• Title/Summary/Keyword: 무기 부산물

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Nutritional Effect of Carbonized Tobacco Leaf Debris Neutralized by Nitric and Phosphoric Acid on Nursery Seedlings (연초가공부산물(煙草加工副産物)의 탄화정도(炭化程度)에 따른 질산중화능력(窒酸中和能力)과 비효(肥效))

  • Lee, Yun-Hwan;Hong, Soon-Dal
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.1
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    • pp.89-93
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    • 1985
  • In order to develop the nutrient material for growing plants, tobacco leaf debris (T.L.D) that is a residual product of cigarette processing was carbonated at about 50% of its weight and neutralized its alkalinity by nitric and phosphoric acid. This material ($T.L.D+3N-HNO_3+1N-H_3PO_4$ (10:1:1), as a consequence, contained 4.1% of nitrogen, 2.1% of phosphte, and 6.6% of potassium in value of about pH 7. It was very effective on seedling growth to apply 1 Kg of nutrient material per 110 1 of bed soil as basic dressing because of containing not only quick-acting nitrate but also slow-releasing organo-nitrogen and sufficient potassium.

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An experimental study on preparation of precipitated calcium carbonate using Ca component dissolution characteristics and liquid carbonation by the Industrial byproducts (산업부산물의 Ca 성분 용출 특성 및 액상탄산화 반응을 이용한 침강성 탄산칼슘 제조에 관한 실험적 연구)

  • Lim, Yun-Hui;Lee, Ju-Yeol;Shin, Jae-Ran;Choi, Chang-Sik;Hong, Bum-Ui;Kang, Ho Jong;Park, Byung Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.116-126
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    • 2015
  • The present study utilized a shuttle mechanism of wet chemical absorption using MEA. In addition, industrial by-products containing a large amount of inorganic alkali substances were utilized for wet carbonization process. Chemical pretreatment of industrial by-products extracted calcium ions. ICP result of calcium ion was obtained up to 17,900 ppm(17.9%) by acidic substance. And also, In this work, 94% of recovery rate was obtained using wet MEA absorption process from $CO_2$ flow at the ambient condition. Through the liquid carbonation process, a sludge was fixed with rate of 0.175 mg of $CO_2$ per mg of sludge. It was found from XRD results that the structure of final product was composed of a calcite structure which is general structure of $CaCO_3$.

Effect of Autoclaved Lightweight Concrete on the Growth of Zoysia Japonica Steud (경량기포 콘크리트 부산물 시용이 잔디의 생육에 미치는 영향)

  • Yuk, Chang-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.4
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    • pp.368-372
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    • 1998
  • A field assay was conducted to study whether the by-product of Autoclaved Lightweight Concrete(ALC) could be used as a silicate fertilizer for Korean Zoysiagrass. ALC application rates (0, 2.0, 4.0, 6.0 and $8.0Mg\;ha^{-1}$) were investigated for their effects on growth status, mineral nutrient concentrations, yield of fresh and dry matter of lawn grass and soil properties after experiments. The number of stolon and length of stolon at 180 day after Zoysiagrass transplanting were increased in the treatemnt of $2.0{\sim}6.0Mg\;ha^{-1}$ of ALC application, but those of $8.0Mg\;ha^{-1}$ of ALC plot were deceased with excess of ALC. The fresh weight and dry matter at harvesting time of lawn grass treated with $6.0Mg\;ha^{-1}$ of ALC was heavier than those of other ALC plots. There were statistically significant between the number of stolon and length of stolon remarkably. Mineral nutrient contents such as Si and Ca in Zoysiagrass were increased by higher ALC application, while T-N, available P and K were no difference with application lavel of ALC. Soil pH and Si contents in soil after experiment were increased by ALC application remarkably.

