• Title/Summary/Keyword: 무기 바인더

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Development of Nontoxic Flame Retardant Paint (친환경 무독성 난연도료에 대한 연구)

  • Do, Young-Woong;Kwon, Myeon-Joo;Joo, Hyun-Ku;Yoon, Jae-Kyung;Ha, Jin-Wook
    • Proceedings of the KAIS Fall Conference
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    • 2008.05a
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    • pp.336-338
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    • 2008
  • 본 연구에서는 EU에서 발효되는 6대 규제유해물질(Pb, Hg, Cd, $C^{6+}$, PBB/PBDE)과 환경부 규제유해물질에 의해 도료의 유해조성물질을 제한하게 됨에 따라 VOC(휘발성유기화합물) 배출이 적고, 브롬계/할로겐계를 탈피하여 인체안전성 확보 및 환경오염을 최소화하며, 방염제 형식승인 및 검정기술기준 (KOFEIS 0201)에 부합하는 수용성 유 무기계 난연도료를 개발하였다. 친환경적인 난연도료 제조에 대한 최적조건으로 Mg(OH)$_2$, $Sb_2O_3$, 붕산아연을 1:2:2로 혼합한 난연제 그리고 바인더(마이셸 2%)와 물의 비율을 1:1로 제조한 후, 난연제:(바인더+물)을 1:1로 제조한 난연도료 3의 성능이 가장 우수하였다.

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Fluoride and nitrate removal in the decentralized water treatment plants by electroadsorption using carbon nano-tube electrodes (소규모 급수 시설의 불소 및 질산성질소 이온 제거를 위한 탄소나노튜브 전극을 활용한 전기흡착 연구)

  • Han, Song-Hee;Chang, In-Soung;Chae, Ki-Woong;Joung, Seun-Young;Lee, Cheol-Ku
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.6
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    • pp.2904-2912
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    • 2011
  • Water qualities in the decentralized water treatment plants do not frequently satisfy the water standard limit, in particular, fluoride and nitrate are notorious for the poor removal. In this study, an electro-adsorption equipped with carbon nonotube (CNT) electrodes were carried out to effectively remove the nitrate and fluoride in the decentralized water treatment plants. Two types of CNT electrodes, coating and sintering electrodes were applied. Coating electrodes were made based on different kinds of binder and sintering electrodes were made based on different sintering temperature. Removal of fluoride and nitrate when the coated electrodes with organic binder were used for electro-adsorption were 46 and 99.9% respectively, which were better performances than the coated electrodes with inorganic binder were used. On the other hand, removal of fluoride and nitrate when the electrodes sintered at higher temperature ($1,000^{\circ}C$) were 77 and 87% respectively, which were better performances than the electrodes sintered at lower temperature ($850^{\circ}C$). As a consequences, the electro-adsorption equipped with a CNT electrodes could be an potential alternative process for the removal of fluoride and nitrate in a decentralized water treatment plants if proper current density and contact time were applied.

A Study on Thermal Insulation Property and Thermal Crack Protection for Expanded Perlite Inorganic Composites (팽창진주암 무기복합재에서의 단열성능 및 열크랙 방지에 관한 연구)

  • Ahn, WonSool
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.5
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    • pp.3286-3291
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    • 2014
  • A study on the crack protection and thermal insulation properties of the expanded perlite inorganic composites was performed. Mixed expanded perlite with a water glass was stabilized for 24 hrs at room temperature in the mold and, thereafter, converted into a massive foamed body through complete drying process at $150^{\circ}C$. Aluminum phosphate and micron size mica powder were used as a reaction accelerator and a stabilizer for thermal crack, respectively. Especially, use of mica exhibited a remarkable effect on the protection of thermal crack at higher temperature over $500^{\circ}C$, and thermal conductivity of the composites was enhanced with higher perlite contents, showing ca. 0.09 W/mK for the sample of 100/200/10/1.5 water glass/perlite/mica/Al phosphate by weight. A severe dimensional deformation of the composite materials was observed over $600^{\circ}C$, however, showing a temperature limitation for a practical application. The facts were considered as the results from the glass transition temperature of the water glass, of which main component is sodium silicate.

