• Title/Summary/Keyword: 무기합성

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유/무기 하이브리드 기술을 이용한 서방형 가공제 합성 연구(2)

  • Park, Seong-Min;Gwon, Il-Jun;Kim, Sang-Uk;Mun, Du-Hwan;Yun, Nam-Sik
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.99-99
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    • 2011
  • 최근 건강에 대한 관심이 높아지면서 천연 기능물질을 이용한 고기능 및 고부가가치 상품개발이 여러 산업분야에서 일반화되는 추세이다. 대표적으로 마이크로캡슐은 원하는 기능을 발휘할 수 있는 기능성 물질을 다양한 방법으로 다양한 제품에 부여함으로써, 기능성 물질을 오랜 기간 동안 외부로 방출하거나 외부의 환경으로부터 보호하는 수단으로 각광받고 있다. 이러한 마이크로캡슐은 의약분야 제초제, 멸충제, 곰팡이 방지제, 살균제로 적용되는 농약분야, 식품 분야, 화장품 분야 등의 전반에 걸쳐 응용 및 연구가 활발히 이루어지고 있다. 이에 본 연구에서는 다양한 나노 합성기술과 유/무기 하이브리드를 이용해 서방화 관련 기술을 개발하여 보습성, 항균, 노화방지, 외부 유해물질로부터의 피부보호 특성을 가진 인체 친화형 복합기능성 섬유 가공조제를 개발하여 다양한 섬유소재에 적용하고자 하며, 궁극적으로 기존 선진국 제품의 기능을 뛰어넘는 원천기술, 즉 새로운 가공제 합성과 응용성, 그 성능평가와 동시에 최적의 처리기술을 개발함으로써 섬유제품의 부가가치를 높이는 계기를 마련하고자 한다. 본 연구에서는 나노미터 직경을 갖는 침상형의 주형(hydroxyapatite)을 이용하여 중공 나노구조체를 제조 한 후 이에 천연고분자를 혼합하여 초음파처리 후 유/무기 하이브리드 기술을 이용한 서방성 가공제를 합성하였다. 중공의 나노구조체 확인은 투과전자현미경(TEM)을 이용하였으며, 주형의 나노구조체는 주사전자현미경(FE-SEM)으로 확인하였다. 이상의 결과를 통해 본 연구에서 제안한 방법이 나노구조체의 새로운 합성방법으로써 가능성을 확인할 수 있었다.

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Synthesis of Cubic Cu2O from Organic-Inorganic Hybrid (유기-무기 혼성화합물로 부터 정육면체 Cu2O 합성)

  • Heo, Yeong-Deok;Song, Ha-Cheol;Guk, Won-Geun
    • Journal of the Korean Chemical Society
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    • v.50 no.1
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    • pp.60-64
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    • 2006
  • has been synthesized using the layered organic-inorganic hybrids, Cu2(OH)3(CH3COO)·H2O as a precursor. Cubic Cu2O is synthesized by reducing Cu2(OH)3(CH3COO)·H2O with glucose in water at 75oC. The effects of precursor and glucose are investigated. The structure of Cu2(OH)3(CH3COO)·H2O plays an important role in preparing the uniform size of Cu2O.

Changes in Amounts of Polysaccharides and Polyphosphates under Catabolic Repression and Derepression in Yeast (V) (Catabolic Repression 및 Derepression에 의한 효모 세포의 다당류 함량 변화와 무기 폴리 인산(제 5 보))

  • Lee, Ki-Sung;Choi, Yong-Keel
    • The Korean Journal of Mycology
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    • v.13 no.4
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    • pp.235-241
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    • 1985
  • The present study was designed to investigate biosynthetic patterns of polysaccharides under catabolic repression and derepression in Saccharomyces uvarum. Correlation coefficients between polysaccharide synthesis and polyphosphate accumulation were examined, according to the culture phase and under various phosphate concentrations (free, limited, sufficient). During catabolic derepression, biosynthesis of glycogen was enhanced. rapidly and highly in the cells grown on minimal medium, compared with those grown on the complete medium. Acid soluble glycogen type was the main component of total glycogen and alkali soluble glycogen was synthesized in small amount, after 24 hr culture, at the time of almost exhaustion of sugar in the medium. Total glycogen was accumulated highly in proportion to the amount of phosphate added to the medium. It could be postulated that type 'C' isoenzyme among ALPase was directly or indirectly correlated with the glucan synthesis. Mannan synthesis indicated maximal amount at the early exponential phase and stationary phase, and also acid soluble sugars at the stationary phase. Correlation coefficient between the mannan synthesis and poly-p-'C' accumulation, and also between mannan synthesis and phospholipid content indicated 0.866 and 0.726, respectively.

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Evaluation on the Performance of Nano Mixed Inorganic Repair Material for Crack Repair of Concrete Structures (콘크리트 구조물의 균열 보수를 위한 나노 합성 무기계 보수 재료의 성능 평가)

  • Kim, Jong-Pil;Jeon, Chan-Ki;Chung, Hoon;Kim, Hong-Seug
    • Journal of the Korean Society of Hazard Mitigation
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    • v.7 no.3
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    • pp.33-39
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    • 2007
  • This paper presents a detailed experimental study on the engineering and durability properties of nano mixed inorganic repair material with rehabilitation and enhancement of performance of concrete structure occur to crack. The performance of specimens was evaluated using bond strength, chloride ion ingress, carbonation and brine resistance. It was shown in the results of the experiments that it had a superior function in the bond strength under the standard and wet-dry condition of all the repair material. Moreover, it had a good function in the experiments for chloride ion ingress, carbonation and brine resistance. Judging from the above-mentioned results, it is expected to be used for the rehabilitation and enhancement of the performance of concrete structure.