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Nutritional Composition, Ginsenoside Content and Fundermental Safety Evaluation with Leaf and Stem Extract of Panax ginseng (인삼잎과 줄기 혼합 추출물의 영양성분, Ginsenoside 함량 및 기본적 안전성 평가)

  • 한종현;박성진;안종남;위재준;김기영;박성혜
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.5
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    • pp.778-784
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    • 2004
  • This study was conducted to investigate the application possibility of leaf and stem extract (LSE) from the mixture of leaf and stem of Panax ginseng. This study measured the general nutritional composition, aminoacid minerals contents and fatty acid composition of LSE. We conducted analysis of the ginsenoside content by HPLC and the cell cytotoxicity tests in normal liver and kidney cells. The approximate composition of LSE was 2.51% of carbohydrate 0.53% of crude ash,0.20% of crude fat and 0.15% of crude protein, respectively. LSE contained 102.56 mg/100 g of K ion and high contents of acidic amino acids such as glutamic acid and aspartic acid. In addition to this, it contained all essential amino acids. The major compositions of fatty acids were 39.99% of palmitic acid 14.96% of linoleic acid, 13.31% of docosatetranoic acid and 12.91% of linolenic acid, The total ginsenoside was 0.82 mg/mL, and ratio of PD/PT was 0.68. Negative effects were not found from the results of the cell toxicity respection. These results imply that leaf and stem of Panax gineng could be used as possible food resources and functional food material and feed stuff.

Evaluation of Flexural Performance of Eco-Friendly Inorganic Binding Material RC Beams Using Sodium Activator (나트륨계 알칼리 활성화제를 사용한 친환경 무기결합재 철근콘크리트 보의 휨성능 평가)

  • Ha, Gee-Joo;Kim, Jin-Hwan;Jang, Kie-Chang
    • Journal of the Korea Concrete Institute
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    • v.25 no.3
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    • pp.261-269
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    • 2013
  • In this study, it was developed eco-friendly inorganic binding material concrete using ground granulated blast furnace slag and alkali activator (water glass, sodium hydroxides). Eight reinforced concrete beam using inoganic binding material concrete were constructed and tested under monotonic loading. The major variables were mixture ratio of alkali activator, type of admixture and admixture. Experimental programs were carried out to improve and evaluate the flexural performance of such test specimens, such as the load-displacement, the failure mode, the maximum load carrying capacity, and ductility capacity. All the specimens were modeled in scale-down size. The eco-friendly concrete using inorganic binding material encouraged alkali activation reaction was rapidly hardening speed and showed possibility as a high strength concrete. Also, the RC beams using new materials showed similar behavior and failed similarly with RC beam used portland cement. It is thought that eco-friendly inorganic binding material concrete can be used with construction material and product as a basic research to replace cement concrete. If there is application to structures in PC member as well as production of 2nd concrete product, it could be improved the productivity and reduction of construction duration etc.

The Effect of Application Adjusted C/N Ratio of Orgaic Matter Resources on Soil Chemical Properties and Growth of Watermelon in Plastic Film Houses (시설재배지 유기물자원 C/N율 조절 시용시 토양화학성 및 수박의 생육에 미치는 영향)