Study on Heat-shield Property of Surface-treated Inorganic Oxide Particles (표면처리된 무기산화물 입자의 열차단 특성에 관한 연구)

  • Kim, Dong Ho;Kim, Gu Ni
    • Journal of Adhesion and Interface
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    • v.14 no.1
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    • pp.28-35
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    • 2013
  • In this study, we produced heat-shield coating materials using surface-treated Ga-doped ZnO (GZO) and investigated the dispersity of particle, visible light transmittance, ultraviolet light cut off, infrared light cut-off, heat-shielding property by surface-treating compounds and treatment conditions. In the case of using IPA or acryl binder for heat-shield coating, the dispersity of inorganic oxide particles was poor but in the case of using surface-treated inorganic oxide particles by hybrid compound having urethane (urea) group, acryl group and silica, dispersity of particle, visible light transmittance and haze were improved. We used the measurement kit and sunlamp for measuring heat-shielding property and confirmed that the internal temperature of the measurement kit using heat-shield film was lower more than $4.8^{\circ}C$ in comparison with using PET film for itself.

Fabrication and Properties of Ceramic Candle Filter for Filtration System of Coal Gasification (석탄가스화 정제시스템용 세라믹 캔들 필터 제조 및 특성)

  • Han, In-Sub;Seo, Doo-Won;Hong, Ki-Seog;Kim, Se-Young;Yu, Ji-Hang;Woo, Sang-Kuk
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.844-847
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    • 2009
  • 진공압출성형 공정을 이용하여 한쪽 끝단이 막힌 다공질 탄화규소 캔들 필터를 단일공정으로 제조하는 기술을 확립하였다. 캔들 필터 지지층의 특성 최적화를 위해 탄화규소 출발입자와 무기바인더의 첨가량 변화를 통해 기계적 특성과 기공크기 등의 분석을 수행하여 상용 캔들 필터의 수준에 대응할 수 있는 조합을 도출하였다. Mullite와 clay를 소결조제로 사용하고, $30{\mu}m$ 입도의 탄화규소 입자로 지지층을 제조한 경우, 30% 이상의 기공율을 보유하면서 50 MPa 이상의 상온 3점 굽힘강도를 나타낼 수 있는 조건이 확립됨에 따라 $125{\mu}m$ 입도의 탄화규소와 bi-modal로 사용할 경우, 상용제품의 특성을 상회하는 탄화규소 캔들 필터가 제조될 수 있음을 확인하였다.

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An experimental study for improvement in physical properties on the alumino-silicate binder for wood wool ceramic board (목모 세라믹 보드용 알루미노-실리케이트계 무기 바인더의 물리적 특성 향상에 관한 실험적 연구)

  • Park, Dong-Cheal;Yang, Wan-Hee;Choi, Hae-Young;Lee, Se-Hyun;Song, Tae-Hyup;Sim, Jong-Woo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.625-628
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    • 2006
  • It is known that cement production not only consumes large amount of energy but also contributes substantially to the green house gas emission. Therefore, there is a demand to develope a new technology to produce energy efficient and environmental conscious cements. The most recent, wood wool ceramic board is being applied in various building material field, for example thermal insulating and acoustic absorption material. This paper focused on improvement of alumino-silicate binder's physical properties for wood wool ceramic board. As the result of this experiment, what we could obtain best fitted alumino-silicate binder's properties such as initial setting time, flow and compressive strength of 3 days aged, was 58min, 110% and 66.0Mpa. This result can be applicable to commercial wood wool ceramic board.

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Fracture Toughness and Slinding Wear Properties of ABOw/AC4CH by Binder Additives (ABOw/AC4CH의 바인더 종류에 따른 파괴인성 및 미끄럼마모 특성)

  • Park, Won-Jo;Jung, Jae-Wook;Choi, Yong-Bum;Lee, Kwung-Young
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2002.10a
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    • pp.373-378
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    • 2002
  • Metal matrix composites have a great interest in recent years because high specific strength, high specific stiffness characteristics, and application ranges of the composites are extend to variety industry. In this paper, an investigation was performed on the plane strain fracture toughness and slinding wear properties of AC4CH alloy(Al-Si-Mg line) reinforced with 20wt% aluminum borate whisker expect one, which contained a inorganic binder($TiO_2$). the binder led to the formation of strengthen the whisker each other. The test of fracture toughness was using CT(half size) specimen of thickness 12.5mm, width 25mm. and test of slinding wear of using tribo a pin-on-disk machine and lubricant is used without paraffine 8.2CST at room temperature. As results, Fracture toughness $K_{IC}$ is $8.7MPa-m^{05}$ for ABOw/AC4CH, $9.28MPa-m^{05}$ for ABOw/AC4CH added $TiO_2$. but AC4CH alloy was violated the critical stipulated by ASTM standard for valid measurement of $K_{IC}$. In case of, it was performed $J_{IC}$ test instead of $K_{IC}$ based on ASTM E 1820.

