• Title/Summary/Keyword: 물리화학적 성분

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Study on the Flame Retardation and Thermal Resistance for CPE Rubber Material Added Etching By-product of Aluminum (알루미늄 엣칭부산물을 첨가한 CPE 고무재료의 난연성 및 내열성 연구)

  • Kim, Kyung Hwan;Lee, Chang Seop
    • Journal of the Korean Chemical Society
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    • v.45 no.4
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    • pp.341-350
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    • 2001
  • Aluminum Hydroxide was employed as a thermal retardent and flame retardent for Chloropolyethylene (CPE) rubbery materials which is the construction material of automotive oil cooler hose. and then cure characteristics, physical properties, thermal resistance and flame retardation of compounded rubber were investigated, and optimum mixing conditions of rubber and flame retarding agent were deduced from the experimental results. CPE rubber material which has excellent properties of chemical corrosion resistance and cold resistance and inexpensive in price was used to prepare rubber specimen. The by-product of ething, produced from the process of surface treatment of aluminum was processed to aluminum hydroxide via crushing and purification, which is characterized by XRD, PSA, SEM and ICP-AES techniques in terms of phase, size, distribution, morphology and components of particles and then mixed to CPE rubber materials in the range of 0~80 phr. Hardness, tensile strength, elongation and thermal properties of compounded rubber specimens were tested. The optimum mixing ratio of rubber to additives to give maximum effect on thermal resistance and flame retardation, within the range of tolerable specification for rubber materials, was determined to be 40 phr. The flame retardation of CPE rubber materials was found to be increased by 5 times at this mixing ratio.

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Physico-Chemical Properties of Soils at Red Pepper, Garlic and Onion Cultivation Areas in Korea (우리나라 고추, 마늘 및 양파 주산지 밭토양의 물리·화학적 특성)

  • Sohn, Bo-Kyoon;Cho, Ju-Sik;Kang, Jong-Gu;Cho, Ja-Yong;Kim, Kil-Yong;Kim, Hyun-Woo;Kim, Hong-Lim
    • Korean Journal of Soil Science and Fertilizer
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    • v.32 no.2
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    • pp.123-131
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    • 1999
  • To get the basic information for the improvement of the optimum levels of upland soil fertility and fertilizer application, the soil samples in two hundred fifteen site were collected from the major condiment vegetable cultivation areas such as red pepper, garlic and onion fields. Physico-chemical properties of the soil samples were investigated. Soil texture distribution of soil samples in red pepper, garlic and onion cultivation areas was in order of loam (L), sandy loam (SL), silt loam (SiL) and clay loam (CL) (35.4, 31.6, 14.9 and 7.0%, respectively). The average pH of soil in garlic and onion cultivation areas were over pH 6.0, whereas in red pepper was under pH 5.5. The frequency distribution of soil pH in total sampling sites were 58.7% in under pH 6.0 and 21.4% in below pH 5.0, in contrast to 10.3% in over pH 7.0. The organic matter contents were in the range of $20{\sim}30g\;kg^{-1}$, and the onion field soils was a little higher than those in red pepper or garlic. The available phosphate contents were in the range of $719{\sim}746mg\;kg^{-1}$ and were not different among in red pepper, garlic and onion. The frequency distribution of available phosphate in total sampling sites were found 62.8% of above $600mg\;kg^{-1}$, which was over the standard level for upland soil improvement, and then 22.3% was exceeded $1,000mg\;kg^{-1}$, especially. In the exchangeable cations, the K and Ca contents in garlic (1.27 and $9.11cmol\;kg^{-1}$) and onion (1.20 and $8.39cmol\;kg^{-1}$) were higher than in red pepper (0.96 and $5.87cmol\;kg^{-1}$), respectively. The Mg contents in garlic field soils ($2.17cmol\;kg^{-1}$) were higher than those in red pepper and onion (1.51 and $1.80cmol\;kg^{-1}$). This exchangeable K, Ca and Mg contents were higher than the standard level for upland soil improvement. The contents of microelement were ranged in $54.3{\sim}60.1mg\;kg^{-1}$ for Fe, $31.3{\sim}42.3mg\;kg^{-1}$ for Mn, $1.7{\sim}2.3mg\;kg^{-1}$ for Cu and $4.8{\sim}5.5mg\;kg^{-1}$ for Zn, respectively.

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A Semi-Automatic Rapid System for In-Field Soil Phosphorus Measurement (현장 토양의 인 분석을 위한 반자동 신속 측정 시스템)

