_2{\to}^2B_1$ occured in the 24,800~$28,000cm^{-1}$ region, charge transfer transition corresponding to ligand-to-molybdenum in the 32,500~33,800, 42,000~$47,500cm^{-1}$ region. The complexes synthesized were yellow or orange and diamagnetic.

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Optimization of Production and Antioxidant Effects of Beverage Prepared using Hot-water Extracts of Polygonatum odoratum, Houttuynia cordata, and Lycium chinensis (둥굴레, 어성초, 구기자 혼합 음료의 배합비 최적화 및 항산화 효과)

  • Kang, Min-Kyung;Kim, Il-Chul;Chang, Kyung-Ho
    • Food Science and Preservation
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    • v.17 no.6
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    • pp.835-846
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    • 2010
  • The manufacture of beverages prepared using hot-water extracts of Polygonatum odoratum var. pluriflorum, Houttuynia cordata, and Lycium chinensis was statistically optimized using response surface methodology. The total polyphenol content, electron donation activity, and reducing power of optimized beverages were measured to evaluate antioxidant properties. The coefficients of determination, the $R_2$ values, were 0.9887~0.9957 for color, taste and overall acceptability. Analysis of variance showed that the model fit was a statistically significant (p<0.05). The optimized compositions of processed beverages were: Polygonatum odoratum var. pluriflorum extract, 2.15%; Houttuynia cordata extract, 1.74%; and Lycium chinensis extract, 0.19% (all w/w). Total polyphenol content, electron donation activity, and reducing power of beverages of optimized composition were 3.61 mg/L, 23.78%, and 0.26, respectively.

Investigation of Occupational EMF Exposure Assessment System (직업인 전자파 노출 평가제도 연구)

  • Jeon, Sang Bong;Lee, Ae-Kyoung;Kwon, Yong-Ki;Jang, Ju-Dong;An, Juno;Pack, Jeong-Ki;Gimm, Youn-Myoung;Choi, Hyung-Do
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.28 no.11
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    • pp.843-852
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    • 2017
  • Recently, as the WHO IARC has classified radio frequency electromagnetic fields as possibly carcinogenic (group 2B) to humans, there is increasing concern about the health effects of overexposure from electromagnetic fields. Especially, the workers are exposed to higher level of electromagnetic radiation than the general public. As a result, in Europe, the protection guidelines for the worker are developed and the exposure of the worker is strictly controlled. In this paper, the EU directive, standards and guidelines of the EMF exposure for the worker were reviewed, and the exposure assessment of EMF was performed for the arc welding. Based on that, we propose a way to introduce a national policy to protect the workers from EMF exposure in working environment.

The Infection Characteristics of Vibrio scophthalmi Isolated from Olive Flounder, Paralichthys olivaceus (양식 넙치, Paralichthys olivaceus에서 분리한 Vibrio scophthalmi의 감염 특성)

  • Kim, Su Hyun;Woo, Sung Ho;Lee, So Jung;Park, Soo Il
    • Journal of fish pathology
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    • v.26 no.3
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    • pp.207-217
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    • 2013
  • Recently high mortality of cultured olive flounder, Paralichthys olivaceus occurred frequently at the fish farms in Ulsan, Korea. The diseased fish showed skinny body and swimming behavior around the water surface with liver atrophy and white enteritis as internal signs. The isolated bacteria were identified to V. scophthalmi by biochemical test, nucleotide analysis of 16S rRNA and dnaJ gene sequencing. The pathogen of this study showed strong pathogenicity as 75% mortality to olive flounder by intraperitoneal injection of $1{\times}10^6$ CFU/fish. The pathological sign was not different between the naturally diseased fish and the artificially infected fish. Histopathological changes were shown to liver atrophy, desquamation of the intestinal mucosa and hyaline droplet like as other previous studies.