  • Kang, Bo-Goo;Lim, Sang-Cheol;Lee, Joung-Won
    • Proceedings of the Korean Society of Organic Agriculture Conference
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    • 2009.12a
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    • pp.304-305
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    • 2009
  • 시설재배지의 토양화학성 변화는 작물재배 기간 시비한 화학비료에서 유래된 무기성분 뿐만아니라, 가축분퇴비의 질소성분의 토양잔류량이 요소비료 보다 9.4배 많아 염류집적 주 요인이라는 보고('05 경기도)가 시사하는 봐와 같이 유기자원으로 시용하는 가축분 등의 부산물비료의 무기화에서 유래된 비료성분이 토양염류집적 및 토양환경악화에 더 큰 영향을 미칠 수 있다. 시설재배지의 유기물자원 시용기준이 토양의 특성에 관계 없이 작물에 따라 양적인 시험성적이 주로되어 있으며, 토양검정에 의한 시용기준도 유기물함량에 따라 볏짚, 우분, 돈분 및 계분으로 돠어 있다. 일반노지와 달리 시설재배지에서는 유기물함량이 토양의 비옥도 및 작물생육에 영향을 미치는 것 보다는 토양의 전기전도도(EC)가 더 중요한 작물생육 조건이 될 수 있다. 따라서 토양의 특성에 따라 물질순환에 의한 유기자원 시용기준으로 개선할 필요성이 있다. 시설재배지의 장기적인 토양관리를 위하여 유기물자원에 의한 토양환경 개선 효과를 구명하고자. 무처리, 가축분부산 물비료 관행 시용 기준 대비 볏짚 등 5개의 유기자원을 토양의 무기태질소 함량 대비 유기자원의 탄소함량을 C/N율 10 조절량을 시용하여 시험하였고, 또한 토양의 전기전도도(EC)가 상이한 3개( <2.0 dS/m, 2.0~6.0 dS/m, 6.0 dS/m<)토양에 유기물자원(우드칩)을 C/N율 10, 20, 30 조절하여 수박을 시험작물로 비닐하우스에서 재배하여 수행하였다. 시험 후 토양의 전기전도도(EC)는 시험 전에 비하여 시험 후 토양에서 가축분부산물비료는7% 증가되었으나 유기물자원 처리는 26~33% 경감되는 효과가 있었다. 수박의 과중은 무처리를 제외하고 처리간에 차이가 없었다. 유기물자원 C/N율 조절간에는 시험전 토양의 EC에 따라 차이가 있어 C/N 10 조절에서는 26~44%, C/N 20 조절에서는 30~51%, C/N 30 조절에서는 27~48% 경감효과가 있었으며, 3토양의 평균 토양EC 경감율은 C/N 10, 20, 30 조절에서 각각 34, 39 및 38 % 이었다. 수박의 생육 및 과중은 토양의 C/N율 조절간에는 차이가 없었으나, 토양의 EC 간에는 토양의 EC가 6.0dS/m 이상 토양에서 가장 낮았다. 따라서 탄소원의 유기자원을 C/N율 조절에 의한 시용기준 개선으로 토양의 무기태질소와 토양의 전기전도도(EC)를 경감시켜 친환경적 토양관리와 수박의 수량과 품질을 향상시킬 수 있을 것으로 평가되었다.

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Development of the Inorganic Coagulants Using Red Mud and Evaluation of Its Coagulation Performance (적니를 이용한 무기응집제의 개발 및 응집성능 평가)

  • Lee, Jae-Rok;Hwang, In-Gook;Bae, Jae-Heum
    • Clean Technology
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    • v.8 no.2
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    • pp.85-92
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    • 2002
  • Red mud is generated as a by-product during the production of aluminum hydroxide from bauxite ore. In this study the red mud coagulants were prepared by reacting 100 ml of 5 M $H_2SO_4$ solution with 10g of red mud at $85^{\circ}C$ or by reacting 100ml of 9M HCl solution with 10g of red mud at $25^{\circ}C$. The prepared red mud coagulants were tested for their coagulation performance of pollutants in the municipal and industrial wastewater. In addition, the coagulation performance was compared with that of a commercially available coagulant ($FeCl_3$). As a result, the red mud coagulants were found to have a good removal efficiency of pollutants in the municipal wastewater (turbidity, phosphate phosphorus) and in the plating wastewater (turbidity, $Pb^{2+}$, $Cd^{2+}$, $Cu^{2+}$, $Zn^{2+}$, $Cr^{3+}$). In the experiment to remove COD in the petrochemical wastewater, the COD removal efficiency by the red mud coagulants was a little poor, but it was better than that by $FeCl_3$.