  • Lee, Sang-Yoon;Park, Hyo-Je;Han, Cheol-Woo;Lee, Seung-Yun;Kweon, Giyoung
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.120-120
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    • 2017
  • 최근 국내 소비자들의 안전한 음식과 환경문제에 대한 관심이 높아지면서 재배작물과 경작지 토양의 물리 화학적 특성 등에 맞추어 적정 시비 및 재배관리를 적용하는 정밀농업이 시도되고 있다. 정밀농업은 농약 및 비료 등의 양을 적절하게 사용하여 생산 비용을 절감할 수 있으며, 과다사용을 막아 환경오염을 줄일 수 있다. 현재 토양의 수분, EC, pH등과 같은 항목은 신속하고 간단하게 분석이 가능하지만 토양의 필수 원소인 N, P, K 성분을 분석하는 제품은 상용화 되지 않았거나 가격이 비싸 일반 농가에서는 사용이 어렵다. 특히, 토양의 인을 현장에서 분석하기 위한 연구가 많이 수행되고 있으나 실제로 현장에서 사용되는 경우 또한 없는 상황이다. 일반적으로 토양에 포함되어 있는 인을 측정하기 위해서 많은 실험실에서는 이화학적 분석법을 사용하고 있다. 하지만 이 분석법은 오랜 시간과 전문적인 인력이 필요하며 주변 환경변화에 민감하여 실시간으로 분석하기에는 어렵다고 한다. 따라서 본 연구에서는 현장에서 실시간으로 토양의 인을 분석하기 위해 반자동 분석시스템을 제작하고 이를 검증하고자 하였다. 이전 연구에서 현장 토양을 이용한 신속측정법의 가능성($R^2>0.7$)을 확인하여 이 분석법을 바탕으로 반자동 분석시스템을 제작하였고 표준결과 값의 약 70% 이상의 수준을 목표로 하였다. 진주 지역의 현장 토양 20개 샘플과 반자동 침출 장치, 여과 장치, 발색 장치 그리고 통합 반자동 시스템을 이용하여 분석한 후 표준 분석 결과와 비교하였을 때 $R^2$ 값이 각각 0.985, 0.817, 0.893, 0.837로 약 70% 이상의 수준을 달성하였다. 추후, 반자동 토양 인 신속측정시스템을 완전 자동화 시스템으로 개발하고 주행 장치를 부착시켜 현장에서 실시간으로 원하는 위치의 인을 측정 할 수 있을 것으로 판단된다.

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Alternative Conceptions of High School Students about the Crust and Interior of the Earth (지각과 지구 내부에 대한 고등학생들의 대안 개념)

  • Jeong, Ku-Song;Jeong, Jin-Woo
    • Journal of the Korean earth science society
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    • v.28 no.3
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    • pp.266-276
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    • 2007
  • This purpose of this study was to analyze high school students' alternative conceptions and understanding levels about rocks, crust, plate tectonics and interior of the Earth. Data were collected through surveys, drawing assignments, and interviews. A total of 158 high school students in the first grade were involved in this study. The results showed that students have lots of major alternative conceptions which are meaning and forming process of rock, distinction of continental crust and ocean crust, formation and disappearance of ocean crust, movement of plate, continental drift, activities of volcano and earthquake. Physical and chemical characteristics, including mantle and core state could be found through analyzing from drawings.

Ozone Application for the Bleaching of Unsaturated Coloring Material (오존을 이용한 불포화 색소물질의 탈색반응)

  • Choi, Hyeong-Ki;Chung, Chang-Nam;Kim, Jum-Sik
    • Applied Chemistry for Engineering
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    • v.2 no.3
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    • pp.262-269
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    • 1991
  • Bleaching effect of ozone on unsaturated coloring material was compared quantitatively with the change of composition of reactants through the ozone oxidation of ${\beta}$-carotene. Beeswax colorized by carotenoids was reacted with ozone in water, 0.5 % and 1.0 % sodium hydroxide solution, and 20 % and 95 % acetic acid solution and bleaching effect of each reaction condition was compared with each other. And then the additive effect of hydrogen peroxide was investigated. Decrease of unsaturated double bond of ${\beta}$-carotene was proportioned quantitatively to the bleaching effect of ozone on ${\beta}$-carotene and was in accordance with the bleaching effect on beeswax. The bleaching effect of ozone on coloring material in 1.0 % sodium hydroxide solution was better than any other condition and the absorbance of beeswax at 390 nm was improved to 0.045 with the addition of hydrogen peroxide(2 % of wax). For the bleaching of beeswax, it was concluded that the ozone oxidation was more effective than physical adsorption.

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Laboratory Weathering Experiment on Mica and Feldspar and Their Mineralogical Characteristics (운모와 장석의 실내 풍화실험 및 광물학적 특성)

  • Lee, Seung-Yeop;Kim, Soo-Jin;Cho, Won-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.2 s.48
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    • pp.63-69
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    • 2006
  • When rocks are exposed to the near surface environment, they are broken down due to several factors such as physical and chemical weathering during the geologic time. The feldspar and mica, which are the main rock-forming minerals, are easily broken down relative to other minerals. In order to reproduce some weathered minerals similar to the ones exist in natural weathered granite, there was an experimental interaction between fresh minerals and acidic solution. In low pH condition, biotite initially dissolved and its surface structure broke down, whereas plagioclase dissolved and had a needle-shaped dissolved morphology with some precipitates composed of Al element. The minerals were deeply dissolved in a strong acid condition, showing the prominent dissolved structure. Some etch pits and dissolved textures developed on the natural mineral surfaces are similarly found in our experiment, suggesting the development of mineral dissolution and weathering texture by the influence of the mineral's intrinsic nature.