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Optimization for Ammonia Decomposition over Ruthenium Alumina Catalyst Coated on Metallic Monolith Using Response Surface Methodology (반응표면분석법을 이용한 루테늄 알루미나 메탈모노리스 코팅촉매의 암모니아 분해 최적화)

  • Choi, Jae Hyung;Lee, Sung-Chan;Lee, Junhyeok;Kim, Gyeong-Min;Lim, Dong-Ha
    • Clean Technology
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    • v.28 no.3
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    • pp.218-226
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    • 2022
  • As a result of the recent social transformation towards a hydrogen economy and carbon-neutrality, the demands for hydrogen energy have been increasing rapidly worldwide. As such, eco-friendly hydrogen production technologies that do not produce carbon dioxide (CO2) emissions are being focused on. Among them, ammonia (NH3) is an economical hydrogen carrier that can easily produce hydrogen (H2). In this study, Ru/Al2O3 catalyst coated onmetallic monolith for hydrogen production from ammonia was prepared by a dip-coating method using a catalyst slurry mixture composed of Ru/Al2O3 catalyst, inorganic binder (alumina sol) and organic binder (methyl cellulose). At the optimized 1:1:0.1 weight ratio of catalyst/inorganic binder/organic binder, the amount of catalyst coated on the metallic monolith after one cycle coating was about 61.6 g L-1. The uniform thickness (about 42 ㎛) and crystal structure of the catalyst coated on the metallic monolith surface were confirmed through scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. Also, a numerical optimization regression equation for NH3 conversion according to the independent variables of reaction temperature (400-600 ℃) and gas hourly space velocity (1,000-5,000 h-1) was calculated by response surface methodology (RSM). This model indicated a determination coefficient (R2) of 0.991 and had statistically significant predictors. This regression model could contribute to the commercial process design of hydrogen production by ammonia decomposition.

Comparison of pigment in automotive solid color paints by FT-IR and XRF spectroscopy for forensic aspect (법과학적 관점에서 FT-IR과 XRF를 이용한 단색 페인트의 안료 비교)

  • Park, Ha-Sun;Kim, Ki-Wook;Heo, Sangcheol;Ryu, Seung-Jin;Lee, Hyunik;Min, Ji-Sook
    • Analytical Science and Technology
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    • v.26 no.4
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    • pp.245-255
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    • 2013
  • Identification of paint on victim's clothing and a vehicle are valuable for forensic examination when investigating hit-and-run accidents. Automotive paints on clothes are used to prove a victim caused by traffic accident and to identify a suspected vehicle. The comparison of transferred paints between victim's vehicle and suspected vehicle can be an important evidence in reconstructing the accident situation and in discovering the truth. The paints such as white, yellow, red, blue, or black are hard to examine particle shape under a stereomicroscope because of it is not included aluminum, pearl, and mica flakes in the pigments. The aim of this study under forensic aspect is to compare pigment among basecoat layers of solid paints by identifying inorganic elemental compositions and binder resins of pigments using by micro-FT-IR and micro-XRF spectrometer. The pigment samples were analyzed by using two methods of FT-IR: Reflectance and ATR method. Two methods of FT-IR were useful in discriminating binder resins of pigments by comparing characteristic peaks and patterns of spectra. Also, XRF spectrometer could identify the elemental compositions in inorganic pigments of trace paints which are difficult to compare the identification by FT-IR.

Preparation and Coating of Red Colored Artificial Pearl by CVD Method (CVD법을 이용한 적색 인조진주 코팅 및 제조)

  • Shin, Cheol-Woo;Choi, Kyoung-Rim;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.857-864
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    • 2018
  • Demand for developing artificial green pearl that meets the needs of modern people has been increasing. In this paper, eco-friendly inorganic pearlescent pigment was used instead of organic pigment and urethane resin was substituted for nitrocellulose which has been used as main materials in previous preparation method, increasing gloss from 73.4% to 86.7%. Urethane was coated on substrate before finishing with CVD, resulting high gloss of 96%. Colorimeteric analysis shows that a* and b* of CIE value was changed from +37.7 and +24.5 to +31.9 and +14.2 respectively because of CVD finishing, obtaining colorful, high gloss and durable artificial pearl. Quality and toxicity of samples was established by chemical resistance, glossiness, colorimeter, surface roughness, wear resistance, content of heavy-metal, and salt water test.