• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.318-321
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• 2003

비소로 오염된 토양, 하천 퇴적물 및 광미의 복원할 때, 토양 세척 공정에서 중요한 인자인 비소의 화학적 결합형태와 세척제에 따른 용출특성과 고효율 세척 및 세척액의 재활용도를 높이기 위한 공정을 바탕으로 토양세척장비를 설계하였다. 화학적 결합형태에 있어서 토양은 잔류 결합형태가 주되고, 퇴적물의 경우는 철산화물과의 결합형태가 강하며, 광미는 황화물과의 결합에 따른 잔류형태와 철산화물과의 결합형태가 상당부분을 차지한다. 세척제에 따른 용출특성으로부터, 철산화물과 황화물과 결합하고 있는 비소의 화학적 결합형태를 파괴하면서 비소를 추출할 수 있는 용제로 HCl, Oxalate, EDTA, M$_2$O$_2$를 사용하였다. 추출 결과, 비소가 철산화물과 결합한 형태가 비중이 높을수록 EDTA 나 Oxalate가 효율이 높으며, 황화물에 대해서는 HCl과 $H_2O$$_2$이 상대적으로 높은 추출 효율을 보였다. 구성된 세척조는 밀폐실린더형과 스크류이송형 세척조로 구성되어 각각 혼합교반에 의한 세척과 토양입자 분급에 따른 세척이 가능하다. 세척 공정중 최적 산도 조절이 중요한 인자가 되며, 세척액의 재활용도를 높일때, 세척수에 용해되어 있는 비소 및 중금속과 미립자의 동시 제거를 위한 응집 침전조에서 응집제에 의해서 미립자와 함께 제거하는 응집, 침전 및 분리공정을 배치하였다.

• Journal of Applied Biological Chemistry
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• v.63 no.1
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• pp.51-60
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• 2020

This study was conducted to investigate changes in pesticide residues in eggplant and lettuce during washing and cooking processes after application with azoxystrobin. Eggplant was processed with running washing, steaming, and stir-frying, and lettuce was processed with soaking washing, running washing, soaking and running washing, ultrasonic cleaning, and blanching. The limit of quantitation of GC analysis of azoxystrobin was 0.01 mg/kg and the recovery rate was 84.7-109.5%. The azoxystrobin processing factors (PFs) and reduction rates in eggplant and lettuce were calculated and the results were as follows. In the case of eggplant, the azoxystrobin PF and reduction rate of running washing were 0.29 and 71.1%, respectively, those of steaming were 0.32 and 68.0%, respectively, and those of stir-frying were 0.24 and 75.7%, respectively. In the case of lettuce, the azoxystrobin PF and reduction rate of soaking washing were 0.25, 75.3%, those of running washing were 0.61 and 38.9%, respectively, those of soaking and running washing were 0.32, 68.0%, those of ultrasonic cleaning were 0.47 and 53.1%, respectively, and those of blanching were 0.26 and 73.6%, respectively. It could be identified that pesticide residues in eggplant and lettuce can be effectively reduced through washing and cooking processes and that most of pesticide residues were removed when cooking processes were undergone after washing. Therefore, azoxystrobin PFs after washing and processing can be provided as basic data for risk assessment.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1998.11a
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• pp.60-63
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• 1998

본 연구에서는 유류 오염토양 복원을 위한 효율적인 세척공정을 구성하여 현장적용 가능성을 검토하였다. 토양세척공정은 co-current식 전세척장치와 counter -current식 세척조로 구성된다. 물이 주입되는 co-current식 전세척장치에서는 스크류 축의 회전력에 의한 토양 이송 및 스크류의 각 pitch 사이에 부착된 임펠러의 기계적 교반력에 의한 세척이 동시에 이루어진다. 전세척장치를 통과한 토양과 물은 세척조로 유입되어 세척용액과 반대방향으로 이동하게 된다. 세척조의 내벽에 부착된 나선형 웨어에 의해 적정 운전조건하에서 일정 크기를 기준으로 토양이 분리되며, 각 웨어 사이에 부착된 임펠러의 교반력에 의해 오염토양이 세척된다. 실험결과, 운전시 고려해야 할 주요 영향인자들은 전세척장치에서의 토양주입량은 1 kg/min, 진탕비는 1, 회전속도는 50 rpm에서 최대 세척효율(#4-, 83.6%)을 보였으며, 세척조에서는 토양.물 주입위치 15 cm, 회전속도 5 rpm, 경사각 6$^{\circ}$, 세척용액 주입유량이 0.8 L/min일 때 최대 세척효율인 97.9%(#4-)를 나타냈다.

• 월간 기계설비
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• s.119
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• pp.71-83
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• 2000

점차 복잡해지고 있는 사회적 욕구를 만족시키기 위한 건물에서는 반드시 복잡한 설비가 요구되고 있고, 이러한 설비시스템 중에는 급수, 급탕 및 배수설비라고 하는 배관시스템이 없다면 기능유지에 막대한 지장을 초래할 것은 자명하다고 하겠다. 이러한 배관시스템에서는 항시 또는 일부 사용되어질 물이나 사용된 물이 흐르기 때문에 배관내부에 발생하는 스케일(scale)이나 슬라임(slime) 등은 피할 수 없는 사실인 것이다. 건축물 내에 설치된 각종 배관은 건물의 기능을 유지하고 보건위생과 직결되는 중요한 기능을 담당하고 있어 세척의 필요성이 매우 높음에도 불구하고 배관의 수명이 다할 때까지 거의 세척이 이루어지지 않고 사용되어 왔다. 이들 배관에 대한 세척은 배관의 수명연장과 관마찰 계수를 낮추어 급수의 수송동력을 절감할 수 있고, 난방관의 열전달 효과를 높여 에너지 절약 효과를 거두어 건물의 유지관리 비용 절감에 기여할 수 있음에도 적절한 세척공법이 개발되지 않고 있다. 이러한 관점에 맞추어 건물배관의 특성에 맞도록 고압 세척장치를 개발하고 이를 이용한 세척공법을 적용하고자 하였다. 즉, 배관 내에 압축공기를 주기적으로 분사하여 맥동현상이 일어나도록 하면서 기포를 발생시켜 기포가 관의 내벽에서 성장하여 파괴될 때 관내에 부착된 이물질을 제거할 수 있고, 또한 세척효과를 높이기 위하여 관의 벽면에 접촉하면서 배출되는 과정에서 이물질을 제거할 수 있도록 구조와 아울러 이들 장치를 이용한 세척방법의 적용성에 대해서 고찰하고자 한다.