Gas permeation properties of $SiO_2$ membranes formed by sol-gel and CVD techniques (솔-젤 및 화학증착법에 의하여 제조된 실리카막의 기체 투과 특성)

  • 남석우;이희준;하홍용;홍성안
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.04a
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    • pp.51-52
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    • 1996
  • 무기막을 기체 분리 및 분리막 반응기에 적용하려면 특정 기체에 대한 선택도 뿐만 아니라 절대 투과 속도 또한 높아야 한다. 박막 담지 무기막은 다공성 지지체를 사용하여 그위 또는 그 기공 내에 선택적 투과성을 지니는 막을 합성한 형태로서, 되도록 얇은 선택적 투과막을 지지체에 제조함으로써 투과도를 향상시킬 수 있다. 고온에서 수소에 투과성이 있는 실리카막의 경우 기공의 크기기 4nm 정도인 다공성 유리를 지지체로 하여 화학증착법으로 제조하는 연구가 많이 수행되어 왔으며 400$\circ$ 이상의 온도에서 막을 통한 수소의 투과도는 0.1 cm$^3$[STP]/min-atm-cm$^2$ 수준이었다. 본 연구에서는 실리카 담지 무기막의 수소 투과성 향상을 위하여 기공의 크기가 다공성 유리보다 큰 다공성 알루미나를 지지체로 사용하였으며, 이 지지체의 기공 내부에 솔-젤 및 화학증착법에 의하여 실리카 막을 합성하고 고온에서의 기체 투과 특성을 살펴보았다.

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Review of the Polycarbonate (Polycarbonate의 고찰)

  • Choi, Gei-Hun
    • Journal of Korean Ophthalmic Optics Society
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    • v.9 no.2
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    • pp.313-322
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    • 2004
  • Glasses are to be classified in organic glasses and inorganic glasses. Generally, we just call glasses instead of calling inorganic glasses and call synthetic resin or plastic instead of calling organic glasses. One of the ophthalmic plastic glasses develops into polycarbonate resin in organic glasses. Recently, polycarbonate resin is widely known because it has larger index and impact than plastic lens. Ours study analyzed about polycarbonate resin in ophthalmic substance.

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Biomineralization and Biomimetics from the Point of Mineral Processing (광물 합성 공정의 관점에서 본 생광물화과정 및 생체모방공학)

  • Lee, Seung-Woo;Jang, Young-Nam;Park, Seung-Bin
    • The Korean Journal of Malacology
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    • v.26 no.1
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    • pp.1-18
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    • 2010
  • Biological organisms produce organic-inorganic nanocomposite composites that are hierarchically organized in composition and microstructure, containing both inorganic and organic components in complicated mixtures. The process related to the generation and regeneration of organic-inorganic complex in nature is called biomineralization process. Understanding how the process operates in a biological environment is a valuable guide to the synthesis of novel advanced material and developing important industrial processes. Like the mechanism of organisms, mollusks were also synthesized from interaction between organic matrices and minerals and their morphology was designed through biomineralization. In this study, shell formation has been studied as a bio-model and the application of biomimetics based on biomineralization is focused.

Effect of Bi and Zr addition on yellow colour properties of environment-friendly ceria-based pigments (비스무스와 지르코늄 첨가를 통한 세리아계 친환경 노란색 안료 특성에 관한 연구)

  • Kim, Tae-Ho;Hwang, Hae-Jin;Kim, Jin-Ho;Hwang, Kwang-Taek;Han, Kyu-Sung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.4
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    • pp.153-159
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    • 2015
  • Inorganic pigments have been received a great attention for various applications including paint, glazed ceramic ink, art tile, and building exterior due to their excellent thermal and chemical stability. Traditionally, the compositions of $PbCrO_4$, CdS and CdSe have been widely used as a yellow inorganic pigment. However, the use of these compositions has been restricted in recent years, because they contain harmful elements such as Cd, Cr, Pb and Se. In this study, new environment-friendly ceria-based pigment was synthesized using solid state reaction. Crystal structure and morphology of the obtained $Ce_{1-x}Zr_xBi_yO_{2-y/2}$ yellow pigment were analyzed using XRD and SEM, respectively. Substitutional effect of Zr and Bi on the pigment color was analyzed using UV-vis. spectrophotometer and CIE $L^*a^*b^*$ analysis. The crystal structure of the obtained pigments was dependent on the calcination temperature. The color characteristics and absorption band of the pigments were dependent on the calcination temperature and Zr, Bi contents. As a result, all the obtained yellow pigments showed the effective absorption ranged from ultraviolet to visible light, and $Ce_{0.44}Zr_{0.36}Bi_{0.20}O_{0.19}$ (x = 0.36, y = 0.20) pigment showed the most brilliant yellow color.