Physicochemical Characteristics of Collagen Peptide from Flatfish Skin (각시가자미 껍질로부터 콜라겐 펩타이드 제조 및 이화학적 특성)

  • Jang, Boo-Sik;Lee, Mi-Jin;Jeong, Noh-Hee;Kim, Tae-Young
    • Applied Chemistry for Engineering
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    • v.24 no.1
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    • pp.18-23
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    • 2013
  • In this research, the collagen peptide powder from flatfish skin (FSCP) was prepared and compared with commercial collagen peptide powder from tilapia scale (TSCP) in the aspect of physiochemical property. The physical property and nutritional components of FSCP appeared almost similarly to those of TSCP, and also in calorie. No differences in calorie between FSCP and TSCP. Amino acid contents of FSCP for example, aspartic acid, serine, histidine, tyrosine and methionine were higher than those of TSCP. In contrast, the hydroxyproline, proline, alanine contents in FSCP were lower than those in TSCP. Especially, the content of essential amino acid of FSCP, which was 22.74%, was higher than that of TSCP evaluated as 13.64%. In the distribution of molecular weight, FSCP was 1000 Da, which showed a comparatively low distribution compared with TSCP, and in emulsion property and stability both FSCP and TSCP showed an excellent trend.

Effect of $Angelica^{(R)}$ against Skin Photo-aging ($Angelica^{(R)}$의 피부 광노화에 대한 효과)

  • Jin, Mu-Hyun;Jung, Min-Hwan;Lim, Young-Hee;Lee, Sang-Hwa;Kang, Sang-Jin;Cho, Wan-Goo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.31 no.3 s.52
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    • pp.227-235
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    • 2005
  • Skin aging is not a disease nor an abnormal phenomenon but a collection of degenerative changes with age, characterized by skin dryness, wrinkle formation, and loss of skin elasticity. The skin wrinkles are caused by either genetically predisposed factors or environmental factors such as UV irradiation or physical/chemical stimulus. The histological manifestations of wrinkles are changes in both amount and integrity of elastic and collagen fibers. Here we report the isolation and characterization of 3 active compounds, prangenidin, 8-hydroxybergapten, and xanthotoxol from Angelica dahurica root. The anti-wrinkle activities of these compounds were also investigated.

Conservation and Analysis of Inner Materials of a Stoneware Bottle from Incheon Ongjingun Yeongheungdo Shipwreck (인천 옹진군 영흥도선 출수 도기병의 보존처리와 내용물 분석)

  • Kim, Hyoyun;Kim, Seojin
    • Journal of Conservation Science
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    • v.32 no.4
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    • pp.449-457
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    • 2016
  • A stoneware bottle was recovered from the Incheon Yeongheungdo Shipwreck in 2013. Primary observations showed that this object had a sealed opening and was covered with a foreign material. After it was cleaned via mechanical and chemical methods, wave patterns were observed on the outer surface of the bottle and a yellowish-brown transparent material was found within. In this paper, the process of conserving the stoneware bottle and the analysis conducted on the unknown material found within is explained. The conservation process included steps such as cleaning, desalination and restoration. After of the missing area located at the rim, the original shape of the bottle was made clear. In addition, the unknown inner material was analyzed using FT-IR and GC-MS. Results showed that the material is similar to golden lacquer. It is speculated that the Yeongheungdo Ship had wrecked during the Unified Silla period while carrying a bottle loaded with golden lacquer.

Studies on Physicochemical and Biological Properties of Depolymerized Alginate from Sea tangle, Laminaria japonicus by Thermal Decomposition 8. Effects of Depolymerized Alginate on Serum Lipid Composition and Its Single-Dose Toxicity yin Oral Route in Rats (다시마 (Laminaria japonicus) Alginate의 가열가수분해에 따른 물리$\cdot$화학적 및 생물학적 특성에 관한 연구 8. 저분자 Alginate투여에 의한 랫드의 혈청지질의 성분 변화 및 경구급성독성 실험)

  • KIM Yuck-Yong;CHO Young-Je
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.3
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    • pp.173-178
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    • 2001
  • This study was performed to know the hypocholesterolemic effect of depolymerized alginate obtained by hydrolysis of alginate through a heating process at $121^{\circ}C$. The changes of total cholesterol, HDL-cholesterol, LDL-cholesterol, triglycerides and phospholipid levels in serum, as well as the atherogenic index were elucidated in rats for 35 days. In order to evaluate single-dose toxicity of HAG-50 in rats via oral routes, induction any mortalities and abnormal signs in clinical finding, body weight, gross findings and histopathological finding, and estimation of $LD_{50}$ were elucidated. Total cholesterol, HDL-cholesterol, LDL-cholesterol, triglycerides and phospholipid levels in the serum significantly decreased and resulted in the decrease of atherogenic index in rats fed diets containing $5\%\;and\;10\%$ HAG-50 (p<0.01). HAG-50 did not induce any mortalities and abnormal signs in clinical findings, body weights, gross findings and histopathological findings in single-dose toxicity test via oral routes of rats, after which it was impossible to estimate $LD_{50}$ values.

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