• Korean Chemical Engineering Research
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• v.60 no.1
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• pp.169-174
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• 2022

In this study, a tandem water and hexane washing process was developed to improve the recovery efficiency of paclitaxel derived from Taxus chinensis. The polar impurities contained in the sample were effectively removed by washing with water at a sample/water ratio of 1:40 (w/v) for 10 min. In addition, the non-polar impurities were effectively removed by washing with hexane at a sample/hexane ratio of 1:160 (w/v) for 20 min. A high purity of paclitaxel (>30.0%) was obtained in a short operating time (~30 min) by sequential washing with water and hexane.

• Journal of Korean Ophthalmic Optics Society
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• v.15 no.4
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• pp.347-353
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• 2010

Purpose: An in vitro study was conducted to compare the lipid cleaning efficacy of care solutions on balafilcon A silicone hydrogel (SiHy) lens. Methods: Lipid spoilation was performed by incubating balafilcon A SiHy lenses in phosphate buffered saline (PBS) containing oleic acid, oleic acid methyl ester and cholesterol. Spoiled contact lenses rinsed with PBS were cleaned with surfactant cleaner, alcohol containing cleaner and multipurpose solution (MPS) respectively and repetitive spoilation and cleaning was conducted up to 14 times. To observe the cleaning effect of ultrasonic wave on the lipid deposit, each spoiled lens was ultrasonicated and then compared with non-sonicated lens. Lipids deposit on the contact lenses was extracted by methanol:chloroform (1:1, v/v) solution. High performance liquid chromatography was used to analyze and quantify lipid deposit extracts. Results: The effectiveness of alcohol containing surfactant cleaner on the lipid deposits was better than that of surfactant cleaner and MPS, and the cleaning efficacy was significantly higher in the ultrasonic wave treated group. Lipid deposits were not removed completely by contact lens care solutions so that lipid deposits increased continuously and cumulatively. Conclusions: The cleaning efficacy of contact lens care solutions was not satisfactory to remove lipid deposits on the SiHy lens that new cleaning products specially designed for SiHy lenses are needed to develop.

• KAPE Magazine
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• s.200
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• pp.10-11
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• 2013

• Journal of Soil and Groundwater Environment
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• v.8 no.3
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• pp.61-73
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• 2003

A model describing the distribution of contaminants in soil/water systems for the application of soil-washing technology using surfactant was developed. The model simulation was conducted for screening the best surfactant, evaluating the effect of water dose, and optimizing soil-washing methodology. Naphthalene, phenanthrene, and pyrene as target compounds and Triton X-l00, Tergitol NP-10, Igepal CA-720, and Brij 30 as surfactants were used in the model simulations. The washing efficiency was not greatly enhanced by increasing water dose with the same total surfactant dose. The approach of successive washings was more efficient than a single washing with the same amount of water and surfactant. Equal allotment of the amount of water and surfactant was the best condition for the successive washings. The model can be applied for the optimal design of the soil washing process without extra experimental efforts.

• Journal of Korea Soil Environment Society
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• v.3 no.3
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• pp.109-116
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• 1998

Treatability tests of a soil washing device were performed for the remediation of eil-contaminated soil. The contaminant-containing soil with water was first fed into a oc-current screw conveyor and then into a counter-current washer. Surfactant was introduced into the washer and feeding soil was continuously separated on the basis of #40 mesh at the same time. A washing efficiency of 97.9% was achieved by the the soil washing device optimized.

• Journal of Korean Ophthalmic Optics Society
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• v.15 no.3
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• pp.227-234
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• 2010

Purpose: The cleaning effect of protein deposit and the change of contact lens parameters by ultrasonic cleaner for eye glasses on the soft contact lenses were investigated. Methods: Etafilcon A contact lenses contaminated with protein, was ultrasonicated by ultrasonic cleaner for eye glasses and for the control group, spoiled contact lenses were cleaned by multi-purpose solution. The remaining protein deposits on the contact lenses were determined after extraction and the changes of overall diameter, base curve, center thickness power, and water contents on contact lenses were measured and surfaces of contact lenses were observed by scanning electron microscope. Results: The cleaning efficacies of multi-purpose solution on protein deposited etafilcon A contact lenses were 6.08%, and 23.73~33.92% in the group of ultrasonic cleaner for eye glasses with multi-purpose solution and 0~12.99% in the group of ultrasonic clear for contact lens with multipurpose solution depending on the treatment time. The changes of parameters and surface on contact lenses by ultrasonication were not observed. Conclusions: Ultrasonic cleaner for eye glasses can be used to eliminate protein deposits for the diagnostic soft contact lens in the office since it was effective to eliminate protein deposits and not caused change of parameters on soft contact lenses.