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A Hardening Properties of Eco-Friendly SCW Grouting Material (친환경 SCW공법용 그라우팅재의 경화특성)

  • Jo, Jung-Kyu;Park, In-Wook;Mun, Kyung-Ju;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.2
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    • pp.109-115
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    • 2018
  • Since the current method of SCW cement milk pouring method uses one to one ratio of cement milk with OPC, there are some problems such as drying shrinkage, increased cost, difficulty of controlling mix proportions for various conditions of applied soil, and precipitation of $Cr^{6+}$ due to the excessively used cement. Specifically, in aspect of sustainability issues of cement manufacturing, the consumption of cement should be reduced. Hence, in this research, as a replacement of cement for SCW method, blast furnace slag with sulfate or alkali as a stimulant, and expansive admixture were used. By using blast furnace slag as a hardening composite of SCW, there are many advantages such as free controllable mix proportions, rapid setting time with less mud occurrence, less cost with less energy for mixing, constant strength development, and less precipitation of $Cr^{6+}$. Regarding the alternative composites for SCW, in this research, durability and chloride resistance were evaluated.

Biodegradation of Potential Diesel-Oxygenate Additive Including DBM(DiButyl Maleate) (DBM(DiButyl Maleate)을 포함한 잠재적 디젤첨가제 생분해특성)

  • Chang, Soonwoong
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.8
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    • pp.65-71
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    • 2010
  • In this study, we have evaluated biodegradability of diesel-oxygenates including DBM and gasoline-oxygenates having similar physio-chemical properties using indigenous aerobic microorganisms from a diesel-contaminated soil. Toluene and Ethanol have shown higher biological activity and the first-order degradation rate constants ranged around $0.11{\sim}0.3day^{-1}$. However, MTBE, gasoline-oxygenate has shown as a limited substrate. Moreover, As increased initial concentrations of DBM and TGME, degradation rates of those were decreased relatively. As a strategy to evaluate biodegradability of DBM and TGME, reduction of diesel-oxygenates, $CO_2$ production and toxicity by algae were monitored. This results indicated possible mineralization of diesel-oxygenates, But we could predict that residual byproduct produced even though complete consumption of diesel-oxygenates were observed if algal toxicity variation considered. In conclusion, it is the first report that diesel-oxygenates including DBM could be biodegraded effectively by indigenous soil microorganisms and this result increased the possibility of bioremediation technology to apply into oil-contaminated sites.

Experimental Study on Engineering Properties of Concrete Using Fluosilicates Based Composite (규불화염계 복합 조성물을 혼입한 콘크리트의 공학적 특성에 관한 실험적 연구)

  • Yang Il-Seung;Yun Hyun-Do;Kim Do-Su;Khil Bae-Su;Han Seung-Gu
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.769-774
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    • 2005
  • Fluosilicic acid(H2SiF6) is recovered as an aqueous solution which absorbs $SiF_4$ produced from the manufacturing of industrial-graded H3PO4 or HF. Generally, fluosilicates are the salts produced by the reaction of H2SiF6 and metal salts. Addition of fluosilicates to cement endows odd properties through unique chemical reaction with the fresh and hardened cement. This study was performed to know mechanical properties and watertightness using fluosilicates based composite made from fluosilicates and other compounds. Mix proportions for experiments were modulated at 0.45 of water to cement ratio and $0.0-2.0\%$ of adding ratio of fluosilicates based composite. Evaluation for mechanical properties of concrete was conducted to know fresh state of concrete, hardening state of concrete, and watertightness. Evaluation for watertightness of concrete was carried out permeability, absorption test and porosity analysis. In addition. Scanning Electron Microscopy(SEM) and Energy Dispersive X-Ray(EDX) used for investigating micro-structure and atomic component distributed in hardened concrete. It is ascertained that characteristics of mechanical properties and watertightness was more improved than non-added because of packing role of fluosilicates based composite and pozzolanic reaction of soluble $SiO_2$. Also, concrete added fluosilicates based composite had a tendency to delay setting time and only $0.5\%$ addition of fluosilicates based composite delayed 150 minutes compared with non-added.